Part Test-2 - PCM
Part Test-2 - PCM
INSTRUCTIONS
Do Not open the Test Booklet until you are asked to do so.
Read all the instructions carefully before start of the test.
1. Test Booklet consists of 90 questions. Please write your name on the top of this test booklet.
2. The Answer Sheet is give at the end of the booklet. Please fill all the particulars on the answer
sheet before attempting the questions.
3. There are three parts in the question paper of Physics, Chemistry and Mathematics having
30 questions in each subject and each subject having Two sections.
(i) Each subject contains 20 multiple choice questions with Only One Correct option.
Marking scheme : +4 for correct answer and 0 if not attempted and –1 in all other cases.
(ii) Each subject contains 10 Integer Type Questions.
Attempt any five Integer Type Questions.
Marking scheme : +4 for correct answer and 0 if not attempted and –1 in all other cases.
4. Use Blue/Black Ball point pen only for writting particulars/marking responses on the OMR
sheet. Use of Pencil is strictly prohibited.
5. Space for rough work is provided at the end.
6. Use of any unfair means during the exam will result in disqualification from attending the tests
further.
JEE/PT-002
2
PHYSICS Q.6 In the figure, pulleys are smooth and strings are
SECTION -A
1
OBJECTIVEQUESTIONS (MCQs) massless. m1 = 1kg and m2 = kg. To keep m3 at rest,
Q.1 Two blocks whose sum of masses is 1 kg were arranged 3
as shown. Acceleration of blocks is twice, when A is mass m3 should be :
hanging that of when B is hanging, the mass of A is
(neglect friction)
B smooth
A
1 1 2 2
(1) kg (2) kg (3) kg (4) kg m3
3 4 5 3
m F=20N
(1) 0 ms–2 (2) 0.8 ms–2 (3) 0.4 ms–2 (4) 3.2 ms–2
Q.5 A body of mass 6 kg moves in a straight line according Q.9 A particle performs circular motion of radius 1m from
to equation x = t2 – 40t where x denotes the distance in rest. The tangential accelration of the particle at any
metre and t the time in seconds. The net force on the time t is given by at = t ms–2. The radial acceleration of
body at t = 4 second is the particle at t = 2 sec is
(1) 12 N (2) 6 N (3) 60 N (4) 144 N (1) 1 ms–2 (2) 2 ms–2 (3) 0.5 ms–2 (4) 4 ms–2
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Q.10 Two particles starts moving on the same circle of radius Q.15 A slab S of mass 1 kg is released from a height of 1cm
2 m, from the same point P at t = 0, with constant from the top of a spring S' of force constant 780 N/m.
tangential accelerations = 2 m/s2 and 6 m/s2, clockwise The maximum compression x of the spring will be :
and anticlockwise, respectively. The point where they
meet for the first time is Q. The smaller angle subtended S
by PQ at center of circle is h0
(1) 120° (2) 60° (3) 135° (4) 90°
t t
S S
(1) 12 m/s (2) 10.5 m/s
(3) 14 m/s (4) All of these
(3) (4)
Q.13 The potential energy of a diatomic molecule is given
A B t t
by U = – 6 . A and B are positive constants. The
r12 r
distance r between them at equilibrium is Q.17 The work done by a force F (6x 3 ˆi) N in displacing
1/ 6 1/ 6
A 2A a particle from x = 4 m to x = –2 m is
(1) (2) (1) –240 J (2) 360 J
B B
(3) 420 J (4) will depend upon the path
1/ 6
A
(3) (4) None of these Q.18 A porter lifts a heavy suitcase of mass 80 kg and at the
2B
destination lowers it down by a distance of 80 cm with
a constant velocity. Calculate the workdone by the
Q.14 An elevator in a building can carry a maximum of 10 porter in lowering the suitcase. (take g = 9.8 ms–2)
persons, with the average mass of each person being (1) –62720.0 J (2) –627.2 J
68 kg. The mass of the elevator itself is 920 kg and it (3) +627.2 J (4) 784.0 J
moves with a constant speed of 3 m/s. The frictional
force opposing the motion is 6000 N. If the elevator is Q.19 Given below is the plot of a potential energy function
moving up with its full capacity, the power delivered U(x) for a system, in which a particle is in one
by the motor to the elevator (g = 10 m/s2) must be at dimensional motion, while a conservative force F(x)
least: acts on it. Suppose that Emech = 8 J, the incorrect
(1) 62360 W (2) 56300W statement for this system is :
(3) 48000W (4) 66000W
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Q.3 A given object takes 2 times as much time to slide
U(J) down at 45° rough incline as it takes to slide down a
perfectly smooth 45° incline. The coefficient of kinetic
10
Emech = 8J friction between the object and the incline is given by
8 µk. Then 100µk = ............................
6
Q.4 In figure shown, the upper block has mass 3 kg and
4 the lower block has mass 5 kg. The uniform vertical
2 rope joining the two has a length of 1 m, and a mass of
2 kg. The constant vertical force F = 200 N is acting on
0 x1 x2 x3 x4 the upper block, and pulling the system upwards with
x
some acceleration. Find the tension at the mid point of
[where K.E. = kinetic energy] the rope (in N)
(1) at x > x4, K.E. is constant throughout the region.
(2) at x < x1, K.E. is smallest and the particle is moving
at the slowest speed.
(3) at x = x2, K.E. is greatest and the particle is moving
at the fastest speed.
(4) at x = x3, K.E. = 4 J
1
is – mv 2 and speed of the body is 2v. Then, the Q.5 In the arrangement shown in the figure, the pulleys
2 are all massless. The load has a mass of 21 kg. The
work done by F2 is: point P is moved by a distance of 2.5 cm. Find the
minimum work (in J) required to be done by the force.
3 2
(1) mv (2) mv2
2
(3) zero (4) 2mv2
P
SECTION - B
F
INTEGERTYPEQUESTION
Q.1 A body of mass 1 kg rests on a horizontal floor with
1
which it has a coefficient of static friction . It is 21 kg
3
desired to make the body move by applying the mini-
mum possible force F N. The value of F will be
Q.6 Compute the least acceleration (in m/s2) with which a
__________. (Round off to the Nearest Integer)
50 kg man can slide down a rope, if the rope can with-
[Take g = 10 ms–2]
stand a tension of 300 N.
Q.2 A constant force, F = 40 N, is applied to the massless
Q.7 A right circular cone is fixed with its axis vertical and
string connected to a block which starts from rest on a
vertex down. A particle is in contact with its smooth
fixed incline.
inside surface and describes circular motion in a
horizontal plane
at a height of 20cm above the vertex. Its velocity
is x m/s. The value of x is..........
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. Then the ratio of P1 & P2 is
Q.8 A particle is moved by a force F 20 ˆi 30 ˆj 15kˆ
along a straight line from point A to point B with 4 7
(1) (2)
5 4
position vectors 2 ˆi 7 ˆj 3kˆ and 5iˆ 3 ˆj 6 kˆ
respectively. Find the work done (in joule) 4
(3) (4) None of these
7
Q.9 A 300 kg piano is being lifted at a constant speed by a
crane from ground to an apartment 24m high. The crane Q.6 If K1 = 10–7 M and K2 = 10–15 M are the equilibrium
being used has a constant power of 960 W. What is constants for the reactions,
the time (in sec.) taken for the lift ? H2S H+ + HS– K1= 10–7 M
and HS– H+ + S2– K2= 10–15 M then calculate
Q.10 A body of mass 1kg starts moving from rest at t = 0 in concentration of [S2–] if [H+] = 10–3 M and [H2S] = 0.1
a circular path of radius 8m. Its kinetic energy varies M in the equilibrium mixture.
with time as k = 2t2 J then magnitude of centripetal (1) [S2– ] = 10–13 M (2) [S2– ] = 10–17 M
acceleration (in m/s2) at t = 2s is: 2–
(3) [S ] = 10 M–5 (4) [S2– ] = 10–7 M
CHEMISTRY Q.7 For gas phase reaction :
SECTION -A Cl2(g) + HBr(g) HCl(g) + Br2(g) H = – 66 kJ/mole
OBJECTIVEQUESTIONS (MCQs) activation energy for reaction is 7 kJ/mol. Then what
Q.1 The equilibrium constant expression for theequilibrium will be the activation energy for reverse reaction :
2NH3(g) + 2O2(g) N2O(g) + 3H2O(g) is (1) – 59 kJ/mol (2) + 59 kJ/mol
(3) – 73 kJ/mol (4) + 73 kJ/mol
[ N 2 O][H 2 O]3 [H 2 O]3 [ N 2 O]
(1) KC = (2) Kc =
[ NH 3 ][O 2 ] [ NH 3 ]2 [O 2 ]2 Q.8 Liquid NH3 ionises to a slight extent. At a certain temp.
it's self ionization constant KSIC(NH3 ) = 10–30. The
2 2
[ NH 3 ] [O 2 ] [ NH 3 ][O 2 ] number of NH4+ ions are present per 100 cm3 of pure
(3) Kc = (4) Kc = [ N O][H O]
3
[ N 2 O][H 2 O] 2 2 liquid are
(1) 10–15 (2) 6.022 × 108
(3) 6.022 × 107 (4) none
Q.2 For which of the following KP is less than Kc?
(1) N2O4 2NO2 Q.9 What volume of 0.2 M NH4Cl solution should be added
(2) N2 + 3H2 2NH3 to 100 ml of 0.1 M NH4OH solution to produce a buffer
solution of pH = 8.7?
(3) H2 + I2 2HI Given : pKb of NH4OH = 4.7 ; anti log 0.6 = 4
(4) CO + H2O CO2 + H2 (1) 50 ml (2) 100 ml
(3) 200 ml (4) none of these
Q.3 A 1 litre container contains 2 moles of PCl5 initially. If
at equilibrium , K C is found to be 1, degree of Q.10 If Ka of RNH3+ (aq) is 10–5 M at 25°C, then equilibrium
dissociation of PCl5 is - constant of the given reaction is
RNH2 (aq) + HCl (aq) RNH3+ (aq) + Cl¯ (aq)
1 (1) 10–5 M (2) 105 M
(1) 4 (2) 3 (3) (4) 50 –9
2 (3) 10 M (4) 109 M
Q.4 Nitrogen gas was injected into an equilibrium mixture Q.11 K a1 , K a 2 and K a3 are the three dissociation constants
of 2SO3(g) 2SO2(g) + O2(g)? The pressure is
increased from 1.0 atm to 10 atm. of H3PO4. Which of the following is a correct order
Which of the following statements is correct - (1) K a1 > K a 2 < K a3 (2) K a1 > K a 2 > K a3
(1) The concentration of the reacting gases are
unchanged. (3) K a3 > K a 2 > K a1 (4) None of these
(2) [SO3] increases
(3) [SO2] increases Q.12 For the reaction at 300 K
(4) [O2] increases A(g) + B(g) C (g)
E = –3.0 kcal ; S = – 10.0 cal/K
Q.5 At same temperature N2O4 is dissociated to 40% & value of G is
50% at total pressure P1 & P2 atm respectively in NO2 (1) –600 cal (2) –6600 cal
(3) –6000 cal (4) None
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Q.13 Calculate f H° (in kJ/mol) for Cr2O3 from the rG° and Q.20 The incorrect expression among the following is :
the S° values provided at 27° G system
4Cr(s) + 3O2(g) 2Cr2O3(s) rG° = – 2093.4 kJ/mol (1) =–T
Stotal
S°(J/K mole) : S°Cr(s) = 24 ; SO2 (g) = 205 ; SCr2O3 (s) = 81
(1) –2258.1 (2) –946.35 Vf
(2) In isothermal process, wreversible = –nRT ln V
(3) –1129.05 (4) None i
Hº TSº
Q.14 A student found that 310 kJ of energy was released on (3) lnK =
burning 10 g of propan-1-ol, CH3CH2CH2OH. From this RT
experiment, what is the enthalpy of combustion, in (4) K = e–Gº/RT
kJmol–1, of propan-1-ol?
SECTION - B
(1) –310 (2) –1296
INTEGERTYPEQUESTIONS
(3) –1860 (4) –3100
Q.1 H3A is a weak triprotic acid ( K a = 10–5 , K a =10–9,
1 2
Q.15 A system undergoes a process in which system releases
200 J heat and workdone by the surroundings is 300J. K a =10–13 ).
3
Change in internal energy of the system is :
(1) – 100 J (2) 100 J Calculate the value of pX of 0.1 M H3A (aq) solution
(3) – 500 J (4) 500 J [A3 ]
where pX = – log X & X = .
[HA 2 ]
Q.16 A reaction at 300 K with G° = – 1743 J /mol consists
of 3 mole of A (g), 6 mole of B (g) and 3 mole of C (g). If Q.2 Calculate the ratio of pH values of a 1M CH3COOH
A, B and C are in equilbrium in 1 litre container then solution and a solution containing equimolar mixture
the reaction may be of CH3COOH and CH3COONa. [Ka(CH3COOH) = 10–5
[Given : 2 = e0.7, R = 8.3 J/K - mol] M]
(1) A + B C (2) A B + 2C [If the ratio is 1 : 5, then answer as 0105]
(3) 2A B + C (4) A + B 2C
Q.3 How many millimoles of NH3 must be added to one
litre of 0.004 M-Ag+ solution to just prevent the
Q.17 For the reaction precipitation of AgCl, when [Cl–] reaches 0.001 M?
N2H4 (g) N2H2 (g) + H2(g) rH°= 109 kJ / mol [Given : Ksp of AgCl = 1.0 × 10–10 and Kinstability of
Calculate the bond enthalpy of N = N. Ag(NH3)2+ = 1.0 × 10–8] [Ans. 0028]
Given : B.E. (N–N) = 163 kJ/mol, B.E. (N–H) = 391 kJ/
mol, B.E. (H–H) = 436 kJ/mol Q.4 For a reaction,
(1) 182 kJ/mol (2) 218 kJ/mol 4C(g) + D(g)
2A(g) + 3B(g)
(3) 400 kJ/mol (4) None
322 2
Q.18 If Hvaporisation of (C2H5)2 O (l) is 350 J/g at it's boiling K oC
27
point 308 K, then molar entropy change for Calculate equilibrium concentration of C if 4 moles of
condensation process is A are mixed with 6 moles of B in 2 l container. Express
(1) 84.09 J/mol.K (2) – 84.09 J/mol.K your answer in moles per m3.
(3) –1.136 J/mol.K (4) None of these
Q.5 The equilibrium constant Kp for the reaction
Q.19 The enthalpy changes for the following process are 2NO2(g) is 4.5 at temperature T..
N2O4 (g)
listed below :
What would be the average molar mass (in gm/mol) of
Cl2(g) 2Cl(g), 242.3 kJ mol–1
an equilibrium mixture of N2O4 & NO2 formed by the
I2(g) 2I(g), 151.0 kJ mol–1 dissociation of pure N2O4 at a total pressure of 2 atm
ICl(g) I(g)+ Cl(g), 211.3 kJ mol–1 at temperature T.
I2(s) I2(g), 62.76 kJ mol–1
Given that the standard states for iodine and chlorine Q.6 At 1000K C(s), CaO(s) and CaCO3(s) are mixed and
are I2(s) and Cl2(g). The standard enthalpy of formation allowed to attain equilibrium at 1000K. What is the
of ICl(g) is pressure (in atm) of CO achieved ?
(1) – 14.6 kJ mol–1 [Given :
(2) – 16.8 kJ mol–1 CaCO3(s) CaO(s) + CO2(g) KP = 4 × 10–2 atm]
(3) + 16.8 kJ mol–1 C(s) + CO2(g) 2CO(g) KP = 1 atm]
(4) + 244.8 kJ mol–1
[Report your answer by multiplying it by 10 ]
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Q.7 The ion A+n is oxidised to AO3– by MnO4– in acidic
medium. 2.5 millimoles of A+n require 10 ml of 0.1 M Q.7 If sin2x + sin x cos x – 6 cos2x = 0 and < x < 0, then
2
KMnO4. What is value of 'n' ?
the value of sin 2x, is
Q.8 RH2 (cation exchange resin) can replace Ca+2
in a 3 3 2 4
sample of hard water as : (1) (2) (3) (4)
10 5 5 5
RH2 + Ca+2 RCa + 2H+
1 litre of such hard water is passed through a cation
exchange resin bed and the resultant solution requires Q.8 If sin 4 4 cos 4 2 = 4 2 sin cos ;
20 ml of 0.5 M NaOH solution for complete
neutralization. Hardness of water is × 102 ppm w.r.t. , [0, ] , then cos( ) cos( ) is
Ca+2. What is the value of ? equal to
(1) 2 (2) 2 (3) 0 (4) – 1
Q.9 An element A form two oxides. The weight ratio of A
and O in oxides are x : y and y : x respectively. If
32 3 3 x
equivalents weight of A in first oxide is . What is Q.9 If tan x = where p < x < , then value of cos
3 4 2 2
equivalent weight of A in second oxides? is
1 3 1 3
Q.10 In the titration of KMnO4 and oxalic acid in acidic (1) (2) (3) (4)
10 10 10 10
medium, change in oxidation number of carbon at the
end point is _______.
Q.10 Let cot = 2P + 3 and cot = 2P + 1 where P is
MATHEMATICS constant. If cosec2– cosec2 = 24 then the value of
SECTION-A tan (+ ), is
OBJECTIVE TYPEQUESTIONS(MCQS) 4 2P 3P
Q.1 Express 1·2 radians in degree measure. (1) (2) (3) (4)None of these
17 17 17
(1) 48º 33’ 37·8” (2) 68º 33’ 37·8”
(3) 48º 43’ 34·8” (4) 68º 43’ 37·8”
tan 3 sin 3
Q.11 If = 4, then the value of equals
Q.2 sin 65° + sin 43° – sin 29° – sin 7° is equal to tan sin
(1) cos 36° (2) cos 18° (3) cos 9° (4) cos 11°
5
(1) (2) 2
4 4 3 4 5 4 7 3
Q.3 Value of sin + sin + sin + sin is
8 8 8 8
8 10
equal to (3) (4)
3 3
1 1 3 3
(1) (2) (3) (4)
2 4 4 2 Q.12 Smallest positive angle satisfying the equation
4 log16(cos 2x) + 2 log4(sin x) + log2(cos x) + 3 = 0, is
Q.4 If x + y = 3 – cos 26º and x – y = 4 sin 13º, then (1) (12.5)° (2) 10° (3) (7.5)° (4) 5°
1 1
(1) x4 + y4 =9 (2) x 2 + y 2 = 16 Q.13 If is eliminated from the equations sec + tan =
p and sec · tan = q then
1 1 (1) p4 + 4p2q + 1 = 0 (2) p4 – 4p2q + 1 = 0
(3) x4 + y4 = 4 (4) x 2 + y2 = 2 4 2
(3) p + 4p q – 1 = 0 (4) p4 – 4p2q – 1 = 0
1024
Q.20 The value of
r2
log 2 cos r + log 2 sin 1024
2 2
is equal to
(1) – 1022 (2) – 1024 (3) – 1023 (4) None
SECTION-B
INTEGERTYPEQUESTIONS
2 4 8 16
Q.1 If A = cos cos cos cos and
15 15 15 15
B = sin36ºsin72ºsin108ºsin144º then the value of
8(A + B) is equal to
3
Q.2 If cos 2 = then 32 (sin · sin 5) equals
4
100 100
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