BOYS/ GIRLS CAMPUS RAWALPINDI

CHANDANI CHOWK

Reg 1st Year Chemistry R& T Session/Test # FLP-3

Time: 3 hours Marks: 85 Dated: 10th May, 2017
Name: ___________________Class/Section: ________________ Roll#:_____________
Qno.1 Choose the correct statement: - (15)
1. Haemoglobin is heavier than a hydrogen atom
a) 65,000 (b) 68,000 (c) 62,000 (d) 60,000
2. 27 grams of Al will react completely with how much mass of O2 to produce Al2O3
a) 8 gm. of oxygen (b) 16 gm. of oxygen (c) 32 gm. of oxygen (d) 24 gm. of oxygen
3. Solvent extraction is an equilibrium process and it is controlled by
a) law of mass action (b) the amount of solvent used (c) distribution law (d) the amount of solute
4. Equal volumes of H2 and He are inserted in the same vessel. The pressure exerted by H2 and He are in the
ratio:
a) 1:1 (b) 2:1 (c) 1:2 (d) all above
5. Most ideal gas at room temperature is:
(a) CO2 (b) NH3 (c) SO2 (d) N2
o
6. Water may boil at 120 C when external pressure is
(a) 760 torr (b) 100 torr (c) 1489 torr (d) 700 torr
7. Certain solids melt to a turbid liquid phase with properties of liquids as well as some degree of order like
solid. Such turbid liquids are called
(a) amorphous solid (b) vitreous solid (c) crystalline solid (d) liquid crystal
8. When the 6d orbital is complete the entering electron goes into
(a) 7f (b) 7s (c) 7p (d) 7d
9. The colour of the glow produced in the discharge tube depends upon
(a) gas (b) electrodes (c) composition of gas (d) pressure
10. Which of the following ions has larger ionic radius?
(a) Na+ (b) K+ (c) Mg2+ (d) Al3+
11. During the formation of chemical bond, the potential energy of the system
(a) Decreases (b) increases (c) does not change (d) none of these
12. The condition for standard enthalpy change is
(a) 1 atm 30oC (b) 1 atm 0oC (c) 1 atm 25oC (d) 760 atm 25oC
13. The PH of 10–3 mole dm–3 of an aqueous solution of H2SO4 is
(a) 3.0 (b) 2.7 (c) 2.0 (d) 1.5
14. The precipitation occurs if the ionic product is
(a) less than Ksp (b) more than Ksp (c) equal to Ksp (d) is present at any moment
15. 1 kg of sea water contains 4.96 x 10–3gm. of dissolved oxygen. The concentration of oxygen in sea water in
ppm is
(a) 4.96 x 10–2 (b) 0.496 (c) 4.96 (d) 49.6
16. In lead accumulator the electrolyte H2SO4 solution is
(a) 30 % (b) 60% H2SO4 (c) 80% (d) 90%
17. Tetra ethyl lead when added to petrol, acts as
(a) Negative catalyst (b) auto catalyst (c) promoter (d) catalyst

BOYS/ GIRLS CAMPUS RAWALPINDI

CHANDANI CHOWK
Reg 1st Year Chemistry R& T Session/Test # FLP-3
Time: 3 hours Marks: 85 Dated: 10th May, 2017
SECTION II 8 × 2= 16

Q NO 2 Attempt any eight short answer questions

1. What is the justification of two strong peaks in the mass spectrum for the bromine, while for iodine only one peak at
127amu is indicated?
2. Why is an experimental work, one or more reactant is /are deliberated used in excess quantity?
3. Write down uses of chromatography
4. Drive the unit for gas constant R in general gas equation when the pressure is in Nm-2 and volume in m3.
5. State the laws of thermo chemistry and shows how are they based on the first law of thermodynamics
6. How does the change of pressure shift the equilibrium position in the synthesis of ammonia?
7. State lechatiler’s principal. What is the effect of change in pressure on the following reaction?
N2 + 3H2⇌ 2NH3
8. Convert -80oC into Fahrenheit
9. A straight line in PV vs P graph goes away from the pressure axis at higher pressure for many gasses.
10. Define mole fraction and give its mathematical form.
11. How will you explain that the value of the constant K in the equation PV=K depends upon the quantity of gas?
12. What is the basic principal of crystallization?

Q No 3 Attempt any eight questions. 8 × 2= 16

1. The radius of an atom cannot be determined precisely give reason

2. State Pauli’s exclusion principal with example
3. Justify the transition temperature is shown by elements having allotropic forms and by compound showing
polymorphism.
4. Sketch a model to justify that unit cell of NaCl has four formula unit in it
5. The e/m values for positive rays are different for different gases, but that of cathode rays obtain from different gases is
the same. Give reasons.
6. Why the lone pair electrons repel strongly than the bond pair of electron?
7. The dipole moment of CO2 and CS2 is zero , but that of SO2 is 1.61D give reason
8. What is the origin of emission of X-rays?
9. Give basic assumptions of VSEPR theory
10. Define crystallographic elements.
11. Zn can displace hydrogen from acids but Cu cannot do so. Why?
12. How do you justify that the greater quantity of CH3COONa in acetic acid decreases the dissociating power of acetic acid
and so the pH increases?

Q NO 4 Attempt any six questions 6 × 2 = 12

1. Under what conditions activated complex is formed.

2. What is auto catalysis give an example?
3. What are colligative properties and why they are called so .
4. How you justify that the boiling point of the one molal urea solution is 100.52oC but the boiling point of two molal urea
solution is less than 101.04oC.
5. Explain with reason a salt bridge maintains the electrical neutrality in the cell
6. What is different between single electrode potential and standard electrode potential? how can it be measured ?
7. What is emf of cell? how it measures
8. Calculate the molarity of glucose solution when 9g of it is dissolved in 250cm3 of solution
9. Prove Ka∝1/Kb

SECTION III

Attempt any three questions 8 × 3= 24

Q No 5 (a) The combustion analysis of an organic compound shows it to contain 65.44% carbon, 5.50% hydrogen and 29.06%
oxygen. What is the empirical formula of the compound if the molecular mass of this compound is 110.15gmol -1? Calculate the
molecular formula of the compound.
(b)What are the metallic solids give its properties?
Q No 6 (a) Writes down applications of Dalton’s law of partial pressure
b) What are the positive rays . Give its properties.
Q No 7 (a) Explain geometries of the following by hybridization (a) BF3 (b) NH3
b) Describe bomb calorimeter method for determine enthalpy of reaction
Q No 8 (a) Benzoic acid CH6C5OOH , is weak mono-basic acid (Ka = 6.4 × 10 -5 mol dm-3 ) . What is the pH of the solution
contacting 7.2 g of sodium benzoate in dm3 of 0.02 mole dm-3 benzoic acid?
b) Describe the four physical methods to determine the rate of reaction.
Q No 9 (a) Describe Beckmann’s method for the measurement of depression in freezing point.
(b)Explain the construction and working of galvanic cell.