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    熔解熱的測定簡

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    部落小帳

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    熔解熱的測定簡

    Uploaded by

    部落小帳
    4 views6 pages

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    4 views6 pages

    熔解熱的測定簡

    Uploaded by

    部落小帳

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    You are on page 1of 6

    √

    20160621

    113 10 18
    mmHg
    mmHg

    4112065027
    4112065007
    (/)

    檢核表
    □
    □
    □
    □
    □
    □
    □
    □
    □
    有效位數□
    文獻列示□
    □
    □
    (: )
    (298K100kPa)
    摩爾 溶質 溶劑 熱量 焓
    1

    · 1 (differential heat of solution)

    · c 1 1c 2 (integral heat of solution)

    · 稀釋熱(w:heat of dilution )

    { : ( ) “”,,}
    +
    ,

    ()1(,1)

    () m 1 t 1 ” 1 ”m 2 t 2 ” 2 ”t 3 k” 1

    ” (m )” ”m )=
    1+k) (t1 –t3 2 2 (t3-t2

    m
    1 +m2 1 = m2
    (±15)t
    1 2

    k (
    )

    m gw gqt0t1m

    |q|=(w+k)*(|t1-t0| )*sp.ht(, cal/K.g) +(m/M)*(|t1-t0| )*sp.ht(, cal/K.mole)


    {ksp.ht. kq,
    } M DH=q·M/m (/)

    (, , ? , , , ? )

    (, ”” ”0”)
    ( Tiamo 360ccHG2233 )(KCl sp.ht
    =10.93+0.00376T, T=273~1043K )(CaCl 2 sp.ht =16.9+0.00386T, T=273~1055K)(NaCl
    sp.ht =10.79+0.00420T, T=273~1074K , cal/K.mole )

    ( )

    1. (1)

    2. ~w g
    , >600rpm
    1

    3. 1~2g/100g

    4. 5

    5. 5

    6.

    7. (cal/g)(cal/mole)
    8. 2

    1.

    2.

    3.

    4. , , k, k KCl NaCl , !

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