CHEMISTRY

PH: V PET -4

PATTERN: ADV GLORIFIRE

SCQ (6)
19.

CH3O H2 C CH CH2Cl X.
O
Then X is

(A) CH3O CH2 HC CH2 (B) H2 C CH CH2O CH3

O O
H2C CH2 CH2 Cl H2C CH 2 CH2 OH
(C) (D)
OCH 3 OCH 3
19. A
20. OH
Ph

H2 SO4

 product is
OH
Ph
OH O

(A) (B)
Ph
Ph
Ph Ph
O Ph
OH
(C) (D)
Ph
Ph Ph

20 B
21. Which of the following alcohols will not give iodoform test?
OH
(A) (B) CH3 CH2 OH
Ph

OH OH
Ph
(C) (D)

21. C
22. CH3 CH3
?
 OH
O

Missing reagents to complete the reaction are

(A) i) O3 , H2O, ii) Zn

(B) i) cold dil. KMnO4 , ii) K 2Cr2O7 ; H2SO4

(C) i) BH3 , THF; H2 O 2 , OH, ii) KMnO 4 , H2 SO 4

(D) i) OsO4 ; NaHSO3 .H2O, ii) HIO 4

22. B
23. The most stable gem diol among the following is
OH OH

(A) CH3 C OH (B) CH3 C OH

H CH3
OH OH

(C) CF3 C OH (D) Cl 3C C OH

H CH3

23. C
23. In which of the following reactions, reactant and products are incorrectly matched?

Cl O
H2 O2
(A) + BH3 - THF
NaOH

Cl O
H2 O NaBH4 NaOH
(B) + Hg(OAc) 2

O
+ mCPBA
(C)

(D) PhBr  CH 3 3 CONa  PhOC CH 3 3

23. D
 MCQ(6)

25. Reagents used to distinguish (CH3)3C– OH and CH3(CH2)3OH in victor mayor test are
(A) HCl (B) P / l2 (C) AgNO2 (D) NaOH
25. BCD
26. Which of the following reactions produces primary alcohol as the final higher product.

H3 O
(A) CH3 – CH2 Mg Br + CH3CHO  
(B) CH3 – CH(CH3) – CH3 + Br2  
h aq.NaOH


(C) CH3-CH2 – C(CH3)=CH2 + BH3 
 
H2 O2 / OH

H3 O
(D) (CH3)2 – CH – Mg Br + HCHO 
 

27. CD
 O
16 
H3 O17

28. H3C C O C2H5  PRODUCTS are

O O
16 17 17 16
(A) (B) C2H 5OH (C) (D) C2H5OH
H3C C OH H3C C OH

27. CD
28. Which of the following reaction(s) is/are correct?
LiAlH 4 OH
OMe MeOH
+ Me
(A) Me H3 O
O
NaBH4 OH
OEt EtOH
+ Me
(B) Me H3 O
O
Ni, H 2 OH
OMe + MeOH
Me
(C) Me

O
LiAlH 4 OH
OEt EtOH
+ Et
(D) Et H3 O
O
28. ACD
29. What are the reaction conditions used for the formation of ethylene glycol from ethylene?
(A) bromine water (B) cold alkaline KMnO4 (dil)
(C) OsO4 / H 3O  (D) RCOOOH, H3O
+

29. B,C,D
30 Iso-butene is converted into ter-butyl alcohol by
+ –
(A) H2O / H (B) BH3, THF / H2O2, OH
–
(C) Conc. H2SO4 / H2O (D) (i) Hg(OAc)2/ THF/ H2O (ii) NaBH4/OH
30. A,C,D
PARA

PASSAGE
An organic compound (A) having the molecular formula C 7H8O is soluble in aqueous NaOH. When ‘A’ is treated with bromine
water the compound (B) is formed with molecular formula C7H6OBr2. Then the compound ‘A’ treated with alkaline KMnO4
followed by acidification gives a steam volatile compound (C) having the molecular formula C 7H6O3.

31. Identify the compound C.

OH
OH OCH3
OCH3
COOH
(A) (B) (C) COOH (D)

COOH
COOH

31. B
32. Identify the compound B.

OH OH
Br CH3 Br
(A) (B)

CH3
Br Br
OH OH

Br CH3 Br
(C) (D)

Br Br CH3

32. A
33. Identify the compound ‘A’.

OH
OH OH
OCH3

(A) CH3 (B) (C) (D) COOH

CH3
CH3

33. A
PARA NUMERICAL

Periodate oxidation is a classic reaction in chemistry used to split bonds between vicinal carbons bearing
unsubstituted hydroxyl, amino groups & carbonyl compounds

34. The number of moles of HIO4 required to complete periodic oxidation of glucose.

34. 5
35. The number of compounds oxidised by NaIO4
(a) H2C OH (b) H2C OH (c) CHO (d) H2C OH
(e) COOH
CH2 (CH-OH)4 H2 C OH C O
H 2C OH
H 2C OH H2 C OH CHO H 2C OH

35. 4
36. The number of moles of carbon dioxide released when complete periodic oxidation of 1 mole of glycerol.
36. 0