Maximum Marks: 80 20 questions: q Q Q π ε R
Maximum Marks: 80 20 questions: q Q Q π ε R
(d)
Kinematics 2-D (Projectile Motion) & √2( 4 π ε 0 R)
Electrostatics 3. A charge Q is distributed uniformly within the
material of a hollow sphere of inner and outer
PART-1 : PHYSICS radii r1 and r2 (See figure). The electric field at
SECTION-I : ( Maximum Marks: 80) distance x from centre for r1< x < r2 will be
This section contains 20 questions. Each
question has 4 options for correct answer.
Multiple-Choice Questions
(MCQs) Only one option is correct. For
3 3
each question, Q(x −r 1 )
(a) 2 3
marks will be awarded as follows: 4 π ϵ 0 x r1
3 3
Full Marks : +4 If correct answer is Q(x −r 1 )
(b) 2 3 3
selected. 4 π ϵ 0 x (r 2 −r 1)
Qx
Zero Marks : 0 If none of the option (c ) 2 3 3
4 π ϵ 0 x (r 2−r 1)
is selected. 3 3
Q(x −r 1 )
Negative Marks : –1 If wrong option is (d ) 2 2 2
4 π ϵ 0 x (r 2−r 1)
selected.
4. A few electric field lines for a system of two
1. A thin disc of radius b = 2a has a concentric hole charges Q and Q fixed at two different points on
of radius 'a' in it (see figure). It carries uniform the x-axis are shown in the figure. These lines
surface charge 'σ' on it. If the electric field on its suggest that :-
axis at height 'h' (h << a) from the centre is
given as 'Ch' then value of 'C' is :-
σ
(a) 4 a ε (A) |Q| = |Q|
0
(B) |Q| < |Q|
σ
(b ) (C) at a finite distance to the left of Q the
2 a ε0
electric field is zero
σ (D) at a finite distance to the right of Q the
(c )
8 a ε0 electric field is zero
σ 5. A dipole is placed at origin of coordinate system
(d) a ε as shown in figure, find the electric field at point
0
(√ 52 ) kPy
work done in moving a charge q from the centre
of one ring to that of the other is:- (a) 3
(a) Zero
kP
(b) √ 5 3
q(Q 1−Q2)( √ 2−1) y
(b)
√ 2(4 π ε 0 R) (c ) ( √ 32 ) kPy
3
q(Q 1−Q2) kP
(c)
(4 π ε 0 R) (d ) √3 3
y
6. Figure given shows four arrangement of charged the axis of cylinder is along X-axis and its
particles, all at the same distance from the centre coincides with origin. The total charge
origin. Rank the situations according to the net inside the cylinder is : [Take : ε = 8.85 × 10-12
electric potentials (V1, V2, V3, V4) at the origin, C2/N–m2]
(a) 0 (b) 1.86 × 10-5 C
-11
(c) 1.77 × 10 C (d) 35.4 × 10-8 C
11. A Tennis ba l is released from a height h and
after freely fa ling on a wooden floor it rebounds
h
and reaches height . . The velocity versus
2
most positive first : height of the ba l during its motion may be
(a) V1 >V2 > V3 > V4 represented graphica ly by :
(b)V2 >V1 > V3 > V4 (graph are drawn schematica ly and on not to scale)
(c) V2 >V1 > V4 > V3
(d) V4 >V1 > V3 > V2
7. As shown in the figure, an insulating rod is set
into the shape of a semicircle. The left half of
the rod has a charge of + Q uniformly
distributed along its length, and the right half of
the rod has a charge of–Q uniformly distributed
along its length. What vector shows the correct
direction of the electric field at point P, the
centre of the semicircle?
(a) A (b) B
( )
2 /3
selected. k1 k2
If overall rate constant,K= , then overall
1. Consider following two reaction, k3
d[A] activation energy of the reaction will be :
A → Product ; – = k1[A]0
dt (a) 140 kJ/mol (b) 150 kJ/mol
d [B] (c) 130 kJ/mol (d) 120 kJ/mol
B → Product ; – = k2[B]
dt 7. For a chemical reaction 3O2 → 2O3 the rate of
Units of k1 and k2 are expressed in terms of formation of O3 is 0.04 mole lit-1 sec-1 .
molarity (mol L-1 ) and time (sec-1 ) as : Determine the rate of disappearance of O2 :
(a) sec-1 , M sec-1 (b)M sec-1 , M sec-1 (a) 0.04 mol lit-1 sec-1 (b) 0.08 mol lit-1 sec-1
-1 -1
(c) sec , M sec -1
(d)M sec-1 , sec-1 (c) 0.10 mol lit-1 sec-1 (d) 0.06 mol lit-1 sec-1
2. For the reaction, following data is given, 8. The potential energy diagram for reaction A → B
−2000 is. The activation energy of reaction is :
A → B ; K1 = 1015 × e T
−1000
C→ D ; K2 = 1014 × e T The temperature
at which K1 = K2 is :-
(a) 1000 K (b) 2000 K
(c) 868.4 K (d) 434.22 K (a)X (b) X + Z
3. In first order reaction initial concentration of (c) Y (d) X – Y
reaction is 20M. Find the time in which 9. For a chemical reaction, A + 2B → C + D, the
concentration is reduced up to 2M and half rate of reaction increases three times, when
life of reaction is 5 Min. concentration of A only is increased to nine
(a) 20 minute (b) 10 minute times. While when concentration of B only is
(c) 16.6 minute (d) 24.6 minute increased 2 times, then rate of reaction also
4. The following data is given for reaction becomes 2 times. The order of this reaction is
between A and B : (a) 3 (b) 3/2
(c) 1/2 (d)None of these
10.Reaction :
−¿¿
2 Br + H2O2 + 2H+ → Br2 + 2H2O
take place in two steps :
+ H+ + H2O2 slow
−¿¿
(a) Br →
HOBr + H2O
+ H + fast
−¿¿
(b) HOBr + Br →
H2O + Br2
Which of the following are correct statements
The order of the reaction is-
(a) 3 (b) 6
(a) Rate constant of the reaction 10–4
(c) 2 (d) 0
(b) Rate law of the reaction is k[A][B]
11. Which of the following oxides is amphoteric in
(c) Rate of reaction increases four times on
character ?
doubling the concentration of both the reactant.
(a) SnO2 (b) SiO2
(A) a, b and c (B) a and b
(c) CO2 (d) CaO
(C) b and c (D) c alone
12. Which represents correct order of acidic
5. Find the ratio of time to for zero order reaction.
strength ?
(a) 4 : 15 (b) 2 : 15
(a)NH3 > PH3 > AsH3 > SbH3 > BiH3
(c) 1 : 15 (d)None of these
(b) La(OH)3 > Nd(OH)3 > Lu (OH)3 1
(c) n = 4, l = 3, m = + 1, s = +
(c) NaOH < KOH < RbOH < CsOH 2
(d)CH4 < H2S < HCl < HI 1
13. Arrange the following statements in order of (d) n = 4, l = 3, m = + 4, s = +
2
True(T)/False (F) : (a) Among Li+ , Be+ and B+ SECTION-II : (Maximum Marks: 20)
ions Li+ has the highest ionization enthalpy This section contains 10 questions Candidates
(b) The negative value of electron gain enthalpy have to attempt any 5 questions out of 10. If
of Cl > F because there is weak electron-electron more than 5 questions are attempted, then
repulsion in the bigger 3p-subshell of Cl as only first 5 attempted questions will be
compared to compact 2p-subshell of F evaluated.
(c) Formation of S-2 and Ar- , both require the The answer to each question is a Numerical
absorption of energy Value. For each question, enter the correct
(d) Incorrect order of electron affinity is S > Se > integer value (In case of non-integer value, the
Te > O answer should be rounded off to the nearest
(a) TTTF (b) FFFT Integer). Answer to each question will be
(c) FFTT (d) TTTT evaluated according to the following marking
14. Which of the following electronegativity order is scheme:
not correct ? Full Marks : +4 If correct answer is
(a)Al < Ga (b) Tl < In entered.
(c) Sr < Ca (d)C < Br Zero Marks : 0 If the question is
15. An element whose IUPAC name is Ununnilium unanswered.
(Uun) belongs to : Negative Marks : –1 If wrong answer is
(a) s-block (b) p-block entered.
(c) d-block (d) f-block
16. The correct order of increasing electron affinity
of the following elements is : 1. Following figure shows a graph in log10 K vs
(a)O < S < F < Cl (b) O < S < Cl < F 1
where K is rate constant and T is
(c) S < O < F < Cl (d) S < O < Cl < F T
17. In the sixth period, the orbitals being filled are : temperature. The straight line BC has
(a) 5s, 5p, 5d (b) 6s, 6p, 6d, 6f 1
slope, tanθ = – and an intercept of 5
(c) 6s, 5f, 6d, 6p (d) 6s, 4f, 5d, 6p 2.303
18. Arrange the following in increasing order of
energy :
(i) n = 4, l = 2, m = –1, s = +½
(ii) n = 3, l = 2, m = –1, s = –½
(iii) n = 4, l = 0, m = 0, s = +½
(iv) n = 5, l = 0, m = 0, s = –½ on Y-axis Thus Ea, the energy of activation
(A) (i) < (ii) < (iii) < (iv) is (in calorie) :
(B) (iii) < (ii) < (iv) < (i)
2. For a certain reaction involving a single
(C) (iii) < (iv) < (ii) < (i)
(D) (ii) < (iii) < (i) < (iv) √
reactant, It is found thatC 0 t 1 is constant
2
19. In an atom, the total number of electrons having
where C0 is the Initial concentration of
1
quantum numbers n = 4, |ml | = 1 and ms = –
2 reactant and t 1 is the half life. The order of
2
is : (a) 6 (b) 7 reaction is –
(c) 8 (d) 9 3. For a first order reaction time required for
20. Which of the following sets of quantum number completion of 99% reaction is 10 minute.
is correct for an electron in 4f orbital ? Calculate time required for completion of
1 99.9% of reaction. (In minute)
(a) n = 3, l = 2, m = – 2, s = +
2 4. Two substances A (t 1/ 2 = 5 mins) and B (t 1/ 2
1 = 15 mins) follow first order kinetics are
(b) n = 4, l = 4, m = – 4, s = –
2 taken in such a way that initially [A] = 4[B].
Calculate the time after which the
concentration of both the substance will be (b) b, c and a are in G.P.
equal (c) b, c and a are in A.P.
5. For a 1st order reaction, find ratio of t75 % (d) a, b and c are in A.P.
tot50%. where t 75% is time for 75% 6. If (m + 1)th , (n + 1)th and (r + 1)th terms of an
completion of reaction. A.P are in G.P. and m, n, r are in H.P. the
6. How many of these have less electron ratio of common difference of A.P to the first
negativity than oxygen ? B,C,N, F, S, Se, P, term is :
Cl, Li, Na 2 −2
(a) (b)
7. Most stable oxidation state of thallium is +n. n n
What is the value of n? n −n
8. Sum of unpaired electrons in the ground (c) (d)
2 2
state of sulphur and number of electrons in 7. Number of integral solutions of
oxygen for which ℓ = 0. F(x)
9. n = 5, m = –1/2, How many orbitals are
√ log (4 sin 2
x−2 √ 3 sinx−2 sinx+ √ 3+1)
in x ∈ [–π, π] is :
2
possible :
10. How many unpaired electrons are present in
Cu+? (A) 4 (B) 5
Topic: Logarithms (Basic Maths), (C) 6 (D) 3
Sequence & Series, Limit, Continuity & 8. If a, b, c ∈ R+ and are in G.P. and log ( 5ac )
Differentiability
one solution (B) two solutions (C) no are the lengths of sides of :-
solution (D) three soutions (a) Equilateral triangle
2. The sum of the 24 terms of the series (b) Accute angle triangle
√ 2+ √ 8+ √ 18+ √ 32+.... is :- (c) Obtuse angle triangle
(A) 300 (B) 300 √ 2 (d)None of them
(C) 200 (D) 200 √ 2 9. If (10)9 + 2(11)1 (10)8 + 3(11)2 (10)7 + ......+
3.
√ ⏟
111… ⏟
… .1 −222
200digits
… … ..2 equal:-
100 digitd
10 (11)9 = k (10)9 , then k is equal to :
(a)
121
(b)
441
√ ⏟
1313 … … .13 10 100
(a)
100 digits (c) 100 (d) 110
√⏟
( b ) 33 … … .3 10. If lnx – ln y = a, lny – lnz = b and lnz – lnx =
100digits
c then the value of
√⏟ () () ()
b−c c−a a−b
2323 … … .23 x y z
(c) × × is :
100 digits y z x
(a)
α
β
(b)
β
α
12. (i)lim ¿ x → ∞sec-1( sinx x ) and
(c)
√ α
β
5. For any three positive real numbers a, b and
(d)
√ β
α
(ii) lim ¿ x → ∞sec (
x )
sin x -1
( )
4 π
2
x−
2 20. K =
16
(∑ )
1000
( x + K )m
(a) (b)
8 2 lim ¿ x → ∞ is (m>101):-
f (2) f (2) k=1
m
x +10
1000
π π
(c) f (2) (d) f (2)
(a) 10 (b) 10
2 4
(c) 10 (d) 104
π π
SECTION-II : (Maximum Marks: 20)
This section contains 10 questions
14. Which of the following functions are
Candidates have to attempt any 5
discontinouous at x = 100 ?
questions out of 10. If more than 5
(a) (x – 100) |x – 100|
questions are attempted, then only first 5
(b) (x – 100) [x – 100]
attempted questions will be evaluated.
(c) sgn (x – 100)
The answer to each question is a Numerical
(d) tan (x – 100)
2
Value. For each question, enter the correct
15. If function f(x) =
( 3 x −1 ) x ≠ 0, is integer value (In case of non-integer value,
sinx . l n (1+ x ) the answer should be rounded off to the
continuous at x = 0. Then the value of f(0) nearest Integer). Answer to each question
is:- will be evaluated according to the following
(a) 2log3e (b) (loge3)2 marking scheme:
6
(C) log2 (d) loge6 Full Marks : +4 If correct answer is
{
√1+ px−√ 1− px ,−1 ≤ x< 0 entered.
x Zero Marks : 0 If the question is
16. If f(x) = is unanswered.
2 x+1
, 0≤ x ≤1 Negative Marks : –1 If wrong answer is
x−2
entered.
continuous in the interval [–1, 1] then p
1. Sum of all the solution(s) of the equation
equals
log10(x) + log10(x + 2) – log10(5x + 4) = 0 is-
(a)– 1 (b) 1
2. Number of negative integers satisfying the
(c) 1/2 (d)–1/2
inequality (log (100x))2 + (log 10x)2 + log10x
17. If the function ≤ 14
g(x) = {kmx+2
√ x +1 , 0 ≤ x ≤3
, 3< x ≤5
is differentiable, 3. If loga3 = 2 & logb8 = 3 then logab equal log3k
then k = ?
then value of k + m is- 4. If the third term of an A.P is 7 and its
10 7th term is 2 more than three times of its
(a) (b) 4
3 3rd term, then sum of its first 20 terms is :-
16 75
(c) 2 (d) 5. The A.M of two number is and G.M is
5 4
18. If f(x) = {
x+ { x } + xsin { x } : x ≠0
0 ; x=0 6.
15 the value of larger number is :-
Number of points where
{
where {x} denotes the fractional part max (|x −x −2| , x −3 x ) : x ≥ 0
2 2
{
3 2 2
x , x <1 x
19. If f(x)= 2 then f(x) is differentiable
x, x ≥1 equal to
at
(a) (–∞, ∞) ~ {1}
8. Let f(x) = [2x3 – 5]; then number of points
in (1, 2) where the function is discontinuous
are where [.] → G.I.F.