SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006,

as amended
ShiftMax 120 Tab 6x6 0228 Page 1(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Trade name
ShiftMax 120 Tab 6x6 0228
Material number: 246084
Chemical nature: Mixture of iron oxide and chromium oxide, promoted

1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Type of use: Catalyst

1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH
Arabellastrasse 4a
81925 München
Telephone no. : +49 (0)89/5110-0
Information about the substance/mixture
BU Catalysts
Product Stewardship
e-mail: SDS.Europe@clariant.com

1.4. Emergency telephone number

00800-5121 5121 (24 h)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4 H302: Harmful if swallowed.

Acute toxicity, Category 4 H332: Harmful if inhaled.

Skin irritation, Category 2 H315: Causes skin irritation.

Eye irritation, Category 2 H319: Causes serious eye irritation.

Respiratory sensitisation, Category 1 H334: May cause allergy or asthma symptoms or

breathing difficulties if inhaled.

Skin sensitisation, Category 1 H317: May cause an allergic skin reaction.

Germ cell mutagenicity, Category 1B H340: May cause genetic defects.

Carcinogenicity, Category 1A H350: May cause cancer.

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 2(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Specific target organ toxicity - single H335: May cause respiratory irritation.
exposure, Category 3, Respiratory
system

Specific target organ toxicity - repeated H373: May cause damage to organs through
exposure, Category 2 prolonged or repeated exposure.

Short-term (acute) aquatic hazard, H400: Very toxic to aquatic life.

Category 1

Long-term (chronic) aquatic hazard, H410: Very toxic to aquatic life with long lasting
Category 1 effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :

Signal word : Danger

Hazard statements : H302 + H332 Harmful if swallowed or if inhaled.

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or
breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H340 May cause genetic defects.
H350 May cause cancer.
H373 May cause damage to organs through prolonged
or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.

Prevention:
Precautionary statements :
P201 Obtain special instructions before use.
P260 Do not breathe dust.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection/ hearing protection.
Response:
P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a
POISON CENTER/ doctor if you feel unwell.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P342 + P311 If experiencing respiratory symptoms: Call a
POISON CENTER/ doctor.
P391 Collect spillage.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 3(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Hazardous components which must be listed on the label:

Chromium trioxide
2.3 Other hazards
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Ecological information: The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Index-No.
Registration number
Chromium trioxide 1333-82-0 Ox. Sol. 1; H271 >= 2,5 - < 3
215-607-8 Acute Tox. 3; H301
024-001-00-0 Acute Tox. 2; H330
01-2119458868-17- Acute Tox. 3; H311
0015 Skin Corr. 1A; H314
01-2119458868-17- Eye Dam. 1; H318
XXXX Resp. Sens. 1; H334
Skin Sens. 1; H317
Muta. 1B; H340
Carc. 1A; H350
Repr. 2; H361f
STOT SE 3; H335
(Respiratory system)
STOT RE 1; H372
Aquatic Acute 1;
H400
Aquatic Chronic 1;
H410

specific concentration
limit
STOT SE 3; H335
>= 1 %

Acute toxicity
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 4(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

estimate

Acute oral toxicity: 52

mg/kg
52 mg/kg
Acute inhalation
toxicity (dust/mist):
0,167 mg/l
0,05 mg/l
Copper oxide 1317-38-0 Aquatic Acute 1; >= 1 - < 2,5
215-269-1 H400
029-016-00-6 Aquatic Chronic 1;
01-2119502447-44- H410
0011
01-2119502447-44- M-Factor (Acute
0043 aquatic toxicity): 100
M-Factor (Chronic
aquatic toxicity): 10

Substances with a workplace exposure limit :

Chromium (III) oxide 1308-38-9 >= 5 - < 10
215-160-9
01-2119433951-39-
0000
01-2119433951-39-
0007
01-2119433951-39-
0020
For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Wash off immediately with soap and plenty of water.

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.

If swallowed : Rinse mouth.

Call a physician immediately.
Do not induce vomiting without medical advice.
Never give anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Risks : see point 2
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 5(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : The product itself does not burn.
Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

Unsuitable extinguishing : High volume water jet

media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Further information : Standard procedure for chemical fires.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Ensure adequate ventilation.
Use personal protective equipment.
Avoid contact with skin, eyes and clothing.

6.2 Environmental precautions

Environmental precautions : Do not flush into surface water or sanitary sewer system.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Sweep up or vacuum up spillage and collect in suitable
container for disposal.

6.4 Reference to other sections

For personal protection see section 8., For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : No special precautions required.
fire and explosion
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 6(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Hygiene measures : Keep working clothes separately. Keep away from food, drink
and animal feedingstuffs. Wash hands before breaks and
immediately after handling the product. Preventive skin
protection (protective ointment for the skin)

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Keep tightly closed in a dry and cool place.
areas and containers

Advice on common storage : No materials to be especially mentioned.

Further information on : Stable under recommended storage conditions.

storage stability

7.3 Specific end use(s)

Specific use(s) : Not relevant

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
Chromium trioxide Workers Inhalation Long-term local 0,01 mg/m3
CAS-No.: 1333-82-0 effects
Remarks:DMEL
Workers Inhalation Acute local effects 0,01 mg/m3
Remarks:DMEL
Graphite Workers Inhalation Long-term systemic 1,2 mg/m3
CAS-No.: 7782-42-5 effects
Remarks:DNEL
Workers Inhalation Long-term local 1,2 mg/m3
effects
General Inhalation Long-term local 0,3 mg/m3
population effects
Remarks:DNEL
General Ingestion Long-term systemic 813 mg/kg
population effects bw/day
Remarks:DNEL
Copper oxide Workers Inhalation Long-term systemic 1 mg/m3
CAS-No.: 1317-38-0 effects
Remarks:DNEL
Workers Inhalation Long-term local 1 mg/m3
effects
Remarks:DNEL
Workers Dermal Long-term systemic 137 mg/kg
effects bw/day
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 7(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Remarks:DNEL
Consumers Oral Acute systemic 0,082 mg/kg
effects bw/day
Remarks:DNEL
Consumers Oral Long-term systemic 0,041 mg/kg
effects bw/day
Remarks:DNEL
Chromium (III) oxide Workers Inhalation Acute local effects 2 mg/m3
CAS-No.: 1308-38-9
Remarks:DNEL
Workers Inhalation Long-term local 0,5 mg/m3
effects
Remarks:DNEL
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
Chromium trioxide Fresh water 0,003 mg/l
CAS-No.: 1333-82-0
Remarks:Cr(VI): Hexavalent chromium
Marine water 0,003 mg/l
Remarks:Cr(VI): Hexavalent chromium
Sewage treatment plant 0,21 mg/l
Remarks:Cr(VI): Hexavalent chromium
Fresh water sediment 0,15 mg/kg wet
weight
Remarks:Cr(VI): Hexavalent chromium
Marine sediment 0,15 mg/kg wet
weight
Remarks:Cr(VI): Hexavalent chromium
Soil 0,031 mg/kg wet
weight
Remarks:Cr(VI): Hexavalent chromium
Oral exposure 17000000 mg/kg
dry weight (d.w.)
Remarks:Cr(VI): Hexavalent chromium, Secondary Poisoning
Copper oxide Fresh water 0,0078 mg Cu/l
CAS-No.: 1317-38-0
Marine water 0,0052 mg Cu/l
Fresh water sediment 87 mg Cu/kg
Soil 65,5 mg Cu/kg
Sewage treatment plant 0,23 mg Cu/l
Chromium (III) oxide Fresh water 0,0047 mg/l
CAS-No.: 1308-38-9
Remarks:chromium
salt water 0,0047 mg/l
Remarks:chromium
Water (intermittent release) 0,0047 mg/l
Remarks:chromium
Sewage treatment plant 10 mg/l
Fresh water sediment 18,2 mg/kg dry
weight (d.w.)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 8(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Remarks:chromium
Marine sediment 1,31 mg/kg dry
weight (d.w.)
Remarks:chromium
Soil 3,2 mg/kg dry
weight (d.w.)
Remarks:chromium
8.2 Exposure controls
Engineering measures
Local exhaust
Personal protective equipment
Eye/face protection : Safety glasses

Hand protection
Remarks : Chemical-resistant protective gloves according to EN 374,
EN 388, EN 420. With full contact/spraying contact: nitrile
rubber, layer thickness 0.4mm, break through time > 480min

Skin and body protection : Dust impervious protective suit

Respiratory protection : not required under normal use

In the case of dust or aerosol formation use respirator with an
approved filter.
Suitable mask with particle filter P3 (European Norm 143)
Applicable national Regulations must be observed. Take note
of the limitations regarding wear-time, in conjunction with the
Regulations for the use of Respiratory Protective Equipment.

Protective measures : Occupational hygiene surveillance (including personal

biomonitoring) is recommended.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : tablet

Colour : dark brown

Odour : odourless

Odour Threshold : not tested.

Melting point : > 650 °C

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 9(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Boiling point : not determined

Upper explosion limit / upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Flash point : Not applicable

Auto-ignition temperature : Not applicable

pH : substance/mixture is non-soluble (in water)

Viscosity
Viscosity, dynamic : cannot be determined

Viscosity, kinematic : cannot be determined

Solubility(ies)
Water solubility : insoluble, Traces of Cr(VI) can be leached out.

Partition coefficient: n- : not tested.

octanol/water

Vapour pressure : Not applicable

Relative density : not tested.

Density : not tested.

Bulk density : 1.100 kg/m3

Relative vapour density : not tested.

Particle characteristics
Particle size : not tested.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 10(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

9.2 Other information

Explosives : Not explosive
Method: Expert judgement

Oxidizing properties : The substance or mixture is not classified as oxidizing.

Flammable solids
Burning number : not tested.

Self-ignition : not tested.

Evaporation rate : Not applicable

Surface tension : Not applicable

Minimum ignition energy : not tested.

SECTION 10: Stability and reactivity

10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
No decomposition if stored and applied as directed.
10.3 Possibility of hazardous reactions
Hazardous reactions : Metal catalysts can form Metal carbonyl M x(CO)y in the
presence of carbon monoxide. Metal carbonyl is highly
flammable and highly toxic and can cause cyanosis and
chemical pneumonia which can be fatal. Symptoms may be
delayed for several hours or days. Extreme care and
specialized handling is required if carbon monoxide is present
in the catalyst process. Hazardous reactions are possible at
temperatures including, but not limited to, ambient
temperatures depending on pressure and carbon monoxide
concentrations.
10.4 Conditions to avoid
Conditions to avoid : Avoid dust formation.

10.5 Incompatible materials

Materials to avoid : Acids and bases
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 11(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

10.6 Hazardous decomposition products

No decomposition if stored and applied as directed.
In case of fire hazardous decomposition products may be produced such as:
see heading 5

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Acute toxicity
Harmful if swallowed or if inhaled.
Product:
Acute oral toxicity : Acute toxicity estimate: 2.000 mg/kg
Method: Calculation method

Acute toxicity estimate: 2.000 mg/kg

Method: Calculation method

Acute inhalation toxicity : Acute toxicity estimate: 1,92 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Acute toxicity estimate: 1,92 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Method: Calculation method

Acute dermal toxicity : Acute toxicity estimate: > 2.000 mg/kg

Method: Calculation method

Acute toxicity estimate: > 2.000 mg/kg

Method: Calculation method

Components:
Chromium trioxide:
Acute oral toxicity : LD50 (Rat, male and female): 52 mg/kg
Method: OECD Test Guideline 401
GLP: yes

Acute inhalation toxicity : LC50 (Rat, male and female): 0,167 - 0,217 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: Other
GLP: yes

Acute dermal toxicity : Assessment: The component/mixture is toxic after single

contact with skin.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 12(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Copper oxide:
Acute oral toxicity : LD50 (Rat, male): > 2.500 mg/kg
Method: OECD Test Guideline 423
GLP: yes
Assessment: The substance or mixture has no acute oral
toxicity

Acute inhalation toxicity : Remarks: no data available

Acute dermal toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
Method: OECD Test Guideline 402
GLP: yes
Assessment: The substance or mixture has no acute dermal
toxicity

Chromium (III) oxide:

Acute oral toxicity : LD50 (Rat, male): > 15.000 mg/kg
Method: OECD Test Guideline 401
GLP: no
Remarks: No significant adverse effects were reported

Acute inhalation toxicity : LC50 (Rat, male and female): > 5,41 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
Method: OECD Test Guideline 403
GLP: yes
Assessment: The substance or mixture has no acute
inhalation toxicity

Acute dermal toxicity : Remarks: no data available

Skin corrosion/irritation
Causes skin irritation.
Product:
Remarks : no data available

Components:
Chromium trioxide:
Species : Rabbit
Exposure time : 0,5 h
Method : Other
Result : Causes severe burns.
GLP : no

Copper oxide:
Species : Rabbit
Exposure time : 4h
Method : OECD Test Guideline 404
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 13(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Result : No skin irritation

GLP : yes

Chromium (III) oxide:

Species : Rabbit
Exposure time : 4h
Method : OECD Test Guideline 404
Result : No skin irritation
GLP : yes

Serious eye damage/eye irritation

Causes serious eye irritation.
Product:
Remarks : no data available

Components:
Chromium trioxide:
Species : Rabbit
Method : Screening test
Result : Risk of serious damage to eyes.
GLP : no

Copper oxide:
Species : Rabbit
Exposure time : 72 h
Method : OECD Test Guideline 405
Result : No eye irritation
GLP : yes

Chromium (III) oxide:

Species : Rabbit
Exposure time : 24 h
Method : OECD Test Guideline 405
Result : No eye irritation
GLP : yes

Respiratory or skin sensitisation

Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Product:
Remarks : no data available
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 14(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Components:
Chromium trioxide:
Result : May cause sensitisation by skin contact.

Result : May cause sensitisation by inhalation.

Assessment : Toxic if swallowed., Fatal in contact with skin or if inhaled.,

Causes severe skin burns and eye damage.
May cause sensitisation by skin contact., May cause allergy or
asthma symptoms or breathing difficulties if inhaled.

Copper oxide:
Test Type : Maximisation Test
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : yes

Chromium (III) oxide:

Test Type : Buehler Test
Exposure routes : Skin contact
Species : Guinea pig
Method : OECD Test Guideline 406
Result : Not a skin sensitizer.
GLP : yes

Remarks : By analogy with a product of similar composition

Germ cell mutagenicity

May cause genetic defects.
Components:
Chromium trioxide:
Genotoxicity in vitro : Test Type: In vitro gene mutation study in bacteria
Result: positive

Test Type: Chromosome aberration test in vitro

Result: positive

Test Type: In vitro gene mutation study in mammalian cells

Result: positive

Genotoxicity in vivo : Test Type: in vivo assay

Result: positive

Germ cell mutagenicity- : In vivo tests showed mutagenic effects, In vitro tests showed
Assessment mutagenic effects
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 15(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Copper oxide:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes

Germ cell mutagenicity- : In vitro tests did not show mutagenic effects
Assessment

Chromium (III) oxide:

Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Method: OECD Test Guideline 471
Result: negative
GLP: yes
Remarks: By analogy with a product of similar composition

Genotoxicity in vivo : Test Type: Micronucleus test

Species: Mouse (male and female)
Strain: NMRI
Cell type: Bone marrow
Application Route: Intraperitoneal injection
Dose: 10000 mg/kg bw
Method: OECD Test Guideline 474
Result: negative
GLP: yes

Germ cell mutagenicity- : In vitro tests did not show mutagenic effects, In vivo tests did
Assessment not show mutagenic effects

Carcinogenicity
May cause cancer.
Components:
Chromium trioxide:
Species : Rat, male and female
Application Route : Drinking water
Exposure time : 2y
Dose : 0, 14.3, 57.3, 172, 516 mg/l
Control Group : yes
Frequency of Treatment : continuous
LOAEL : 2,2 - 2,7 mg/kg body weight
Method : Other
Result : positive
GLP : yes

Application Route : inhalation (dust/mist/fume)

Result : positive
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 16(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Carcinogenicity - : Human carcinogen.

Assessment

Copper oxide:
Carcinogenicity - : No evidence of carcinogenicity in animal studies.
Assessment

Chromium (III) oxide:

Species : Rat, male and female
Application Route : oral (feed)
Exposure time : 104 w
Dose : 0, 1%, 2%, 5% chromium (III) o
Control Group : yes
Frequency of Treatment : 5 days/week
: 50.000 mg/kg food
Method : Other
Result : negative
GLP : no

Carcinogenicity - : No evidence of carcinogenicity in animal studies.

Assessment

Reproductive toxicity
Not classified due to lack of data.
Components:
Chromium trioxide:
Effects on fertility : Test Type: Fertility
Species: Mouse, male and female
Strain: Switzerland
Application Route: Drinking water
Dose: 0, 60, 120, 235, 290 mg/kg bw
Fertility: NOAEL: 166 mg/kg body weight
Method: Other
Result: Some evidence of adverse effects on development,
based on animal experiments.
GLP: no

Effects on foetal : Test Type: Pre-natal

development Species: Mouse, female
Strain: Switzerland
Dose: 0, 250, 500, 750 ppm
Duration of Single Treatment: 9 d
General Toxicity Maternal: LOAEL: 125 mg/kg body weight
Embryo-foetal toxicity: LOAEL: 125 mg/kg body weight
Method: Other
GLP: no
Remarks: This information is not available.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 17(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Reproductive toxicity - : Some evidence of adverse effects on sexual function and

Assessment fertility, and/or on development, based on animal experiments.

Copper oxide:
Effects on fertility : Test Type: Two-generation study
Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: oral (feed)
Dose: 0, 100, 500, 1000, 1500 ppm
General Toxicity - Parent: NOAEL: 23,6 - 33,8 mg/kg body
weight
General Toxicity F1: NOAEL: 23,5 - 35,2 mg/kg body weight
Method: OECD Test Guideline 416
GLP: yes

Effects on foetal : Test Type: Pre-natal

development Species: Rabbit, female
Strain: New Zealand white
Application Route: oral (gavage)
General Toxicity Maternal: NOAEL: 6 mg/kg body weight
Developmental Toxicity: NOAEL: 6 mg/kg body weight
Method: OECD Test Guideline 414
GLP: yes

Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.

Chromium (III) oxide:

Effects on fertility : Test Type: Fertility/early embryonic development
Species: Rat, male and female
Strain: Sprague-Dawley
Application Route: oral (feed)
Dose: 0, 4, 15 and 60 ppm
General Toxicity - Parent: NOAEL: > 8 mg/kg body weight
General Toxicity F1: NOAEL: > 8 mg/kg body weight
General Toxicity F2: NOAEL: > 8 mg/kg body weight
Method: Other
GLP: yes
Remarks: By analogy with a product of similar composition

Effects on foetal : Test Type: Pre-natal

development Species: Mouse, female
Strain: CD1
Application Route: oral (feed)
Dose: 0, 15, 120, 200 mg/kg bw/d
Duration of Single Treatment: 11 d
General Toxicity Maternal: NOAEL: > 25 mg/kg body weight
Teratogenicity: NOAEL: > 25 mg/kg body weight
Developmental Toxicity: NOAEL: > 25 mg/kg body weight
Method: Other
GLP: No information available.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 18(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
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Remarks: By analogy with a product of similar composition

Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.

STOT - single exposure

May cause respiratory irritation.
Components:
Chromium trioxide:
Assessment : The substance or mixture is classified as specific target organ
toxicant, single exposure, category 3 with respiratory tract
irritation.

Copper oxide:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

Chromium (III) oxide:

Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.

STOT - repeated exposure

May cause damage to organs through prolonged or repeated exposure.
Components:
Chromium trioxide:
Assessment : The substance or mixture is classified as specific target organ
toxicant, repeated exposure, category 1.

Copper oxide:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Chromium (III) oxide:

Assessment : The substance or mixture is not classified as specific target
organ toxicant, repeated exposure.

Repeated dose toxicity

Components:
Chromium trioxide:
Species : Rat, male and female
NOAEL : 5 mg/kg bw/day
Application Route : Drinking water
Exposure time : 90 d
Number of exposures : continuous
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 19(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
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Dose : 0, 5, 10, 17, 32, 60 mg/kg bw/

Control Group : yes
Method : Other
GLP : yes
Remarks : Significant toxicity observed in testing

Species : Mouse, female

LOAEL : 1,81 mg/m³
Application Route : inhalation (dust/mist/fume)
Exposure time : 1y
Number of exposures : two periods of 60 minutes per
Dose : 1.81 mg/m3
Control Group : yes
Method : Other
GLP : no
Remarks : Significant toxicity observed in testing

Repeated dose toxicity - : Toxic if swallowed., Fatal in contact with skin or if inhaled.,
Assessment Causes severe skin burns and eye damage.

Copper oxide:
Species : Mouse, male and female
NOAEL : 44 - 52 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 92 d
Number of exposures : daily
Dose : 0, 1000, 2000, 4000, 8000 or 1
Method : Regulation (EC) No. 440/2008, Annex, B.26
GLP : yes

Species : Rat, male and female

NOAEL : >= 0,002 mg/l
Application Route : inhalation (dust/mist/fume)
Exposure time : 28 d
Number of exposures : 5 days per week, 6 hours per d
Dose : 0.2, 0.4, 0.8, 2.0 mg/m3
Method : OECD Test Guideline 412
GLP : yes

Chromium (III) oxide:

Species : Rat, male and female
NOAEL : 2000 mg/kg bw/day
Application Route : oral (feed)
Exposure time : 90 d
Number of exposures : 5 days/week
Dose : 2% and 5%
Control Group : yes
Method : Other
GLP : No information available.

Species : Rat, male and female

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 20(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
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LOAEL : 0,0044 mg/l

Application Route : inhalation (dust/mist/fume)
Exposure time : 13 wk
Number of exposures : 6 hours per day/5 days per we
Dose : 4.4, 15 or 44 mg/m3
Control Group : yes
Method : OECD Test Guideline 413
GLP : No information available.

Aspiration toxicity
Not classified due to lack of data.
Components:
Chromium trioxide:
no data available

Copper oxide:
No aspiration toxicity classification

Chromium (III) oxide:

No aspiration toxicity classification

11.2 Information on other hazards

Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

SECTION 12: Ecological information

12.1 Toxicity
Product:
Toxicity to fish : Remarks: no data available

Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates

Toxicity to algae/aquatic : Remarks: no data available

plants

Toxicity to microorganisms :
Remarks: no data available
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 21(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Components:
Chromium trioxide:
Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): 13 mg/l
End point: mortality
Exposure time: 96 h
Test Type: Other
Analytical monitoring: yes
Method: Other
GLP: No information available.

LC50 (Carassius auratus (goldfish)): 37,5 mg/l

End point: mortality
Exposure time: 96 h
Test Type: Other
Analytical monitoring: yes
Method: Other
GLP: No information available.

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0,53 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 48 h
Analytical monitoring: yes
Method: Other
GLP: no

Toxicity to algae/aquatic : ErC50 (Selenastrum capricornutum (green algae)): 0,233 mg/l

plants End point: Growth rate
Exposure time: 72 h
Test Type: static test
Analytical monitoring: yes
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

ErC10 (Selenastrum capricornutum (green algae)): 0,01 mg/l

End point: Growth rate
Exposure time: 72 h
Test Type: static test
Analytical monitoring: yes
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

NOEC (Lemna minor (duckweed)): 0,11 mg/l

End point: Growth rate
Exposure time: 7 d
Analytical monitoring: yes
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

Toxicity to microorganisms : IC50 (activated sludge): 30 mg/l

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 22(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
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Exposure time: 3 h
Analytical monitoring: yes
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

Toxicity to fish (Chronic : NOEC: 0,105 mg/l

toxicity) End point: Other
Exposure time: 60 d
Species: Salvelinus namaycush (lake trout)
Test Type: no data available
Analytical monitoring: yes
Method: Other
GLP: no

Toxicity to daphnia and other : NOEC: 18 mg/l

aquatic invertebrates End point: mortality
(Chronic toxicity) Exposure time: 21 d
Species: Daphnia magna (Water flea)
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

Toxicity to soil dwelling : LC50: 146 mg/kg

organisms Exposure time: 28 d
End point: mortality
Species: Other
Method: Other
GLP:no

Plant toxicity : NOEC: 0,12 mg/l

Species: Avena sativa (oats)
Method: OECD Test Guideline 208
GLP:No information available.
Remarks: By analogy with a product of similar composition

NOEC: 0,04 mg/l

Species: Lactuca sativa (lettuce)
Method: OECD Test Guideline 208
GLP:No information available.
Remarks: By analogy with a product of similar composition

NOEC: 0,11 mg/l

Species: Lycopersicon esculentum
Method: OECD Test Guideline 208
GLP:No information available.
Remarks: By analogy with a product of similar composition

Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.

Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 23(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
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Copper oxide:
Toxicity to fish : Remarks: no data available

M-Factor (Acute aquatic : 100

toxicity)

M-Factor (Chronic aquatic : 10

toxicity)

Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.

Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.

Chromium (III) oxide:

Toxicity to fish : LC50 (Danio rerio (zebra fish)): > 10.000 mg/l
End point: mortality
Exposure time: 96 h
Test Type: static test
Analytical monitoring: yes
Method: ISO 7346/1
GLP: yes

Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates

Toxicity to algae/aquatic : (Desmodesmus subspicatus (green algae)): 0,47 mg/l

plants Method: OECD Test Guideline 201

Toxicity to microorganisms : EC50 (activated sludge): > 10.000 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: static test
Analytical monitoring: no
Method: ISO 8192
GLP: yes
Remarks: By analogy with a product of similar composition

Toxicity to fish (Chronic : NOEC: 1.000 mg/l

toxicity) End point: Reproduction rate
Exposure time: 30 d
Species: Danio rerio (zebra fish)
Test Type: semi-static test
Analytical monitoring: yes
Method: OECD Test Guideline 210
GLP: yes
Remarks: By analogy with a product of similar composition

Toxicity to daphnia and other : NOEC: 0,02 mg/l

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 24(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
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aquatic invertebrates End point: Immobilization

(Chronic toxicity) Exposure time: 21 d
Species: Daphnia magna (Water flea)
Test Type: semi-static test
Method: OECD Test Guideline 202
GLP: yes
Remarks: No toxicity at the limit of solubility

Sediment toxicity : EC50: > 350 mg/l

Analytical monitoring: yes
Sediment: Artificial sediment
Exposure duration: 42 d
Species: Hyalella azteca (Scud)
Nominal / Measured: nominal
Basis for effect: Reproduction
Method: Other
GLP: no
Remarks: By analogy with a product of similar composition

12.2 Persistence and degradability

Product:
Biodegradability : Remarks: Not applicable

Components:
Chromium trioxide:
Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

Copper oxide:
Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

Chromium (III) oxide:

Biodegradability : Remarks: The methods for determining biodegradability are
not applicable to inorganic substances.

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: no data available

Components:
Copper oxide:
Bioaccumulation : Remarks: Not applicable

Chromium (III) oxide:

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 25(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Bioaccumulation : Remarks: Bioaccumulation is unlikely.

12.4 Mobility in soil

Product:
Distribution among : Remarks: no data available
environmental compartments

Components:
Copper oxide:
Distribution among : Remarks: After release, adsorbs onto soil.
environmental compartments

12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Components:
Chromium trioxide:
Assessment : The substance is not identified as a PBT or as a vPvB
substance.

Copper oxide:
Assessment : Remarks: Not relevant for inorganic substances

Chromium (III) oxide:

Assessment : Remarks: Not relevant for inorganic substances

12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

12.7 Other adverse effects

Product:
Additional ecological : highly hazardous to water
information
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 26(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
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Components:
Chromium trioxide:
Environmental fate and : no data available
pathways

Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Refer to manufacturer/supplier for information on
recovery/recycling.
Used catalysts may have different hazards or properties than
the original product. This SDS does not apply to used
catalysts.

Contaminated packaging : Dispose of as unused product.

SECTION 14: Transport information

Section 14.1. to 14.5.

ADR
UN no. UN 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s.
Hazard inducer(s): Chromium trioxide
Copper oxide
Class: 9
Primary risk: 9
Packing group: III
Hazard no. : 90
Remarks Shipment permitted
ADN
UN no. UN 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s.
Hazard inducer(s): Chromium trioxide
Copper oxide
Class: 9
Primary risk: 9
Packing group: III
Remarks Shipment permitted
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 27(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

RID
UN no. UN 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s.
Hazard inducer(s): Chromium trioxide
Copper oxide
Class: 9
Primary risk: 9
Packing group: III
Hazard no. : 90
Remarks Shipment permitted
IATA
UN no. UN 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s.
Hazard inducer(s): Chromium trioxide
Copper oxide
Class: 9
Primary risk: 9
Packing group: III
Remarks Shipment permitted
IMDG
UN no. UN 3077
Proper shipping name: Environmentally hazardous substance, solid, n.o.s.
Hazard inducer(s): Chromium trioxide
Copper oxide
Class: 9
Primary risk: 9
Packing group: III
Remarks Shipment permitted
Marine pollutant: Marine Pollutant
EmS : F-A S-F

14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7. Maritime transport in bulk according to IMO instruments

No transport as bulk according IBC - Code.
Further information
Non-dangerous good of class 9 for packagings <= 5 L / 5 kg

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
REACH - Restrictions on the manufacture, placing on : Conditions of restriction for the
the market and use of certain dangerous substances, following entries should be
mixtures and articles (Annex XVII) considered:
Number on list 75 Chromium trioxide
(Number on list 72, 29, 28)
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 28(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

If you intend to use this product as

tattoo ink, please contact your
vendor.

Chromium trioxide (Number on list

72, 29, 28)

REACH - Candidate List of Substances of Very High : Chromium trioxide

Concern for Authorisation (Article 59).

Regulation (EC) on substances that deplete the ozone : Not applicable

layer

Regulation (EU) 2019/1021 on persistent organic : Not applicable

pollutants (recast)

Council Regulation (EC) No 111/2005 laying down rules : Neither banned nor restricted
for the monitoring of trade between the Community and
third countries in drug precursors

Council Regulation (EC) No 273/2004 on drug : Not applicable

precursors

Regulation (EU) No 649/2012 of the European : Not applicable

Parliament and the Council concerning the export and
import of dangerous chemicals

REACH - List of substances subject to authorisation : Chromium trioxide

(Annex XIV)

Seveso III: Directive 2012/18/EU of the E1 ENVIRONMENTAL HAZARDS

European Parliament and of the Council on the
control of major-accident hazards involving
dangerous substances.

15.2 Chemical safety assessment

Chemical Safety Assessments have been carried out for these substances.

SECTION 16: Other information

Full text of H-Statements

H271 : May cause fire or explosion; strong oxidizer.
H301 : Toxic if swallowed.
H311 : Toxic in contact with skin.
H314 : Causes severe skin burns and eye damage.
H317 : May cause an allergic skin reaction.
H318 : Causes serious eye damage.
H330 : Fatal if inhaled.
H334 : May cause allergy or asthma symptoms or breathing
SAFETY DATA SHEET
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as amended
ShiftMax 120 Tab 6x6 0228 Page 29(30)
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difficulties if inhaled.
H335 : May cause respiratory irritation.
H340 : May cause genetic defects.
H350 : May cause cancer.
H361f : Suspected of damaging fertility.
H372 : Causes damage to organs through prolonged or repeated
exposure.
H400 : Very toxic to aquatic life.
H410 : Very toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Short-term (acute) aquatic hazard
Aquatic Chronic : Long-term (chronic) aquatic hazard
Carc. : Carcinogenicity
Eye Dam. : Serious eye damage
Muta. : Germ cell mutagenicity
Ox. Sol. : Oxidizing solids
Repr. : Reproductive toxicity
Resp. Sens. : Respiratory sensitisation
Skin Corr. : Skin corrosion
Skin Sens. : Skin sensitisation
STOT RE : Specific target organ toxicity - repeated exposure
STOT SE : Specific target organ toxicity - single exposure

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - Agreement concerning the International Carriage of Dangerous Goods by
Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society for the
Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation;
Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Canada);
ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006,
as amended
ShiftMax 120 Tab 6x6 0228 Page 30(30)
Substance key: SC0000901549 Revision Date: 29.07.2024
Date of last issue: 12.10.2023
Version : 4 - 2 / EU Date of printing : 16.08.2024

Accelerating Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very
High Concern; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals
Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances Control
Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative
Further information
Classification of the mixture: Classification procedure:
Acute Tox. 4 H302 Calculation method
Acute Tox. 4 H332 Calculation method
Skin Irrit. 2 H315 Calculation method
Eye Irrit. 2 H319 Calculation method
Resp. Sens. 1 H334 Calculation method
Skin Sens. 1 H317 Calculation method
Muta. 1B H340 Calculation method
Carc. 1A H350 Calculation method
STOT SE 3 H335 Calculation method
STOT RE 2 H373 Calculation method
Aquatic Acute 1 H400 Calculation method
Aquatic Chronic 1 H410 Calculation method

This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.

REG_EU / EN