Date

Topic

CHEaSTRY

Name i
Avifa andey
Fathers ndomel- Mr. Mukesh Pondey

8S (matts)
Rollno 230019001907(22):

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 Topic Date...Sltl24

Puestinslosaens
Collision Theovy

Postulates
must collide fa a uxn to accU4
a (2). SRetiu tollišion- sy toltistans a
-only afuathion
lPectiue eechiue coltision mwt houl sulficieat

3). Actiotion Enexgy'- TheHe is ainimum eneHg4- Khoun

ackyction onaxgy aqui ed faarh toþxozeed

l4). Qerienkation of Peeeieles- The Llatiuo 0euientatoo

olliaing molecutes fs Cuuchae fou succeshu eh

L) Auequunty af colnsion!- the suate oteat Hon hcxcaeg

oithaun inOSein the conch osuatkant andtemherakaun

leoding to mage sequent ond enaugetlt cauisn

Assophonsi
U). lay clet axe in constoant Motion- Roactont hauticte

aluay mouing. ohc h leods tocaisicn

(2) colision aul Mandom! Caltision bus haticle
DccLLH ondomly o0d notin þtodtckoble monner

fuachonof collision hadk ip chemical HeaCkion

mast auu inejfe ue.

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 Date
Topic

Desivafon fox Rate

Fora bimoleculag

AB
Exþression

Rrn '
x faaLhonaf molecules
,
Rade

,-ba/er

whese 7 the callcion kuuguenty ofac kont AR

'
uaclion molecules oithenesty 4

qreatey than a egual to Ea

effictiunese
Facau a4fet ting coukon fugunty
Eacs a4fecing rotlision fuupunsq'
to
() co0cegtration! Highuy conch ouOctontleod
Mase uiqunt collžciong

incueoset tAe
Thuacing Temheuotase
)Temþeaku.
a tauqeu
L9). aSuyfac Aen- Eauasolid uacankc,
maye cotlicion to 0cY.
ylate auea allow)S
uuale canis ion ffectiueness.
factocy
U Colltsion mut occuswith re

Orientaton fa a yyn to toke ploca

mustiollide ith
Maleculea
2) Enexqy CA•£)!-
to ovexome the atHuation fnmqy
Bulficientenxgt
bawxien
louey thuattuntion eneogy
2) alalyet! atalyst can

effechunew y collit ion.

incaeasinq the
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 Date.
4 Topic

TeANS? TIONN Bale

Theosny
Achwated Comþley'

The artiuced comþler also Knocoo as the tcansition

aSdate,isa temhauay unstable aMongement of

atoms-ha toxms ckiuing thu Aransformo tiop fsom
Pactant to huauce

ahene bonds au þuutiay huokan au armed

The ncua ed comhley Canno t he isalacd,; it

exist fa UeNy hox time as the xn h oaseD

>The txanstion Qhat isthe highet enen qy þaint

Comeshondy to the actiucted com hlex bud embhasie
the enesgy athect
A this haint, the System hauthe higheat þotentias

Pneaqy and the eockant auin hutoceu beih

Conueate c to þetodutk
desiyahon of Rade Capstant!

neactant

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Ys the
Qctiuated comþlex
equilibaum consant
,
Topic Date

Now

Ohey 12i, vibxatianad fuquaty

Accox to uantum machanit& -

Acor: to clossical mechoni'CS

pulin e0)

4=LAJLR70

TAB kaT=

Acco.to Standad ibbe enzg

at equilierium,

then

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DOIOIOIOOO
Topic Date

RT

h
aiPoential Energy 96unfau'
Aþalential

a the
eny
enexgy fa
ylace

byeiem
ica toa cehtual

luhlcally
apLentatan.
intheconiext :
hosition of itt afoas.'ax f# nabs hou the
hatentfal onexqy changes eohen the tanligLYaho n
moleceler

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 Topic Date.

3. Companišon ba collision theory ond.

Brensition Slale thear

FOCUS theoxy emh has izes coLlion and

-collision

heiy chaLl euistis aohile dronsition stee heory

kendtcape ond
the formatibp
Cnengy
of daansitionstate
Ajplection- olis i'on theoxis similay and

theoxy pxaui de aa more

nmo detailed

1 o hìmolec ula
Nugeeicals
Eost Xh, he toll'SLon fequny
l2) 's 3-0X(6'°s- fth enexgy o Qctiuat'ons
7 kImol and emhexotun 998 k calcalate the
uete toslant (e)

2e-faer
Z= collision fregusnty a.0 La°

R Uniwexsal

Tembeutu lintatuin )
=30:27
RT
8-314X298
pdo•27
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,
 Topic
Date

=k= 7e-taleT

mol'sUSing TIdolexmin hHot Constuntat

310 k if t acthuotfon encsgy 's 5 okImal
enugys
kAe-€a le
KBeo Ae-taleT
kgooeE/e,
500
(20xlo-3)e&3+4go0 0

3:3YX300 futineg

-5000

Kl46AIomol/

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 Topic
Date

Q3 calcul ade the chongein Activation Enexgy

he
Naf e Con

0693

=-0:693 Eq
83/4 340 3r0
=-0-693=
3[o-34o
83/4 340X3o
-o693
8314 ||9000
- 0o693= -Coy:4o3XIo
8314

8403XLo-S
68S59 Tmol
8:4o3xIo 68-6kT

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