UnitTest_D20-May-2024
UnitTest_D20-May-2024
UnitTest_D20-May-2024
A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [10]
AY
1. Which one is not equal to zero for an ideal solution ?
(A) DHmix (B) DSmix
(C) DVmix (D) DP = Pobserved – PRaoult
AL
(A) 0.0354 (B) 0.0177 (C) 0.177 (D) 1.770
3. 18 g glucose (C6H12O6) is added to 178.2 g water. The vapour pressure of water (in torr) for this
aqueous solution is :
(A) 759.0 (B) 7.6 (C) 76.0 (D) 752.4
Y
4. At 100°C the vapour pressure of a solution of 6.5 gm of a solute in 100 g water is 732 mm. If Kb = 0.52,
the boiling point of this solution will be :
5.
(A) 100°C (B) 102°C.
VID (C) 103° C
The mixture which shows positive deviation from Raoult’s law is :
(A) Acetone + Chloroform
(C) Ethanol + Acetone
(D) 101° C
Section B
//X
• Write the answer of the following questions. [Each carries 2 Marks] [6]
1. Vapour pressure of water at 293 K is 17.535 mm Hg. Calculate the vapour pressure of water at 293K
when 25 g of glucose is dissolved in 450 g of water.
AS
3. The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. Calculate its molar conductivity.
Section C
//X
A
• Write the answer of the following questions. [Each carries 3 Marks] [6]
4. Calculate (a) molality (b) molarity and (c) mole fraction of KI if the density of 20 % (mass/mass)
AY
aqueous KI is 1.202 g mL–1 .
5. Write the Nernst equation and calculate potential of the following cell at 298 K.
o o
Mg(s) | Mg2+(0.001 M) || Cu2+(0.0001 M) | Cu(s) E 2+ = –2.36 V and E 2+ = +0.34 V
Mg /Mg Cu /Cu
AL
Section D
//X
• Write the answer of the following questions. [Each carries 4 Marks] [8]
6. Calculate the depression in the freezing point of water when 10 g of CH3CH2CHCl COOH is added
Y
to 250 g of water. [Ka = 1.4 × 10–3, Kf = 1.86 K kg mol–1] (Atomic mass : H = 1, C = 12, O = 16, Cl
= 35.5)
7.
VID
Explain chemistry of corrosion and state two methods to stop corrosion.
GH
A MA
HW
AS