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 Series ARSP/01 Set ~ 1
Roll No. Q.P Code 15/1/1
Candidates must write the Q.P Code
on the title page of the answer-book.

 Please check that this question paper contains 06 printed pages.

 Q.P. Code given on the right hand side of the question paper should be written
on the title page of the answer-book by the candidate.
 Please check that this question paper contains 33questions.
 Please write down the serial number of the question in the answer-book
before attempting it.
 15 Minute times has been allotted to read this question paper. The question
paper will be distributed at 10:15 a.m. From 10.15 a.m to 10.30 a.m, the students
will read the question paper only and will not write any answer on the answer –
book during this period.

CHEMISTRY

Time allowed: 3 hours Maximum Marks: 70

General Instructions:
Read the following instructions carefully.

1. There are 33 questions in this question paper with internal choice.

2. SECTION A consists of 16 multiple-choice questions carrying 1 mark each.

3. SECTION B consists of 5 very short answer questions carrying 2 marks each.

4. SECTION C consists of 7 short answer questions carrying 3 marks each.

5. SECTION D consists of 2 case-based questions carrying 4 marks each.

6. SECTION E consists of 3 long answer questions carrying 5 marks each.

7. All questions are compulsory.

8. Use of log tables and calculators is not allowed.

Section A
1. Name the following compound as per the IUPAC system [1]
CH3

C H3 - C - C = CH - C H3
| |

CH3 CH3

a) 3, 4, 4 - trimethylpent - 2 - ene b) 2 diethyl, 3 - ethyl pentene

c) 4 diethyl, 2 - ethyl pentene d) 2, 2, 3 - trimethylpent - 4 - ene

2. Deficiency of which of the following vitamins causes Pernicious anaemia? [1]

a) Vitamin B2 b) Vitamin B1

c) Vitamin B12 d) Vitamin B6

3. One of the following alcohols do not undergo oxidation reaction: [1]

a) Primary alcohol and Secondary alcohol b) Tertiary alcohol

c) Secondary alcohol d) Primary alcohol

4. Compound 'A' undergoes the formation of cyanohydrins which on hydrolysis gives lactic acid [1]
(CH3CHOHCOOH). Therefore, compound 'A' is:

a) Acetone b) Benzaldehyde

c) Acetaldehyde d) Formaldehyde
5. Which of the following relations is incorrect? [1]
 a) G = k(
a
) b) G = k(
l

a
)
l

c) ∧ m =
k

c
d) R =
1
(
l

a
)
k

6. Match the item given in Column I with expression given in Column II. [1]

Column I Column II

(a) Osmotic Pressure (i) p = KH . χ

B

(b) Relative lowering of vapour pressure (ii) △P

o
= χ
B
P A

(c) Henry Law (iii) △T b = Kb . m

(d) Elevation in boiling point (iv) p = iCRT

a) (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i). b) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i).

c) (a) - (iii), (b) - (i), (c) - (ii), (d) - (iv). d) (a) - (iv), (b) - (ii), (c) - (i), (d) - (iii).
7. IUPAC name of neo-Pentylbromide is: [1]

a) 1-Bromo-3-methylbutane b) 1-Bromo-2,2-dimethylpropane.

c) 1-Bromo-1,2-dimethylpropane d) 1-Bromo-2-methylbutane
8. Which of the following is a diamagnetic ion? (Atomic numbers of Sc, V, Mn and Cu are 21, 23, 25 and 29 [1]
respectively)

a) V2 b) Mn3+

c) Cu2+ d) Sc3+

9. Name the order of reaction which proceeds with a uniform rate throughout. [1]

a) Third order b) Second order

c) First order d) Zero order

10. A mixture of benzaldehyde and formaldehyde on heating with aqueous NaOH solution gives: [1]

a) Benzyl alcohol and methyl alcohol b) Benzyl alcohol and sodium formate

c) Sodium benzoate and methyl alcohol d) Sodium benzoate and sodium formate
11. Arrange the following compounds in increasing order of boiling point: Propan-1-ol, butan-1-ol, butan-2-ol, [1]
pentan-1-ol

a) Propan-1-ol, butan-2-ol, butan-1-ol, pentan- b) Pentan-1-ol, butan-2-ol, butan-1-ol, propan-

1-ol 1-ol

c) Propan-1-ol, butan-1-ol, butan-2-ol, pentan- d) Pentan-1-ol, butan-1-ol, butan-2-ol, propan-

1-ol 1-ol
12. Which of the following is a secondary amine _ [1]

a) N,N-dimethylaniline b) 3 – pentanamine

c) N-ethyl propan -1-amine d) cyclohexylamine

13. Assertion (A): Vitamin B5 is also called as pyridoxin. [1]

Reason (R): Deficiency of vitamin B5 causes dermatitis and dementia.

 a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

14. Assertion (A): Acetaldehyde is more reactive than trichloroacetaldehyde. [1]
Reason (R): Chlorine atom exhibit -I effect in trichloro acetaldehyde.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

15. Assertion (A): Addition of Br2 to but-1-ene gives two optical isomers. [1]

Reason (R): The product contains one asymmetric carbon atom.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

16. Assertion (A): Alcohols are easily protonated as compared to phenols. [1]
Reason (R): Alcohols undergo intermolecular hydrogen bonding due to the presence of highly electronegative
oxygen.

a) Both A and R are true and R is the correct b) Both A and R are true but R is not the
explanation of A. correct explanation of A.

c) A is true but R is false. d) A is false but R is true.

Section B
17. Give the formulae of the following compounds: [2]
a. Potassium tetrahydroxidozincate (II)
b. Hexaammineplatinum (IV) chloride
18. Why is any transition series, melting points first increase and then decrease and also they show a dip in the [2]
middle?
19. Answer the following: [2]
(a) The reaction between H2(g) and O2(g) is highly feasible yet allowing the gases to stand at room [1]
temperature in the same vessel does not lead to the formation of water. Explain
(b) Is rate of reaction always constant? [1]
20. At 300 K, 30 g of glucose present in a litre of its solution has an osmotic pressure of 4.98 bar. If the osmotic [2]
pressure of a glucose solution is 1.52 bar at the same temperature, what would be its concentration?
OR
A solution of glucose (molar mass = 180 g mol-1) in water has a boiling point of 100.20oC. Calculate the freezing
point of the same solution. Molal constants for water Kf and Kb are 1.86 K kg mol-1and 0.512 K kg mol1
respectively.
21. Identify the compounds A, B and C in the following reaction. [2]
+
Mg/ether (i) C O2 C H3 OH /H

C H3 − Br −−−−−→ (A) −−−−−−→ (B) −−−−−−−→ (C )

(ii) W ater Δ

Section C
22. How long will it take an electric current of 0.15 A to deposit all the copper from 500 ml of 0.15 M copper [3]
sulphate solution?
23. The following data were obtained during the first order thermal decomposition of N2O5 (g) at constant volume: [3]
2N2O5 (g) → 2N2O4 (g) + O2 (g)
Total Pressure
S. No.
T ime

s (atm)

a. 0 0.5

b. 100 0.512

Calculate the rate constant.

24. Write the reactions of Williamson synthesis of 2-ethoxy-3 methylpentane starting from ethanol and 3- [3]
methylpentan-2-ol.
OR
Explain why is O=C= O non polar while R-O-R is polar.
25. Predict the products of the following reactions: [3]
i.

ii.

O
+
|| H

iii. R − C H = C H − C HO + N H2 − C − N H2 − N H2 −→
−

iv.

+
H

+ CH 3
CH2 NH2 −
−→

26. Consider the reaction: [3]

2− + − 3+
C r2 O + 14H + 6e → 2C r + 7H2 O
7

What is the quantity of electricity in coulombs needed to reduce 1 mol of C r 2−

2 O7 ?
27. Mention the problems related to extensive use of DDT. [3]
28. What is a salt bridge? What is it used for? [3]
Section D
29. Read the following text carefully and answer the questions that follow: [4]
The f-block consists of elements in which 4f and 5f orbitals are progressively filled. They are placed in a
separate panel at the bottom of the periodic table. The names transition metals and inner transition metals are
often used to refer to the elements of d-and f-blocks respectively. The d–block occupies the large middle section
of the periodic table flanked between s and p blocks in the periodic table. In general, the electronic configuration

of the outer orbitals of these elements is (n - 1)d1-10ns1-2. The electronic configurations of outer orbitals of Zn,
 Cd, Hg and Cn are represented by the general formula (n - 1)d10ns2. The transition metals and their compounds
also exhibit catalytic property and paramagnetic behaviour. Transition metal also forms an alloy. An alloy is a
blend of metals prepared by mixing the components. Alloys may be homogeneous solid solutions in which the
atoms of one metal are distributed randomly among the atoms of the other.
i. Transition metals form alloys. Justify? (1)
ii. Why do transition elements exhibit higher enthalpies of atomization? (1)
iii. Transition metals and many of their compounds show paramagnetic behaviour. Give reason. (2)
OR
Transition metals and their many compounds act as good catalyst. Give reason. (2)
30. Read the following text carefully and answer the questions that follow: [4]
Vapour pressure of a liquid or a solution is the pressure exerted by the vapour in equilibrium with the liquid or
solution at a particular temperature. It depends upon the nature of the liquid and temperature. The non-volatile
solute in solution reduces the escaping tendency of the solvent molecules in the vapour phase because some of
the solute particles occupy the positions of the solvent molecules on the liquid surface. The relative lowering of
the vapour pressure of a solution containing a non-volatile solute is equal to the mole fraction of the solute in the
solution. This is also known as Raoult's law. However, for solutions of volatile solutes, the vapour pressure of a
component in a solution at a given temperature is equal to the mole fraction of that component in the solution
multiplied by the vapour pressure of that pure component. The solutions in which each component obeys
Raoult's law is called an ideal solution. For ideal solutions ΔH mixing and ΔVmixing are also zero. Practically no
solution is ideal. A non-ideal solution is that solution in which solute and solvent molecules interact with one
another with a different force than the forces of interaction between the molecules of the pure components.
There are two types of non-ideal solutions, showing positive deviations and negative deviations from ideal
behaviour. If for the two components A and B, the forces of interaction between A and B molecules are less than
the A-A and B-B interactions, the non-ideal solutions have positive deviations. On the other hand, if the forces
of interaction between A and B molecules are more than the A-A and B-B interactions, the non-ideal solutions
have negative deviations.
i. What is the mole fraction of A in solution obeying result's low if the vapour pressure of a pure liquid A is 40
mm of Hg at 300 K. The vapour pressure of this liquid in solution with liquid B is 32 mm of Hg? (1)
ii. Vapour pressure of a solution of heptane & octane is given by the equation: (1)
P(sol.)(mm Hg) = 35 + 65x, where x is the mole fraction of heptane. Calculate the vapour pressure of pure
octane. (2)
iii. What is the value of ΔVmixing and ΔHmixing for non-ideal solution showing negative deviation?
OR
Acetic acid + pyridine, the mixture is an example of which type of solution? (2)
Section E
31. Attempt any five of the following: [5]
(a) Write uses of B-Complex. [1]
(b) Name the disaccharide which on hydrolysis gives glucose and galactose. [1]
(c) During curdling of milk, what happens to sugar present in it? [1]
(d) α -Helix is a secondary structure of proteins formed by twisting of the polypeptide chain into right- [1]
handed screw like structures. Which type of interactions is responsible for making the α-helix
structure stable?
 (e) What type of linkage holds together the monomers of DNA? [1]
(f) Deficiency of which vitamin causes night-blindness. [1]
(g) What is the basic structural difference between glucose and fructose? [1]
32. a. Amongst the following, the most stable complex is: [5]

i. [Fe(H2O)6]3+

ii. [Fe(NH3)6]3+

iii. [Fe(C2O4)3]3-

iv. [FeCl6]3+

b. What will be the correct order for the wavelength of absorption in the visible region for the following:
[Ni(NO2)6]4-, [Ni(NH3)6]2+, [Ni(H2O)6]2+

OR
Using crystal field theory, draw energy level diagram, write the electronic configuration of the central metal atom/ion
and determine the magnetic moment value in the following:

i. [CoF6]3-, [Co(H2O)6]2+, [Co(CN)6]3-

ii. [FeF6]3-, [Fe(H2O)6]2+, [Fe(CN)6]4-

33. Complete the following reaction: [5]

i. CH3CH2NH2 + CHCl3 + alc. KOH ⟶
H2 O

ii. C 6
+
H5 N
2
−
Cl −−−−−−−−−−−−−→
(At room temperature)

iii.

OR
a. Give reasons for the following :
i. Acetylation of aniline reduces its activation effect.
ii. CH3NH2 is more basic than C6H5NH2.

iii. Although -NH2 is o/p-directing group, yet aniline on nitration gives a significant amount of m-nitroaniline.

b. Explain the following reactions:

i. Coupling reaction
ii. Gabriel phthalimide reaction
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