Chemical Kinetics Assignement 2023

Chemical Kinetics
Chemistry Assignment
Class – XII
BALAJI TUTORIALS NEET -IIT JEE CLASSES
JI
1. How is rate of reaction related to concentration of the reactants ?
2. What is meant by relative rates of reaction ? Write the relative rates expressions for the following
chemical reaction :
4NH3  g   5O 2  g  
 4NO  g   6H 2 O (g)
3. Differentiate between reaction rate and reaction rate constant.

4. What is meant by order and molecularity of a reaction ? Distinguish between order and molecularity.
5.
LA
Explain with suitable examples how the molecularity of reaction is different from order of rection.
6. The kinetics of the reaction : A  2B   C  D , obeys the rate equation: Rate = k[A]x[B]y. For it,
find (i) order of the reaction (ii) apparent molecularity of reaction (iii) order of the reaction when B is
present in large excess.
7. Show by using rate law, how much rate of reaction: 2NO  g   O 2  g  

 2NO 2  g  will change if
the volume of the reaction vessel is reduced to one-third of tis initial value.
8. Show graphically, how the rate of reaction depends on the concentration of reactant when there is only
one reactant and the reaction is of first order.
A
9. What are pseudo unimolecular reactions ? Give two examples.
10. Derive integrated rate equation for firwst order reaction.
11. (a) Draw a schematic graph showing how the rate of a first order reaction changes with change in
cocentration of the reactant.
(b) Rate of a reaction is given by the equation: Rate = k[A]2 [B]
B
What are the units for the rate and the rate constant for this reaction ?
12. Write the rate law for the first order reaction and justify the statement that half-life of such a reaction
is independent of its initial concentration.
13. (a) Express the relationship between the rate of production of oxygen and the rate of disappearance of
H2O2 in the following reaction:
2H 2 O 2  l  
 2H 2 O  l   O 2  g 
(b) The rate of formation of a dimer in second order dimerization reaction is 6.5 5 10–6 mol L–1 s–1 at
0.01 mol L–1 monomer concentration. Calculate the rate constant.
–1–
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14. The rate constant for a first order reaction is 0.005 min–1. Calculate its half-life.
15. The rate constant of a first order reaction becomes 5 times when the temperature is raised from 350 K
to 400 K. Calculate the activation energy for the reaction. (R = 8.314 J K –1 mol–1)
16. A first order reaction is 30% complete in 50 minutes. Calculate the value of rate constant.
17. Show that time required for t99.9% of the reaction is 10 times t1/2.
18. A first order reaction is 20% completed in 10 minutes. How much time does it take for 75% completion ?
19. A first order reaction is 20% complete in 20 minutes. Calculate the time it will take the reaction to
complete 80%.
20. The reaction SO2 Cl2  SO 2  Cl2 is a first order reaction with half-life 3.15 × 104 s at 320º C.
What percentage of SO2Cl2 would be decomposed on heating at 320º C for 90 minutes ?
JI
21. What will be the initial rate of reaction if its rate constant is 10 –3 s–1 and the concentration of the
reactant is 0.2 mol L–1 ? What fraction of the reactant will be converted into the products in 200
seconds ?
22. The reaction SO 2 Cl 2 ƒ SO 2  Cl 2 is a first order reaction with k = 2.2 × 10–5 s–1 at 575 K. What
percentage of SO2Cl2 will get decomposed in 80 minutes, when the reaction is carried out at 575 K ?
23. Rate constant k of a reaction varies with temperature according to the equation:
LA
log k = constant 
Ea 1
. ,
2.303R T
1
where Ea is athe energy of activation for the reaction. When a graph is plotted for log k versus ,a
T
straight line with a slope – 6670 K is obtained. Calculate energy of activation for this reaction. State the
units. (R = 8.314 J K–1 mol–1)
24. The specific rate constant for a particular reaction is 2.34 × 10 –3 mol L–1 s–1 at 370 K and 7.50 × 10–2
mol L–1 s–1 at 400 K. Calculate the activation energy for the reaction. [R = 8.314 JK –1 mol–1]
A
25. The rate of a particular reaction triples when temperature changes from 50ºC to 100ºC. Calculate the
activation energy of the reaction. [log 3 = 0.4771; R = 8.314 JK –1 mol–1]
26. A certain reaction is 50% complete in 20 minutes at 300 K and the same reaction is again 50%
complete in 5 minutes at 350 K. Calculate the activation energy if it is a first order reaction.
27. Derive the relationship between half-life of a first order reaction and its rate constant.
B
28. What is meant by the ‘rate constant’, k  of a reaction ?

If the concentration be expressed in mol L–1 units and time in seconds, what would be the units of k
(i) for a zero order reaction and (ii) for a first order reaction ?
29. (a) A first order reaction is 15% completed in 20 minutes. How long will it take to complete 60%.
(b) What is the significance of rate constant in a rate law ?
30. A first order reaction takes 69.3 minutes for 50% completion. Set up an equation for determining the
time needed for 80% completion of this reaction. (Calculate of result is not required)
31. The rate constant for a first order reaction is 60 s–1. How much time will it take to reduce the concen-
tration of the reactant to 1/10th of its initial value ?
–2–

32. A reaction is first order in A and second order in B.
(i) Write differential rate equation.
(ii) How is the rate affected if the concentration of B is tripled ?
(iii) How is the rate affected when the concentrations of both A and B are doubled ?
What is the significance of rate constant in the rate expression ?
33. (a) How is half-life period related to initial concentration for a second order reaction ?
(b) Dissociation of SO2Cl2 in the gas phase is a first order reaction with rate constant 2.3 × 10 –5 s–1 at
600 K. Calculate the percentage of SO2Cl2 that would remain after 200 minutes of reaction time.
34. In general it is observed that the rate of a chemical reaction doubles with every 10º rise in temperature.
If this generalization holds for a reaction in the temperature range 295 K to 305 K, what would be the
JI
value of activation energy for this reaction ? (R = 8.314 JK –1 mol–1)
35. If the rate constant of ra reaction is 2.0 mol–1 L s–1 at 700 K and 32.0 mol–1 L s –1 at 800 K, what is the
activation energy ?
1
36. If the slope of line obtained by plot of log k against is – 5.3 × 103, calculate the activation energy..
T
37. If slope of line obtained by plot of log [N2O5] vs, time is –2.147 × 10–4 s–1, calculate the value of ‘k’.
38.
LA
The activation energy of a reaction is 75.2 kJ mol–1 in the absence of a catalyst and 50.14 kJ mol–1 with
a catalyst. How mnay times will the rate of reaction grow in the presence of the cataylst if the raction
proceeds at 25º C ? (R = 8.314 JK–1 mol–1)
39. Following reaction takes place in one step,
2NO  g   O 2  g  ƒ 2NO 2  g 
How will the rate of the above reaction change if the volume of the reaction vessel is diminished to one-
third of tis original volume ? Wil there be any change in the order of the reaction with the reduced
volume ?
40. (a) Decomposition of N2O5 (g) is a first order reaction with a rate constant of 5 × 10–4 sec–1 at 45º C.
A
i.e. 2N 2 O5  g  
 4NO 2  g   O 2  g  . If initial concentration of N2O5 is 0.25 M, calculate tis
concentration after 2 min. Also calculate half-life for decomposition of N2O5 (g).
(b) For an elementary reaction: 2A  B 
 3C
the rate of appearance of C at time ‘t’ is 1.3 × 10–4 mol L–1 s–1. Calculate at this time
B
(i) Rate of the reaction.

(ii) Rate of disappearance of A.
–3–

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Chemical Kinetics

3. Differentiate between reaction rate and reaction rate constant.

7. Show by using rate law, how much rate of reaction: 2NO  g   O 2  g  

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28. What is meant by the ‘rate constant’, k  of a reaction ?

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(i) Rate of the reaction.

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