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    GOC - Short Notes - Arjuna NEET 2.0 2025 (Organic Chemistry)

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    GOC - Short Notes - Arjuna NEET 2.0 2025 (Organic Chemistry)

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    Original Title

    GOC _ Short Notes __ Arjuna NEET 2.0 2025 ~ (Organic Chemistry) (1)

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    GOC - Short Notes - Arjuna NEET 2.0 2025 (Organic Chemistry)

    Uploaded by

    pramath.vittal

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    © All Rights Reserved
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    CHAPTER

    14 General Organic Chemistry

    Electrophiles are electron deficient species. (B) Stability of free radical


    E.g. H⊕, R⊕, NO⊕2, X⊕, PCl3, PCl5 (Ph)3C > (Ph)2CH > CH2 = CH – CH2 > PhCH2 > (CH3)3C
    ⊕
    (NH4 and H3O⊕ are not electrophile) > (CH3)2CH > CH3CH2 > CH3
    Nucleophiles are electron rich species. (C) Stability of carbanion
    $ $ $ .. ..
    E.g. Cl$, C H3, OH, RO$,C N, NH3, RO .. H, CH2= CH2, (Ph)3 C > (Ph)2 CH > Ph – CH2 > CH2 = CH – CH2 >
    CH≡CH
    CH3 > CH3 CH2 > (CH3)2 CH > (CH3)3 C
    Relative electron withdrawing order (–I order)
    ⊕ ⊕ ⊕ Reactivity towards nucleophile (NAR)
    –NF3 > –NR3 > –NH3 > –NO2 > –CN > –COOH > –X > – (1) HCHO > CH3CHO > (CH3)2CO
    OR > –OH > –C≡CH > –NH2 > –C6H5 > –CH = CH2 (2) CCl3CHO > CHCl2CHO > CH2ClCHO
    Relative electron releasing order (+I order)
     ™ Reactivity order towards acyl nucleophilic substitution
    –N H > –O > –COO > 3° alkyl > 2° alkyl > 1° alkyl > reaction
    –CH3
    Acid chloride > anhydride > ester > amide
    Relative Stability Order ™ Order of electronic effect
    (A) Stability of carbocation Mesomeric > Hyperconjugation > Inductive effect
    ⊕ ™ Stability of alkene ∝ no. of a-hydrogen
    ⊕ ⊕ ⊕ ⊕
    > (Ph)3 C > (Ph)2 C H > Ph – C H2 > CH2 = CH – C H2 R 2 C=CR 2 > R 2 C=CHR > R 2 C=CH 2 > RCH=CHR >
    trans form
    ⊕ ⊕ ⊕ ⊕ ⊕ RCH=CHR > RCH=CH 2 > CH 2 =CH 2
    > (CH3)3 C > (CH3)2 C H > CH3 C H2 > C H3 > CH2 = C H cis form
    1
    ⊕ ™ Heat of hydrogenation ∝
    > CH ≡ C Stability of alkene

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