SOLUTIONS Very_short ams type questions CI Mone) Bl Why aaah species are mine Or ortable tx, colol water an im Warm wate, C2018? Ars Sobublaty of omy Aer decreases WHR jacneage in Lempaatine of water Hence aqmake 5 comporteoble Sw Cobol Water, Cube | 4gee Tem wot tate He anain, onku ankoge of Share *tolity ovr naoloaiy a3 the ume g vontnlsodion® Ans Mofabity, does not Range with Ramge in fempurake pale bosib clecreases With Use tn temperaline Mo Goxit ae . Mokabit: =n Moray Note solution ms) 4 wit of svent — tn Dabs inka 9203 Whos 4appens when acetone ts added to pure Ans len acckore is added to ethomo€ , some of H-bond belween Be chamk molecules break olown gesuttong mm am inuease nV Ua, PResBUAe of am ixtine: The muxture show postive dleviabon fom Raguot's 2a ethan” C2020) 84 pefene the followin Lem MotoL CE | Ars Dib: Ekevaktontn bovking pome gabe) =m 2 molality, The defined os elevation im bowling pont phon He mol ality, of Be so2ntion is warty Unt > KEG 2BS Gwe 12050n tn the folborsing : Measurement of osmw tic pee fn ae dobemiination, bm eee. he ‘and. polymers’ (2018 : fre oe . PS etc sos pls mag nctacle uw Loage even 6% Vay dhuke Some ee tone te Mauomolecules Auk, jn ane mot gene, . mehook us pregerseat os What oe uoton Ane Teun Sorkin’Bt Awe reason ‘a a followirg ELevakuon of Bn point (mM kee 40 Cutco meorly dowble han a gate a? “hare “a ke pete Ars (Be Rem ane hed an a ene Sugar qoludwon LEE vel DTb ime gobudson is HOUb™ houble 68 Some Beapek on amixeng fom azentropes - ee oe az eokop> eer GC 20l) Ae They qe He spenaty Mrs Z ix Lure of 708 wat composer. g. Beautol amol Bone He same vapour phase amd boils ak constant s :64 ° oie, : AA Tdent-by whick Beaptoe vith Rave a higher vapour pues ak 9c if the bokin pout of Bun Bayi A aml B ane (4c and [BC Aispectevely (2022) Am The Oequtd with a Lowe, boibing pout hos a hiigka vapour pene Hence Hawick A Kos igh vapome pene He vapour pressing of a 8° Ment ofpected is ’ solvent” caolw) ele How when anon volatile wolute Ars In Gen non vobotihe podabets added t fhe solvent Vapow, perane of 40luhon becomes Lowe than ve seas of pure wohrenk at same te mpernbine Vopout PGl! Define the following Let Abnowmak mobos mar Qo) Ars The moZar mors bik & ether dower o Rages Heo expected a momma value = Awmocaknn & Dinouzabion Lace te Dood 2hL olz What Loppen when we P paler gpotone 270ehor) Gave eO#ON c2ols> Art pue 40 osmasis Water molecules move 2. ooet cok. AS a pearl blood cor swell amch mag even Busse:Shovt answer type Lanesbions C2morks? G13 State Hemy's Dow. W&y our bs olelrsect ch Rellismn in Hae Lank wed by scuba bic ers”. Ars The pastoll pauwure of the g™ fn vapour phone i is proportional bo mole fratton of gas 2) m Aodeas kus Hemg> : te = To avotol bends as were Os - tke hloo é combuatuon of Nogen i» e aggect of Rah § ecmuse Boutalu Git Cah i - fosdoke ae mnnlanity of 4.8% CW/W) Hobution of 4. Are embity of, 40ludrow ts 02g mo" CM obo mars H,S0y= 984 Ars — Mass oH, S04 = 9-84 Mol Mo. mokanty = er gta? Max% of solution 10°4 ao hes of, Hy S04 = Mans iaoCon mn = 0s! 2 48 0.1 ae ee Ape Density > = Onl K0°P lame ae = 2. 1,02M aeGIS Write fuwo dif, eene bets é i mon tdeok *tprmue el Edeok solution and Ars Tdeak solution Non-cdkeal solution L Obey Racnlt's Low 1. Donnt obey Raonlt's ak ail Lempaature anc Lous ak ale Lemnpacrtine Contonbrakion amd. concentration P, =AiG P, #PiX 2 DNemx $¢O 2 LNemumz0 DH mtx =0 DH mixt 0BIG ra He freezeng pome of & solution mbounions, 604 of fucose Cmolor ras 180g mae”) in 2503 of waiter Cke f waters Leek rgmot’) (Bole) Ars . Ans mars of glucose = 6° oe of, tim 3 My 3 Morea, wort = 25 0% 1.86 162 xt Wh) 2 ee ke = 186 eam KE AtTbe ausk Die= ke™ t i facertngt 100s Hue age eee Diez key Wz xloe0 ux Wy a>2Fo5LkGIt Give season © o.1mkee Bas Reger bouking pom Ham o.IM g@ucose * © Meat preservedt be Songer time by salting (202? ArsO = ATezilth™ ki atte” chose b=! : ; 4g abe? tow okuor. of bong x Nod partis pome @® Salk comoves water fom oment by pros Jenown O% osmosis - Since there mo wokr tba mead , MAHON, anism ore unabte t gevmenate Ths Deby te stme moat. fa. Long ex Limeaig What is meant by positive deniation fom Raoulk's Law? Gwe am example. hoe is the sign fm Danix H $e positive deviation’ (? 1s) Ars A-B Unk wattriors ae weater (nterador . Due fo this Vapour P hick arsnlt w positive deviation from Raoulk's 6g Ethanol + Acetone Lean A-A amt B-B nessure Indenses Law: AUimix = NE6l4 Fon §%o weution of Useo CMoLor mars 260g mot) Coheubok 0 Hh ; . eee pussuae of go00/e Mass of Usa ¢p20.08el Lamm oa 5q% 7 4 toond of soe i [m= eR) : g_0.0821839° ne Boor 60% 108 i : Too° oe = 1 0.082183 ° in ol = ap.5| atmiE ee we azertope. What type $ azeobops formed by poodve deviation fom Raonte's Caw? c2es> Gyre am examp' un topes u famed b > Define azertope What £ype% azeo eregabwe dovtodion from Raoult’s Caw? ave an exam . Ane Ménemnumn bouling apectope e Etonol* Woe C4gfoby Nome on Maxtemum bo ing azecwope 4 Nit omc Wate CO8% by moss)G21 Blood cells a ee ee a yotonme yi 9 Li spain alba Rapper % ae Soot coll es a solubion contdining rants O12z% Nath go@ution ae © 047. Nach solution Ave (Lae Note soubor. ( Rypestonic phood eth, water wilh $oow one of the cell om would sBaink: tonic WU sexpert to wih ae, a @ oH Zo Nae goOteon ts Rypo phook et, water wil fee Cdn ch amd wonle swell:Foss wheei Vast Hogs gare’ What type of value nea gm forming the yoluhor Hee sbule omnolecule undergo C2014) ; (> Dusoctakon © Anoetation ce | Are Jt bs defied os the sakn of experimental value of te cothigative proprey ho the caboubabedt value ob iollizgabve pps, : ie seve colina Pepa, Cabeubaked witigoive pope’ O picowaton v7 l © Anowakar celShort amswer. type TequestionsC> BQ Some ethylene glswL HOCH,CHOH oe added to goum ail cooling system along with Skg of water 1 the feezing pomb of Water - gfyiol soltuon vt -1S%c. hoe & poking ports of the soduhiom” Cleb= 0-52 lehgmal ke = 86 KG 15% = 1.86% Wax (00° Am Ate 2 Ise G2 x 500° WW, = 2 o M,, CHocuychon) =6? Ws sA6re I. w= kg Il 2 250°$ Alps kb™ 2 item Je ad BE | Bip: Kb Wax ooo \ My W Ste Mi XH = 0.SAXZG500x 1085 = 4.19 some Th= 3734419 2399 rnO24 Ak 300k, 309 of wse pusont iw a Bhre of Us solution £08 an osmoée pressure off 4.98 bar. Ty ne Osmotic pressure of 0. pucose soGution is |/S2bar ak Ane same Lemperotine,, bot wouldl be us cont ae et Rive om (2018) Mp2 RT a se 300% yagea xRT [s22 Ca RT Mav 4.49 = 22421 jsrecpht Teor i aa ee Ts2 6 xc, RTB25 Colculote the bovling poimt: elevation fr a Aud Dn prepared. +4 adehing 10g of Cah, 40.2008 of woter Clb fr water = oSalckg ol) Moor mars of Co.ULs 4) = Ulhg mare Ars Cah, — Corte DE ott? be? Alpe tke ™ 5 kgm Wa x 1000 Paxhh = ax 082n Joe = 0-F0ak = 200 ae ALO26 + 3.99 of bonpoie aoid cusolved wm 44 4 of benzene shows a depression, dn freezing pome of 162k. Calculate the vant Hoy fate ome predué the noture of 40 Cube (orsouiabed & duwociabed) - Gwen Mo kar marsog bene 7 leg 249 Keg mat aud |2 24 /met> me fe kee Die ze bye Wa rlovo po b6exe2 A MxW, aa kee igre ExYaK BA REEP is 050F : Te 44 oe pel amowatinO24 7 oe Of F-CH,-Cooh CMolo mors * FS ant"! ae a0, of water. tHe ctosion fs F-Cy, ed. tobe Ic. Calculate dogec ai 7 | -CoOH. C kp of water = Lae ickge Or he Ars Waly 2 4S3 Mz 248g mot”! Wh > 50° 3 ce e . 4.Sk2 Ate = ike ™ 1.86 x! f pelote te UKE ae oY c-cH,cook = p-cH coo THT vy Wh ea 1+ Cr“ 0% og» olegree S nog ahion I = Ex LO 6K IME x Woe 2? No 48 Boo jor el4 C2-N% povece roasel 4 dosousto = Lots-! = 0.045 = #5%‘026 30g of Urea (Mebogmol') is dusoled m S404 of waren . Coleulote the Vapour prssne of water fot Hes solution of VOpons pussure of pwe walir ok 247% 23-8 nny: (204? fre My = 399 ° Ky = 8463 Pa = Pax Xa Muren > 32-20. 2 23.8% Japa mrwsoten tT NwCE mr wobue B16.47 223.8% oF ie as = 23.8x 094 . a3.Senm Ha =B24 Whe 25 ~oeSa, bbe ae af sulphur, wos disotuedl im [00 Caleulake {reezing pont i Lowered by 0.3030 é fowmulaos Se Ck oo x Che of Cs, = 3.8ak ig mee ‘ mien $, ine Ars Ars Idi = 2.863 Wy = 1004 (2016) My: % = B.93K 2.56% 1007 Ale kpexm @-38>x100 Sapeee| savas M Ws pipbeceLon mers 5% we x BP EASE x > 26 EF 32 Fowmnuda= 58 09.3832 3.85% 2S 6x 1000 My loo| | 3° AY Yo sokutionCW/W) of sucnose CM= 242g nant / kh. Cokeubale 7 Pe fos freezing point of 241.15 é © freezing pomt of 5 70 gf wse CM= [90g moe"! nw / a 2 ( Facezing pont of pre woken? 275! Aws Mavs of Suirose = "§ eel Mays of InNafe 2 [00-4 aon of aoe ci S cH.) = 489 bacon Nake Cn) = oi Digs kex™ i = W, 100? : his 100? QEBIS- AFIS ken Meee pres kee be xt : Ux leek 21S. SSK 102? ; Kets 46 Atle e4S4le eo 45 - i nb 2 REBAS Ire = 15.58 Kkgmet 1 freezing parka tre! a 2268: 61kG3! the a uh ae Vapour pressure of pure BiapihX amd pure Eaubel V care [20mm of Ha and \6omm of Hg res actively FY equal moles of Xamd.y axe mixed to form am Edeok solution. Cakeulake He vop ovr pressure of he whidion? (202 a : amos — No of emobes of K oma Y= Vv. Pq pure Leaicr * CPx) : Moe fraction X= 2 = = |2omm Hg | Moke fraction g y= V-P 4, puse aA toy cry) sraeol welubion __ a : we Pet - | panubts daw [otalpeame Ene Bay, 2 20xb4 Wort | 2 6or8° . Womm Hsci iinsuaaiaennaueemaueueeeennne B32 OWRy ts the value of Van't Ho : ackd in 4 enzene chose youn i ca | @ petamine He osmotic presure Ho ere ab olisrolving 2.32 xg o IeeSOn Gn QL of, s0CueiOw o£ 28¢) orbuming Kiso ts completely aingctated’. Ce | Ans two morecubes of the ethamote ath amotake | =O In benzene ze form dime 2CH,CooK = (CH,COOH2,, ge Numba solute particles in olution qreoretical number sebate portirtsacid tn benzene chore 05° @ petarmtne the osmotic piers ure oO solute by oiissobving 2. 32 X10" hy k,$0u mn 22 of 20 | arsuming 8 son % comp Lotely dinociated’. ass O Why 1 the value of Var't Ho fate §% ethancie | ar foes a, (2023) amos Arg | ABs @D We 232x107 “a Te ase oot Mo Lar mars KS? Ve ak gg BAKDE BAEK | kz $04 ak + Sour eres ies ta" | re ee kT\ tm pet = 4g x10 atm = 3K 2:32K8 0.08 2x 298 UFY XZ833 A solution is prepared by olissolrving 10g of nonvolatile 7 H00uLe in 2003 of water: Tt kas a Vopow. ALAE URC | 31.84 mm Hq af 308k- Calculate the molar mors of he wote Vv ater ak 308 | = 32mm) © Abs Cae eRe *" (ae2s) = Wye log Pye 32mmHy My = 18g Ine aManks 2 Wy = 200g P= BiBummHe = My = PoP. %: 7 ae a | Caitude solotan ) a antms ° a M7778 mh. Bs ats aa 32-31-84 = ley JB pe Ba Mz 20> Pi-Pr 2 WaxMi ole cyte My = WRB PI M,xW), 32 MM, 20 o-16x20 | | = Wog ine? 4than that of IM glucose solution © Amon volodtbe solute XC Molar mar = So when oliroolved in #83 40%. Colonkate te mors moh") benzene reduced UA v OpoUr prsome ox olisokvech mthe so Lution- (20239 o °° BM, | | Ans © + Nate % £onie amd. vom etoly dismodate 4 f give 2 éons px molecule whick & not postbte m vant Hoff sale be a faNa ce and && | for glucose Alp = tkyem Tnoeose En boifing point Dil be mate fri Nace than CLntorefe © Why ts the boiking point: of IMNaLe solution. mate than that of IM gfusose olution @ A nonvolatile yobute XC Molar mar = sogmo£”!) Ben olissolved bn 789 of benzene seduced. 1 vapour presure 4 0%. Colcuhote the mor % X dlosokve mthe so Lution- (2023) - Maal, An @ Ne=? My= 50g met! y2 CoH Se Wi= #83 roo moved Benzene C= 6 M6 é 78g ime! VP benzene CEL™ oe ‘ 3290! GF! . ° V.P 4 So@etion CP 0.4 Fe OAPi = We pZP ° PY Soe 5, = te WexMs Om Me A olP 1. We ies. a 1 W, = 9: Isp