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STP Phase 5 Paper 2

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0% found this document useful (0 votes)
65 views29 pages

STP Phase 5 Paper 2

Uploaded by

vatsalgupta.1805
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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FIITJEE INTERNAL TEST

PHYSICS, CHEMISTRY & MATHEMATICS


CPT–1 CODE: 101324.1 PAPER–2
Sankalp2325 S1, T1 & P1(Phase-5)

Time Allotted: 3 Hours Maximum Marks: 183

 Pleas e r ead the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each part is further divided into one part: Part – A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All One Part.
Part–A (01 – 07) contains 07 multiple choice questions which have one or more than one correct answer.
Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Part–A (08 – 14) contains 07 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Part–A (15 – 18) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer
and 0 mark for a wrong answer.

Name of the Candidate :______________________________________________________

Batch :______________________________ Date of Examination :___________________

Enrolment Number :_________________________________________________________

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-2

SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

1. A student performed the experiment of determination of focal length of a concave mirror by u – v


method using an optical bench of length 1.5 meter. The focal length of the mirror used is 24 cm. The
maximum error in the location of the image can be 0.2 cm. The 5 sets of (u, v) values recorded by
the student (in cm) are: (42, 56), (48, 48), (60, 40), (66, 33), (78, 39). The data set(s) that cannot
come from experiment and is (are) incorrectly recorded, is (are)
(A) (42, 56) (B) (48, 48)
(C) (66, 33) (D) (78, 39)

2. A Young's double slits experiment is conducted by using light y


of wavelength 3300nm as shown in the figure. Separation 1 = 4/3 P
between slits and screen is 2m and separation between the S1
slits is 0.50mm. The slits are covered by transparent sheets
each of thickness 10m and having refractive index (4/3) and O x
(3/2) respectively. Find
S2
2 =3/2

(A) Position of central maximum on the y-axis has magnitude 6.67mm.


(B) Intensity at point O, if I0 is intensity at slits is minimum.
(C) Intensity at point O, if I0 is intensity at slits is maximum.
(D) Minimum possible thickness (t) of the sheets such that point O becomes dark is 9.9m.

3. In a certain series LCR A.C. circuit it is found that XL = 2XC and phase difference between the current
and voltage is /4. If now capacitance is made 1/4th & the inductance and resistance are doubled then
which are not correct.
(A) voltage will lead current by a phase of tan1(1/2).
(B) voltage will lag behind current by a phase of tan1(1/2).
(C) voltage will lag behind current by a phase of /4.
(D) voltage and current will be in same phase.

4. If Planck constant h, Gravitational constant G and viscosity of a fluid  are considered as fundamental
quantities, then dimensions of mass M and length L will be
 5 1 1   1 5 1 
(A) M  h 9 G 3 9  (B) M  h 3 G 9 9 
   
1 1 5 1
     
(C) L   h 3 G 0  3  (D) L   h 9 G 0  3 
   

Space for rough work

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website: www.fiitjee.com.
Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-3

5. A parallel beam of wavelength  = 4000 A falls on a Young’s Screen


double slit apparatus. The slits and the screen are kept fixed
and a converging lens is moved between the slits and the S1
screen. For two positions of the lens (between the slits and the
screen), we get two sharp images of slits on the screen in each
case. The images are separated from each other by distance S2
4.5 mm in one case and 2 mm in the other. If the lens is
removed and interference pattern is observed on the screen. D = 150 cm
Then
(A) The fringe width of the pattern on the screen is 0.2 mm.
(B) The fringe width of the pattern on the screen is 0.1 mm
(C) The focal length of the lens is 36 cm
(D) The focal length of the lens is 24 cm.

6. Energy liberated in the de–excitation of hydrogen atom from 3rd level to 1st level falls on a photo–
cathode. Later when the same photo–cathode is exposed to a spectrum of some unknown hydrogen
like gas, excited to 2nd energy level, it is found that the de–Broglie wavelength of the fastest
photoelectrons, now ejected has decreased by a factor of 3. For this new gas, difference of energies
of 2nd Lyman line and 1st Balmer line is found to be 3 times the ionization potential of the hydrogen
atom. Select the correct statement(s) :
(A) The gas is lithium.
(B) The gas is helium.
(C) The work function of photo–cathode is 8.5 eV.
(D) The work function of photo–cathode is 5.5 eV.

7. A wire frame in the form of a part of circle (sector) of radius l Region - I Region - II
and resistance R is free to rotate about an axis passing x x x x x
through O and perpendicular to plane of paper as shown in x x x x x

figure. The angle of the sector is and it is rotating with x x x x x
4
x x x x x
constant velocity  as shown. Above line PQ uniform
x x x x x
magnetic field of magnitude B exists in the direction
P O Q
perpendicular to plane of paper. In region I field is outward l
/4
while in region II, field is inward. 

B 2 l4
(A) The thermal energy dissipated in wire frame when it moves from region I to region II, is .
4R
(B) The thermal energy dissipated in wire frame when it moves from region I to region II, is zero.
3B2 l4
(C) Total thermal energy dissipated in one cycle is
8R
3B2 2l4
(D) Average power produced in wire frame is
16R

Space for rough work

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website: www.fiitjee.com.
Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-4

PART – A: (Single Correct Answer Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.

8. A uniform disc of radius r and mass m is charged uniformly with the charge q. Disc
B
This disc is placed flat on a rough horizontal surface having coefficient of
friction . A uniform magnetic field is present in a circular region (a > r) but a
varying as kt3 as shown in figure. The time after which the disc begins to r
rotate is (Given r = 1 m, m = 18 kg, q = 1C,  = 0.1, K = 4 Ts3, g = 10 m/s2)

(A) 1 sec (B) 2 sec


(C) 4 sec (D) 6 sec

9. The graph shows the variation of cutoff wavelength in X-ray min


experiment with respect to the de-Broglie wavelength of the incident
electron. Cutoff wavelength  min  is plotted along y –axis and
wavelength of incident electrons ( e ) is plotted along x – axis. The
given X–ray tube is functioning corresponding to the point P. The P(x,a)
value of x – co-ordinate of point P is
ha ha
(A) (B)
2mc mc e

2ha
(C) (D) none of these
mc
h  planck’s constant ; m  mass of electron ; c  speed of light

10. Consider two coherent monochromatic (wavelength ) sources S1


P
S1 and S2 separated by distance d. The ratio of intensity of S1
and that of S2 (which is responsible for interference at point P, d
where detector is located) is 4. The distance of point P
S2
9
from S1 is (if the resultant intensity at point P is equal to times of intensity of S1)
4
[Given S2 S1P is 90] (d > 0, n is a positive integer)
d2  n2  2 d2  n2  2
(A) (B)
2n  2n 
n d 2n  d
(C) (D)
2 2 2
d n  d2  n2  2

Space for rough work

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website: www.fiitjee.com.
Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-5
n
x
11. If Q  and x, y are absolute errors in the measurement of x and y, then absolute error Q in Q
ym
is
 x y   x y 
(A) Q =   n m  (B) Q =   n m Q
 x y   x y 
 x y   x y 
(C) Q =   n m Q (D) Q =   n m Q
 x y   y x 

12. In the figure B1, B2 and B3 represent uniform  


time varying magnetic fields in three different   B1        B2   
infinitely long cylindrical regions with axis  
P
passing through P, Q and R and perpendicular   Q   
 
to the plane of the paper. PQR is an equilateral
 
triangle of side 43 r, where r is the radius of  
each cylindrical region (r = 1m). The magnetic
inductions vary with time t as B1 = A + at, B2 = A
– bt and B3 = A + ct. Here a = 2 Tesla/s, b = 2    
Tesla/s and c = 1 Tesla/s and A is a constant      
with dimensions of magnetic field and ‘t’ is time.       
The induced electric field strength at the centroid R B3
     
of the triangle PQR is,
   

5 1
(A) V/m (B) V/m
8 8
13
(C) V/m (D) zero
8

13. The diameter of a cylinder in measured using a vernier calipers with no zero error. It is found that the
zero of the vernier scale lies between 5.10 and 5.15 cm of the main scale. The vernier scale has 50
divisions equivalent to 2.45 cm. The 24th division of the vernier scale exactly coincides with one of the
main scale divisions. The diameter of the cylinder is
(A) 5.112 cm (B) 5.124 cm
(C) 5.136 cm (D) 5.148 cm


14. A ray of light traveling in glass ( = 3/2) is incident on a horizontal C D
glass air surface at the critical angle C. If a thin layer of water ( = Water O r
A B
4/3) is now poured on the glass air surface, the ray of light emerge
into air at the water air surface at an angle of …… R 3
c R 
  2
(A) rad (B) rad
2 6
 
(C) rad (D) rad
3 4

Space for rough work

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-6

PART – A: (Paragraph Type)

This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 15 to 16

A square loop, consisting of an inductor L and a


capacitor C is placed between two long parallel wires
each carrying time varying current of magnitude I = L
I0sin(t) in opposite directions as shown in the figure.
Based on the above information answer the following I = I0 sin (t) C
I = I0 sin (t)
questions. (assume Biot Savart’s law is valid)
a a a

15. The magnetic flux due to the magnetic field produced by the long parallel wires through the square
loop is
 I a n(2) sin( t)  I a n(2) sin( t)
(A) 0 0 (B) 0 0
2 
0I0 a n(3) sin( t) 0I0 a n(3) sin( t)
(C) (D)
2 

16. The function of current through the square loop is


 0I0 an2    0I0 an2  
(A) cos  t   (B) cos  t  
 1   2  1   2
  L  2  L 
 C   C 
 0I0 an2    0I0 an3  
(C) cos  t   (D) cos  t  
 1   2   1   2 
  L    L 
 C   C 

Space for rough work

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-7

Paragraph for Question Nos. 17 to 18

A convex lens of focal length f1 is placed in front of a luminous point object. The separation between the
object and the lens is 3f 1. A glass slab of thickness t is placed between object and the lens. A real image of
the object is formed at the shortest possible distance from the object.

17. The refractive index of the slab is


t 2t
(A) (B)
t  f1 t  f1
t 2t
(C) (D)
t  f1 t  f1

18. Now, if a concave lens of very large focal length f2 is placed in contact with the convex lens, then the
shifting of the image is
f2 4f 2
(A) 1 (B) 1
f2 f2
8f12 f12
(C) (D)
f2 4f2

Space for rough work

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-8

SECTION- II: CHEMISTRY


PART– A (One or More Than One Type)
This section contains 7 multiple choice type questions. Each question has four choices (A), (B), (C) and
(D). ONE OR MORE THAN ONE of these four option(s) is (are) correct.

1. Which of the following is/are correct?


(A) Lime water is used for the test of carbonate radical
2+ 2+
(B) Addition of Na2CO3 to an aqueous solution of Ba and Mg will ppt both
2+
(C) Ammonium thiocyanate forms coloured ppt with Co
(D) CuS is soluble in dilute HCl solution

2. Table for some ionic radii are given


Ions K Cs Mg2 Sr 2 Br  O 2 S 2
 
Ionic radii A 0 1.33 1.69 0.66 1.12 1.96 1.40 1.86
Then predict the compound(s) which can exist in FCC(rock salt type) is / are
(A) KBr (B) CsBr
(C) MgO (D) SrS

3. Choose INCORRECT statement/s


(A) EDTA4- is pentadentate ligand
2 2 2
(B) Cd  CH3NH2 4   Cd  en 2   Cd  trien   [where trien  triethylene tetraamine] is the
decreasing order of stability
(C) Ni(DMG)2  is possessing two intra molecular hydrogen bonds.
(D) Cu  OH 2 is soluble in excess of aq. NaOH

4. Which of the following oxyacids of sulphur have S – S bond?


(A) H2S2O7 (B) H2S2O8
(C) H2S2O6 (D) H2S2O5

Space for rough work

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-9

5. Which of the following is/are correct?

(A) Cold solution of Ba(NO2)2 on mixing with dil.H2SO4 produces BaSO4 and nitric oxide gas

(B) HNO3 can not be used for the preparation of H2S from metal sulphides.

H2 O
(C) P4  NaOH   PH3  NaH2PO3
(D) P4O10 on absorbing limited amount of H2O may form meta phosphoric acid.

6. Which of the following option(s) is/are correct?


Heat
(A) NH4NO3   N2O  2H2O
(B) 2NaNO2  2FeSO 4  3H2SO 4  Fe2  SO4 3  2NaHSO 4  2H2O  2NO
673K
(C) 2Pb  NO3 2   4NO2  2PbO  O 2
(D) 4HNO3  P4 O10  4HPO3  2N2O5

– –
7. For I2 + 2e  2I , standard reduction potential = +0.54 volt.
For, 2Br–  Br2 + 2e–, standard oxidation potential = – 1.09 volt
For, Fe  Fe2+ + 2e–, standard oxidation potential = +0.44 volt
Which of the following actions are spontaneous?
(A) Br2 + 2I–  2Br– + I2 (B) Fe + Br2  Fe2+ + 2Br–
(C) Fe + I2  Fe2+ + 2I– (D) I2 + 2Br–  2I– + Br2

PART – A (Single Correct Type)


This section contains 7 multiple choice type questions. Each question has four choices (A), (B), (C) and
(D). ONLY ONE of these four option(s) is(are) correct.

8. In the normal spinel having one eighth of the tetrahedral holes, occupied by one type of metal ion and
one half of the octahedral holes occupied by another type of metal ion. Such a spinel is formed by
Mg2+, Al3+ and O2–. If oxide ion is replaced by X-8/3, the number of anionic vacancies per unit cell is;
(A) 1 (B) 2
(C) 3 (D) 3/4

Space for rough work

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-10

9. 1.0 g of a monobasic acid HB (having pKa = 5) in 100 g water lowers the freezing point by 0.155 K. if
0.45 g of same acid required 15 ml M/5 NaOH solution for complete neutralization
(Kf H2O = 1.86 k kg mol-1, density of H2O is 1g ml-1) then which of the following option is incorrect
regarding above question:
(A) degree of ionization of acid is 25%
(B) the pH of the resultant solution at the end point of neutralization is greater than 7
(C) normal molecular mass of acid is 150
(D) 1.5g of acid HB is hypotonic with 0.625 g urea at the same temperature and same volume of H2O

10. Consider the following co-ordination compounds



2-
(i) Ni(CO)4 (ii)  Co(CO)4  (iii) Fe(CO)4 
The stretching frequency of M – C bond (which is directly proportional to synergic bond strength)
follows the order
(A) (ii) > (iii) > (i) (B) (iii) > (ii) > (i)
(C) (i) > (ii) > (iii) (D) (i) > (iii) > (ii)

11. Resistance of a conductivity cell filled with 0.1 mol L–1 KCl solution is 100. If the resistance of the
–1
same cell when filled with 0.02 mol L KCl solution is 520, calculate the molar conductivity of 0.02
mol L KCl solution. The conductivity of 0.1 mol L–1 KCl solution is 1.29 S/m.
–1

(A) 124 S cm2 mol1 (B) 62 S cm2 mol1


(C) 102 S cm2 mol1 (D) 148 S cm2 mol1

12. Which of the following species has/have same number of X – O – X linkages where X = S or P or B.
(I)   SO3 (II) P4 O6
(III)   SO3 (IV)  HPO3 3
(A) II and III (B) I and III
(C) I and IV (D) II and IV

13. What is the value of Ecell of the following, at 250C?


Pt  s  |Cl2 1 atm  | Cl  0.1 M || Cr2O72  0.01 M , Cr 3  0.1 Min 0.05 M H2SO4  | Pt  s 
Given EoCr O2 |Cr 3  1.23 V; E oCl /Cl  1.36 V , (log 2 = 0.3, take 2.303 RT/F = 0.0591)
2 7 2

(A) 0.371 V (B) 0.237 V


(C) 0.327 V (D) + 0.237 V

14. A solid is formed and it has three types of atoms X, Y and Z. X forms a FCC lattice with Y atoms
occupying all tetrahedral voids and Z atoms occupying half of octahedral voids. The formula of solid
is:
(A) X4YZ2 (B) X4Y2Z
(C) XY2Z4 (D) X2Y4Z

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PART – A (Paragraph Type)


This section contains 2 questions. Based on each paragraph, there will be TWO questions. Each question
has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct

Paragraph for Question Nos. 15 and 16

In 1886, the French chemist, Francois Raoult after a series of experiments on a number of solvents including
water, benzene and ether, succeeded in establishing a relationship between the lowering of vapour pressure
of a solution and the mole fraction of the non volatile solute.
0
P1 = X1P1
0
Where P1 is vapour pressure of solvent in an ideal solution and P1 is vapour pressure of a pure solvent.
X1 mole fraction of solvent and X2 mole fraction of solute.
X1 + X2 = 1
P1 = (1–X2) P10
P10  P1
= X2
P10
The relative lowering of vapour pressure of a solution containing a non-volatile solute is equal to the
mole fraction of solute present in the solution.

15. The vapour pressure of pure liquid X and pure liquid Y are 36 and 100 mm of Hg respectively at 400
K. A liquid mixture of X and Y is composed of 1 mole each. What will be the pressure, when 1 mole of
the mixture has been vapourized at 400 K
(A) 60 (B) 67
(C) 49.2 (D) 55

16. A solution of non-volatile solute AX in a mixture of solvent A and Solvent B has a vapour pressure of
40 mm of Hg at 20°C and 68 mm of Hg at 30°C. The vapour pressure of pure solvent (A) is 15 mm of
Hg at 20°C and 34 mm of Hg at 30°C and the vapour pressure of pure solvent (B) is 85 mm of Hg at
20°C and 136 mm Hg at 30°C. Find the mole fraction of solvent A and solute respectively.
(A) 0.4 and 0.2 (B) 0.4 and 0.4
(C) 0.2 and 0.4 (D) 0.4 and 0.3

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Paragraph for Questions 17 and 18

Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides. Most
metals are obtained by direct treatment of theirs ores with chemical agents, but the extraction of certain
others require electrolysis. An example of the former type of process is the extraction of iron from its oxide,
described by the following equation:
Fe2 O3 + 3C  2Fe + 3CO
The relative ease of extraction of a metal from its oxide can be estimated using the Ellingham diagram, as
shown in the figure.
The diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a function
of absolute temperature.

0
-100 2CO2
of metal oxide formation

eO + O2
-200 2F 2CO
-300 + O2 C + O2 CO2
2Fe
-400
-500 2C
+O
2
-600 2CO
-700
-1
G/kJ mol

-800
-900
-1000
-1100
-1200

0oC 400oC 800oC 1200oC 1600oC 2000oC


273 K 673 K 1073 K 1473 K 1873 K 2273 K
Temperature

17. Which of the following statements is correct regarding thermochemical reduction of FeO at 8000C?
(A) C  CO is best reducing agent (B) C  CO2 is best reducing agent
(C) CO  CO2 is best reducing agent (D) All are equally efficient reducing agent

18. Which of the following best explains why the free energy of formation of Fe2O3 becomes less negative
as the temperature is increased:
(A) The free energy of formation is independent of the absolute temperature.
(B) Entropy drops as a result of the consumption of oxygen.
(C) At low temperature, the free energy of formation becomes less dependent on the enthalpy of
formation.
(D) As entropy increases, the free energy of formation increases.

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SECTION – III : MATHEMATICS


PART – A: (Multi Correct Answer Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.

dy
1. Let y = f(x) satisfies the differential equation 1  x 2   2xy  3x and f(0) = 2 then the correct
dx
statement about y = f(x) is
(A) it is differentiable in the entire domain (B) it has exactly two points of inflections
(C) if has exactly one integer in its range (D) it is a monotonic function in the domain

1  sin 2 x cos 2 x sin 2 x

2. If maximum and minimum values of the determinant sin 2 x 1  cos 2 x sin 2 x are 

sin 2 x cos 2 x 1  sin 2x


and  respectively (x  R), then
(A)  +99 = 4
(B) 3 - 17 = 26
(C) (2n - 2n) is always an even integer for nN
(D) a triangle can be constructed having it’s sides as ,  and  - .

 1 0 0
3. If A =  1 0 1 , then
0 1 0 
(A) A3 – A2 = A – I3 (B) Det (A2010 – I3) = 0
 1 0 0  1 1 0
(C) A =  25 1 0  (D) A =  25 1 0 
50 50

 25 0 1  25 0 1

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   
4. Let a, b and c are three mutually perpendicular unit vectors and a unit vector r satisfying the
            
equation  b  c    r  a    c  a    r  b    a  b    r  c   0 , then r is
1    1    
(A) abc (B)  2a  3b  c 
3 14
1     1   
(C) 2a  3b  c  (D)  abc
14 3

5. The set of natural number N is partitioned into arrays of rows and columns in the form of matrices as
6 7 8 . . .
2 3    
m1 = (1), m2    , m3   9 10 11  , ….. mn   . . .  and so on, then
4 5  12 13 14  . . . 
  
(A) the first term in m 10 matrix is 286
(B) the first term in m 10 matrix is 386
(C) sum of the elements of the diagonal in m10 is 3355
(D) sum of the elements of the diagonal in m10 is 4455

6. Area bounded by the curves y = [x2/64 + 2], y = x – 1, and x = 0 above x – axis is:
(A) 2 (B) 3
(C) 4 (D) none of these

x 2  4x  3 2x  4 13
2
7. If (x)  2x  5x  9 4x  5 26  ax 3  bx 2  cx  d , then
8x 2  6x  1 16x  6 104
(A) a = 3 (B) b = 0
(C) c = 0 (D) none of these

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PART – A: (Single Correct Answer Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
2 3
8. The area between the curve y (a + x) = (a – x) and its vertical asymptote is
 2
(A) a (B) 2a2
2
2
(C) 3a (D) none of these

d3 y d2 y dy
9. If y1/ m  y 1/ m  2x then  x 2  1 3
 3x 2
 f m   0 , f(m) is equal to
dx dx dx
2 2
(A) 1 + m (B) 2 – m
(C) m + m2 (D) 1 – m2

10. Bag ‘A’ contains 9 green and 1 red ball, Bag ‘B’ contains 10 balls all of them being green, 9 balls are
drawn randomly from Bag ‘A’ and put into bag ‘B’, and then 9 balls are randomly transferred from bag
p
‘B’ to bag ‘A’. If (in its lowest form) is the chance that the red ball is still there in the bag ‘A’ then
q
the value of (q – p) is equal to _____
(A) 3 (B) 5
(C) 7 (D) 9
  
11. Let O be the interior point of ABC such that 2OA  3OB  6OC  0 where O is origin. If
Area of (ABC) m
 , where m and n are relatively prime, then (m – n) is equal to _____
Area of (AOB) n
(A) 3 (B) 5
(C) 7 (D) 9

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12. The volume of the parallelopiped whose coterminous edges are represented by the vectors
      
2b  c, 3c  a and 4a  b where a  1  sin  i  cos j  sin 2k ,
  2    2    4     2   2    4  
b  sin     i  cos     j  sin  2   k , c  sin    3  i  cos    3  j  sin  2  3  k is
 3   3   3       
 
18 cubic units, then the values of  , in the interval  0,  , is/are
 2
 2
(A) (B)
9 9
 4
(C) (D)
3 9

13. A plane passing through (1, 1, 1) cuts positive direction of co-ordinate axes at A, B and C the volume
of tetrahedron OABC satisfies
9 9
(A) V  (B) V 
2 2
9
(C) V = (D) none of these
2

 3 1 
 
14. Let A =  2 2  , B =  1 1 and C = ABAT, then ATC3A is equal to
 
 1 3 0 1
 
 2 2 
 3 1  1 0
(A)   (B)  3 
 2 2  1
 1 0   2 
 3
1 1 3
(C)  2 
 (D)  
 0 1
0 3 

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PART – A: (Paragraph Type)

This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 15 to 16

A ray of light is coming along the line L = 0 and strikes the plane mirror kept along the plane P = 0 at B. A(2,
x  2 y 1 z  6
1, 6) is a point on the line L = 0 whose image about P = 0 is A. It is given that L = 0 is  
3 4 5
and P = 0 is x + y – 2z = 3.

15. Co-ordinates of A are


(A) (6, 5, 2) (B) (6, 5, – 2)
(C) (6, – 5, – 2) (D) none of these

16. If L1 = 0 is the reflected ray, then its equation is


x  10 y  5 z  2 x  10 y  15 z  14
(A)   (B)  
4 4 3 3 5 5
x  10 y  15 z  14
(C)   (D) none of these
4 5 3

Paragraph for Question Nos. 17 to 18

B and C are the only two people who will enter the Lady Gaga Jingle contest. Only one entry is allowed per
contestant and the judge will declare the one winner as soon as he receives a suitably inane entry, which may
be never. B writes inane jingles rapidly but poorly. He has probability 0.7 of submitting his entry first. If C has
not already won the contest, B’s entry will be declared the winner with probability 0.3. C writes slowly, but he
has a gift for this sort of thing. If B has not already won the contest by the time of C’s entry, C will be declared
the winner with probability 0.6.

17. What is the probability that B will win?


(A) 0.24 (B) 0.142
(C) 0.18 (D) 0.246

18. Given that B wins, what is the probability that C’s entry arrived first?
(A) 0.146 (B) 0.124
(C) 0.28 (D) 0.236

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FIITJEE INTERNAL TEST


PHYSICS, CHEMISTRY & MATHEMATICS
CPT–1 PHASE–5 CODE: 101324.1 PAPER–2

ANSWERS
PHYSICS (SECTION –I)

1. C, D 2. A, B, D 3. A, B, C 4. A, C
5. A, C 6. B, C 7. A, C, D 8. B
9. A 10. A 11. B 12. C
13. B 14. A 15. B 16. A
17. C 18. B

CHEMISTRY (SECTION –II)

1. A, B, C 2. A, C, D 3. A, B 4. C, D
5. A, B, D 6. ABCD 7. A, B, C 8. A
9. D 10. B 11 A 12. C
13. C 14. D 15. A 16. A
17. A 18. B

MATHEMATICS (SECTION –III)

1. A, B, C 2. A, B, C 3. A, B, C 4. A, D
5. A, C 6. C 7. B, C 8. C
9. D 10. D 11. B 12. C
13. B 14. D 15. B 16. C
17. D 18. A

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HINTS & SOLUTIONS


PHYSICS (SECTION –I)

1. C, D
1 1 1
  (mirror formula)
f v u
f =  24 cm

2. A, B, D
(A) x = (S2P t + 2t)  (S1P  t + 1t)
dy
=(S2P  S1P) + t(2  1) = + t(2  1)
D
For central max, x = 0
Dt
y= (1  2) = 6.67mm
d
10
(B) Path difference at point O = t(2  1) = m
6
2
 Phase difference  = x  

Hence intensity will be minimum i.e. dark.

(D) For point O to become dark



t (2 ~ 1) = (2n + 1)
2
 2n  1 
t=
2  2 ~ 1 

 tmin = = 9.9m
2   2 ~ 1 

3. A, B, C
XL = 2XC
XC = 4XC
XL = 2XL
 XL  XC = 2XL  4XC = 2[XL  2XC] = 0

4. A, C
Let M  kha Gb c , where k is a dimensionless constant
a b c
 ML0 T 0   ML2 T 1  M1L3 T 2  ML1T 1 
5 1 1
 a ,b and c 
9 3 9
Let L  kha Gb c , where k is a dimensionless constant
a b c
 M0LT 0   ML2 T 1  M1L3 T 2  ML1T 1 
1 1
 a  , b  0 and c 
3 3

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5. A, C
u + v = 150 cm
du
In case I 2     4.5 mm
2 v 
d v 
In case II 2     2 mm
2u 
On solving u = 90 cm, v = 60 cm and d = 3mm
So, f = 36 cm and  = 0.2 mm

6. B, C
 1  1 1
E0 z2  1    E0 z2     3E0
 9 4 9
z=2
1/2 = 3
 1
KE1  E0  1    
 9
 1
KE2  E0 z2  1    
 4 
1
KE  2 = 8.5 eV.

7. A, C, D
 T
Time taken by wire loop to enter into the magnetic field (Region I) above PQ is, t =  , during
4 8
this time induced emf and hence current will appear through wire frame .
Bl2
e1  induced emf =
2
Thermal energy dissipated in time t1
e2 B2 l4
=H1 = 1 t1 
R 16R
B 2 l4
Similarly, thermal energy developed when frame moves from region I to region II is, H2 =
4R
Thermal energy will also develop when loop comes out from magnetic field and is given by, H3 =
B2 l4
16R
So, total thermal energy developed in one revolution is,
3B2 l4
H  H1  H2  H3 
8R
H 3B2 l4
Average power produced, Pav  
T 16R

8. B
x dB
E
2 dt
3Kxt 2 x
E dx
2
3Kxt 2 2xdx
d   q.x
2 r 2

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2 r
3Kt q 3

r2
x dx
0

3Kq.t 2 2
 .r …(i)
4
torque due to friction force
d  dmgx
r
qm 2 2
  2g 2 x dx  mgr …(ii)
r 0
3
3Kq.t 2r 2 2
 mgr
4 3
8mg
t = 2 seconds.
9Kqr

9. A
1 hc
mu2  ev 
2 min
10. A
9
intensity of S1 = 9 times of intensity S2
4
2
Intensity of maxima =  I1  I2  = 9 I2
 S2P – S1P = n for maxima
d2  n2  2
d2  x 2  x  n  x=
2n
11. B
Q  x m y 
  n  
Q  x y 

12. C
The contribution due to any one the 4 3r
cylinder P
  Q
E2 E1
r 2 dB r 2 dB 1 dB 60°
| E |   4r
2x dt 8r dt 8 dt 4r
1 E3
O
E1  V / m
4
|E2| = 1/4 V/m 4r
|E3| = 1/8 V/m
(directions as shown in the figure)
   13
E1  E 2  E3  V/m
8 R E3

13. B
Smallest main scale division = 0.05 cm
Diamter = Main scale reading + Vernier coincidence L.C.
= 5.10 + 24  0.001 = 5.124 cm

14. A
1sin i = 2 sin r

15. B

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16. A

0 2i
15-16. d  B  adx  adx
dx
4 x
 L
0 a  an2
 i | nx |2a
a
 0 i0 sin t I = I0 sin (t) C
I = I0 sin (t)
2 
emf =
x
dy 0  0 an2
  cos t  K cos t
dt 

0  0 an2
where K =

1 L C
Z  x L  x C  L 
C
i

~
e K   eL
i  cos  t  
Z  1   2
 L  C  eL  eC
 
i
 0  0 an2    
i  cos  t   eC
 1   2
  L 
 C 

17. C
In a convex lens for the distance between an object and its real image is minimum when
u = 2f 1. Hence after separation through the glass slab the image formed will act as object placed at a
distance 2f 1. Hence shifting s = 3f 1 - 2f 1 = f 1
 1 t
but s = t  1     =
  t  f1

18. B
When the concave lens of focal length f2 is placed in contact with the convex lens. The focal length of
the combination
1 1 1
 
F f1 f2
1 1 1
also  
v u F
u = 2f1
1 1 1 f  2f1
  = 2
v  2f1 f2 2f1f2
2f1f2
v =
f2  2f1
2f1f2 4f12
shift of the image = v - v = - 2f 1 =
f2  2f1 f2  2f1
4f12
As f 2 >> f1 Hence shifting of image =
f2

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-23

CHEMISTRY (SECTION –II)

1. A, B, C

2. A, C, D
rK  1.33
Radius ratio,   0.678 which is less than 0.73  KBr has FCC lattice.
rBr  1.96
rCs 1.69
  0.863 which is greater than 0.73  CsBr has BCC lattice.
rBr  1.96
rMg2 0.66
  0.472 which less than 0.73  MgO has FCC lattice.
rO2 1.40
rSr 2 1.12
  0.609 which is less than 0.736  SrS has FCC lattice.
rS2 1.84

3. A, B
More is the chelation more is the stability so for the given complexes stability is gradually increasing
from [Cd(CH3NH2)4]2+ to [Cd(trien)]2+. Or in the formation of the given complexes entropy is gradually
increasing in the order [Cd(CH3NH2)4]2+ < [Cd(en)2]2+ < [Cd(trien)]2+. So given order is wrong.
H

O O-

CH 3  C  N N  C  CH 3

Ni2+

CH 3  C  N N  C  CH 3

O- O

H
So, two intramolecular hydrogen bonds are there.

4. C, D

5. A, B, D
(A) Ba  NO2 2  H2SO 4  BaSO 4  HNO2
(B) HNO3 is oxidizing acid, which oxidize H2S to ‘S’.
(C) P4  3NaOH  3H2 O  PH3  3NaH2PO2
(D) P4O10  2H2O 
 4H3PO3

6. ABCD

7. A, B, C

8. A
O2– is replaced by X-8/3, so formula of spinel is MgAl2X3 and deficiency by one anion.

9. D
Tf  K f M

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-24

(Macid)observed = 120
Meq of acid = Meq of base
(Macid)Normal = 150
150
i  1.25
120
i=1+
 = 25%
pH > 7 as the solution contains salt of strong base and weak acid.
Osmotic pressure is same by calculation.

10. B
Due to high charge density on central metal electron transfer through back bonding increases which
increases M-C bond strength & thus its stretching frequency.

11 A

Cell constant = G* = conductivity × resistance = 1.29 S/m × 100 W = 129 m –1 = 1.29 cm–1
–1 G * 129m 1
Conductivity of 0.02 mol L KCl solution = cell constant / resistance    0.248S m1
R 520
Concentration = 0.02 mol L–1 = = 1000 × 0.02 mol m –3 = 20 mol m–3
K 248  103 Sm 1
Molar conductivity = m    124  10 4 S m2mol1
C 20mol m 3
1.29cm 1
Alternatively, K   0.248  102 S cm 1
520
0.248  10 2 S cm1  1000 cm3 L1
and m  K  1000 cm3 L1molarity 1   124 S cm2 mol1
0.02 mol L1

12. C

O O O O
O
S P P
O O HO OH
O O O O
S S P
O
O O O OH
  SO3 HPO3 3
13. C
Cr2 O72   14H  6e   2Cr 3   7H2 O;
 2Cl 
 Cl2  2e   3
 
2
Cr2 O 7  14H  6Cl  2Cr 3   3Cl2  7H2 O;
 

Eocell  1.23   1.36 


 0.13
2 3
0.0591 Cr 3   PCl2  0.0591  0.1 1
2 3

Ecell  0.13  log 6 14


 0.13  log 6 14
 0.327 V
6 Cr2 O72   Cl  H  6  0.01 0.1  0.1
14. D
X – FCC = 4
Y – Tetrahedral Void = 8
Z – ½ of Octahedral Void = 2
Hence, X4Y8Z2  X2Y4Z

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-25

15. A
If mole fraction of liquid A in vapour is = x
Mole fraction of liquid A in solution is = 1 – x
Mole fraction of liquid B in vapour is 1– x
Mole fraction of liquid B in solution is = x
PA PA0 XA PB PB0 XB
YA   YB  
PT PT PT PT
102(1 x) 32 x
x  YA  (1 x)  YB 
P P
x 102 (1 x)
Dividing =
(1  x) 32 x
x2 102
2
=
(1 x) 32
x = 0.641
YB = 0.641 YA = 0.359
XB = 0.359 XA = 0.641
P = PB0 XB  PT0 XT = 102 × 0.359 + 32 × 0.64 = 57.13

16. A
Solvent A moles =a
Solvent B moles =b
Solute moles =c
a b
At 20°C 15   85  40 ....(1)
abc ab c
a b
At 30°C  34  136  68 ....(2)
ab c abc
On simplifying we get a = b then using eq. (1)
we get a + b+ c = 2.5 b = 2.5 a
a b
= 0.4 →  0.4
ab c ab c
c = 0.2
Solvent XA = 0.4
Solvent XB = 0.4
Solute = 0.2
17. A
18. B

MATHEMATICS (SECTION –III)

1. A, B, C
d  3x2
1  x 2 y   3x  y 1  x2  
   c and y(0) = 2  c = 2
dx   2
3x2 3x2  4 3 1
y 1  x 2   2  y  = 
2 2  x  1
2 2 2  x  1
2

3 
Range of f(x) =  , 2 
2 

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-26

2. A, B, C
Applying C1  C1 + C2 , we get
2 cos 2 x sin 2 x

2 1  cos 2 x sin 2 x

1 cos 2 x 1  sin 2x

Applying R2  R2 – R1 and R3 R3 – R1 , we get


2 cos 2 x sin 2 x

0 1 0 = 2 + sin2x.   = 3 ,  = 1

1 0 1

3. A, B, C
 1 0 0   1 0 0  1 0 0 
A =  1 0 1  1 0 1  1 1 0 
2

0 1 0  0 1 0  1 0 1


 1 0 0  1 0 0   1 0 0 
A =  1 0 1 1 1 0   2 0 1
3

0 1 0  1 0 1  1 1 0 


 A – A2 = A – I 3
3

Det A n  I = Det((A – I)(I + A + A2 + … + An –1)) = Det (A – I) Det(I + A + A2 + … + An – 1) = 0


If n is even An – An – 1 = A2 – A
If n is odd An – An – 1 = A – I
n n2
Consider n is even, An =   A 2   I
 2  2 

4. A, D
  
 b  c    r  a    b  c   a  r   b  c   r  a
           
Now,  b  c    r  a    c  a    r  b    a  b    r  c   0
                     
  b  c   a   c  a   b   a  b   c  r  b  c   r  a   c  a   r  b   a  b   r  c = 0
              
 b  r  c  r  a  c  r  a  r  b  a  r  b  r  c  0
     
 br  cr  ar  
   
therefore r    a  b  c 
2 1
r  1  3 2  1    
3
 1   
 r  abc
3

5. A, C
Sum of number of elements of mn – 1 matrices will give you the last element of m n – 1 matrix
n  n  1  2n  1
So, last element of mn – 1 matrix is = 12 + 22 + 32 + ….. + (n – 1)2 =
6
10  9  19
So, first element of m 10 matrix =  1  286
6
Common difference in the diagonal elements of mn matrix is n + 1, so in m10, common different = 11

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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-27

10
Sum of diagonal elements = 2  286  10  1  11 = 5(572 + 99) = 5  671 = 3355
2

6. C
y = [x2/64 + 2], y = x – 1 and x = 0 above x-axis is
y

(0, 3)
B
C

(-8, 0) O A (3, 0) (8, 0) x

y=x-1

so required area of trapezium (OABCO)


1
= 1  3  2  = 4.
2

Alternate
-8 < x < 8  y = 2
A=22
= 4 sq. units.

7. B, C
2x  4 2x  4 13 x 2  4x  3 2 13
 (x)  4x  5 4x  5 26  2x 2  5x  9 4 26 = 0
16x  6 16x  6 104 2
8x  6x  1 16 104

8. C
x = –a is the only asymptote to the given curve N
a
A  2 ydx  3a2

a (–a, 0)B (a, 0)

9. D
y 2/m  2xy1/m  1  0
2x  4x 2  4
y1/ m 
2
 
log y  mlog x  x 2  1 further differential w.r.t x
y1 m
   x 2  1 y12  m2 y 2
y 2
x 1
  x 2  1 y 2  xy1  m2 y (diff.....)

10. D
9
p C  1C1 18 C9 9 10
 1  108  19  1 
q C9 C9 19 19
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-28

So q – p = 19 – 10 = 9

11. B
1      
Area of ABC = a  b  b  c  c  a
2
  
Now given 2a  3b  6c  0
    
Cross with a , 3a  b  6a  c  0
   
or a  b  2  c  a  ..... (1)

Again cross with b
   
2a  b  6c  b = 0
   
or a  b  3  b  c 
1  
Area of OAB = a  b
2
1  1 1
a  b 1   
Area of ABC 2  2 3  11
  
Area of AOB 1  6
ab
2
So m = 11, n = 6  (m – n) = 5

12. C
     
Volume = 2b  c,3c  a,4a  b   18
 2  3
24 a b c   18  a b c  
2

1  sin   cos  sin 2


  2   2   4 
Now, abc   sin     cos     sin  2  
 3   3   3 
 2   2   4 
sin     cos     sin  2 
 3   3   3 
Applying R1  R1  R2  R3 we get after simplification ,

abc   3 cos3  3
  2
1  2 4  2 4 
 cos 3    3  , ,   , , .
2 3 3 3 9 9 9

13. B
x y z
Let the equation of the plane be   1
a b c
1 1 1
   1
a b c
1
 volume of tetrahedron OABC = v =  abc 
6
3
Now (abc)1/3  3
1 1 1
 
a b c
9
 abc  27  v  .
2

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14. D
T T T –1
AA = A A = I  A = A
–1
C = ABA
–1 –1
A C = BA
T 3 –1 2 –1 2 –1 3
Now A C A = A (C.C )A = A C(C A) = BA (C)(CA) = B
1 3
=  .
0 1

15. B
Let A(x2, y2, z2) be image of A(2, 1, 6) about mirror x + y – 2z = 3 then
x 2  2 y 2  1 z 2  6 2  2  1  12  3 
   =4
1 1 2 12  12  22
 (x2, y2, z2)  (6, 5, – 2).

16. C
Equation of reflected ray L1 = 0 is
line joining A(x2, y2, z2) and B(– 10, – 15, – 14)
x  10 y  15 z  14
i.e.  
16 20 12
x  10 y  15 z  14
   .
4 5 3

17. D

18. A

17–18. B1: B submits his entry first


C1: C submits his entry first
Bw: B’s entry wins
Cw: C’s entry wins

Bw 0.21
0.3
0.6 Cw 0.294
B1
0.7 0.7 Bw
0.4 Cw 0.196
Entry

Cw 0.18
0.6
0.3 Bw 0.036
C1
0.4 Cw
0.7 Bw 0.084

17. P(B will win) = 0.21 + 0.036 = 0.246.

18. P(C’s entry arrived first/ B wins)


0.036
=  0.1463 .
0.246

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