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    Ua+ Chem 23Q Geo Isomerism - Mka

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    Ua+ Chem 23Q Geo Isomerism - Mka

    Uploaded by

    prachisingla579
    5 views3 pages

    Original Title

    UA+ CHEM 23Q GEO ISOMERISM_MKA

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    5 views3 pages

    Ua+ Chem 23Q Geo Isomerism - Mka

    Uploaded by

    prachisingla579

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 3

     V= lR

    2
    a+b =c
    2 2
    y

    BATCH: DROPPER ELP NO.: 23Q OC TOPIC: GEOMETRICAL ISOMERISM

    1. Geometrical isomers are different in:


    (a) molecular formula (b) structural formula
    (c) stereochemical formula (d) emperical formula
    2. Which of the following compound show geometrical isomerism :
    (a) CH2==CH2 (b) CH3—CH==CH2 (c) CH3—C C—CH 3
    (d) CH3—CH==CH—CH3
    3. In which of the following compound geometrical isomerism is not possible :

    (a) (b) (c) CH3—CH==NH (d)

    4. Geometrical isomerism is not possible in :

    (a) (b) (c) (d)

    5. Cycloalkene having geometrical isomer is :

    (a) (b) (c) (d)

    6. Which of the following compound does not show stereoisomerism :

    (a) (b) (c) (d)

    7. Which of the following can show geometrical isomerism :

    (a) (b) (c) (d)

    8. Which of the following carbonyl compound give geometrical isomers as product after reaction with
    NH2OH?

    (a) (b) (c) (d)

    9. Which one of the following can exhibit cis-trans isomerism :

    (a) H—C C—H (b) ClCH==CHCl (c) (d) ClCH2—CH2Cl

    10. Which of the following has geometrical isomer:

    (a) (b) (c) (d) All of these

    9
    11. Cis isomer is -

    (a) (b) (c) (d)

    12. Which of the following is trans-isomer

    (a) (b) (c) (d)

    13. Syn-oxime is:

    (a) (b) (c) (d)

    14. Anti-oxyme is:

    (a) (b) (c) (d)

    15. Which of the following group has least priority according to CIP rule?
    (a) —F (b) —OH (c) —NH2 (d) —CH==CH2
    16. Which of the following has Z configuration?

    (a) (b) (c) (d)

    17. Which of the following group has highest priority according to CIP rule?
    (a) —CH3 (b) —CH2CH3 (c) —CH(CH3)2 (d) —C(CH3)3
    18. Which of the following has E configuration?

    (a) (b) (c) (d)

    19. Geometrical Isomerism is not possible in:

    (a) (b) (c) (d)

    20. Which has zero dipole moment?

    (a) (b) (c) (d)

    21. Which order is correct for given pair of isomers ?

    (I) (II)

    (a) I > II (Dipole moment) (b) I > II (Boiling point) (c) I >II (Solubility) (d) II > I
    (Stability)
    22. How many stereocenters are present in given species?
    ••
    CH2==CH—CH==CH—CH==NH (a) 1 (b) 2 (c) 3 (d) 4
    a

    C
    23. In given species group a is present : d b
    c
    (a) Above the plane (b) Below the plane (c) With in the plane (d) Can't be predicted

    10
    24. How many chiral atoms are present in given species?

    (a) 2 (b) 4 (c) 3 (d) 5

    25. How many chiral atoms are present in given species?

    (a) 1 (b) 2 (c) 3 (d) 4

    26. Which of the following molecule has 2 chiral carbon atoms :

    (a) (b) (c) (d)

    27. Number of chiral centres in given molecule are :

    (a) 6 (b) 7 (c) 8 (d) 9

    28. Correct fischer projection formula of given compound is :


    COOH
    COOH COOH CH3 OH
    C
    (a) HO H (b) H OH (c) H OH (d) H COOH
    H CH 3
    OH CH 3 CH3 COOH CH3
    29. Convert the given Newman projection formula in to fischer projection formula :
    CH3
    Br H CH3 CH3 CH3 CH 3
    Br H H Br H Br
    H Br (a) H Br (b) H Br (c) Br H (d) H 3C H
    Br H
    CH3 CH3 CH3 CH3 Br
    30. Convet the given fischer projection formula in to wedge dash formula :
    COOH CH 3 COOH OH
    COOH
    F OH C C C C
    (a) (b) (c) (d) F
    F CH F COOH HO CH HOOC
    CH 3 3 3
    H 3C
    OH OH F
    31. Correct fischer projection formula of given species is :
    H
    H 3C OH CH3 CH3 CH3 CH3
    H OH H OH HO H
    (a) HO H (b) H OH (c) HO CH3 (d)
    H OH
    H H
    H 3C H CH3 CH3 OH CH3
    OH
    32. Which of the following is chiral :
    (a) Hand (b) Fan (c) Table (d) Chair
    33 Which of the following compound is chiral :

    (a) CH3—CH2—OH (b) CH3—CH2—CH2—CH2—OH (c) (d)

    11

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