UnitTest_D20-May-2024

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Section A

A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [10]

AY
1. Which one is not equal to zero for an ideal solution ?
(A) DHmix (B) DSmix
(C) DVmix (D) DP = Pobserved – PRaoult

2. What is the mole fraction of the solute in a 1.00m aqueous solution ?

AL
(A) 0.0354 (B) 0.0177 (C) 0.177 (D) 1.770
3. 18 g glucose (C6H12O6) is added to 178.2 g water. The vapour pressure of water (in torr) for this
aqueous solution is :
(A) 759.0 (B) 7.6 (C) 76.0 (D) 752.4

Y
4. At 100°C the vapour pressure of a solution of 6.5 gm of a solute in 100 g water is 732 mm. If Kb = 0.52,
the boiling point of this solution will be :

5.
(A) 100°C (B) 102°C.
VID (C) 103° C
The mixture which shows positive deviation from Raoult’s law is :
(A) Acetone + Chloroform
(C) Ethanol + Acetone
(D) 101° C

(B) Chloroethane + Bromoethane


(D) Benzene + Toluene
6. What is emf of Pt | H2(P1) | H+(aq) | | H+(aq) | H2(P2) | Pt cell ?
GH
RT P1 RT P2 RT P1 RT P2
(A) ln (B) ln (C) ln (D) ln
F P2 2F P1 2F P2 F P1
7. Which of the following reaction is not possible ?
(A) 2KBr + Cl2® 2KCl + Br2 (B) 2Kl + Br2® 2KBr + l2
(C) 2KBr + l2® 2Kl + Br2 (D) 2H2O + 2F2 ® 4HF + O2
MA

8. What is true for spontaneity of cell ?


(A) DG = 0, DH = 0 (B) DG = –ve, DH = 0 (C) DG = +ve, DH = 0 (D) DG = –ve
9. Which elements can be obtained as anode mud in purification reaction of copper by electrolysis ?
(A) Al, Ni (B) Ag, Au (C) Sn, Pb (D) Pb, Ni
A

10. Capacity of fuel cell is ………


DG DG DS DH
(A) (B) (C) (D)
DS DH DG DG
HW

Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [6]

1. Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293K
when 25 g of glucose is dissolved in 450 g of water.
AS

2. Calculate the molarity of each of the following solutions :


(a) 30 g of Co(NO3)2 · 6H2O in 4.3 L of solution
(b) 30 mL of 0.5 M H2SO4 diluted to 500 mL.

3. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. Calculate its molar conductivity.

Wish You - All The Best


//X
OR
3. ) The standard electrode potential for Daniell cell is 1.1 V. Calculate the standard Gibbs energy for the
(aq) ® Zn (aq) + Cu(s)
reaction : Zn(s) + Cu2+ 2+

Section C
//X

A
• Write the answer of the following questions. [Each carries 3 Marks] [6]
4. Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20 % (mass/mass)

AY
aqueous KI is 1.202 g mL–1 .
5. Write the Nernst equation and calculate potential of the following cell at 298 K.
o o
Mg(s) | Mg2+(0.001 M) || Cu2+(0.0001 M) | Cu(s) E 2+ = –2.36 V and E 2+ = +0.34 V
Mg /Mg Cu /Cu

AL
Section D
//X
• Write the answer of the following questions. [Each carries 4 Marks] [8]

6. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHCl COOH is added

Y
to 250 g of water. [Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1] (Atomic mass : H = 1, C = 12, O = 16, Cl
= 35.5)
7.

VID
Explain chemistry of corrosion and state two methods to stop corrosion.
GH
A MA
HW
AS

Wish You - All The Best


Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que Universal_QueId


1. B Chap 1 S6 50 QP23P11B1212_P1C1S6Q50
2. B Chap 1 S6 51 QP23P11B1212_P1C1S6Q51
3. D Chap 1 S6 52 QP23P11B1212_P1C1S6Q52
4. D Chap 1 S6 53 QP23P11B1212_P1C1S6Q53
5. C Chap 1 S6 66 QP23P11B1212_P1C1S6Q66
6. B Chap 2 S6 28 QP23P11B1212_P1C2S6Q28
7. C Chap 2 S6 27 QP23P11B1212_P1C2S6Q27
8. D Chap 2 S6 36 QP23P11B1212_P1C2S6Q36
9. B Chap 2 S6 40 QP23P11B1212_P1C2S6Q40
10. B Chap 2 S6 46 QP23P11B1212_P1C2S6Q46

Section [ B ] : 2 Marks Questions

No Ans Chap Sec Que Universal_QueId


1. - Chap 1 S3 34 QP23P11B1212_P1C1S3Q34
2. - Chap 1 S2 3 QP23P11B1212_P1C1S2Q3
3. - Chap 2 S3 8 QP23P11B1212_P1C2S3Q8
3. - Chap 2 S8 3.3 QP23P11B1212_P1C2S8Q3.3

Section [ C ] : 3 Marks Questions

No Ans Chap Sec Que Universal_QueId


4. - Chap 1 S2 5 QP23P11B1212_P1C1S2Q5
5. - Chap 2 S10 6 QP23P11B1212_P1C2S10Q6

Section [ D ] : 4 Marks Questions

No Ans Chap Sec Que Universal_QueId


6. - Chap 1 S9 6 QP23P11B1212_P1C1S9Q6
7. - Chap 2 S10 11 QP23P11B1212_P1C2S10Q11

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