01.12.

2024 Bihar Board

TAD
Test and Discussion for BSEB XII – 2024 – 25
Quantum Coaching Centre, Darbhanga
Chemistry Minor Test – 1
Total no. of Questions: 70+20+6 = 96 Full Marks – 60
Time: 3 Hours 15 Minutes
Instructions for the candidates:
1. Candidate must enter his/her Question Booklet Serial No. (10 digits) in the OMR Answer
Sheet.
2. Candidates are required to give their answers in own words as far as practicable.
3. Figures in the right-hand margin indicate full marks.
4. 15 minutes of extra time has been allotted for the candidates to read the questions carefully.
5. This question booklet is divided into two sections – Section-A and Section-B.
6. In Section-A, there are 100 objective type questions, out of which any 50 questions are to be
answered (each carrying 1 mark). First 50 answers will be evaluated by the computer in case
more than 50 questions are answered. For answering these darken the circle with blue / black
ball pen against the correct option on OMR Answer Sheet provided to you. Do not use
Whitener/liquid/blade/nail etc. on OMR-sheet, otherwise the result will be treated invalid.
7. In Section-B, there are 30 short answer type questions, out of which any 15 questions are to
be answered (each carrying 2 marks). Apart from this, there are 8 long answer type questions,
3out of which any 4 questions are to be answered (each carrying 5 marks).
8. Use of any electronic appliances is strictly prohibited.
Chemistry (Theory)
(English Medium)

Topic to be covered:

➢ Solution
➢ Chemical Kinetics
➢ P-Block
➢ D-Block

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 Objective Type Questions
Questions Nos. 1 to 70 have four options out of which only one is correct. You have to Mark
your selected option on the OMR sheet. Answer any 35 questions. 𝟑𝟓 × 𝟏 = 𝟑𝟓
1. 234.2 gm of sugar syrup contains 34.2 gm of sugar. What is the molarity of the solution
(a) 0.1 (b) 2.0 (c) 3.0 (d) 4.0
2. A 5% solution of cane sugar (molecular weight = 342) is isotonic with 1% solution of
substance X. The molecular weight of X is
(a) 68.4 (b) 34.2 (c) 171.2 (d) 136.8
3. If 2gm of NaoH is present in 200 ml of its solution. Its molarity will be
(a) 0.25 (b) 0.5 (c) 5 (d) 10
4. The number of moles of solute per kg of solvent is called
(a) Molarity (b) Molality (c) Normality (b) Mole Fraction
5. Which of the following is the property of ideal solution?
(a) Obeys Raoult’s law (b) Doesn’t obey Raoult’s law
(c) Both a and b (d) None of these
6. Which of the following is not an ideal solution?
(a) Benzene + Toluene (b) Methyl alcohol + Ethyl alcohol
(c) Chloroform + Acetone (d) CCl4 + Sicily
7. The minimum amount of energy required to convert reactant molecule into product is
(a) Kinetic Energy (b) Potential Energy (c) Activation Energy (d) K.E+P.E
8. The rate at which a substance reacts depends upon its
(a) Atomic mass (b) Equivalent mass (c) Molecular mass (d) Activate mass
9. The rate of chemical reaction
(a) Increases with time (b) Decreases with time
(c) May increase or decrease with time (d) Remains constant with time
10. The temperature co-efficient of most of the reaction lies between _____.
(a) 2 & 3 (b) 1 & 2 (c) 2 & 4 (d) 3 & 4
11. The rate of chemical reaction 2A + B → C can be represented by which of the following?
1 𝑑[𝐴] 𝑑[𝐵] 𝑑[𝐶]
(a) − (b) − (c) + (d) All of these
2 𝑑𝑡 𝑑𝑡 𝑑𝑡
12. The rate constant of a chemical reaction depends upon which of the following?
(a) Temperature (b) Mass (c) Height (d) Time
13. Chlorine reacts with excess of ammonia to form
(a) NH4Cl (b) N2 + HCl (c) N2 + NH4Cl (d) N2 + NCl3
14. White and yellow phosphorus are
(a) Allotropes (b) Isotopes (c) Isobars (d) None of these
15. In the reaction N2 + 3H2 ↔ 2NH3, if temperature increases then,
(a) Formation of NH3 increases (b) Formation of NH3 decreases
(c) No effect on the formation of ammonia (d) None of these
16. Ammonia changes the moist red litmus paper into
(a) Blue (b) Green (c) Black (d) White
17. The formula of nitric acid
(a) HNO3 (b) H2N2O2 (c) NHO2 (d) HNO4
18. The hybridization of H in NH3 is
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(a) Sp3 (b) Sp2 (c) Sp (d) d2sp3
19. Which of the following gives yellow or brown precipitate with alkaline nessler’s reagent?
(a) CO2 (b) NH3 (c) NaCl (d) KI
20. The most stable oxidation state of bismuth is
(a) +3 (b) +5 (c) +3 & +5 both (d) None of these
21. Which metal nitrate gives colourless gas on thermal decomposition
(a) NaNO3 (b) Ca(NO3)2 (c) Ba(NO3)2 (d) Hg(NO3)
22. Carbon atom in the carbonyl group is
(a) sp-hybridised (b) sp2- hybridised (c) sp3-hybridised (d) dsp2-hybridised
23. Which of the following is coloured?
(a) NH3 (b) NO2 (c) N2O (d) NO
24. Which of the following catalyst is used in the manufacturing of NH3 in Harber’s process?
(a) Finely divided Fe (b) Finely divided Mb
(c) Finely divided Ni (d) Finely divided pt
25. The substance which exhibit paramagnetism.
(a) H2O (b) O2 (c) NaCl (d) C6H6
26. Which of the following has 𝑝𝜋 − 𝑑𝜋 bond
(a)𝑁𝑂3− (b) 𝐶𝑂3−2 (c) 𝐵𝑂3−2 (d) 𝑆𝑂3−2
27. The elements of group 1.6 are known as
(a) Halogens (b) Chalcogene (c) Transition elements (d) Noble gas
28. Other than oxygen in group 1.6 of PT, the element found in
(a) S (b) Na (c) Fe (d) N2
29. The formula of oleum is
(a) H2S2O7 (b) H2SO4 (c) H2SO3 (d) H2Cl2
30. Oleum is composed of H2SO4 and which other constituent.
(a) SO2 (b) SO3 (c) H2S (d) 𝐻𝑆𝑂4−
31. H2SO4 is
(a) Oibasic acid (b) Monobasic acid (c) Mono acid (d) Diacid
32. The oxidation state of S in S8 is
(a) +2 (b) +4 (c) +8 (d) 0
33. Which of the following is the least volatile
(a) H2Se (b) H2Te (c) H2S (d) H2O
34. Which of the following acts as both oxidising agent as well as reducing agent?
(a) H2S (b) H2SO4 (c) SO2 (d) SO3
35. In which of the following is a polar compound?
(a) SO2 (b) SO3 (c) BF3 (d) CO2
36. The strongest acid is
(a) HClO4 (b) HClO3 (c) HClO2 (d) HClO
37. Which of the following bond is strongest
(a) F-F (b) Cl-Cl (c) I-I (d) Br-Br
38. Element found from sea water
(a) mg (b) Na (c) I (d) None of these
39. In which of the following oxidation state of oxygen is +2?

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(a) F2O (b) Cl2O (c) Na2O2 (d) Na2O
40. Which of the following form only one oxyacids?
(a) F2 (b) Cl2 (c) Br2 (d) I2
41. Which of the following does not form hydrogen bonding?
(a) NH3 (b) H2O (c) HCl (d) HF
42. Which of the following gas is mono-atomic?
(a) Chlorine (b) Helium (c) Nitrogen (d) Oxygen
43. The symbol of helium is
(a) He (b) Hi (c) Hm (d) All of these
44. Which of the following is the gas with lowest boiling point?
(a) H2 (b) He (c) N2 (d) Ar
45. Which of the following is a radioactive noble gas?
(a) He (b) Ne (c) Xe (d) Rn
46. By which of the following noble gases, the maximum number compounds have been
formed?
(a) He (b) Ne (c) Ar (d) Xe
47. The element showing highest oxidation state among first transition states is
(a) Ni (b) Cr (c) Fe (d) Mn
48. Which of the following metal do not liberate H2 gas on reaction with acids?
(a) Fe (b) 2n (c) Cu (d) mg
49. Transition element are also known as
(a) S-block elements (b) p-block elements
(c) d-block elements (d) d-block elements
50. The general electronic configuration of transition metals.
(a) (𝑛 − 1)𝑑5 (b) (𝑛 − 1)𝑑(1−10) 𝑛𝑠 0,1 𝑜𝑟 2
(c) (𝑛 − 1)𝑑(1−10) 𝑚𝑠1 (d) None of these
51. The highest magnetic moment shown by the transition metal ion with the outermost
electronic configuration is
(a) 3d5 (b) 3d2 (c) 3d7 (d) 3d9
52. Oxidation number of gold metal is
(a) +1 (b) 0 (c) -1 (d) None of these
53. Which of the following element is liquid in normal temperature?
(a) 2n (b) Hg (c) Br (d) Both b and c
54. Which of the following is called vitriol?
(a) FeSO4.7H2O (b) CuSO4.5H2O (c) CuSO4.2H2O (d) None of these
55. Which of the following is diamagnetic ion?
(a) CO+2 (b) Ni+2 (c) Cu+2 (d) 2n+2
56. The most abundant metal in the earth crust is
(a) Al (b) Fe (c) Ca (d) Na
57. In which of the following is the oxidation state of Mn lowest?
(a) MnSO4 (b) MnO2 (c) Mn3O4 (d) Mn2O7
58. Which of the following is not an actinide?
(a) Curium (b) Californium (c) Uranium (d) Terbium

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59. Which of the following ions are colourless?
(a) Cu+ (b) CO+2 (c) Ni+2 (d) Fe+3
60. Which of the following ions are diamagnetic?
(a) Cr+3 (b) V+2 (c) Sc+3 (d) Ti+3
61. Which of the following ions of transition element is paramagnetic?
(a) Ag+ (b) Cu+2 (c) Zn+2 (d) Au+2
62. Which of the following are coinage metal?
(a) Fe, Co, & Ni (b) Cu & Zn (c) Cu, Ag &Au (d) Au & pt
63. Which of the following is member of first transition series?
(a) Ni (b) Ac (c) Cd (d) Au
+2
64. The electronic configuration of Cu is
(a) 18[𝐴𝑟]3𝑑8 4𝑠1 (b) 18[𝐴𝑟]3𝑑7 4𝑠 2
(c) 18[𝐴𝑟]3𝑑9 (d) 18[𝐴𝑟]3𝑑 6 4𝑠 2 4𝑝1
65. The most common oxidation state shown by Ist row of transition element is
(a) +2 (b) +3 (c) +4 (d) Au
66. The shape of XeF4 is
(a) Tetrahedral (b) Square Planar (c) Pyramidal (d) Linear
67. Which of the following gas cannot be collected over water?
(a) O2 (b) H2S (c) SO2 (d) N2
1
68. Species having bond order 2 is/are
2
+ +
(a) N2 ` (b) O2
-2
(c) O2 (d) N2-2
69. Which of the following halogens is the strongest oxidising agent?
(a) I (b) Cl (c) F (d) Br
70. H2SO4 is a
(a) Acid (b) Base (c) alkali (d) All of these
Question Nos. 1 to 20 are short Answer Type. Answer any 10 questions. Each question
carries 2 marks. 𝟏𝟎 × 𝟐 = 𝟐𝟎
1. What do you mean by elevation of boiling points?
2. Discuss Raoult’s law of relative lowering of vapour pressure.
3. When 10 gm of a non-volatile solute is dissolve in 100 gm of C6H6 its boiling point raised by
10. What is the molecular mass of solute (k4 for C6H6=2.53)
4. What are isotonic solutions?
5. What is molal elevation constant? How is it related to molarity of a solution?
6. What is the effect of temperature on the rate of the reaction?
7. What are average and instantaneous rate of reaction?
8. The rate constant for first order reaction is 0.0005 min-1. Calculate its half-life.
9. Show that half-life period of 1st order reaction is independent of initial concentration.
10. The rate constant of a 1st order reaction is 60 sec-1. How much time will it take to reduces
75% of its initial concentration?
11. Why is the nitrogen molecule less reactive?
12. Write the name of catalyst used in contact process and Ostwald method.

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13. Outline the principle for the preparation of ammonia by Harber’s process. How is nitric acid
prepared from ammonia? Write the equation.
14. Why does H3PO3 act as reducing agent but H3PO4 does not?
15. Noble gases have comparatively large atomic radius. Why?
16. Write the electronic configuration of the following elements.
(i) V(Z=23) (ii) Zn (Z=30)
17. Transition elements exhibit variable oxidation state. Why?
18. Write the chemical reaction of NH3 gas with aqueous CuSO4 and AgNO3 solution
respectively.
19. Transition element form coloured compound. Explain.
20. Silver is a good conductor of electricity. Why?
Questions Nos. 21 to 26 are Long Answer Type Questions. Answer any 3 questions. Each
question carries 5 marks. 𝟑 × 𝟓 = 𝟏𝟓
21. Differentiate between Osmosis and diffusion (Dispersion). How is osmotic pressure
determined by Berkeley-Hartley method.
22. What do you mean by Vapour pressure? What happens to the vapour pressure when
(i) Volatile solute is dissolve in solution?
(ii) Non-volatile solute is dissolved in solution
23. Derive the expression for the rate constant of a first order reaction.
24. For a chemical reaction the energy of activation of 80 KJ/mol. If the frequency factor is
4.0 × 1010 𝐿/𝑚𝑜𝑙. What is the rate constant at 400K.
25.(a) Write the principle of manufacture of sulphuric acid by constant process.
(b) How is sulphuric acid prepared by lead chamber process? Give its principle.
26. How does SO2 react with the acidic solution of the following
(a) KmnO4 (b) K2Cr2O7

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