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U04730W

The document provides safety information for ACROLON 7300 BLANCO paint. It identifies the product and supplier, lists hazards like flammability and skin irritation, and provides guidance on first aid and firefighting. The product contains chemicals like n-butyl acetate and xylene and can cause mild skin and eye irritation upon contact.

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francisca ferrer
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0% found this document useful (0 votes)
23 views11 pages

U04730W

The document provides safety information for ACROLON 7300 BLANCO paint. It identifies the product and supplier, lists hazards like flammability and skin irritation, and provides guidance on first aid and firefighting. The product contains chemicals like n-butyl acetate and xylene and can cause mild skin and eye irritation upon contact.

Uploaded by

francisca ferrer
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 11

ACROLON 7300 BLANCO

SAFETY DATA SHEET


Date of revision : 09, Oct, 2022. Page : 1/11
Version : 1.01

Elaborated according to NCh2245

Section 1. Identification of the hazardous chemical and of the


supplier
GHS product identifier : ACROLON 7300 BLANCO
U04730T910035 / U04730W22NR35 / U04730W22BL35
Identified uses
Paint or paint related material.
Uses advised against
Any use not described in the Safety Data Sheet is discouraged.

Supplier name : Sherwin Williams Chile S.A.


Supplier address : Avenida La Divisa 0689, Comuna San Bernardo
Supplier telephone number : 600 200 1222

Emergency telephone : En caso de emergencia química, derrame o incendio llame al CITUC Químico,
number Centro de Información para Emergencias Químicas del Hospital Clínico de la
Pontificia Universidad Católica Chile, teléfono 56 - 22 - 247 3600.

Toxicological information : En caso de intoxicación o ingesta accidental llame al CITUC, Centro de Información
phone number in Chile Toxicológica de la Facultad de Medicina de la Pontificia Universidad Católica,
teléfono 22 635 38 00.

Supplier Website : www.sherwin.cl

Section 2. Hazard(s) identification


Classification according to : Class 3: Flammable liquid. , UN1263 , III , PAINT
NCh382
Pictogram according to :
NCh2190

Classification according to : FLAMMABLE LIQUIDS - Category 3


GHS SKIN IRRITATION - Category 3
GHS Label :

Warning
Flammable liquid and vapor.
Causes mild skin irritation.
Wear protective gloves, protective clothing, eye protection, face protection, or
hearing protection. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking.
IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water. If skin irritation occurs: Get medical advice or attention.
Dispose of contents and container in accordance with all local, regional, national
and international regulations.
NFPA pictogram :
according to NCh1411/4
ACROLON 7300 BLANCO

Date of revision : 09, Oct, Página : 2/11


2022.
Version : 1.01

Section 2. Hazard(s) identification

3
4 4

Specific classification : Not applicable.


Specific pictogram : Not applicable.
Hazard statements : Flammable liquid and vapor.
Causes mild skin irritation.
Specific hazard : Not available.
statements
Other hazards : None known.

Section 3. Composition/ components information


Substance/mixture : Mixture

Ingredient name % CAS number


Barium Sulfate ≥25 - ≤50 7727-43-7
Titanium Dioxide ≥10 - ≤25 13463-67-7
n-Butyl Acetate ≤10 123-86-4
Xylene, mixed isomers ≤8.4 1330-20-7
2-methoxy-1-methylethyl acetate ≤2.9 108-65-6
Light Aromatic Hydrocarbons <2.5 64742-95-6
Phosphoric Acid Ester ≤1.5 -
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing.
If not breathing, if breathing is irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by trained personnel. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Get medical attention if
adverse health effects persist or are severe. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention if adverse
health effects persist or are severe. Wash clothing before reuse. Clean shoes
thoroughly before reuse.
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. If irritation persists, get medical attention.
ACROLON 7300 BLANCO

Date of revision : 09, Oct, Página : 3/11


2022.
Version : 1.01

Section 4. First aid measures


Ingestion : Wash out mouth with water. Remove dentures if any. If material has been
swallowed and the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not
induce vomiting unless directed to do so by medical personnel. If vomiting occurs,
the head should be kept low so that vomit does not enter the lungs. Get medical
attention if adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen tight clothing such
as a collar, tie, belt or waistband.

Potential acute health effects: No known significant effects or critical hazards.


No known significant effects or critical hazards.
Causes mild skin irritation.
No known significant effects or critical hazards.
Delayed effects expected : Not available.
Most important symptoms/effects
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
See toxicological information (Section 11)

Section 5. Firefighting measures


Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Hazardous thermal : Decomposition products may include the following materials:


decomposition products carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides
Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard.
from the chemical In a fire or if heated, a pressure increase will occur and the container may burst, with
the risk of a subsequent explosion.

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
ACROLON 7300 BLANCO

Date of revision : 09, Oct, Página : 4/11


2022.
Version : 1.01

Section 5. Firefighting measures


Special protective : Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Measures to be taken in case of accidental spillage


Personal precautions : No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
Protective equipment entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist.
Emergency procedures Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
If specialized clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains and sewers. Inform the relevant authorities if the product has caused
environmental pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
Recovery explosion-proof equipment. Dilute with water and mop up if water-soluble.
Neutralization Alternatively, or if water-insoluble, absorb with an inert dry material and place in an
Final disposition appropriate waste disposal container. Dispose of via a licensed waste disposal
contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
Recovery explosion-proof equipment. Approach release from upwind. Prevent entry into
Neutralization sewers, water courses, basements or confined areas. Wash spillages into an
Final disposition effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Dispose of via a licensed waste disposal contractor. Contaminated absorbent
material may pose the same hazard as the spilled product. Note: see Section 1 for
emergency contact information and Section 13 for waste disposal.
Additional accident : Evacuate the danger area. Maintain proper ventilation and operate according to
prevention measures established emergency procedures. Do not dispose of waste in drains or waterways.

Section 7. Handling and storage


Handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not ingest.
Advice on general Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only
occupational hygiene with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from
heat, sparks, open flame or any other ignition source. Use explosion-proof electrical
(ventilating, lighting and material handling) equipment. Use only non-sparking tools.
Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before
eating, drinking and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8 for additional
information on hygiene measures.
ACROLON 7300 BLANCO

Date of revision : 09, Oct, Página : 5/11


2022.
Version : 1.01

Section 7. Handling and storage


Storage
Conditions for safe : Store in accordance with local regulations. Store in a segregated and approved
storage, including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabeled containers. Use appropriate containment to avoid environmental
contamination. See Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection


Occupational exposure limits
Values indicated as "Ministry of HEALTH: TWA / STEL" correspond to LPP / LPT values according to national
regulations DS 594
Ingredient name Exposure limits
Barium Sulfate Ministry of Health (Chile, 2/2018).
TWA: 8.8 mg/m³ 8 hours. Form: Total dust containing no asbestos
and less than 1% free silica
Titanium Dioxide ACGIH TLV (United States, 1/2021).
TWA: 10 mg/m³ 8 hours.
n-Butyl Acetate Ministry of Health (Chile, 2/2018).
TWA: 624 mg/m³ 8 hours.
TWA: 131 ppm 8 hours.
STEL: 200 ppm 15 minutes.
STEL: 950 mg/m³ 15 minutes.
Xylene, mixed isomers Ministry of Health (Chile, 2/2018). []
TWA: 380 mg/m³ 8 hours.
TWA: 87 ppm 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risks, as required by other health and safety legislation. The provisions of the national health and
safety at work regulations apply to the use of this product at work.
Individual protection measures
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.
If personal exposure cannot be controlled below applicable limits by ventilation, wear
a properly fitted organic vapor/particulate respirator.
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. Considering the parameters specified by the glove manufacturer,
check during use that the gloves are still retaining their protective properties. It
should be noted that the time to breakthrough for any glove material may be
different for different glove manufacturers. In the case of mixtures, consisting of
several substances, the protection time of the gloves cannot be accurately
estimated.
Recommended gloves: Nitrile gloves
ACROLON 7300 BLANCO

Date of revision : 09, Oct, Página : 6/11


2022.
Version : 1.01

Section 8. Exposure controls/personal protection


Eye protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Body and skin protection : Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product. When there is a risk of ignition from static electricity,
wear anti-static protective clothing. For the greatest protection from static
discharges, clothing should include anti-static overalls, boots and gloves.
Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved and should be
approved by a specialist before handling this product.
Nota(s): Closed shoes are recommended for protection.
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Engineering measures : Not available.

Section 9. Physical and chemical properties


Physical state : Liquid.
Physical state : Liquid.
Color : Various
Odor : Characteristic.
pH : Not applicable.
Melting point : Not available.
Boiling point : 124°C (255.2°F)
Flash point : Closed cup: 35°C (95°F)
Lowerand upper explosive : Lower: 0.7%
(flammable) limits Upper: 13.1%
Vapor pressure : 1.3 kPa (10 mm Hg)
Vapor density : Not available.
Density : 1.662995451 g/cm³
Solubility : Not available.
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Odor threshold : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Viscosity : Kinematic (40°C (104°F)): >20.5 mm2/s (>20.5 cSt)
ACROLON 7300 BLANCO

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2022.
Version : 1.01

Section 10. Stability and reactivity


Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials:


oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information


Acute toxicity (LD50 y LC50)
n-Butyl Acetate LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 10768 mg/kg -
Xylene, mixed isomers LC50 Inhalation Gas. Rat 6700 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
2-methoxy-1-methylethyl LD50 Dermal Rabbit >5 g/kg -
acetate
LD50 Oral Rat 8532 mg/kg -
Light Aromatic Hydrocarbons LD50 Oral Rat 8400 mg/kg -
Irritation/Corrosion
Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 -
ug I
n-Butyl Acetate Eyes - Moderate irritant Rabbit - 100 mg -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 -
mg
Skin - Mild irritant Rat - 8 hours 60 uL -
Skin - Moderate irritant Rabbit - 100 % -
Skin - Moderate irritant Rabbit - 24 hours 500 -
mg
Light Aromatic Hydrocarbons Eyes - Mild irritant Rabbit - 24 hours 100 -
uL
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Specific target organ toxicity (single exposure)
ACROLON 7300 BLANCO

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2022.
Version : 1.01

Section 11. Toxicological information


n-Butyl Acetate Category 3 - Narcotic effects
Xylene, mixed isomers Category 3 - Respiratory tract
irritation
2-methoxy-1-methylethyl acetate Category 3 - Narcotic effects
Light Aromatic Hydrocarbons Category 3 - Respiratory tract
irritation
Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Xylene, mixed isomers Category 2 - -
Aspiration hazard
Xylene, mixed isomers ASPIRATION HAZARD - Category 1
Light Aromatic Hydrocarbons ASPIRATION HAZARD - Category 1
Toxicokinetics : Not available.
Metabolism : Not available.
Distribution : Not available.
Pathogenicity and acute : Not available.
infectivity (oral, dermal
and inhalation)
Endocrine disruption : Not available.
Neurotoxicity : Not available.
Immunotoxicity
"Related symptoms" : Not available.

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
Barium Sulfate Acute EC50 634 mg/l Fresh water Crustaceans - Cypris 48 hours
subglobosa
Acute EC50 32 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Titanium Dioxide Acute LC50 >1000000 µg/l Marine Fish - Fundulus heteroclitus 96 hours
water
n-Butyl Acetate Acute LC50 32 mg/l Marine water Crustaceans - Artemia salina 48 hours
Acute LC50 18000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Xylene, mixed isomers Acute LC50 8500 µg/l Marine water Crustaceans - Palaemonetes 48 hours
pugio
Acute LC50 13400 µg/l Fresh water Fish - Pimephales promelas 96 hours

Persistence/degradability
Product/ingredient name Aquatic half-life Photolysis Biodegradability
n-Butyl Acetate - - Readily
Xylene, mixed isomers - - Readily
Light Aromatic Hydrocarbons - - Readily

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Xylene, mixed isomers - 8.1 to 25.9 low
Light Aromatic Hydrocarbons - 10 to 2500 high
ACROLON 7300 BLANCO

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2022.
Version : 1.01

Section 12. Ecological information


Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible. This material and its
container must be disposed of in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or rinsed out. Empty containers or
liners may retain some product residues. Vapor from product residues may create a
highly flammable or explosive atmosphere inside the container. Do not cut, weld or
grind used containers unless they have been cleaned thoroughly internally. Avoid
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.

Section 14. Transport information


Modality of transport
Overland Maritime Air
Regulations Chile (NCh2190.Of2003) IMDG IATA
UN number UN1263 UN1263 UN1263

UN proper PAINT PAINT PAINT


shipping name
Transport hazard 3 3 3
class(es)

Packing group/ III III III


container
Environmental No. No. No.
hazards
Additional - -
information

Transport in bulk according : Not available.


to MARPOL 73/78, Annex II,
and with IBC Code
ACROLON 7300 BLANCO

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2022.
Version : 1.01

Section 15. Regulatory information


National regulations : DS 43: Reglamento de Almacenamiento de Sustancias Peligrosas.
DS 148: Reglamento Sanitario sobre el Manejo de Residuos Peligrosos.
DS 298: Reglamenta el Transporte de Cargas Peligrosas por Calles y Caminos.
DS 594: Reglamento sobre Condiciones Sanitarias y Ambientales básicas en los
lugares de trabajo.
NCh 382: Clasificación de Sustancias Peligrosas.
NCh 2190: Transporte de Sustancias Peligrosas; Distintivos de Seguridad.
NCh2245: Safety data sheet for chemical product-content and order of the sections.
DS No. 40: Regulation on the prevention of occupational risks.
NCh1411 / 4: Risk prevention - Part 4: identification of material risks.

International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
The receiver should verify the possible existence of local regulations applicable to the chemical

Section 16. Other information


History
Indicates information that has changed from previously issued version.
Date of issue/Date of : 09, Oct, 2022. Next revision - 3 years from this date
revision
Date of previous issue : 09, Sep, 2022.
Version : 1.01
Version of the Product : 009 00
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships,
1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
ACROLON 7300 BLANCO

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2022.
Version : 1.01

Section 16. Other information


LC50: Lethal Concentration
DL50: Lethal Dose
CE50: Effective Concentration
NOEC: No Observed Effect Concentration
LPP: Weighted allowable limit
LPT: Temporary permissible limit
TWA: Time Weighted Average
CAS: Chemical Abstracts Service
References : Not available.
Notice to reader
It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and
consult resources, as necessary or appropriate, to become aware of and understand the data contained in
this SDS and any hazards associated with the product. This information is provided in good faith and
believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given.
The information presented here applies only to the product as shipped. The addition of any material can
change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or
tinted except as specifically instructed by Sherwin-Williams, including but not limited to the incorporation of
non Sherwin-Williams products or the use or addition of products in proportions not specified by Sherwin-
Williams. Regulatory requirements are subject to change and may differ between various locations and
jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country,
federal, state, provincial or local laws. The conditions for use of the product are not under the control of the
manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use
of this product. The customer/buyer/user should not use the product for any purpose other than the purpose
shown in the applicable section of this SDS without first referring to the supplier and obtaining written
handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS,
the manufacturer cannot be responsible for SDSs obtained from any other source.

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