MSDS HF0 150 SA Oil

MATERIAL SAFETY
DATA SHEET:
OIL Pages: 4
Issued: 18-03-2024
Product: HFO
1) PRODUCT DETAILS:
Product name: Heavy Fuel Oil
Chemical nature: Complex mixture of liquid
hydrocarbons (C10 to C20)
Synonyms: HFO, HBF 100, BF150
UN/ SIN: 1268
ERG: 128 (3YE)
2) COMPOSITION
Complex blend of liquid hydrocarbons (C10 to C20). Contains aromatic
oils including
polycyclic aromatic hydrocarbon (PAH) compounds. Sulphur content
ranges to a maximum of 3% by volume.
Dangerous Substances % (m/m) Risk Phrase
Polycyclic Hydrocarbons 5 - 40 Probable
carcinogenic,
harmful
3) HAZARDS IDENTIFICATION
Inflammable liquid; may be fatal if inhaled; harmful if swallowed or if
absorbed through skin; probable carcinogen; severe skin irritant. Fuel
oils are stored and handled hot; risk of thermal burns on skin contact.
4) FIRST AID MEASURES

Symptom and Effect First Aid
Skin Prolonged and repeated contact with Wash with soap and water
skin may cause severe irritation; until no odour
Toxic if dermally absorbed; remains.Coolburns
potentially carcinogenic; Burns immediately with cool water. Seek
medical advise
Eyes Contact with eyes may cause Flush eyes with clean water for 15
redness, tearing, blurred vision and minutes. Seek medical advise if
moderate irritation irritation persists
Ingestion Harmful or fatal if swallowed. If victim is alert, give large amounts

Ingestion of this product may cause of water and seek medical advice.
central nervous system effects Small amounts can be washed from
mouth until no taste persists DO
NOT INDUCE VOMITING
Inhalation Excessive exposure may cause Immediately remove to fresh air Give
respiratory tract irritation. Repeated oxygen if required. Seek medical
prolonged exposure to high advice if required
concentrations may lead to central
nervous system effects, headaches,
dizziness and loss of co-ordination
5) FIRE FIGHTING MEASURES
SMALL FIRES: Use CO2, foam or dry chemical
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LARGE FIRES: Use CO2, fluro protein foam or dry chemicals to extinguish
the fire. Use water to cool fire exposed containers/ structures and to
protect personnel.
Combustion may release toxic chemicals; utilize respirators; avoid low
lying areas.
6) ACCIDENTAL RELEASE MEASURES
Full protective clothing, rubber gloves (PVC, Neoprene, Nitrile, or Viton),
gumboots and respirator to be worn. Shut off leaks. Remove all sources
of heat or flame.
Control spill by use of booms, sand, sawdust or any other suitable
available medium. Recover as much free product as possible using
pumps or mechanical means. Absorb residue with sawdust, sand or other
absorbent material. Avoid the product entering storm water drains or
waterways.
7) HANDLING AND STORAGE
Handling: Full protective clothing should be worn when handling the

product. A high standard of personal hygiene is essential. Application of
protective hand creams may be beneficial.
Handling temperature: Avoid extreme temperatures
Storage: Store away from strong oxidizers. Incompatible with sulphuric

acid, nitric acid, caustics, aliphatic amines and amides.
Storage Conditions: Storage conditions should comply with SABS

Code 0131:1979-2 and SABS Code 089:1999-1. Product should be
stored in a well ventilated area. Sparks, flames and other sources
of ignition near the product should be avoided. Do not eat, drink or
smoke in storage area.
8) EXPOSURE CONTROLS/ PERSONAL PROTECTION
Occupational Exposure Limits: OHSA 0.2mg/m3 TWA OEL-RL

Controls: Store in accordance to
SABS089:1999- 1or SABS0131:1979
Personal protection Ensure adequate tank ventilation
If engineering controls and work
practices are not effective in
controlling this material, then wear
suitable personal protection
equipment including overalls,
impervious gloves, respirators,
safety goggles, safety boots or
gumboots.
9) PHYSICAL AND CHEMICAL PROPERTIES
Black viscous liquid with characteristic hydrocarbon odour. Low solubility

in water. Density @ 200C, kg/l: 0.87 – 0.99
Flashpoint @ 101, 325 kPa: 660C
Boiling Point: +1500C
Viscosity (cSt): 120 @ 500C
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10) STABILITY AND REACTIVITY
Partially volatile at temperatures in excess of 70 C; avoid strong oxidizers.

Incompatible with sulphuric acid, nitric acid, caustics, aliphatic amines
and amides
11) TOXICOLOGICAL INFORMATION
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Some components of the product are suspected carcinogens. Potential
harmful effects to liver, kidneys, heart, lungs and nervous system may
result from chronic over exposure. Some of the components of the
product have been associated with immunological, reproductive,
fetotoxic and genotoxic effects
12) ECOLOGICAL INFORMATION
No ecological problems are expected if the product is handled and used

with due care. When released to the environmental, some evaporation
and biodegradation will occur. Some components of the product are
soluble in water and may contaminate groundwater reserves. Some
components of the product will persist in soil. Material is moderately
toxic to aquatic organisms.
13) DISPOSAL CONSIDERATIONS
Do not flush to drain/ storm sewer. Product must be disposed of in an

approved hazardous waste disposal site or an approved incinerator.
14) TRANSPORT INFORMATION
SIN 1268
ERG: 128 3YE
ICS: Class 3: Group III
IMDG Code: Class 3
Marine Yes
Pollutant:
15) REGULATORY INFORMATION
National Legislation N/A
16) OTHER INFORMATION
For more information please contact SA Oil Refiners on (031) 7646126

All information is given in good faith but without guarantee in respect of accuracy and
no responsibility is accepted for errors or omissions or the consequences thereof
MCID-MSDSI022 5

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MATERIAL SAFETY

4) FIRST AID MEASURES

Ingestion Harmful or fatal if swallowed. If victim is alert, give large amounts

Handling: Full protective clothing should be worn when handling the

Handling temperature: Avoid extreme temperatures

Storage: Store away from strong oxidizers. Incompatible with sulphuric

Storage Conditions: Storage conditions should comply with SABS

Occupational Exposure Limits: OHSA 0.2mg/m3 TWA OEL-RL

Black viscous liquid with characteristic hydrocarbon odour. Low solubility

Partially volatile at temperatures in excess of 70 C; avoid strong oxidizers.

No ecological problems are expected if the product is handled and used

Do not flush to drain/ storm sewer. Product must be disposed of in an

14) TRANSPORT INFORMATION

National Legislation N/A

16) OTHER INFORMATION

For more information please contact SA Oil Refiners on (031) 7646126

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