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    Ce - 2

    Uploaded by

    Keshav Agrawal
    chemical equilibrium

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    © All Rights Reserved
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    Ce - 2

    Uploaded by

    Keshav Agrawal
    5 views3 pages
    chemical equilibrium

    Original Title

    CE - 2

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    © © All Rights Reserved

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    PDF, TXT or read online from Scribd

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    chemical equilibrium

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    5 views3 pages

    Ce - 2

    Uploaded by

    Keshav Agrawal
    chemical equilibrium

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 3

    (Expression of k, &k Relation between k, & ke)

    LEVEL- 1
    1. For the system 3A + 2B C, the what is the expression for equilibrium constant

    2. In the reversible reaction A + B C+ D the concentration of eachCand D at equilibrium is 0.4


    mole/litre and concentration of A and B is 0.6 mo/litre, what is the equilibrium constant K ?

    3 Find the value of K, in the reaction MgCOss) MgO,, +CO9) ?


    4 The reaction 2HCI (g) Hlg) + Ch(g) has K= 3.2 x 10 at 298 K. The initial partial pressures are H2.
    1.0 bar; HCI, 2.0 bar; Clz, 3.0 bar. At equilibrium there is 1.0 mol Hg). What is the volume of the container?
    5 When 3 moles of ethyl alcohol are mixed with 3 moles of acetic acid, 2 moles of ester are formed at
    equilibrium according to the equation CH,COOH(I) +C,H,0H() CH,CO0C,H,() +H,0).What is the
    equilibrium constant for the reaction ?
    6. K, and K, are equilibrium constant for reactions (i) and ()
    N,(g) +O, (9) 2NO(g) .0

    NO(g)
    (0)o,(0)
    Then, What will be the relationship between k, and k,.
    ...(i)

    7. Identify the correct relation between K, and K, for the reaction aX( + bYg) bZ + aWa is
    8 For reaction N(g) + 3H2(9) 2NH,(g) at 400 K, K= 41. Find the value of Kfor each of the following
    reactions at same temperature
    a) 2NHg) N(g) + 3Ha(g)
    b) ½ N2g) + 3/2 H(9) NHs(g)
    c) 2N2(g) + 6H2(g) e4 NHs(g)

    9 If Kp fora reaction, A(g)+ 2B(g) = 3C(g)+D(g) is 0.05 atm at 1000 K. Find its K, in terms of R?

    10. One mole of nitrogen is mixed with three moles of hydrogen in a 4 litre conainer. If 0.25 per cent of nitrogen is
    converted to ammonia by the following reaction
    Ne(g) +3H,(g) 2NH(g),
    Calculate the equilibrium constant (K) in concentration units. What will be the value of K, for the following
    equilibrium?
    3
    NA9)+H9) NH(9)
    LEVEL -2

    11
    2NO9) 2NO, +Oggi K= 1.6x 10, NOe NOg K'=?
    1
    (a) K'= K (b) K'=
    (c) K'=K (d) K'=K1
    12 Carbon monoxide and water vapour, each at 200 torr, were introduced into a 250 mL container. When the
    mixture reached equilibrium at 700°C. The partial pressure of CO,g) was 88 torr. Calculate the value of Kfor
    the equilibrium.
    CO(g) + H,O(g) CO,(9) + Hz(g)
    (a) Kp = 0.5 (b) K,= 0.617
    (c) K, = 0.45 (d) K= 0.8
    13 5 moles of SO, and 5 moles of O, are allowed to react to form SO, in a closed vessel. At the equilibrium
    stage 60% of SO, is used up. The total number of moles of SO,, O, and SO, in the vessel now is
    (a) 10.0 (b) 8.5
    (c) 10.5 (d) 3.9
    14 If concentrations of N,, H, and NH, are 1, 2 and 3 respectively. Their concentration at equilibrium will be
    3H 2NH,
    (a) (1-x) (2-3x) 2x
    2x
    (2-x) 3
    (c) (1-x) (2-x) (3+ x)
    (d) (1-x) (2-3x) (3+2x)

    15 Select the reaction for which the equilibrium constant is written as [MX, =K[IMX,I [X,]
    (a) MX, = MX, (b) 2MX, MX, +X,
    (c) 2MX, + X, 2MX, (d) MX, MX,

    16 The equilibrium constant for the reversible reaction, N, +3H, 2NH, is K and for the reaction
    1 N, + H, NH, the equlibrium constant is K. Kand K' will be related as
    (a) K=K" (b) K'= VK
    (c) K=K (d) KxK'-1

    Paragraph for Questions 17& 20


    In a 7.0 L evacuated chamber, 0.50 mol H, and 0.50 mol l, reacts at 427°C.
    Hz(g) + l2g) HI(g)
    At the given temperature, K = 49 for the reaction
    17. What is K,
    (A) 7 (B) 49 (C) 24.5 (D) None of these

    18 what is the total pressure (atm) in the chamber


    (A) 83.14 (B) 831.4 (C) 8.21 (D) none of these

    19 How many moles of l, remain unreacted at equilibrium?


    (A) 0.388 (B) 0.112 (C) 0.25 (D) 0.125

    20. What is the partial pressure (atm) of HI in the equilibrium mixture?


    (A) 6.385 (B) 12.77 (C) 40.768 (D) 646.58
    ANSWERS KEY CHEMICAL EQUILIBRIUM - SHEET-2

    4
    2.
    9
    3 K, =Poo
    4 9.7x 10L
    5. 4

    6 K, =
    7 K, =K,
    8 a) 0.024
    b) 6.4
    C) 1.68 x 10
    9.
    5x 10
    R
    10 1.48x 10mol?, 3.82 x 10litre mofr
    11 D
    12
    13 B
    14 D
    15. C
    16
    17
    18
    19 B
    20. A

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