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    Test - (Chemical Kinetics) 24-25

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    Test - (Chemical Kinetics) 24-25

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    Test - (Chemical Kinetics) 24-25

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    sepmoulds666

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    of 1

    CLASSIC TUTORIALS A & G ACADEMY

    (SHIVAJI PARK) (BABARPUR ROAD)

    BY – Atish Gupta (MOB : 9718604866)


     JOIN US FOR QUALITY EDUCATION 
    -----Tyari Jeet Ki-----
    -----All The Best-----
    Class :- XIIth TEST – 3 M.M : 30

    (Syllabus :- Chemical Kinetics)


    SECTION – A (1 MARK) SECTION – C (3 MARK)
    Q.1. Calculate the overall of the reaction whose rate Q.11. The following results have been obtained
    law expression was predicted as : during the kinetic studies of the reaction :
    Rate = k[NO]3/2 [O2]1/2. Exper [A] mol L‒1 [B] mol L‒1 Initial rate of
    Q.2. For a reaction R → P, half-life (t1/2) is observed iment formation of
    to be independent of the initial concentration of D/mol L‒1 min‒1
    reactants. What is the order of reaction ? I 0.1 0.1 6.0 × 𝟏𝟎 𝟑
    II 0.3 0.2 7.2 × 𝟏𝟎 𝟐
    Q.3. A reaction is second order with respect to a
    III 0.3 0.4 2.88 × 𝟏𝟎 𝟏
    reactant. How will the rate of reaction affected is
    IV 0.4 0.1 2.40 × 𝟏𝟎 𝟐
    conc. of reactant is doubled ?
    Determine the rate law and the rate constant for the
    Q.4. What is the slope of the graph plotted between
    reaction.
    lnk and l/T as per Arrhenius equation ?
    Q.12. Observe the graph shown in figure and answer
    Q.5. The decomposition of NH3 on platinum surface
    the following questions :
    is zero order reaction. If rate constant (k) is 4
    (a) What is the order of the
    × 𝟏𝟎 𝟑 M s‒1, how long will it take to reduce the
    reaction ?
    initial concentration of NH3 from 0.1 M to 0.064 M ?
    (b) What is the slope of the
    SECTION – B (2 MARKS) curve ?
    Q.6. Write any four differences between ‘order of (c) Write the relationship
    reaction’ and ‘molecularity of reaction’. between k and t1/2 (half-life period).
    Q.7. For a reaction A + B → P, the rate is given by Q.13. A first order reaction is 50% completed in 40
    Rate = k[A][B]2 minutes at 300 K and in 20 minutes at 320 K.
    (i) How is the rate of reaction affected if the Calculate the activation energy of the reaction.
    concentration of B is doubled ? (Given : log 2 = 0.3010, log 4 = 0.6022, R = 8.314 J K‒
    (ii) What is the overall order of reaction if A is 1 mol‒1)

    present in large excess ? Q.14. The following data were obtained during the
    Q.8. Show that for a first order reaction the time first order thermal decomposition of SO2Cl2 at a
    required for 99% completion is twice as that of 90% constant volume.
    completion. SO2Cl2(g) → SO2(g) + Cl2(g)
    Q.9. The decomposition of NH3 on platinum surface Experiment Time/s‒1 Total pressure/atm
    is zero order reaction. What are the rates of 1 0 0.5
    production of N2 and H2 if k = 2.5 × 𝟏𝟎 𝟒 mol‒1 Ls‒1 ? 2 100 0.6
    Q.10. (a) Explain the role of catalyst graphically for Calculate rate constant.
    a reaction. Q.15. A first order takes 100 min for completion of
    (b) Define pseudo first order reaction with example. 60% of the reaction find the time when 90% of the
    reaction will be completed. (log 5 = 0.699, log 2 =
    301, log 4 = 0.602, log 10 = 1)

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