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26 views

course 1 pdf

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hesham.ziada2007
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Model answer lesson 4 chapter 3

Question Answer Question Answer


1 C 34 A
2 B 35 D
3 B 36 C
4 B 37 A
5 D 38 C
6 C 39 B
7 D 40 C
8 C 41 C
9 A 42 A
10 A 43 C
11 B 44 C
12 B 45 A
13 B 46 C
14 A 47 Bsteps↓
15 B 48 A steps↓
16 B 49 B steps↓
17 C 50 D steps↓
18 A 51 C steps↓
19 C 52 B steps↓
20 C 53 A steps↓
21 B 54 edit↓ First : A steps↓
Second : D steps↓
22 A 55 First : A steps↓
Second : C steps↓
23 D 56 B steps↓
24 A 57 C steps↓
25 C 58 B steps↓
26 D 59 B steps↓
27 B 60 B steps↓
28 A 61 C
29 D 62 A
30 C 63 A steps↓
31 B 64 A steps↓
32 C 65 D steps↓
33 B

Steps
47)

CH3COOH + H2O ⇌ H3O+ + CH3COO-

[H3 O+ ] = √Ka × Ca = √1.8 × 10−5 × 0.1 =1.3416 ×10-3 ≃ 1.342 ×10-3 M

48)

HF + H2O ⇌ H3O+ + F-

Ka = ∝2 × Ca

ka 6.7 × 10−4
∝ = √ = √ = 0.081853 ≃ 0.08185
Ca 0.1

49)

HX + H2O ⇌ H3O+ + X-

7.15
∝ = 7.15% = = 0.0715
100

Ka = ∝2 × Ca

Ka = 0.07152 × 0.1

Ka = 5.11225 × 10-4 ≃5.11 × 10-4


50)

3
∝ = 3% = = 0.03
100

Kb = ∝2 × Cb

Kb = 0.032 × 0.02

Kb = 1.8 × 10-5

51)

HCN + H2O ⇌ H3O+ + CN-

[H3 O+ ] = [H + ]

[H+] = √Ka × Ca = √7.2 × 10−10 × 0.01 = 2.6832×10-6 M ≃ 2.68×10-6 M

52)

NH3 + H2O ⇌ NH4+ + OH-

[OH − ] = √Kb × Cb = √1.8 × 10−5 × 0.01 = 4.242×10-4 ≃ 4.3×10-4 M


53)

Ethanoic acid = Acetic acid = CH₃COOH

(this acid (one of organic acids which are weak) will be studied in organic

chemistry and this question will be answered with same steps as acetic acid)

CH3COOH + H2O ⇌ H3O+ + CH3COO-

[H3 O+ ] = √Ka × Ca

[H3 O+ ]2 = Ka × Ca

[H3 O+ ]2 (1.34 × 10−3 )2 1.7956 × 10−6


Ka = = = = 1.7956 × 10-5 ≃ 1.8 × 10-5
Ca 0.1 0.1

54)

Edit: ionization constant pf acid = 1.8x10-5

CH3COOH + H2O ⇌ H3O+ + CH3COO-

First:

Ka = ∝2 × Ca

Ka 1.8 × 10−5
α = √ Ca = √ = 1.8973 × 10-2 ≃ 1.897 × 10-2
0.05

Second:

[H3O+] = √Ka × Ca = √1.8 × 10−5 × 0.05 = 9.48 × 10-4 M


55)

NH4OH ⇌ NH4+ + OH-

First:

Kb = ∝2 × Cb

Kb 1.6 × 10−6
α = √ Cb = √ = 4 × 10-3
0.1

Second:

[OH-] = √Kb × Cb = √1.6 × 10−6 × 0.1 = 4 × 10-4 M

56)

HX + H2O ⇌ H3O+ + X-

Since same temperature, therefore, same Ka

1st solution:

Ka = ∝2 × Ca

Ka = 0.15 × 0.0082 = 9.6 × 10-6

1st solution:

Ka = ∝2 × Ca

Ka 9.6 × 10−6
α = √ Ca = √ =9.797 × 10-3 ≃ 9.8 × 10-3 (shift ENG [on calculator]➔ 0.0098)
0.1
57)

number of moles 0.25


Concentration (Ca) = = = 0.25M
volume of solution (L) 1

Ka = ∝2 × Ca

Ka = (2x10−2)2 x 0.25 = 1x10−4

58)

CH3COOH + H2O ⇌ H3O+ + CH3COO-

1.34
α = 1.34 % = = 0.0134
100

Ka = ∝2 × Ca

Ka = (0.0134)2 x 0.1 = 1.7956x10−5

[H3 O+ ] = √ka x Ca = √1.7956x10−5 x 0.1 = 1.34x10−3 M

59)

CH3COOH + H2O ⇌ H3O+ + CH3COO-

[CH3 COO− ] = [H3 O+ ] = √ka x Ca = √1.8x10−5 x 0.02 = 6x10−4 M


60)

Kb = ∝2 × cb

Kb
∝ = √Cb

Kb 1.8x10−5
a) α = √Cb = √ = 0.0134
0.10

Kb 4.5x10−4
b) α = √Cb = √ = 0.042
0.25

Kb 1.7x10−4
c) α = √Cb = √ = 0.013
1

Kb 4.4x10−4
d) α = √Cb = √ = 0.014
2

α of B is the greatest ➔ highest conduction

63)

1
α = 1%= = 0.01
100

Ka = ∝2 × Ca

Ka = (0.01)2 x 0.1 = 1x10−5

By dilution at constant temperature :

1x10-5 = ∝2 × 0.025

∝2 = 0.0004

α = 0.02 = 2%
64)

number of moles 0.25


Concentration (Ca) = = = 0.5M
volume of solution (L) 500x10−3

Ka = ∝2 × Ca

Ka = (2x10−4 )2 x 0.5 = 2x10−8

65)

Ka = ∝2 × Ca

5.1x10-4 = ∝2 × 0.2

∝2 = 0.00255

α = 0.0505

𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑑𝑖𝑠𝑠𝑜𝑐𝑖𝑎𝑡𝑒𝑑 𝑚𝑜𝑙𝑒𝑠 (𝑖𝑜𝑛𝑖𝑧𝑒𝑑)


α =
𝑡𝑜𝑡𝑎𝑙 𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙𝑒𝑠 𝑏𝑒𝑓𝑜𝑟𝑒 𝑑𝑖𝑠𝑠𝑜𝑐𝑖𝑎𝑡𝑖𝑜𝑛

Total number of moles before dissociation = MV = 0.2 x 200 x 10-3 = 0.04 mol.

𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑑𝑖𝑠𝑠𝑜𝑐𝑖𝑎𝑡𝑒𝑑 𝑚𝑜𝑙𝑒𝑠 (𝑖𝑜𝑛𝑖𝑧𝑒𝑑)


0.0505 =
0.04

Number of dissociated moles = 0.002019 = 2.02x10-3 mol

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