FIITJEE – Phase Test (JEE-Advanced)

PHYSICS, CHEMISTRY & MATHEMATICS

Pattern - CPT-2 QP CODE: PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 186

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCH – CTY (1921)

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. All the section can be filled in PART-A & B of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Two Parts.

(i) Part-A (01-04) – Contains Six (04) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.

(ii) PART–A (05–12) contains (8) Multiple Choice Questions which have One or More Than One Correct
answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: 1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in 1
marks, as a wrong option is also darkened.

(iii) Part-B (01-06) contains six (06) Numerical based questions, the answer of which maybe positive or
negative numbers or decimals (e.g. 6.25, 7.00, -0.33, -.30, 30.27, -127.30) and each question carries
+3 marks for correct answer. There is no negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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 CTY_PT-5_PAPER-1_2

SECTION – I
PHYSICS
PART-A
(Straight Objective Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE option is correct.

1.
@QS
An object moves with velocity V (  ˆj) towards the inclined plane mirror as Y( ˆj)
shown in figure. The velocity of the image is V

3 ˆ Vˆ
(A) V ˆj (B) V (  i)  j
2 2
3 ˆ Vˆ V ˆ 3 ˆ
(C) V i j (D) (  i)  V ( j) 30°
X(iˆ )
2 2 2 2

2.
P
As shown in figure P and Q are two co-axial Q
conducting loops separated by some distance. When
the switch S is closed, a clockwise current Ip flows in
P (as seen by E) and an induced current IQ1 and
E
IQ2 flows in Q when the current is increasing and
decreasing respectively in loop P then the directions S
of IQ1 and IQ2 (as seen by E) are: Battery

(A) respectively clockwise and anticlockwise

(B) both clockwise
(C) both anticlockwise
(D) respectively anticlockwise and clockwise

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3.
A conducting rod of length l is fixed at the centre and rotated with an B
angular velocity  . The emf induced across the two end is

Bl 2 Bl 2 X X X
(A) (B) A  B
2 4 X X X
Bl 2
(C) (D) zero
8 A
4.
In a young’s double-slit experiment  = 500 nm, d = 1 mm and D = 1 m. The minimum distance from
the central maximum for which the intensity is half of the maximum intensity is
(A) 2 × 10–4 m (B) 1.25 × 10–4 m
–4 –4
(C) 4 × 10 m (D) 2.5 × 10 m

(Multiple Correct Answer(s) Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE are correct.
5.
An object is placed at 30 cm from a convex lens of focal length 15 cm on one side and on the other
side of the convex lens a convex mirror of focal length 12 cm is placed so that the principal axis of
both coincide. It is observed that the object and image coincide. What is the separation between the
lens and mirror?
(A) 6 cm (B) 30 cm
(C) 24 cm (D) 60 cm

6.
A nucleus splits into two nuclear parts which have their velocities in the ratio of 2 : 1. Then :
(A) Momentum of both parts are equal and opposite
(B) The ratio of their nuclear radii 21/3 : 1
1/3
(C) The ratio of their nuclear radii 1 : 2
(D) None of these

7.
An object is placed before a convex lens. The image formed by it
(A) may be diminished, magnified or equal to the size of the object.
(B) may be real or virtual.
(C) always real, inverted and magnified.
(D) always virtual, erect and diminished.

8.
A light ray may suffer total internal reflection when:
(A) it goes from rarer to denser medium.
(B) it goes from denser to rarer medium.
(C) it goes from glass to water.
(D) angle of incidence is greater than critical angle.

9.
A conducting rod PQ of length L = 1.0 m is moving with a uniform × × P ×
×
speed v = 2 m/s in a uniform magnetic field B  4 .0 T directed into the
paper. A capacitor of capacity C = 10 F is connected as shown in A
× × × × ×

figure. Then v
B× × × × ×

(a) qA = + 80 C and qB = – 80 C × × × × ×
(b) qA = – 80 C and qB = + 80 C Q
(c) qA = 0 = qB
(d) P  Higher potential and Q  Lower potential

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10.
The x-z plane separates two media A and B of refractive indices 1 = 1.5 and 2 =2. A ray of light

travels from A to B. Its directions in the two media are given by unit vectors u1  aiˆ  bˆj and

u 2  ciˆ  dˆj . Then
a 4 a 3
(A)  (B) 
c 3 c 4
b 4 b 3
(C)  (D) 
d 3 d 4

11.
In an A.C. circuit the current
(a) Always leads the voltage
(b) may lags behind the voltage
(c) Is always in phase with the voltage
(d) May lead or be in phase with the voltage

12.
The figure shows three circuits with identical batteries, inductors, and resistors. Rank the circuits
according to the current through the battery (i) just after the switch is closed and (ii) a long time later,
greatest first

(1) (2) (3)

(a) i2  i3  i1 (i1  0) (b) i2  i3  i1
(c) i2  i3  i1 (i1  0) (d) i2  i3  i1 (i1  0)

PART-B
(Numerical Answer Type)
This section contains 6 questions. The answer to each question is a numerical answer type with answer
(XXXXX.XX).
13.
A
One face of a prism ABC of  = 2 is silvered and the ray
incident at angle 45 retraces its initial path. Then the angle
CAB is n  10°. Then the value of n is
i = 2

B
C

14.

A rectangular loop has a sliding connector PQ of length l x x x x l x

and resistance R and it is moving with a speed v as P
shown. The set-up is placed in a uniform magnetic field x x x x x
going into the plane of the paper, then the current I is v
2Bl v R x R R
and value of y is______
yR x x x I x x
I2
x x I1 Q x x

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15.
In a thin spherical fish bowl of radius 10 cm filled with water of
refractive index 4/3 there is a small fish at a distance of 4 cm from the
centre C as shown in figure. Where will the image of fish appears, if C E
seen from E is
4 cm

16.
Photon of frequency  has a momentum associated with it. If c is the velocity of light, the momentum
yh
is , and then y is
c
17.
A biconvex lens of focal length 15 cm is in front of a plane mirror. The distance between the lens and
the mirror is 10 cm. A small object is kept at a distance of 30 cm from the lens. The final image is real
and x cm from the mirror then the value of x is
18.
Two identical glass rods S1 and S2 (refractive index = S1 S2
1.5) have one convex end of radius of curvature 10 cm.
They are placed with the curved surfaces at a distance P
d as shown in the figure, with their axes (shown by the 50 cm
dashed line) aligned. When a point source of light P is d
placed inside rod S1 on its axis at a distance of 50 cm from the curved face, the light rays emanating
from it are found to be parallel to the axis inside S2. The distance d is

Space for rough work

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 CTY_PT-5_PAPER-1_6

SECTION – II
CHEMISTRY
PART-A
(Straight Objective Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE option is correct.

1.
The zero magnetic moment of octahedral K 2NiF6 is due to
(A) low spin d6Ni IV  complex (B) low spin d8Ni II complex
(C) high spin d8Ni II complex (D) high spin d6Ni IV  complex
2.
The infra-red stretching frequency VCO of P–S follows the order

(P) Mn  CO 6 (S)  V  CO 6 

(Q) CO (R) H3B  CO
(A) P > R > S > Q (B) S > P > R > Q
(C) Q >S >P > R (D) R > Q > P > S
3.
In a Copper voltameter, mass deposited in 30 sec. is ‘m’ g. If the current vs time graph is as shown in
figure, calculate the electrochemical equivalent of Cu.
m
(A) z = m (B) z 
2
m
(C) z  (D) z can’t be calculated from the given data
5

4.
The osmotic pressure of blood is 7.65 atm. at 310 K. An aqueous solution of glucose which is isotonic
with blood has the percentage (wt./volume)
(A) 5.41 (B) 3.54 (C) 4.53 (D) 53.4
(Multiple Correct Answer(s) Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE are correct.

5.
+2 -1 -1
Choose the correct option for Ni complex in presence of CN and Cl ligand?
2- 2-
(A) [NiCl4] is paramagnetic while [NiCN4] is diamagnetic.
2- 2-
(B) [NiCl4] is diamagnetic while [NiCN4] is paramagnetic.
(C) Splitting diagrams For [NiCl4]2- and [NiCN4]2- left to right shown below , the eight electrons occupy
the d Orbitals

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 CTY_PT-5_PAPER-1_7

Orbital
Enegy

Reaction Coordinate
2- 2-
(D) [NiCl4] and [NiCN4] are square planar and tetrahedral respectively.

6.

Choose the correct option?

(A) [Fe(H 2 O)6 ]3  is low spin complex.
(B) [Fe(CN)6 ]3  is low spin complex.
(C) Number of electrons present in non-axial orbitals of followings compound as [Fe(H 2 O)6 ]3  is 3.
(D) Number of electrons present in non-axial orbitals of followings compound as [Fe(H 2 O )6 ]3  is 5.
7.
1 mole benzene  pbenzene
0
 42 mm of Hg  and 2 mole toluene  p0toluene  36mm of Hg  will have
(A) total vapour pressure 38 mm of Hg
(B) mole fraction of vapours of benzene above liquid mixture is 7/19
(C) positive deviation from Raoult’s law
(D) negative deviation from Raoult’s law
8.

Choose the correct regarding X, Y and Z from given information:

Added con. H2SO 4

till just wet mixture

warm
Z
non  redox reaction
Deep red vapour

Pass NaOH
NaCl  K 2Cr2O7 salt
1:3
Y  2Cl

(i)dil CH3COOH for being Neutral soln

(ii) Pb (CH3 COO)2

X
yellow ppt.

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 CTY_PT-5_PAPER-1_8
2-
(A) X = PbCrO4 (B) Y = CrO4
(C) Z = CrO2Cl2 (D) Y = Cr2O72-

9.
1 1
Liquids A and B form an ideal solution. The plot of (Y-axis) versus (X-axis) (where XA and YA
XA YA
are the mole fractions of A in liquid and vapour phases at equilibrium, respectively) is linear whose
slope and intercept are not given as respectively
Po (Po  Po ) Po (Po  Po )
(A) Ao , A o B (B) Ao , B o A
PB PB PB PB
PBo (PAo  PBo ) PBo (PBo  PAo )
(C) , (D) ,
PAo PBo PAo PBo
10.
For the equilibrium
1/2 N2 (g) + 3/2 H 2 (g) NH3 (g)
Given statements for above equation
(1) The Haber process is a classic application of physicochemical principle to a system in equilibrium.
(2) For industrial viability, NH3 must be formed in optimum yield and reasonable rate; increasing the
temperature increases the rate of reaction, but decreases the yield since the forward reaction is
exothermic.
Choose correct option?
(A) Only 1 (B) Only 2
(C) Both incorrect (D) Both correct
11.
Cl2  hot & conc.NaOH  x  y  H2O,
find out x, y and the equivalent weight of Cl2 (where M is molecular weight of Cl2) in above
reaction
(A) NaCl, NaClO3 (B) 3M/5
(C) 6M/5 (D) NaCl, NaCl

12.
The flocculating power of the given ions for the specified colloidal sols will be such that:
Arsenic sulphide sol and Ferric hydroxide sol
4
(A) Fe  CN6   PO34  SO24  Cl Al3   Ba2   Na
4
(B) Al3  Ba2  Na Fe  CN6   PO34  SO24  Cl
4
(C) Na  Ba2  Al3 Cl  SO24  PO34   Fe  CN6 
4
(D) Cl  SO24  PO34   Fe  CN6  Na  Ba2  Al3

PART-B
(Numerical Answer Type)
This section contains 6 questions. The answer to each question is a numerical answer type with answer
(XXXXX.XX).
13.
The standard reduction potential at 25oC of the reaction 2H2O  2e  ƒ H2  2OH is -0.84V.
o (5x)
Equilibrium constant for the reaction: 2H2 O ƒ H3 O   OH at 25 C is 10 than value of x.
(2.303RT/F = 0.06)

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14.

n-factor of oxidizing agent in a reaction Cl  MnO4  
H
 Cl2  Mn2 

15.
The standard reduction potential for the reactions: Ag  e   Ag and Ag(NH3 )2 1  e   Ag  2NH3
are 0.79V and +0.37V, respectively. From these values and the Nernst equation, K f for the Ag(NH3 )2 
ion is 1014x than value of x?
[Given: 2.303 RT/F = 0.06]
Find out the value of Y where Y is the correct option?
(i) Electrochemical reactions reverse the action of electrolysis. Whereas electrolysis converts
electrical energy to chemical energy, electrochemical reactions convert chemical energy directly to
electrical energy.
(ii) There is a convenient difference between electrochemical reactions and chemical reactions: the
Gibbs energy change for an electrochemical reaction is equivalent to the maximum electrical work
done by system on surrounding.
(iii) The purpose of the salt bridge is to complete the electrical circuit between the two solutions and to
facilitate the movement of ions from one compartment to the other.
(iv) An equation relating the emf of a cell to variables such as temperature and the concentrations of
reacting species is known as Nernst equation.
17.
Go  298 K  = -xF for the following reduction process.
2 NH3OH  aq.  H  aq.  2e  N2H5   aq.  2H2O  l 
 

Given Potential diagram for Nitrogen at pH = 0

NO3 
0.79
 N2O4 
1.07
 HNO2 0.98
 NO 1.59
 N2O 1.77
 N2 ,
 NH3 OH   N2H5    NH4 
1.87 
1.41  
N2  1.28

Then what is value of x

18.
How many of the following are the ore of iron?
Haematite, malachite, azurite, magnetite, cerussite, limonite, argentite.

Space for rough work

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 CTY_PT-5_PAPER-1_10

SECTION – III
MATHEMATICS
PART-A
(Straight Objective Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE option is correct.

1.
10 0 
For any 2  2 matrix, if A.  adj A     . Then A , is
 0 10 
(A) 20 (B) 100
(C) 10 (D) 0

2.
Let r be a unit vector satisfying r  a  b, where a  3 and b  2, then
2 1
(A) r  (a  a  b) (B) r  ( a  a  b)
3 3
1 2
(C) r  ( a  a  b) (D) r  (a  a  b)
4 3

3.
The number of 3  3 matrices A whose entries are either 0 or 1 and for which the system
 x  1 
A  y   0  has exactly two distinct solution is
 z  0 
(A) zero (B) one
(C) two (D) none of these

4.
If the line x = y = z intersect the line  sin A  x   sinB  y   sin C  z  2d2 ,
sin 2Ax  sin 2By  sin 2Cz  d2 , then
A B C
sin sin sin is equal to
2 2 2
(where, A  B  C  
1 1
(A) (B)
16 4
1 1
(C) (D)
13 15

(Multiple Correct Answer(s) Type)

This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE are correct.
5.
r r r r r
If unit vector î and ĵ are at right angles to each other and p  3 ˆi  4 ˆj, q  5i,
ˆ 4r  p  q and
r r r
2s  p  q, then
r r r r r r
(A) r  ks  r  k s for all real k (B) r is perpendicular to s
r r r r r r r r
(C) r  s is perpendicular to r  s (D) r  s  p  q

6.
If P(2, 3, 1) is a point and x  y  z  2  0 is a plane then
(A) Origin and P lie on the same side of the plane
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4
(B) Distance of P from the plane is
3
 10 5 1 
(C) Foot of perpendicular is  , ,  
 3 3 3
 10 5 1
(D) Image of point P by the plane is  , ,   .
 3 3 3
7.
Let f  x, y   0 be a curve passing through the point (0, 2) such that all the rays coming from
a fixed point source when reflected from it are parallel to x axis, Then
(A) y 2  2  x  2  (B) y 2  2  x  2 
(C) y 2  4  x  1 (D) y 2  4  x  1

8.
a b 
If A    (where b  c ) satisfies the equation x  k  0 , then
2

c d
(A) a  d  0 (B) k   A
(C) k  A (D) k 2  A

9.
The parabolas y 2  4x and x 2  4y, divide the square region bounded by lines x  4, y  4
and the coordinate axes. If S1,S 2 ,S3 are respectively the areas of these parts numbered
from top to bottom, then
(A) S13  S33  2S 32 (B) S1,S 2 ,S3 are in AP
(C) S1,S 2 ,S3 are in GP (D) None of these

10.
If the probability of choosing an integer ‘k’ out of 2m integers 1, 2, 3,……..2m is inversely
proportional to k 4 1  k  m  . If x1 is the probability that choosen number is odd and x 2 is
the probability that chosen number is even, then
2 1
(A) x1  (B) x1 
3 2
2 1
(C) x1  (D) x 2 
3 2
11.
The probability that if a 12-element sequence of integers (a1, a2, ……a12) (not necessarily
distinct) is selected from {1, 2, 3, ……,50)} satisfies the condition,
1  a1  a 2  ......  a11  a12  50 is
50 61
C12 C12
(A) (B)
 50 12
 50 12
50 61
C12 C11
(C) greater than (D)
 50  12
 50 12

12.
From a bag containing 5 pairs of socks, each pair a different color, a random sample of 4
single socks is drawn. Any complete pairs in the draw are discarded and replaced by the
same number of socks drawn again from the bag. The process continues until the bag is
empty or there are 4 socks of different colours held in the hand. The probability of latter
alternative is
1 1 3 9
(A) greater than (B) greater than (C) greater than (D) greater than
2 4 4 16

PART-B
(Numerical Answer Type)

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 CTY_PT-5_PAPER-1_12

This section contains 6 questions. The answer to each question is a numerical answer type with answer
(XXXXX.XX).
13.
The volume of the tetrahedron included between the plane 3x  4y  5z  60  0 and the
coordinate planes is equal to 100 then  is equal to

14.
Let a, b and c be three unit vectors such that a is perpendicular to the plane of b and c. If the
angle between b and c is /3, then
2
a  b  a  c is equal to

15.
Let f be a real valued differential function on R such that f(2) = 3. If the y intercept of the
tangent at any point P(x, y) on curve y = f(x) is equal to square of the abscissa of P, then
value of |f(4)| is
16.
r r r r r r r
Let r and s be unit vectors. If t is a vector such that t   t  r   s, the maximum volume of
r r r 3
the parallelepiped formed by r, s and t is , then k is equal to
2k
17.
If P  1, 7, 2  be a point and line L is 2 2  x  1  y  2, z  0. If PQ is the distance of plane
2x  y  z  1 from point P measured along a line inclined at an angle of 45º with the line L
and is minimum. The value of PQ is

18.
 u 2 1
If A   1 1 2  , where  u    and det(adj(adjA)) = (23)4, then the value of u is
11
 3
 2 1 1 

Space for rough work

FIITJEE Ltd., Plot No. 47, Sector – 12B, Opposite Bal Bhawan International School, Dwarka, New Delhi – 110 075,
Ph. : 011-28035963/64/65 website : www.fiitjee.com