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NIRMALA MATHA CONVENT MATRIC Hr. Sc.

SCHOOL
Kuniyamuthur
STD:12th CHEMISTRY Total marks:70

I. Choose the appropriate answer 15x1=15


1. Splitting of spectral lines in the presence of electric field is
known as :
A)Stark effect B)Zeeman's effect
C)Moseley's effect D)Compton effect
2. The law of triad is NOT applicable to a group of :
A)Ca,Sr,Ba B)Cl,Br,I C)Be,B,C D)Li,Na,K

3. What would be the IUPAC name for an element with


atomic number 222
A)bibibiium B)bididium C)didibium D)bibibium
4)What is the shape of IF5
A)Trigonal bipyramidal b)Tetrahedral
c)Square bipyramidal d)Octahedral
5.The temperature at which real gases obey the ideal gas law
over a wide range of pressure is called:
A)Boyle's temperature B)reduced temperature
C)critical temperature D)inversion temperature
6. The effect of a catalyst an on equilibrium is to
A) increase the rate of the forward reaction only.
B) increase the equilibrium constant so that products are
favored.
C) slow the reverse reaction only.
D) increase the rate at which equilibrium is achieved without
changing the composition of the equilibrium mixture.

7. Match List I and List II


List-I List-II
A
Boyle’s Law E) PV = NkBT
)
P/T = constant,
B at
Charles’s law F)
) constant
volume

V∝T at
C G
Gay-Lussac’s law constant
) )
pressure
D Equation of state of an H P1V1 =
) ideal gas ) constant

a) A-G,B-H,C-F,D-E b) A-H,B-G,C-E,D-F
c) A-E,B-G,C-F,D-H d) A-H,B-G,C-F,D-E
8) Select the correct IUPAC name of neopentane.
A)3, 3–dimethylpropane B)1, 2–dimethylpropane
C)2, 3–dimethylpropane D)2, 2–dimethylpropane
9. ……………..is the general formula of alkene
A)CnH2n B)CnH2n+2 C)CnH2n+2 D)CnHn−2

10. Which of the following is not an example of aromatic


compound ?
A)Benzene C)Naphthalene
C)Cyclobutane D)Phenol

11. Consider the following equilibrium reaction and

(i) N2+O2⇔2NO, K1
relate their equilibrium constants ….

(ii) 2NO+O2⇔2NO2, K2
(iii) N2+2O2⇔2NO2, K3
A)K3=K2=K1 B)K1×K3=K2
c)K1×K2=K3 D)K1K2=K3
12.Which of the following is absolute zero
A )293K B)273K C)-273.15OC D)0OC
13. Which element has the least electron affinity
A)Phosphorous B)Oxygen C)Sulphur D)Nitrogen
14. Two electrons occupying an orbital are
distinguished by:
A)principal quantum number
B)angular momentum quantum number
C)magnetic quantum number
D)spin quantum number
15. Which of the following is the standard for atomic mass?
1 12 13
A) 1H B) 6C C) 6C
D) 6C14

II.Answer any six questions.Q.no 22 is compulsory 6x2=12


16.Define relative atomic mass
17.Define Electronegativity
18. Write the Equation to calculate the energy of nth orbir
19.State Boyle’s law
20.State Octet rule
21.Explain why aerated water bottles are kept under water
during summer
22.What is Le-Chatlier’s principle
23. Explain diagonal relationship
24.What is the iupac name of the following compound
III.Answer any 6 questions.Q.no 33 is compulsory 6x3=18
25.Explain the periodic trend of Ionisation potential
26.Explain about principle of chromatography.What is
adsorption chromatography
27.What is displacement and decomposition reaction?Give
suitable Examples for each
28.Define orbital. What are n and l values for 3px & 4dx2 -y2
electron?
29.What are Lewis structures?Write Lewis structures for
H2,BF2,H2O
30.What is boiling point and condensation point of a liquid?
31.Calculate the molar mass of the following compounds
(i)Urea[ CO(NH2)2] ii)Sulphuric acid[H2SO4]
32.What are isoelectronic species?Give 2 examples
33.Describe Aufbau princple

IV.ANSWER ALL THE QUESTIONS 25x5=25


34.
A)(i)What is equilibrium and Explain the classification of
equilibrium
(ii)How many orbitals are possible for n=4
(OR)
B)(i) What is density of N2 gas at 227oC at 5 atm pressure ?
(R=0.0821atm K−1 mol−1)
(ii)State and explain Pauli exclusion principle

35.
(A)(i)What is Screening effect?
(ii) Give explaination why
a)Liquid ammonia bottle is cooled before opening the seal
b)Aerosol canes carry clear warning of heating of the can
(OR)
B.(i)Why halogens act as oxidizing agents
(ii)What is geometrical isomerism.Give example

36.
A) )(i)State Mendeleev’s periodic law
(ii)Describe about any 3 drawbacks of Mendeleev’s
periodic table
(OR)
B)Draw and explain M.O diagram of Carbon molecule

37.
A)(i) What is meant by Limiting Reagent
(ii)a)Define Coordinate covalent bond with example
b)Define metamerism
(OR)
B) Explain the various types of Constitutional isomerism.

38.
(i)Mention any 3 anonmalous properties of Second period
elements
(ii)What is homologous series

(OR)
B)(i)One mole of H2 and one mole of I2 are allowed to attain
equilibrium in 1L container. If the equilibrium mixture
contains 0.4Mole of HI .Calculate the equilibrium constant.
(ii)40 ml of methane is completely burnt using 80 ml of
oxygen at room temperature. The volume of gas left after
cooling to room temperature is

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