Chemistry Set II
Chemistry Set II
A) MgO B) BaO
Attempt all questions
C) P2O5 D) ZnO
Group-A 8. IUPAC name of CH2=CH-CH2-CH2-OH is
A) Butenol B) But-3-en-1-ol
Choose the best alternative [11x1=11]
C) But-1-en-4-ol D) 4-Hydroxy but-1-ene
1. Which of the following doesn’t exist in liquid state? 9. Propene on treating with HBr in presence of organic
a. Hg b) Ga peroxide gives
c) Br d)Na A) 1-Bromopropane B) 2-Bromopropane
2. Magnetic quantum number specifies C) 1,2-Dibromopropane D) 2,2-Dibromopropane
A) Orbital shape B) orbital size
10. Which property is not common in organic compounds?
C) Nuclear stability D)orbital orientation
3. The compound that contains both ionic and covalent bond a. Low melting point b. Slow chemical reaction
is c) Isomerism d. Fast chemical reaction
A) CH4 B) H2
C) KCN D) KCl 11. In contact process, the impurities of arsenic are removed by
4. 2gm of silver were deposited by 1A current through AgNO 3 A) Fe(OH)2 B) Fe(OH)3
solution for 35mins.The efficiency of current is (Ag = 108). C) Al(OH)3 D) Cr(OH)3
A) 78% B) 81%
C) 85% D) 100% Group-B
5. Which has maximum electron affinity? Short-answer questions [8x5=40]
A) F B) Cl 1. a. State Avogadro’s Law. [1]
C) Br D) I b. Define Surface tension and viscosity. [2]
6. Alkali metals can be extracted from their salts by c. Give reason:
A) Electrolysis of fused halides B) reduction with carbon (i) Falling liquid drops are spherical
C) Reduction with aluminium D) electrolysis of aqueous (ii) Evaporation takes place from the surface of liquid
solution of their halides [3]
2. In a redox reaction both oxidation and reduction happen c. What happens when sodium is exposed to moist air?
side by side Write chemical reactions. [1]
a. Define oxidizing agent. [1] 5. What happens when [5]
b. Balance the following redox reaction either by oxidation a. Nascent hydrogen is passed to acidified KMnO4?
number method or ion-electron method b. Carbon monoxide reacts with Ni?
Zn + HNO3 Zn(NO3)2 + NO + H2O c. Chlorine reacts with hot and conc. NaOH?
[3] d. Sodium carbonate reacts with SO2?
c. How many number of HNO3 act as oxidizing agent in (b) e. H2S is passed to acidified KMnO4?
[1] 6. Qualitative analysis is an important tool for detection of
OR foreign element in the organic compounds.
Atomic spectra deal with the energy associate with a. Write test reaction for the detection of nitrogen. [3]
electron, b. What is the purpose for making sodium extract? [1]
a. How do atomic spectra originate? [2] c. If blood red colouration appears during N-detection, what
b. Name 5-hydrogen spectra. [1] is your conclusion? Also, write chemical reaction. [1]
c. write the ground state electronic configuration of Cr and OR
Cu. [2] Organic compounds have tendency to form homologous
3. a. Write the Lewis dot structure of i) NH3 ii) H2SO4 series
[2] a. Define homologous series. 1
b. predict the geometry of CH4 on the basis of hybridization. b. Write second member of alkene homologous series and
[2] give its IUPAC name. 1
c. How does H-bonding affect the boiling point of covalent c. Mention the characteristics of homologous series. 3
compounds? [1] 7. Answer the followings
4. Sodium is a highly reactive metal which causes fire with a. What happens when But-1-ene is subjected for
water, ozonolysis? [2]
a. Write the principle reaction for the extraction of sodium b. How will you distinguish ethene and ethyne? [2]
by Down’s process. [2] c. what happens when benzene is heated with nitrating
b. Draw the diagram of Down’s cell. [2] mixture? [1]
8. Modern manufactures have vital role in applied chemistry, c. Define efflorescent and deliquescent solid with example
a. Write the principle reaction for the manufacture of [2]
sodium carbonate by Solvay process. [2] d. Draw the Diagram of Kipp’s apparatus when it supplies
b. Draw flow-sheet diagram for this process. [2] H2S gas. [2]
c. Why is aqueous solution of sodium carbonate alkaline? 11. Organic compounds having same molecular formula but
[1] different structural formula are called isomers and the
Group-C phenomenon is called isomerism. This phenomenon is
Long-answer questions 3x8=24 responsible for existing of large number of organic
9. Answer the followings compounds
a. The rate of diffusion of a saturated hydrocarbon (C nH2n+2) a. Write the possible isomers of C3H6O and give their IUPAC
gas is 1.206 times that of SO2 gas under identical conditions. name. [2]
Find the molecular mass and value of n for the gas. b. What happens when 2-chloropropane is heated with Na
(molecular weight of SO2 = 64) [3] in presence of dry ether?
b. Derive a relationship between Kp and Kc. [3] [2]
c. Differentiate between Evaporation and boiling [2] c. What is the name of reaction for (b)? [1]
10. Metallurgy is an technique for the extraction of metal d. How can you prepare benzene from i) ethyne ii) phenol
a. Define hydrometallurgy with example [2] iii) sodium benzoate? [3]
b. Differentiating between calcination and roasting [2] OR
c. Define flux and slag and gangue with example. [2] Nitric acid is highly corrosive mineral acid used as a starting
d. Write important use of bleaching powder and plaster of material for the preparation of ammonium nitrate and
paris. [2] nitrogenous fertilizer.
OR a. Write the principle reaction for the manufacture of HNO3
Answer the followings by Ostwald’s process. [2]
a. Write the test reaction involved in the ring test for nitrate. b. Draw a flow-sheet diagram for Ostwald’s process. [3]
[2]
c. What happens when Conc. HNO3 reacts with Iron and Zinc
b. What is bleaching action? Write a chemical reaction
[3]
involved in the bleaching action of Cl2. [2]