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    SOLUTIONS WORKSHEET - 12th

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    Riya Bell

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    SOLUTIONS WORKSHEET - 12th

    Uploaded by

    Riya Bell
    4 views6 pages

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    SOLUTIONS WORKSHEET- 12th

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    4 views6 pages

    SOLUTIONS WORKSHEET - 12th

    Uploaded by

    Riya Bell

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 6

    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    1. The experimentally determined molar mass for what type of substances is always
    lower than the true value when water is used as solvent. Explain. Give one example
    of such a substance and one example of a substance which does not show a large
    variation from the true value.
    When there is dissociation of solute into ions, in dilute solutions (ignoring interionic
    attractions) the number of particles increases. As the value of colligative properties
    depends on the number of particles of the solute , the experimentally observed value of
    colligative property will be higher than the true value, therefore the experimentally
    determined (observed) molar mass is always lower than the true value.
    For KCl(electrolyte) the experimentally determined molar mass is always lower than the
    true value when water is used as solvent. Glucose (non-electrolyte) does not show a
    large variation from the true value.

    2. Calculate the freezing point of a solution containing 0.5 g KCl (Molar mass = 74.5g/mol)
    dissolved in 100 g water, assuming KCl to be 92% ionized. Kf of water = 1.86 K kg / mol.

    3. Calculate the freezing point of a solution containing 8.1 g of HBr in 100 g of water,
    assuming the acid to be 90 % ionized. [Given: Molar mass Br = 81 g/mol,
    Kf water = 1.86 K kg / mol]

    4. Calculate the molality of ethanol solution in which the mole fraction of water is 0.88.
    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    5. Give reasons for the following:


    a. When 2g of benzoic acid is dissolved in 25 g of benzene, the experimentally
    determined molar mass is always greater than the true value.
    b. Mixture of ethanol and acetone shows positive deviation from Raoult’s Law.
    c. The preservation of fruits by adding concentrated sugar solution protects against
    bacterial action.

    6.

    7.
    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    8.

    9. Give reasons for the following:


    (a) Measurement of osmotic pressure method is preferred for the determination of
    molar masses of macromolecules such as proteins and polymers.
    (b) Aquatic animals are more comfortable in cold water than in warm water.
    (c) Elevation of boiling point of 1 M KCl solution is nearly double than that of 1 M sugar
    solution.

    10.

    11.
    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    12.

    13.
    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    14.

    15.

    16. Define osmotic pressure of a solution. How is the osmotic pressure related to the
    concentration of a solute in a solution ?
    SOLUTIONS WORKSHEET 1 – CBSE QUESTIONS

    17.

    18.

    19.

    20.

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