STP Phase 5 Paper 2
STP Phase 5 Paper 2
Pleas e r ead the instructions carefully. You are allotted 5 minutes specific ally for this purpose.
You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. SECTION–I is Physics, SECTION–II is Chemistry and SECTION–III is Mathematics.
4. Each part is further divided into one part: Part – A
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All One Part.
Part–A (01 – 07) contains 07 multiple choice questions which have one or more than one correct answer.
Each question will be evaluated according to the following marking scheme.
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of
which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Part–A (08 – 14) contains 07 Multiple Choice Questions which have Only One Correct answer. Each
question will be evaluated according to the following marking scheme.
Full Marks : +3 If only (all) the correct option(s) is (are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Part–A (15 – 18) contains 2 Paragraphs. Based upon each paragraph, 2 Multiple Choice Questions have to
be answered. Each question has Only One Correct answer and carries +3 marks for the correct answer
and 0 mark for a wrong answer.
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-2
SECTION – I : PHYSICS
PART – A: (Multi Correct Answer Type)
This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
3. In a certain series LCR A.C. circuit it is found that XL = 2XC and phase difference between the current
and voltage is /4. If now capacitance is made 1/4th & the inductance and resistance are doubled then
which are not correct.
(A) voltage will lead current by a phase of tan1(1/2).
(B) voltage will lag behind current by a phase of tan1(1/2).
(C) voltage will lag behind current by a phase of /4.
(D) voltage and current will be in same phase.
4. If Planck constant h, Gravitational constant G and viscosity of a fluid are considered as fundamental
quantities, then dimensions of mass M and length L will be
5 1 1 1 5 1
(A) M h 9 G 3 9 (B) M h 3 G 9 9
1 1 5 1
(C) L h 3 G 0 3 (D) L h 9 G 0 3
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-3
6. Energy liberated in the de–excitation of hydrogen atom from 3rd level to 1st level falls on a photo–
cathode. Later when the same photo–cathode is exposed to a spectrum of some unknown hydrogen
like gas, excited to 2nd energy level, it is found that the de–Broglie wavelength of the fastest
photoelectrons, now ejected has decreased by a factor of 3. For this new gas, difference of energies
of 2nd Lyman line and 1st Balmer line is found to be 3 times the ionization potential of the hydrogen
atom. Select the correct statement(s) :
(A) The gas is lithium.
(B) The gas is helium.
(C) The work function of photo–cathode is 8.5 eV.
(D) The work function of photo–cathode is 5.5 eV.
7. A wire frame in the form of a part of circle (sector) of radius l Region - I Region - II
and resistance R is free to rotate about an axis passing x x x x x
through O and perpendicular to plane of paper as shown in x x x x x
figure. The angle of the sector is and it is rotating with x x x x x
4
x x x x x
constant velocity as shown. Above line PQ uniform
x x x x x
magnetic field of magnitude B exists in the direction
P O Q
perpendicular to plane of paper. In region I field is outward l
/4
while in region II, field is inward.
B 2 l4
(A) The thermal energy dissipated in wire frame when it moves from region I to region II, is .
4R
(B) The thermal energy dissipated in wire frame when it moves from region I to region II, is zero.
3B2 l4
(C) Total thermal energy dissipated in one cycle is
8R
3B2 2l4
(D) Average power produced in wire frame is
16R
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This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
8. A uniform disc of radius r and mass m is charged uniformly with the charge q. Disc
B
This disc is placed flat on a rough horizontal surface having coefficient of
friction . A uniform magnetic field is present in a circular region (a > r) but a
varying as kt3 as shown in figure. The time after which the disc begins to r
rotate is (Given r = 1 m, m = 18 kg, q = 1C, = 0.1, K = 4 Ts3, g = 10 m/s2)
2ha
(C) (D) none of these
mc
h planck’s constant ; m mass of electron ; c speed of light
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-5
n
x
11. If Q and x, y are absolute errors in the measurement of x and y, then absolute error Q in Q
ym
is
x y x y
(A) Q = n m (B) Q = n m Q
x y x y
x y x y
(C) Q = n m Q (D) Q = n m Q
x y y x
5 1
(A) V/m (B) V/m
8 8
13
(C) V/m (D) zero
8
13. The diameter of a cylinder in measured using a vernier calipers with no zero error. It is found that the
zero of the vernier scale lies between 5.10 and 5.15 cm of the main scale. The vernier scale has 50
divisions equivalent to 2.45 cm. The 24th division of the vernier scale exactly coincides with one of the
main scale divisions. The diameter of the cylinder is
(A) 5.112 cm (B) 5.124 cm
(C) 5.136 cm (D) 5.148 cm
14. A ray of light traveling in glass ( = 3/2) is incident on a horizontal C D
glass air surface at the critical angle C. If a thin layer of water ( = Water O r
A B
4/3) is now poured on the glass air surface, the ray of light emerge
into air at the water air surface at an angle of …… R 3
c R
2
(A) rad (B) rad
2 6
(C) rad (D) rad
3 4
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-6
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
15. The magnetic flux due to the magnetic field produced by the long parallel wires through the square
loop is
I a n(2) sin( t) I a n(2) sin( t)
(A) 0 0 (B) 0 0
2
0I0 a n(3) sin( t) 0I0 a n(3) sin( t)
(C) (D)
2
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-7
A convex lens of focal length f1 is placed in front of a luminous point object. The separation between the
object and the lens is 3f 1. A glass slab of thickness t is placed between object and the lens. A real image of
the object is formed at the shortest possible distance from the object.
18. Now, if a concave lens of very large focal length f2 is placed in contact with the convex lens, then the
shifting of the image is
f2 4f 2
(A) 1 (B) 1
f2 f2
8f12 f12
(C) (D)
f2 4f2
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(A) Cold solution of Ba(NO2)2 on mixing with dil.H2SO4 produces BaSO4 and nitric oxide gas
(B) HNO3 can not be used for the preparation of H2S from metal sulphides.
H2 O
(C) P4 NaOH PH3 NaH2PO3
(D) P4O10 on absorbing limited amount of H2O may form meta phosphoric acid.
– –
7. For I2 + 2e 2I , standard reduction potential = +0.54 volt.
For, 2Br– Br2 + 2e–, standard oxidation potential = – 1.09 volt
For, Fe Fe2+ + 2e–, standard oxidation potential = +0.44 volt
Which of the following actions are spontaneous?
(A) Br2 + 2I– 2Br– + I2 (B) Fe + Br2 Fe2+ + 2Br–
(C) Fe + I2 Fe2+ + 2I– (D) I2 + 2Br– 2I– + Br2
8. In the normal spinel having one eighth of the tetrahedral holes, occupied by one type of metal ion and
one half of the octahedral holes occupied by another type of metal ion. Such a spinel is formed by
Mg2+, Al3+ and O2–. If oxide ion is replaced by X-8/3, the number of anionic vacancies per unit cell is;
(A) 1 (B) 2
(C) 3 (D) 3/4
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-10
9. 1.0 g of a monobasic acid HB (having pKa = 5) in 100 g water lowers the freezing point by 0.155 K. if
0.45 g of same acid required 15 ml M/5 NaOH solution for complete neutralization
(Kf H2O = 1.86 k kg mol-1, density of H2O is 1g ml-1) then which of the following option is incorrect
regarding above question:
(A) degree of ionization of acid is 25%
(B) the pH of the resultant solution at the end point of neutralization is greater than 7
(C) normal molecular mass of acid is 150
(D) 1.5g of acid HB is hypotonic with 0.625 g urea at the same temperature and same volume of H2O
11. Resistance of a conductivity cell filled with 0.1 mol L–1 KCl solution is 100. If the resistance of the
–1
same cell when filled with 0.02 mol L KCl solution is 520, calculate the molar conductivity of 0.02
mol L KCl solution. The conductivity of 0.1 mol L–1 KCl solution is 1.29 S/m.
–1
12. Which of the following species has/have same number of X – O – X linkages where X = S or P or B.
(I) SO3 (II) P4 O6
(III) SO3 (IV) HPO3 3
(A) II and III (B) I and III
(C) I and IV (D) II and IV
14. A solid is formed and it has three types of atoms X, Y and Z. X forms a FCC lattice with Y atoms
occupying all tetrahedral voids and Z atoms occupying half of octahedral voids. The formula of solid
is:
(A) X4YZ2 (B) X4Y2Z
(C) XY2Z4 (D) X2Y4Z
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-11
In 1886, the French chemist, Francois Raoult after a series of experiments on a number of solvents including
water, benzene and ether, succeeded in establishing a relationship between the lowering of vapour pressure
of a solution and the mole fraction of the non volatile solute.
0
P1 = X1P1
0
Where P1 is vapour pressure of solvent in an ideal solution and P1 is vapour pressure of a pure solvent.
X1 mole fraction of solvent and X2 mole fraction of solute.
X1 + X2 = 1
P1 = (1–X2) P10
P10 P1
= X2
P10
The relative lowering of vapour pressure of a solution containing a non-volatile solute is equal to the
mole fraction of solute present in the solution.
15. The vapour pressure of pure liquid X and pure liquid Y are 36 and 100 mm of Hg respectively at 400
K. A liquid mixture of X and Y is composed of 1 mole each. What will be the pressure, when 1 mole of
the mixture has been vapourized at 400 K
(A) 60 (B) 67
(C) 49.2 (D) 55
16. A solution of non-volatile solute AX in a mixture of solvent A and Solvent B has a vapour pressure of
40 mm of Hg at 20°C and 68 mm of Hg at 30°C. The vapour pressure of pure solvent (A) is 15 mm of
Hg at 20°C and 34 mm of Hg at 30°C and the vapour pressure of pure solvent (B) is 85 mm of Hg at
20°C and 136 mm Hg at 30°C. Find the mole fraction of solvent A and solute respectively.
(A) 0.4 and 0.2 (B) 0.4 and 0.4
(C) 0.2 and 0.4 (D) 0.4 and 0.3
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-12
Metals are extracted from their ores by a wide variety of techniques. The most common ores are oxides. Most
metals are obtained by direct treatment of theirs ores with chemical agents, but the extraction of certain
others require electrolysis. An example of the former type of process is the extraction of iron from its oxide,
described by the following equation:
Fe2 O3 + 3C 2Fe + 3CO
The relative ease of extraction of a metal from its oxide can be estimated using the Ellingham diagram, as
shown in the figure.
The diagram plots the free energies of formation of various oxides per mole of consumed oxygen as a function
of absolute temperature.
0
-100 2CO2
of metal oxide formation
eO + O2
-200 2F 2CO
-300 + O2 C + O2 CO2
2Fe
-400
-500 2C
+O
2
-600 2CO
-700
-1
G/kJ mol
-800
-900
-1000
-1100
-1200
17. Which of the following statements is correct regarding thermochemical reduction of FeO at 8000C?
(A) C CO is best reducing agent (B) C CO2 is best reducing agent
(C) CO CO2 is best reducing agent (D) All are equally efficient reducing agent
18. Which of the following best explains why the free energy of formation of Fe2O3 becomes less negative
as the temperature is increased:
(A) The free energy of formation is independent of the absolute temperature.
(B) Entropy drops as a result of the consumption of oxygen.
(C) At low temperature, the free energy of formation becomes less dependent on the enthalpy of
formation.
(D) As entropy increases, the free energy of formation increases.
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This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
dy
1. Let y = f(x) satisfies the differential equation 1 x 2 2xy 3x and f(0) = 2 then the correct
dx
statement about y = f(x) is
(A) it is differentiable in the entire domain (B) it has exactly two points of inflections
(C) if has exactly one integer in its range (D) it is a monotonic function in the domain
2. If maximum and minimum values of the determinant sin 2 x 1 cos 2 x sin 2 x are
1 0 0
3. If A = 1 0 1 , then
0 1 0
(A) A3 – A2 = A – I3 (B) Det (A2010 – I3) = 0
1 0 0 1 1 0
(C) A = 25 1 0 (D) A = 25 1 0
50 50
25 0 1 25 0 1
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-14
4. Let a, b and c are three mutually perpendicular unit vectors and a unit vector r satisfying the
equation b c r a c a r b a b r c 0 , then r is
1 1
(A) abc (B) 2a 3b c
3 14
1 1
(C) 2a 3b c (D) abc
14 3
5. The set of natural number N is partitioned into arrays of rows and columns in the form of matrices as
6 7 8 . . .
2 3
m1 = (1), m2 , m3 9 10 11 , ….. mn . . . and so on, then
4 5 12 13 14 . . .
(A) the first term in m 10 matrix is 286
(B) the first term in m 10 matrix is 386
(C) sum of the elements of the diagonal in m10 is 3355
(D) sum of the elements of the diagonal in m10 is 4455
6. Area bounded by the curves y = [x2/64 + 2], y = x – 1, and x = 0 above x – axis is:
(A) 2 (B) 3
(C) 4 (D) none of these
x 2 4x 3 2x 4 13
2
7. If (x) 2x 5x 9 4x 5 26 ax 3 bx 2 cx d , then
8x 2 6x 1 16x 6 104
(A) a = 3 (B) b = 0
(C) c = 0 (D) none of these
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This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
2 3
8. The area between the curve y (a + x) = (a – x) and its vertical asymptote is
2
(A) a (B) 2a2
2
2
(C) 3a (D) none of these
d3 y d2 y dy
9. If y1/ m y 1/ m 2x then x 2 1 3
3x 2
f m 0 , f(m) is equal to
dx dx dx
2 2
(A) 1 + m (B) 2 – m
(C) m + m2 (D) 1 – m2
10. Bag ‘A’ contains 9 green and 1 red ball, Bag ‘B’ contains 10 balls all of them being green, 9 balls are
drawn randomly from Bag ‘A’ and put into bag ‘B’, and then 9 balls are randomly transferred from bag
p
‘B’ to bag ‘A’. If (in its lowest form) is the chance that the red ball is still there in the bag ‘A’ then
q
the value of (q – p) is equal to _____
(A) 3 (B) 5
(C) 7 (D) 9
11. Let O be the interior point of ABC such that 2OA 3OB 6OC 0 where O is origin. If
Area of (ABC) m
, where m and n are relatively prime, then (m – n) is equal to _____
Area of (AOB) n
(A) 3 (B) 5
(C) 7 (D) 9
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-16
12. The volume of the parallelopiped whose coterminous edges are represented by the vectors
2b c, 3c a and 4a b where a 1 sin i cos j sin 2k ,
2 2 4 2 2 4
b sin i cos j sin 2 k , c sin 3 i cos 3 j sin 2 3 k is
3 3 3
18 cubic units, then the values of , in the interval 0, , is/are
2
2
(A) (B)
9 9
4
(C) (D)
3 9
13. A plane passing through (1, 1, 1) cuts positive direction of co-ordinate axes at A, B and C the volume
of tetrahedron OABC satisfies
9 9
(A) V (B) V
2 2
9
(C) V = (D) none of these
2
3 1
14. Let A = 2 2 , B = 1 1 and C = ABAT, then ATC3A is equal to
1 3 0 1
2 2
3 1 1 0
(A) (B) 3
2 2 1
1 0 2
3
1 1 3
(C) 2
(D)
0 1
0 3
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This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
A ray of light is coming along the line L = 0 and strikes the plane mirror kept along the plane P = 0 at B. A(2,
x 2 y 1 z 6
1, 6) is a point on the line L = 0 whose image about P = 0 is A. It is given that L = 0 is
3 4 5
and P = 0 is x + y – 2z = 3.
B and C are the only two people who will enter the Lady Gaga Jingle contest. Only one entry is allowed per
contestant and the judge will declare the one winner as soon as he receives a suitably inane entry, which may
be never. B writes inane jingles rapidly but poorly. He has probability 0.7 of submitting his entry first. If C has
not already won the contest, B’s entry will be declared the winner with probability 0.3. C writes slowly, but he
has a gift for this sort of thing. If B has not already won the contest by the time of C’s entry, C will be declared
the winner with probability 0.6.
18. Given that B wins, what is the probability that C’s entry arrived first?
(A) 0.146 (B) 0.124
(C) 0.28 (D) 0.236
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ANSWERS
PHYSICS (SECTION –I)
1. C, D 2. A, B, D 3. A, B, C 4. A, C
5. A, C 6. B, C 7. A, C, D 8. B
9. A 10. A 11. B 12. C
13. B 14. A 15. B 16. A
17. C 18. B
1. A, B, C 2. A, C, D 3. A, B 4. C, D
5. A, B, D 6. ABCD 7. A, B, C 8. A
9. D 10. B 11 A 12. C
13. C 14. D 15. A 16. A
17. A 18. B
1. A, B, C 2. A, B, C 3. A, B, C 4. A, D
5. A, C 6. C 7. B, C 8. C
9. D 10. D 11. B 12. C
13. B 14. D 15. B 16. C
17. D 18. A
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-19
1. C, D
1 1 1
(mirror formula)
f v u
f = 24 cm
2. A, B, D
(A) x = (S2P t + 2t) (S1P t + 1t)
dy
=(S2P S1P) + t(2 1) = + t(2 1)
D
For central max, x = 0
Dt
y= (1 2) = 6.67mm
d
10
(B) Path difference at point O = t(2 1) = m
6
2
Phase difference = x
Hence intensity will be minimum i.e. dark.
3. A, B, C
XL = 2XC
XC = 4XC
XL = 2XL
XL XC = 2XL 4XC = 2[XL 2XC] = 0
4. A, C
Let M kha Gb c , where k is a dimensionless constant
a b c
ML0 T 0 ML2 T 1 M1L3 T 2 ML1T 1
5 1 1
a ,b and c
9 3 9
Let L kha Gb c , where k is a dimensionless constant
a b c
M0LT 0 ML2 T 1 M1L3 T 2 ML1T 1
1 1
a , b 0 and c
3 3
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-20
5. A, C
u + v = 150 cm
du
In case I 2 4.5 mm
2 v
d v
In case II 2 2 mm
2u
On solving u = 90 cm, v = 60 cm and d = 3mm
So, f = 36 cm and = 0.2 mm
6. B, C
1 1 1
E0 z2 1 E0 z2 3E0
9 4 9
z=2
1/2 = 3
1
KE1 E0 1
9
1
KE2 E0 z2 1
4
1
KE 2 = 8.5 eV.
7. A, C, D
T
Time taken by wire loop to enter into the magnetic field (Region I) above PQ is, t = , during
4 8
this time induced emf and hence current will appear through wire frame .
Bl2
e1 induced emf =
2
Thermal energy dissipated in time t1
e2 B2 l4
=H1 = 1 t1
R 16R
B 2 l4
Similarly, thermal energy developed when frame moves from region I to region II is, H2 =
4R
Thermal energy will also develop when loop comes out from magnetic field and is given by, H3 =
B2 l4
16R
So, total thermal energy developed in one revolution is,
3B2 l4
H H1 H2 H3
8R
H 3B2 l4
Average power produced, Pav
T 16R
8. B
x dB
E
2 dt
3Kxt 2 x
E dx
2
3Kxt 2 2xdx
d q.x
2 r 2
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-21
2 r
3Kt q 3
r2
x dx
0
3Kq.t 2 2
.r …(i)
4
torque due to friction force
d dmgx
r
qm 2 2
2g 2 x dx mgr …(ii)
r 0
3
3Kq.t 2r 2 2
mgr
4 3
8mg
t = 2 seconds.
9Kqr
9. A
1 hc
mu2 ev
2 min
10. A
9
intensity of S1 = 9 times of intensity S2
4
2
Intensity of maxima = I1 I2 = 9 I2
S2P – S1P = n for maxima
d2 n2 2
d2 x 2 x n x=
2n
11. B
Q x m y
n
Q x y
12. C
The contribution due to any one the 4 3r
cylinder P
Q
E2 E1
r 2 dB r 2 dB 1 dB 60°
| E | 4r
2x dt 8r dt 8 dt 4r
1 E3
O
E1 V / m
4
|E2| = 1/4 V/m 4r
|E3| = 1/8 V/m
(directions as shown in the figure)
13
E1 E 2 E3 V/m
8 R E3
13. B
Smallest main scale division = 0.05 cm
Diamter = Main scale reading + Vernier coincidence L.C.
= 5.10 + 24 0.001 = 5.124 cm
14. A
1sin i = 2 sin r
15. B
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-22
16. A
0 2i
15-16. d B adx adx
dx
4 x
L
0 a an2
i | nx |2a
a
0 i0 sin t I = I0 sin (t) C
I = I0 sin (t)
2
emf =
x
dy 0 0 an2
cos t K cos t
dt
0 0 an2
where K =
1 L C
Z x L x C L
C
i
~
e K eL
i cos t
Z 1 2
L C eL eC
i
0 0 an2
i cos t eC
1 2
L
C
17. C
In a convex lens for the distance between an object and its real image is minimum when
u = 2f 1. Hence after separation through the glass slab the image formed will act as object placed at a
distance 2f 1. Hence shifting s = 3f 1 - 2f 1 = f 1
1 t
but s = t 1 =
t f1
18. B
When the concave lens of focal length f2 is placed in contact with the convex lens. The focal length of
the combination
1 1 1
F f1 f2
1 1 1
also
v u F
u = 2f1
1 1 1 f 2f1
= 2
v 2f1 f2 2f1f2
2f1f2
v =
f2 2f1
2f1f2 4f12
shift of the image = v - v = - 2f 1 =
f2 2f1 f2 2f1
4f12
As f 2 >> f1 Hence shifting of image =
f2
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-23
1. A, B, C
2. A, C, D
rK 1.33
Radius ratio, 0.678 which is less than 0.73 KBr has FCC lattice.
rBr 1.96
rCs 1.69
0.863 which is greater than 0.73 CsBr has BCC lattice.
rBr 1.96
rMg2 0.66
0.472 which less than 0.73 MgO has FCC lattice.
rO2 1.40
rSr 2 1.12
0.609 which is less than 0.736 SrS has FCC lattice.
rS2 1.84
3. A, B
More is the chelation more is the stability so for the given complexes stability is gradually increasing
from [Cd(CH3NH2)4]2+ to [Cd(trien)]2+. Or in the formation of the given complexes entropy is gradually
increasing in the order [Cd(CH3NH2)4]2+ < [Cd(en)2]2+ < [Cd(trien)]2+. So given order is wrong.
H
O O-
CH 3 C N N C CH 3
Ni2+
CH 3 C N N C CH 3
O- O
H
So, two intramolecular hydrogen bonds are there.
4. C, D
5. A, B, D
(A) Ba NO2 2 H2SO 4 BaSO 4 HNO2
(B) HNO3 is oxidizing acid, which oxidize H2S to ‘S’.
(C) P4 3NaOH 3H2 O PH3 3NaH2PO2
(D) P4O10 2H2O
4H3PO3
6. ABCD
7. A, B, C
8. A
O2– is replaced by X-8/3, so formula of spinel is MgAl2X3 and deficiency by one anion.
9. D
Tf K f M
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-24
(Macid)observed = 120
Meq of acid = Meq of base
(Macid)Normal = 150
150
i 1.25
120
i=1+
= 25%
pH > 7 as the solution contains salt of strong base and weak acid.
Osmotic pressure is same by calculation.
10. B
Due to high charge density on central metal electron transfer through back bonding increases which
increases M-C bond strength & thus its stretching frequency.
11 A
Cell constant = G* = conductivity × resistance = 1.29 S/m × 100 W = 129 m –1 = 1.29 cm–1
–1 G * 129m 1
Conductivity of 0.02 mol L KCl solution = cell constant / resistance 0.248S m1
R 520
Concentration = 0.02 mol L–1 = = 1000 × 0.02 mol m –3 = 20 mol m–3
K 248 103 Sm 1
Molar conductivity = m 124 10 4 S m2mol1
C 20mol m 3
1.29cm 1
Alternatively, K 0.248 102 S cm 1
520
0.248 10 2 S cm1 1000 cm3 L1
and m K 1000 cm3 L1molarity 1 124 S cm2 mol1
0.02 mol L1
12. C
O O O O
O
S P P
O O HO OH
O O O O
S S P
O
O O O OH
SO3 HPO3 3
13. C
Cr2 O72 14H 6e 2Cr 3 7H2 O;
2Cl
Cl2 2e 3
2
Cr2 O 7 14H 6Cl 2Cr 3 3Cl2 7H2 O;
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-25
15. A
If mole fraction of liquid A in vapour is = x
Mole fraction of liquid A in solution is = 1 – x
Mole fraction of liquid B in vapour is 1– x
Mole fraction of liquid B in solution is = x
PA PA0 XA PB PB0 XB
YA YB
PT PT PT PT
102(1 x) 32 x
x YA (1 x) YB
P P
x 102 (1 x)
Dividing =
(1 x) 32 x
x2 102
2
=
(1 x) 32
x = 0.641
YB = 0.641 YA = 0.359
XB = 0.359 XA = 0.641
P = PB0 XB PT0 XT = 102 × 0.359 + 32 × 0.64 = 57.13
16. A
Solvent A moles =a
Solvent B moles =b
Solute moles =c
a b
At 20°C 15 85 40 ....(1)
abc ab c
a b
At 30°C 34 136 68 ....(2)
ab c abc
On simplifying we get a = b then using eq. (1)
we get a + b+ c = 2.5 b = 2.5 a
a b
= 0.4 → 0.4
ab c ab c
c = 0.2
Solvent XA = 0.4
Solvent XB = 0.4
Solute = 0.2
17. A
18. B
1. A, B, C
d 3x2
1 x 2 y 3x y 1 x2
c and y(0) = 2 c = 2
dx 2
3x2 3x2 4 3 1
y 1 x 2 2 y =
2 2 x 1
2 2 2 x 1
2
3
Range of f(x) = , 2
2
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-26
2. A, B, C
Applying C1 C1 + C2 , we get
2 cos 2 x sin 2 x
2 1 cos 2 x sin 2 x
1 cos 2 x 1 sin 2x
0 1 0 = 2 + sin2x. = 3 , = 1
1 0 1
3. A, B, C
1 0 0 1 0 0 1 0 0
A = 1 0 1 1 0 1 1 1 0
2
4. A, D
b c r a b c a r b c r a
Now, b c r a c a r b a b r c 0
b c a c a b a b c r b c r a c a r b a b r c = 0
b r c r a c r a r b a r b r c 0
br cr ar
therefore r a b c
2 1
r 1 3 2 1
3
1
r abc
3
5. A, C
Sum of number of elements of mn – 1 matrices will give you the last element of m n – 1 matrix
n n 1 2n 1
So, last element of mn – 1 matrix is = 12 + 22 + 32 + ….. + (n – 1)2 =
6
10 9 19
So, first element of m 10 matrix = 1 286
6
Common difference in the diagonal elements of mn matrix is n + 1, so in m10, common different = 11
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-27
10
Sum of diagonal elements = 2 286 10 1 11 = 5(572 + 99) = 5 671 = 3355
2
6. C
y = [x2/64 + 2], y = x – 1 and x = 0 above x-axis is
y
(0, 3)
B
C
y=x-1
Alternate
-8 < x < 8 y = 2
A=22
= 4 sq. units.
7. B, C
2x 4 2x 4 13 x 2 4x 3 2 13
(x) 4x 5 4x 5 26 2x 2 5x 9 4 26 = 0
16x 6 16x 6 104 2
8x 6x 1 16 104
8. C
x = –a is the only asymptote to the given curve N
a
A 2 ydx 3a2
a (–a, 0)B (a, 0)
9. D
y 2/m 2xy1/m 1 0
2x 4x 2 4
y1/ m
2
log y mlog x x 2 1 further differential w.r.t x
y1 m
x 2 1 y12 m2 y 2
y 2
x 1
x 2 1 y 2 xy1 m2 y (diff.....)
10. D
9
p C 1C1 18 C9 9 10
1 108 19 1
q C9 C9 19 19
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-28
So q – p = 19 – 10 = 9
11. B
1
Area of ABC = a b b c c a
2
Now given 2a 3b 6c 0
Cross with a , 3a b 6a c 0
or a b 2 c a ..... (1)
Again cross with b
2a b 6c b = 0
or a b 3 b c
1
Area of OAB = a b
2
1 1 1
a b 1
Area of ABC 2 2 3 11
Area of AOB 1 6
ab
2
So m = 11, n = 6 (m – n) = 5
12. C
Volume = 2b c,3c a,4a b 18
2 3
24 a b c 18 a b c
2
13. B
x y z
Let the equation of the plane be 1
a b c
1 1 1
1
a b c
1
volume of tetrahedron OABC = v = abc
6
3
Now (abc)1/3 3
1 1 1
a b c
9
abc 27 v .
2
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Sankalp2325 S1, T1 & P1(Ph-5)_Paper-2_PCM(101324.1)-29
14. D
T T T –1
AA = A A = I A = A
–1
C = ABA
–1 –1
A C = BA
T 3 –1 2 –1 2 –1 3
Now A C A = A (C.C )A = A C(C A) = BA (C)(CA) = B
1 3
= .
0 1
15. B
Let A(x2, y2, z2) be image of A(2, 1, 6) about mirror x + y – 2z = 3 then
x 2 2 y 2 1 z 2 6 2 2 1 12 3
=4
1 1 2 12 12 22
(x2, y2, z2) (6, 5, – 2).
16. C
Equation of reflected ray L1 = 0 is
line joining A(x2, y2, z2) and B(– 10, – 15, – 14)
x 10 y 15 z 14
i.e.
16 20 12
x 10 y 15 z 14
.
4 5 3
17. D
18. A
Bw 0.21
0.3
0.6 Cw 0.294
B1
0.7 0.7 Bw
0.4 Cw 0.196
Entry
Cw 0.18
0.6
0.3 Bw 0.036
C1
0.4 Cw
0.7 Bw 0.084
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