Volumetric Exp - 1 & 2

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VoLumeTaic ANALY" ™ Ex'T(Ruled | ESTIMATION OF KMnOx SOLUTION USING STANDARD FAS goLUTION AIM To estimate the strength of the given 4720 ferrous ammonium sulphate solution. MATERIALS REQUIRED = Burette , Pipette, M/20 FAS, KMnO , standard flask. PRINCIPLE = KMnO, reacts with FAS at room temperature. It is a redox titration « Manganese is reduced (+7 to +2) and Fe is oxidized (+2 to +3) MnO; +8H* +5¢° ———» Mn” +410 [Fe 9 ———+_ Fe" te] x5 oe MnO, + 8H'+ SFe"” ———* Mn” +4110 + SFe" SIMPLE PROCEDURE : Burette Solution : KMnO4 Pipette Solution = 20mI of std. FAS KMnO, solution using the standard dil:Hy SOx Funnel, conical flask, Temperature — : Room temperature Medium 20m! of 2N dil. H:SO, (Acidic medium) Indicator : KMn0, (self) End point : Appearance of pale permanent pink colour. RESULT: M. 1. The molarity of the KMnO, solution is 2. The strength of KMnQ, solution with standard M/20 FAS is. ‘Scanned wih CamScanner fer it in 250ml standard flask. {ferrous sulphate dissolve them in standard flask, ans! Add Sm of cone. soe eh 49g of FAS and water to prepare 250 im ie check hydrolysis © 0 FAS solution Weight sae we gpoq2s0el/ 00x20 Molarity of FAS =4,9g in 250m. Molecular mass — =M/20 or 0.05 M OBSERVATION: = 302g Concordant Volume of KMn0, (ml) k ue a Final. (ml) | CALCULATION ; | moles of KMnQy reacts EX 5 51 (Unru led , p encl I) M2V;/ MV, = 1/5 M,— Molarity of Mohr's salt (M20) = 0.05M — Volume of standard Mohr’s salt = 20 m| V2 - Volume of KMnQ, = M; - Molarity of KMnO, =1 x ViMi/ SV, = M. Strength of KMnO,= Molarity of KMn0« *Moleculac mass of eavancy 4 x 158g g/l. ‘Scanned wih CamScanner prion! soll? B sino) ESTIMATION OF MOU ACID SOLUTION AIM : tla (Ruled) + estimate the strengt OF MS the stan in To esti M/S0 solution of oxalic acl MATERIALS REQUIRED acid, KMNO« :AILILS0, Burette , Pipette, M/S0 ON 250ml standard flask. Fi UIMNEL, conical flask 4 at room 60°C 79%, 4 + "is a redox titration, PRINCIPLE : ¢), Oxalate ion js oi, ized KMnQ, reacts with Manganese is reduce’ [Mno, +811" +5 [C;0.2——_ 20 He I x5 Oxatic ne! y7ito4 + Mn" +411,0) x 2MnOg + 16+ SC 104° ————»_2Mn" + 810+ 100; SIMPLE PROCEDURE : Burette Solution; KMnO, Pipette Solution = 20ml of std. Oxalic acid Temperature : 60°c-70"c Medium : 20ml of 2N ail, H,8Oe (Acidic medion) Indicator + KMn0, (self) End point ‘Appearance of ‘pale permanent pink colour. RESULT: M. 1, The molarit: jon i ) Y of the ution dard MI 2. The strength Tk 30 with standard M/50 INQ, solution oxalic acid jg gf ‘Scanned wih CamScanner OBSERVATIONS: Weigh 0.63 g of Oxalic agi 1A . > i; cid and transfer it in 250ml standard flask, water to prepare 20 ml of MUSO Oxatic acid solution in o standard flask,” Sd eight of Oxalic acig = 126 x250x1/1000x50 =0,63g in 250ml. Molarity of oxalic acid s, ol - .02 M Molecular mass. of Oxalic acid ae wre OBSERVATION : qaliine of Volume of Concordant xalic acid KMnQ, (ml) | value of KMn0, (ml) used (nil) Initial} Final 20 0 20 0 20 0 catcutation: [xX 2 (Unruled, pencil) 2 moles of KMn04 reacts with 5 moles of Oxalie acid M;V;/M,V, = 2/5 M,- Molarity of Oxalic acid (M/50) = 0.02M V,- Volume of standard Oxalic acid = 20 ml V; - Volume of KMnO, M, - Molarity of KMnO, = 25 ViMV/5¥, = M. Strength of KMnO, = Molarity of KMnOs x Molecular mass of KMn0i x 158 g/l = gl. a ‘Scanned wih CamScanner

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