CTY1315_PH_4_CDE_Lot_Paper_1_03.08

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FIITJEE COMMON TEST

PHYSICS, CHEMISTRY & MATHEMATICS

SET – A CODE: 130434.1 PH-IV PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 240


 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
BATCH – NETW35Y01

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-B
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.

B. Filling of OMR Sheet


1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with HB pencil for each character of your Enrolment No.
and write in ink your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For All Three Parts.


(i) Section-A (01 – 08) contains 8 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and – 1 mark for wrong answer.

Section-A (9 – 12) contains 4 multiple choice questions which have one & more than one correct answer.
Each question carries +4 marks for correct answer and – 1 mark for wrong answer.

Section-A (13 – 18) contains 2 paragraphs. Based upon paragraph, 3 multiple choice questions have to be
answered. Each question has only one correct answer and carries +4 marks for correct answer and – 1
mark for wrong answer.
(ii) Section-B (01-02) contains 2 Matrix Match Type question containing statements given in 2 columns.
Statements in the first column have to be matched with statements in the second column. Each question
carries +8 marks for all correct answer. For each correct row +2 mark will be awarded. There may be one
or more than one correct choice. No marks will be given for any wrong match in any question. There is no
negative marking.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -2-

P
PAAR
RTT –– II :: P
PHHY
YSSIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
1. A hemispherical shell of radius R is uniformly charged to Q. Q
If the potential at the centre C is V the potential difference
between C and P is
(a) Zero (b) 2 V R

3V V P
(c) (d) C
2 2
2R

2. Stream of protons with each having kinetic energy 1000 eV (electron volt) are projected radially
from a very large distance towards a solid conducting sphere of capacitance 2F . If the protons
striking the sphere get deposited, the maximum charge on the sphere is
(a) 40 mC (b) 20 mC (c) 10 mC (d) 60 mC
3. A particle is dropped from a height of 500 m and at the same time another particle is projected
upward vertically along the line joining the two particles with a velocity 1 m/s. The approximate
time of collision is (g = 10m/s2)
(a) 500 s (b) 400 s (c) 10 s (d) 100 s
4. A uniformly charged solid sphere has a spherical
cavity of radius r passing through the centre of the
charged sphere. S is a spherical Gaussian surface of
radius r concentric with the sphere. P is the centre of
cavity and Q is a point on the Gaussian surface. P, C S
and Q lie on a straight line as shown in the figure
(a) Electric fields at P and Q are equal Q P
C r
3
(b) Electric field at Q is times the electric field at P
4
1
(c) Electric field at Q is times the electric field at P
4
(d) Data insufficient
5. An infinite resistance grid with a
battery is shown in the figure
R1  R 2  R3  ..........  16 
R1  R2  R3  .........  32  R1 R2 R3
E = 128 V ...............upto 
1 A current flows through E
(a) R2 and R2 R'1 R'2 R'3
(b) R3 and R3
(c) R3 and R2
(d) R4 and R4

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -3-

6. The maximum resistance R that must be connected in R


parallel to a cell of emf 20 V and internal resistance 2  to
measure the potential difference across the cell using a
Potentiometer having a potential difference of 10 V across
the potentiometer wire
20 V 2 G
(a) 4  J

(b) 3
(c) 2
(d) 1 10 V

7. If along a uniform rod of length  carrying current I, the


voltage V changes with position x along the length of the rod x

such that dV/dx = – k, where k is a positive number, then the x=0


resistance of the rod is
(a) k/2I (b) k/I
(c) I/k (d) kI
8. In the middle of a box of mass m is a small ball of same mass. v
The whole system (box and the ball) is moving with the velocity v
towards a wall. Assume gravity free space and all collisions
perfectly elastic. Total number of collisions possible is
(a) 2 (b) 3 Box
(c) 4 (d) Infinity wall

Multiple Correct Answer(s) Type


This section contains 4 multiple choice type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE are correct.
9. An infinitely long cylindrical conductor of radius R contains
current of uniform density J along axis of the cylinder. Two
infinitely long cylindrical holes of radius r are drilled
symmetrically throughout the length of the cylinder. The axes
of the holes are parallel to the axis of cylinder and at distance d
d from it in the same plane.

(a) Magnetic field on the axis of one of the hole will be


0 J  r2 
 d  
2  2d 
(b) Magnetic field on the axis of one of the hole will be
0 J  r2 
 d  
2  d
0J r 2
(c) Magnetic field on the axis of cylinder will be
2 d
(d) Magnetic field on the axis of cylinder will be zero

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -4-

10. A steady electric current is flowing through a cylindrical conductor


(a) the electric field at the axis of the conductor is zero.
(b) the magnetic field at the axis of the conductor is zero.
(c) the electric field in the vicinity of the conductor is zero.
(d) the magnetic field in the vicinity of the conductor is zero.
In the circuit shown, the bulb B glows equally 90 
11. S
bright whether the switch is closed or open
(a) The resistance of the bulb is 60  B
180  90 
(b) The resistance of the bulb is 30 
(c) The voltage across the bulb is 6 V 54 V
(d) The voltage across the bulb is 12 V
12. A wooden cubical block ABCDEFG of mass m and
side a is wrapped by a square wire loop of
perimeter 4a, carrying current I. The whole system
is placed on frictionless horizontal surface in a
 Z
uniform magnetic field B  Bo ˆj as shown in the
figure. In this situation normal force between the G
F
block and the surface passes through a point at a
distance x from the centre. Select the correct 
B
statement (s). B a
C
mg O
(a) the block must not topple if I  Y
aBo E
mg
(b) the block must not topple if I  A
2aB o D
a mg X
(c) x  if I 
4 2aBo
a mg
(d) x  if I 
4 4aB o
Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE
is correct.
Paragraph for question number 13 to 15
A graph of the x-component of the electric field as a Ex(N/c)
function of x in a region of space is shown in the figure. 20
The y and z-components of the electric field are zero in
this region. The electric potential at the origin is zero.
1 3 4 5 6 7 8 x(m)
–20

13. The electric potential at x = 2m is :

(a)10 V (b) 20 V (c) 30 V (d) 40 V

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -5-

14. The greatest positive value of electric potential for points of the x-axis for which 0  x  6m
is :
(a) 10 V (b) 20 V (c) 30 V (d) 40 V

15. The value of x for which potential is zero is :


(a) 2m (b) 3m (c) 4m (d) 5m

Paragraph for question number 16 to 18


On a rough horizontal table top rests a thin uniform
conducting disc of radius 0.5 m and mass 1 kg. From two
conducting sliding contacts P1 and P2 on the rim of the disk B
are connected two flexible wires, which facilitate current I to
flow through the disk. On the table top is established a P Q
I I
uniform magnetic field B = 4T pointing vertically upward.
(take g = 10m/s2)
16. For I = 2A and P1 and P2 subtends an angle of 60o at the centre of the disc, the disc just starts
moving. Find the coefficient of friction between the disc and the table
(a) 0.6 (b) 0.4
(c) 0.2 (d) 0.1
17. Find the angle subtended at the centre of the disc by P1 and P2 so that the disc starts moving
for minimum current I
(a) 180o (b) 90o
(c) 45o (d) 30o
18. Find the minimum current I required for the disc to move
(a) 1 A (b) 2 A
(c) 3 A (d) 4 A

SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t

Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
D p q r s t
particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.
1. A constant current flows through a conductor of variable cross section at a given
temperarture as shown in the figure. Now match the following along the length of the
conductor.

I I

V
Column-I Column-II
(A) Relaxation time (P) First increases then decreases
(B) Drift speed (Q) First decreasess then increases
(C) Electric Field (R) Constant
(D) Resistivity (S) Increases

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -6-

2. Four conducting plates are arranged with equal spacings and surfaces of all the plates are
marked as 1, 2, 3, 4, 5, 6, 7, 8 as shown in the figures. Two middle plates are given charges
+ Q and – Q and different operations are performed. S1, S2, S3 are the switches. Column II
gives the charge distribution on the surfaces of conducting plates from 1 to 8 in order and
column I gives different operations performed with the switches.
Q -Q

1 2 3 4 5 6 7 8

S3

S1 S2

Column-I Column-II
(A) S1, S2 closed and S3 open (P) 0, 0, 0, 0, 0, 0, 0, 0
Q Q 2Q 2Q Q Q
(B) S1, S3 open and S2 closed (Q) 0, , , , , , ,0
3 3 3 3 3 3
(C) S1 closed and S2, S3 open (R) 0, 0, 0, Q, - Q, 0, 0, 0
Q Q Q Q
(D) S1, S2, S3 closed (S) 0, , , 0, 0, , ,0
3 3 3 3

PARTII: CHEMISTRY
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

1. OH
In the cannizzaro’s reaction given below : 2 Ph  CHO   Ph  CH 2OH  PhCOO  the
slowest step is
(a) The attack of OH  at the carbonyl group
(b) The transfer of hydride to the Carbonyl group
(c) The abstraction of proton from the carboxylic acid
(d) The deprotonation of Ph  CH 2 OH
2. The nitrogen atom in the following cyclic compounds can be removed as trimethylamine by
successive Hoffmann eliminations (involving exhaustive Methylation followed by heating with
AgOH). The amine which will require a greater number of Hoffmann eliminations is
CH3
N
(a) (b)
N

CH3
CH3
N
CH3 N
(c) (d)

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -7-

3. How many moles of Grignard reagent reacts with following O


compound? H C
(a) 2 C N
(b) 3
HS
(c) 4
(d) 5 Cl

4. O
H2SO4
(A)  C NH CH3 [  = Ph] Reactant (A) is
 OH CH3 OH

(a) C N (b) C N
CH3 

 NH2
O
(c) (d) C N
H3C C NH 
Et

5. Bakelite is obtained from phenol by reaction with


(a) CH3CHO (b) HCHO (c) (CH2OH)2 (d) CH3COCH3

6. Which product(s) should be formed in the following reaction?


O
NaOH, H2O

O
O
O

O O

a b c d
(a) a and b (b) a, b and c (c) c and d (d) c only

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -8-

7.
H
(A): Product (A) is
HO 

(a) (b)

(c) (d)

8. How many different products are obtained upon the ozonolysis of the following C20-tetraene?

(a) 2 (b) 3 (c) 4 (d) 5

Multiple Correct Answer(s) Type


This section contains 4 multiple choice type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE are correct.
9. Which of the following is/are ketoxime?
N OH
(a) N OH (b)

Ph
(c) N OH (d) N NH2
CH3

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -9-

O
CH3
NaOI
10. (A) (B) CO2
H 

Structure of (A) is
CO 2H O O
O
(a) (b)

O OH

(c) (d) None of these

11. The correct statement (s) about the following sugars X and Y is (are)
CH2OH

O H
CH2 OH CH2OH H
H
H OH
O H O OH
H H HOH2 C H O
H H HO H OH H
HO OH H CH2OH
O HO OH H
H
OH H
H OH OH
H
(X) (Y)

(a) X is a reducing sugar and Y is a non-reducing sugar


(b) X is a non-reducing sugar and Y is a reducing sugar
(c) The glucosidic linkages in X and Y are  and  , respectively
(d) The glucosidic linkages in X and Y are  and  , respectively
12. Compound (A) C5 H 10O forms a Phenyl hydrazone and gives negative Tollen’s and iodoform
tests. Compound (A) on reduction gives n – pentane. Compound (A) is :
(a) A primary alcohol (b) An Aldehyde (c) A ketone (d) A secondary alcohol

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -10-

Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE
is correct.
Paragraph for question number 13 to 15
E2 reaction  Elimination bimolecular
In the general mechanism of the E2 reaction a strong base abstract a proton on a carbon atom
adjacent to the one of the leaving group. As the base abstracts a proton, a double bond forms
and the leaving group leaves.
CH3
H
CH3ONa
H3C CH2 CH CH3
CH3OH H
Br H3C
(major)
Mechanism:

H 
CH3O H
CH3ONa H3C CH CH CH3
H3C CH CH CH3
Br (trans-2-butene)
Br
anti - coplanar transition state
(staggered conformation
-lower energy)
13. Give the order of reaction rate with alc. KOH

Br
(i) Br (ii) Br (iii)

(a) (i) > (ii) > (iii) (b) (ii) > (i) > (iii)
(c) (iii) > (ii) > (i) (d) (iii) > (i) > (ii)

14. How many isomer of C4H9Br when reacts with NaNH2, diastereomers will form? (excluding
stereoisomer)
(a) 0 (b) 1 (c) 2 (d) 3

15. O Cl

x PCl5 y NaNH2 CH3I

O C C CH3

Sum of x + y
(a) 4 (b) 5 (c) 3 (d) 2
Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -11-

Paragraph for question number 16 to 18


A compound (A) gives positive test with Br2/CCI4. When (A) undergoes reductive ozonolysis
product (B) is obtained. When (B) reacts with dil. KOH followed by heating (C) will obtained (C)
gives positive Tollens test. When (C) reacts with NH2 – NH2/ KOH  product (D) will obtained.

(D) = CH3

16. Compound (A) is

(a) (b)

CH2

(c) (d)

17. Compound (B) is


O
CHO

(a) (b)

CHO
CH2 CH2 CH O
O

(c) (d) O CH CH O

18. Compound (C) is

(a) CHO (b)

CHO
O

(c) (d) CHO

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -12-

SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t

Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
q t
particular question, against statement B, darken the bubbles corresponding to D p r s

q and r in the ORS.


1.
Column-I Column-II
OH OH

K 2 Cr2 O7
H 

  O2N NO 2
(A) (P)

NO 2
Picric acid
OH OH

Br2 Water
 
(B) (Q) Br

Ortho-bromophenol
OH OH

 f . HNO
 3
Conc.H2SO 4

Br Br
(C) (R)

Br
Tri-bromophenol
OH O

Br 2

CS2   

(D) (S)

O
Para-benzoquinone
OH

(T)

Br
Para-bromophenol

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -13-

2. Match the following


Column-I Column-II
(A) HCHO + Water 60% (P) Urotropin
(B) HCHO + NH3 (Q) Bakelite
(C) HCHO + Phenol (R) CH3OH
(D) HCHO + NaOH (S) Formalin
(T) HCOONa

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -14-

P
PAAR
RTT –– IIIIII :: M
MAATTH
HEEM
MAATTIIC
CSS
SECTION – A
(Single Correct Choice Type)
This section contains 8 multiple choice questions. Each question has four choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
4n
n
1. The value of lim  2
is equal to
n
r 1

r 3 r 4 n 
1 1 1 1
(a) (b) (c) (d)
35 14 10 5
1
2. If f(x) = cos (tan-1x), then the value of the integral  x f   x  dx is
0

3 2 3 2 3
(a) (b) (c) 1 (d) 1 
2 2 2 2

3. 3 sin x  2cos x
If  3cos x  2 sin x dx  ax  b n| 2 sin x  3cos x |  c then
12 15 7 6 12 15 7 6
(a) a   ,b  (b) a   ,b  (c) a  ,b   (d) a   ,b  
13 39 13 13 13 39 13 13
4. 
If f   x   0, x R,f   3   0 and g  x   f  tan2 x  2 tan x  4  0  x  , then g(x) is increasing in
2
        
(a)  0,  (b)  ,  (c)  0,  (d)  , 
4  6 3  3   4 2
5. Let C be the curve y = x3  x R  . The tangent at A meets the curve again at B. If the gradient at
B is K times the gradient at A then K is equal to
1
(a) 4 (b) 2 (c) – 2 (d)
4
x 
6. f  x   max  , sin  x  ,nN has maximum points of non – differentiability for x  0,4  , then n can
n 
not be
(a) 4 (b) 3 (c) 5 (d) 6
7. 1 x  1 x 2 .............. 1 x 2n 
Lt 2
,nN
x 1
1 x  1 x 2 .......... 1 xn 
(a) 2nPn (b) 2nCn (c) (2n)! (d) None of these
8.  2x 
If f :R  0,   is a function such that f  x  1  f  x  1  3 f  x  , then the period of f   is
 3 
(a) 9 (b) 18 (c) 27 (d) None of these

Space For Rough Work

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -15-

Multiple Correct Answer(s) Type


This section contains 4 multiple choice type questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE are correct.

9. Parabola y2 = 4x and the circle having it’s centre at (6, 5) intersect at right angle. Possible point
of intersection of these curves can be
(a) (9, 6) (b) (2, 2 2 ) (c) (4, 4) (d) (1, 2)

10. If x2 + 2hxy + y2 = 0 represents the equation of the straight lines through the origin which make
an angle  with y + x = 0, then
1 h 1 h h  1
(a) sec 2  h (b) cos   (c) 2sin   (d) cot  
2h h h  1
11. Which of the following function(s) has/have removable discontinuity at x = 1?
1
1 x 2 1 1 x x  1  2x
(a) f  x   (b) f  x   (c) f  x   22 (d) f  x  
n x x3 1 x2  x

12. f  x   x2  2ax  a a  1 ,f : a,    a,   . If one of the solutions of the equation f(x) = f-1(x) is 5049,
then the other may be
(a) 5051 (b) 5048 (c) 5052 (d) 5050

Paragraph Type
This section contains 2 paragraphs. Based upon each paragraph, 3 multiple choice questions
have to be answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE
is correct.
Paragraph for question number 13 to 15

x
Let f :R  R be a differentiable function such that f  x   x 2   e  t f  x  t  dt
0

13. f(x) increases for


(a) x > 1 (b) x < - 2 (c) x > 2 (d) All of these
14. y = f(x) is
(a) injective but not surjective (b) surjective but not injective
(c) bijective (d) neither injective nor surjective
15. 2
The value of  f  x  d  x  is
1

17
(a) 6 (b) (c) 8 (d) None of these
4

Paragraph for question number 16 to 18

Let f(x) = x3 – 3 (7 – a) x2 – 3 (9 – a2) x + 2


16. The values of parameter a if f(x) has a negative point of local minima are
 58 
(a)  (b)  3,3  (c)  ,  (d) None of these
 14 

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CTY CDE LOT (CPT4-1) PH-4 PAPER-1 (PCM) SET - A -16-

17. The values of parameter a if f(x) has a positive point of local maxima are
 58   58 
(a)  (b)   ,  3    ,   (c)  ,  (d) None of these
 14   14 

18. The values of parameter a if f(x) has points of extrema which are opposite in sign are
 58 
(a)  (b) (- 3, 3) (c)  ,  (d) None of these
14 

SECTION–B
MatrixMatch Type
p q r s t
This Section contains 2 questions. Each question has four statements (A, B,
C and D) given in Column I and five statements (p, q, r, s and t) in Column II. A p q r s t

Any given statement in Column I can have correct matching with ONE or B p q r s t
MORE statement(s) given in Column II. For example, if for a given question, C p q r s t
statement B matches with the statements given in q and r, then for the
D p q r s t
particular question, against statement B, darken the bubbles corresponding to
q and r in the ORS.

1 1 1
1 1 1
e tan x
xe tan x
x 2 e tan x
1. Consider I1   dx, I2   dx, I 3   dx , then
0 1 x 2 0 1 x 2 0 1 x 2

Column-I Column-II
(A) I1 + I2= (P) 3/2
(B) I1 + I 2 – 4 I3 = (Q) 1
I1  I2 1
(C)  (R) 2 e / 4  1
I1  I2  2I3
2  I1  I2 
(D)  (S) 2 e / 4
2I3  1
(T) 2 e / 4 - 3

2. Match the following


Column-I Column-II
2x
If   k sin1  f  x    C,then k is greater
(A) 1 4 x
(P) 0
than
5

If 
 x dx = a n
xk
 C , then ak is
7 k
(B) x 1 (Q) 1
 x x 6

less than
x4 1 m
x 2
dx  k n x   C , then mk is
(C) x 2
1 1 x 2 (R) 3
greater than
dx 1  x k
 5  4cos x  k tan  m tan   C, then is
(D)  2 m (S) 4
greater than
(T) 5

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