CTY1315_PH_4_CDE_Lot_Paper_1_03.08
CTY1315_PH_4_CDE_Lot_Paper_1_03.08
CTY1315_PH_4_CDE_Lot_Paper_1_03.08
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-B
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
Section-A (9 – 12) contains 4 multiple choice questions which have one & more than one correct answer.
Each question carries +4 marks for correct answer and – 1 mark for wrong answer.
Section-A (13 – 18) contains 2 paragraphs. Based upon paragraph, 3 multiple choice questions have to be
answered. Each question has only one correct answer and carries +4 marks for correct answer and – 1
mark for wrong answer.
(ii) Section-B (01-02) contains 2 Matrix Match Type question containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 mark will be awarded. There may be one
or more than one correct choice. No marks will be given for any wrong match in any question. There is no
negative marking.
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -2-
P
PAAR
RTT –– II :: P
PHHY
YSSIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
1. A hemispherical shell of radius R is uniformly charged to Q. Q
If the potential at the centre C is V the potential difference
between C and P is
(a) Zero (b) 2 V R
3V V P
(c) (d) C
2 2
2R
2. Stream of protons with each having kinetic energy 1000 eV (electron volt) are projected radially
from a very large distance towards a solid conducting sphere of capacitance 2F . If the protons
striking the sphere get deposited, the maximum charge on the sphere is
(a) 40 mC (b) 20 mC (c) 10 mC (d) 60 mC
3. A particle is dropped from a height of 500 m and at the same time another particle is projected
upward vertically along the line joining the two particles with a velocity 1 m/s. The approximate
time of collision is (g = 10m/s2)
(a) 500 s (b) 400 s (c) 10 s (d) 100 s
4. A uniformly charged solid sphere has a spherical
cavity of radius r passing through the centre of the
charged sphere. S is a spherical Gaussian surface of
radius r concentric with the sphere. P is the centre of
cavity and Q is a point on the Gaussian surface. P, C S
and Q lie on a straight line as shown in the figure
(a) Electric fields at P and Q are equal Q P
C r
3
(b) Electric field at Q is times the electric field at P
4
1
(c) Electric field at Q is times the electric field at P
4
(d) Data insufficient
5. An infinite resistance grid with a
battery is shown in the figure
R1 R 2 R3 .......... 16
R1 R2 R3 ......... 32 R1 R2 R3
E = 128 V ...............upto
1 A current flows through E
(a) R2 and R2 R'1 R'2 R'3
(b) R3 and R3
(c) R3 and R2
(d) R4 and R4
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -3-
(b) 3
(c) 2
(d) 1 10 V
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -4-
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -5-
14. The greatest positive value of electric potential for points of the x-axis for which 0 x 6m
is :
(a) 10 V (b) 20 V (c) 30 V (d) 40 V
SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t
Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
D p q r s t
particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
1. A constant current flows through a conductor of variable cross section at a given
temperarture as shown in the figure. Now match the following along the length of the
conductor.
I I
V
Column-I Column-II
(A) Relaxation time (P) First increases then decreases
(B) Drift speed (Q) First decreasess then increases
(C) Electric Field (R) Constant
(D) Resistivity (S) Increases
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -6-
2. Four conducting plates are arranged with equal spacings and surfaces of all the plates are
marked as 1, 2, 3, 4, 5, 6, 7, 8 as shown in the figures. Two middle plates are given charges
+ Q and – Q and different operations are performed. S1, S2, S3 are the switches. Column II
gives the charge distribution on the surfaces of conducting plates from 1 to 8 in order and
column I gives different operations performed with the switches.
Q -Q
1 2 3 4 5 6 7 8
S3
S1 S2
Column-I Column-II
(A) S1, S2 closed and S3 open (P) 0, 0, 0, 0, 0, 0, 0, 0
Q Q 2Q 2Q Q Q
(B) S1, S3 open and S2 closed (Q) 0, , , , , , ,0
3 3 3 3 3 3
(C) S1 closed and S2, S3 open (R) 0, 0, 0, Q, - Q, 0, 0, 0
Q Q Q Q
(D) S1, S2, S3 closed (S) 0, , , 0, 0, , ,0
3 3 3 3
PARTII: CHEMISTRY
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
1. OH
In the cannizzaro’s reaction given below : 2 Ph CHO Ph CH 2OH PhCOO the
slowest step is
(a) The attack of OH at the carbonyl group
(b) The transfer of hydride to the Carbonyl group
(c) The abstraction of proton from the carboxylic acid
(d) The deprotonation of Ph CH 2 OH
2. The nitrogen atom in the following cyclic compounds can be removed as trimethylamine by
successive Hoffmann eliminations (involving exhaustive Methylation followed by heating with
AgOH). The amine which will require a greater number of Hoffmann eliminations is
CH3
N
(a) (b)
N
CH3
CH3
N
CH3 N
(c) (d)
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -7-
4. O
H2SO4
(A) C NH CH3 [ = Ph] Reactant (A) is
OH CH3 OH
(a) C N (b) C N
CH3
NH2
O
(c) (d) C N
H3C C NH
Et
O
O
O
O O
a b c d
(a) a and b (b) a, b and c (c) c and d (d) c only
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -8-
7.
H
(A): Product (A) is
HO
(a) (b)
(c) (d)
8. How many different products are obtained upon the ozonolysis of the following C20-tetraene?
Ph
(c) N OH (d) N NH2
CH3
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -9-
O
CH3
NaOI
10. (A) (B) CO2
H
Structure of (A) is
CO 2H O O
O
(a) (b)
O OH
11. The correct statement (s) about the following sugars X and Y is (are)
CH2OH
O H
CH2 OH CH2OH H
H
H OH
O H O OH
H H HOH2 C H O
H H HO H OH H
HO OH H CH2OH
O HO OH H
H
OH H
H OH OH
H
(X) (Y)
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -10-
Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE
is correct.
Paragraph for question number 13 to 15
E2 reaction Elimination bimolecular
In the general mechanism of the E2 reaction a strong base abstract a proton on a carbon atom
adjacent to the one of the leaving group. As the base abstracts a proton, a double bond forms
and the leaving group leaves.
CH3
H
CH3ONa
H3C CH2 CH CH3
CH3OH H
Br H3C
(major)
Mechanism:
H
CH3O H
CH3ONa H3C CH CH CH3
H3C CH CH CH3
Br (trans-2-butene)
Br
anti - coplanar transition state
(staggered conformation
-lower energy)
13. Give the order of reaction rate with alc. KOH
Br
(i) Br (ii) Br (iii)
(a) (i) > (ii) > (iii) (b) (ii) > (i) > (iii)
(c) (iii) > (ii) > (i) (d) (iii) > (i) > (ii)
14. How many isomer of C4H9Br when reacts with NaNH2, diastereomers will form? (excluding
stereoisomer)
(a) 0 (b) 1 (c) 2 (d) 3
15. O Cl
O C C CH3
Sum of x + y
(a) 4 (b) 5 (c) 3 (d) 2
Space For Rough Work
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -11-
(D) = CH3
(a) (b)
CH2
(c) (d)
(a) (b)
CHO
CH2 CH2 CH O
O
(c) (d) O CH CH O
CHO
O
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -12-
SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t
Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
q t
particular question, against statement B, darken the bubbles corresponding to D p r s
K 2 Cr2 O7
H
O2N NO 2
(A) (P)
NO 2
Picric acid
OH OH
Br2 Water
(B) (Q) Br
Ortho-bromophenol
OH OH
f . HNO
3
Conc.H2SO 4
Br Br
(C) (R)
Br
Tri-bromophenol
OH O
Br 2
CS2
(D) (S)
O
Para-benzoquinone
OH
(T)
Br
Para-bromophenol
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -13-
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -14-
P
PAAR
RTT –– IIIIII :: M
MAATTH
HEEM
MAATTIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
4n
n
1. The value of lim 2
is equal to
n
r 1
r 3 r 4 n
1 1 1 1
(a) (b) (c) (d)
35 14 10 5
1
2. If f(x) = cos (tan-1x), then the value of the integral x f x dx is
0
3 2 3 2 3
(a) (b) (c) 1 (d) 1
2 2 2 2
3. 3 sin x 2cos x
If 3cos x 2 sin x dx ax b n| 2 sin x 3cos x | c then
12 15 7 6 12 15 7 6
(a) a ,b (b) a ,b (c) a ,b (d) a ,b
13 39 13 13 13 39 13 13
4.
If f x 0, x R,f 3 0 and g x f tan2 x 2 tan x 4 0 x , then g(x) is increasing in
2
(a) 0, (b) , (c) 0, (d) ,
4 6 3 3 4 2
5. Let C be the curve y = x3 x R . The tangent at A meets the curve again at B. If the gradient at
B is K times the gradient at A then K is equal to
1
(a) 4 (b) 2 (c) – 2 (d)
4
x
6. f x max , sin x ,nN has maximum points of non – differentiability for x 0,4 , then n can
n
not be
(a) 4 (b) 3 (c) 5 (d) 6
7. 1 x 1 x 2 .............. 1 x 2n
Lt 2
,nN
x 1
1 x 1 x 2 .......... 1 xn
(a) 2nPn (b) 2nCn (c) (2n)! (d) None of these
8. 2x
If f :R 0, is a function such that f x 1 f x 1 3 f x , then the period of f is
3
(a) 9 (b) 18 (c) 27 (d) None of these
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -15-
9. Parabola y2 = 4x and the circle having it’s centre at (6, 5) intersect at right angle. Possible point
of intersection of these curves can be
(a) (9, 6) (b) (2, 2 2 ) (c) (4, 4) (d) (1, 2)
10. If x2 + 2hxy + y2 = 0 represents the equation of the straight lines through the origin which make
an angle with y + x = 0, then
1 h 1 h h 1
(a) sec 2 h (b) cos (c) 2sin (d) cot
2h h h 1
11. Which of the following function(s) has/have removable discontinuity at x = 1?
1
1 x 2 1 1 x x 1 2x
(a) f x (b) f x (c) f x 22 (d) f x
n x x3 1 x2 x
12. f x x2 2ax a a 1 ,f : a, a, . If one of the solutions of the equation f(x) = f-1(x) is 5049,
then the other may be
(a) 5051 (b) 5048 (c) 5052 (d) 5050
Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE
is correct.
Paragraph for question number 13 to 15
x
Let f :R R be a differentiable function such that f x x 2 e t f x t dt
0
17
(a) 6 (b) (c) 8 (d) None of these
4
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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -16-
17. The values of parameter a if f(x) has a positive point of local maxima are
58 58
(a) (b) , 3 , (c) , (d) None of these
14 14
18. The values of parameter a if f(x) has points of extrema which are opposite in sign are
58
(a) (b) (- 3, 3) (c) , (d) None of these
14
SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t
Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
D p q r s t
particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
1 1 1
1 1 1
e tan x
xe tan x
x 2 e tan x
1. Consider I1 dx, I2 dx, I 3 dx , then
0 1 x 2 0 1 x 2 0 1 x 2
Column-I Column-II
(A) I1 + I2= (P) 3/2
(B) I1 + I 2 – 4 I3 = (Q) 1
I1 I2 1
(C) (R) 2 e / 4 1
I1 I2 2I3
2 I1 I2
(D) (S) 2 e / 4
2I3 1
(T) 2 e / 4 - 3
If
x dx = a n
xk
C , then ak is
7 k
(B) x 1 (Q) 1
x x 6
less than
x4 1 m
x 2
dx k n x C , then mk is
(C) x 2
1 1 x 2 (R) 3
greater than
dx 1 x k
5 4cos x k tan m tan C, then is
(D) 2 m (S) 4
greater than
(T) 5
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