Chapter - 1 Chemical_Reactions_and_Equations
Chapter - 1 Chemical_Reactions_and_Equations
Chapter - 1 Chemical_Reactions_and_Equations
CLASSES
(DDA, KALKAJI)
www.upilclasses.in
SCIENCE
(Chemistry)
Chapter 1: Chemical Reactions and Equations
CHEMIST CHEMICAL REACTIONS AND
RY EQUATIONS
Chemical Reactions and Equations
● Most of the substance around us undergoes various changes. Some of these changes are
temporary with no new substance being formed. They are called physical changes.
Example: Water changes to steam on boiling but no new substance is formed(Even
though steam and water look different when they are made to react with a piece of Na,
they react the same way and give the exact same products). This involves only a change
in state (liquid to vapour).
● A substance is said to undergo a chemical change when the chemical properties of a
substance alter. As a result, there is either formation or breaking of atomic bonds at the
molecular level. Some characteristics of a chemical change are:
o New substances are produced during a chemical reaction.
o Changes in energy are involved.
o During the reaction, there occurs a change in mass.
o There is a permanent alteration.
Examples:
● Cooking of food
● Rusting of iron
● Heating of Lead nitrate
● Souring of milk
● Ripening of fruit.
Chemical Equation
Writing Chemical Equations
● In a chemical reaction, the reactants are written on the left hand side and the products
on the right hand side of the equation.
● An arrow (→) pointing towards the products is inserted between the reactants and the
products. It also represents the direction of the reaction.
● A single arrow (→) indicates the direction in which the reaction proceeds.
● A double arrow ( ) indicates a reversible reaction, i.e. the products recombine to form
the reactants.
● A plus sign (+) is inserted between two or more reactants or products formed.
● If reactions are carried out under specific conditions of temperature, pressure, catalyst
etc., then these conditions are mentioned on the arrow.
● The chemical equation can be made more informative by mentioning the physical states
of the reactants and products.
● If gas is liberated as a product, then it is represented by an arrow pointing upwards (↑).
CHEMIST CHEMICAL REACTIONS AND
EQUATIONS
RY If the product formed is in the form of a precipitate, it is represented by an arrow
pointing downwards (↓).
Balancing the Chemical Equations
● In a balanced chemical equation, the total number of atoms of each element of the
reactants on the left hand side of the equation is equal to the number of atoms of the
products formed on the right hand side of the equation.
● The total mass of the reactants is equal to the total mass of the products or the number
of atoms of each element before the reaction and after the reaction is equal.
Steps Involved in Balancing a Chemical Equation
Consider the chemical reaction between magnesium and oxygen to understand the steps
involved in balancing a chemical equation.
Step 1
Let us first write the word equation for this reaction.
Magnesium + Oxygen → Magnesium oxide
Step 2
Write the chemical equation for the reaction between magnesium and oxygen.
Mg + O2 → MgO
Step 3
Count the number atoms of an element occurring on both L.H.S. and R.H.S. in this equation.
Mg + O2 → MgO
Component Reactant Product
Magnesium 1 1
Oxygen 2 1
● Choose a reactant or a product which has the maximum number of atoms in it. In that
compound, select the element which has the maximum number of atoms. In this equation
we shall select MgO i.e. magnesium oxide and the element oxygen in it.
● To balance the oxygen atoms, let us multiply magnesium oxide molecule by 2 on the right
hand side. The equation can now be expressed as,
CHEMIST CHEMICAL REACTIONS AND
RY EQUATIONS
Component Reactant Product
Magnesium 1 1×2=2
Oxygen 2 1×2=2
Step 5
There are two oxygen atoms on either side of the equation but one magnesium atom on
the reactant's side and two on the product's side. Therefore, multiply the magnesium atom
by 2 on the left hand side.
Component Reactant Product
Magnesium 1×2=2 2
Oxygen 2 2
Balanced equation is,
∴ The number of atoms of each element of reactants = The number of atoms of each
element of products
Step 6
Writing Specific Conditions on the Arrow
The reaction is carried out in the presence of ‘Heat’. On heating, magnesium combines with
oxygen present in air to form magnesium oxide.
Step 7
Writing Symbols of Physical States
Correct way of heating the boiling tube containing crystals of ferrous sulphate and of smelling the odour
For example:
When mercuric oxide is heated in a crucible, the orange-red powder begins to darken and a
silver mirror begins to deposit on the cooler parts of the crucible.
Corrosion
The slow process of decay and destruction of metals due to the action of air, moisture or
acids is called corrosion.
For example:
Iron combines with oxygen present in the air, in the presence of water, to form a red-brown
flaky substance called rust. This process is commonly called the rusting of iron.
The chemical formula of rust is Fe2O3. × H2O.
Prevention of Corrosion
● Corrosion damages buildings, bridges, ships, automobiles and other articles made of iron.
Hence, prevention of corrosion is necessary. This will not only save money but can also
prevent the occurrence of accidents.
● It can be prevented by processes like galvanising and electroplating with other metals.
Rancidity
● Oils and fats react with oxygen and get oxidised or turn rancid. This process is called
rancidity.
● Rancidity can be prevented by keeping food in air tight containers or by using
antioxidants.
● Antioxidants are used to prevent oxidation of food containing fats and oils.
● Storage of food in air tight containers also decelerates oxidation.
CHEMIST CHEMICAL REACTIONS AND
RY EQUATIONS
CHEMIST CHEMICAL REACTIONS AND
RY EQUATIONS Important Questions
2. On heating blue coloured powder of copper (II) nitrate in a boiling tube, copper
oxide (black), oxygen gas and a brown gas X is formed.
(а) Write a balanced chemical equation of the reaction.
(b) Identify the brown gas X evolved.
(c) Identify the type of reaction.
(d) What could be the pH range of aqueous solution of the gas X?
3. (A) Name the type of chemical reaction represented by the following equation:
CHEMIST CHEMICAL REACTIONS AND
EQUATIONS
RY(c) Zn(s) + H2SO4(ag) → ZnSO4(aq) + H2(g)
(B) “A solution of potassium chloride when mixed with silver nitrate solution, and an
insoluble white substance is formed”.
(i) Translate the above statement into a chemical equation.
(ii) State two types for the classification of this reaction.
⮚ Assertion Reason Questions:
1. For two statements are given-one labelled Assertion (A) and the other labelled Reason
(R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as
given below:
a. Both A and R are true, and R is correct explanation of the assertion.
b. Both A and R are true, but R is not the correct explanation of the assertion.
c. A is true, but R is false.
d. A is false, but R is true.
Assertion: Silver articles become black after sometime when exposed to sunlight.
Reason: It is because silver reacts with carbonates present in the air.
2. For two statements are given-one labelled Assertion (A) and the other labelled Reason
(R). Select the correct answer to these questions from the codes (a), (b), (c) and (d) as
given below:
a. Both A and R are true, and R is correct explanation of the assertion.
b. Both A and R are true, but R is not the correct explanation of the assertion.
c. A is true, but R is false.
d. A is false, but R is true.
Assertion: A lead nitrate on thermal decomposition gives lead oxide, brown coloured
nitrogen dioxide and oxygen gas.
Reason: Lead nitrate reacts with potassium iodide to form yellow ppt. of lead iodide and
the reaction is double displacement as well as precipitation reaction.
⮚ Case Study Questions:
1. Read the following and answer any four questions from (i) to (v).
Oxidation has damaging effect on metals as well as on food. The damaging effect of
oxidation on metal is studied as corrosion and that on food is studied as rancidity. The
phenomenon due to which metals are slowly eaten away by the reaction of air, water
and chemicals present in atmosphere, is called corrosion. For example, iron articles are
shiny when new, but get coated with a reddish-brown powder when left for some time.
This process is known as rusting of iron. Rancidity is the process of slow oxidation of oil
and fat (which are volatile in nature) present in the food materials resulting in the
change of smell and taste in them.
i. Rancidity can be prevented by:
a. Adding antioxidants.
CHEMIST CHEMICAL REACTIONS AND
RY b. EQUATIONS
Packaging oily food in nitrogen gas.
c. Both (a) and (b).
d. None of these.
ii. Combination of phosphorus and oxygen is an example of:
a. Oxidation.
b. Reduction.
c. Rancidity.
d. None of these.
iii. A science teacher wrote the following statements about rancidity:
I. When fats and oils are reduced, they become rancid.
II. ln chips packet, rancidity is prevented by oxygen.
III. Rancidity is prevented by adding antioxidants.
Select the correct option.
a. (I) only
b. (II) and (III) only
c. (III) only
d. (I), (II) and (III)
iv. Two statements are given below regarding rusting of iron.
I. The rusting of iron is a redox reaction and reaction occurs as, 4Fe + 3O 2 →
4Fe3+ + 6O2-
II. The metallic iron is oxidised to Fe2+ and O2 is reduced to O2-.
Select the correct statement(s).
a. I only.
b. II only.
c. Both I and II.
d. None of these.
v. Which of the following measures can be adopted to prevent or slow down
rancidity?
I. Food materials should be packed in airtight container.
II. Food should be refrigerated.
III. Food materials and cooked food should be kept away from direct sunlight.
a. Only II and III.
b. Only I and III.
c. Only II and III.
d. I, II and III.
2. Read the following and answer any four questions from (i) to (v).
Chemical equation is a method of representing a chemical reaction with the help of
symbols and formulae of the substances involved in it. ln a chemical equation, the
substances which combine or react are called reactants and new substances produced are
CHEMIST CHEMICAL REACTIONS AND
EQUATIONS
RYcalled products. A chemical equation is a shorthand method of representing a chemical
reaction. A balanced chemical equation has equal number of atoms of different elements
in the reactants and products side. An unbalanced chemical equation has unequal number
of atoms of one or more elements in reactants and products. Formulae of elements and
compounds are not changed to balance an equation.
i. Consider the following reaction:
pMg3N2 + qH2O → rMg(OH)2 + sNH3
When the equation is balanced, the coefficients p, q, r, s respectively are:
a. 1, 3, 3, 2
b. 1, 6, 3, 2
c. 1, 2, 3, 2
d. 2, 3, 6, 2
ii. Which of the following information is not conveyed by a balanced chemical equation?
a. Physical states of reactants and products.
b. Symbols and formulae of all the substances involved in a particular reaction.
c. Number of atoms/ molecules of the reactants and products formed.
d. Whether a particular reaction is actually feasible or not.
iii. The balancing of chemical equations is in accordance with:
a. law of combining volumes.
b. law of constant proportions.
c. law of conservation of mass.
d. both (b) and (c).
iv. Which of the following chemical equations is an unbalanced one?
a. 2NaHCO3 → Na2CO3 + H2O + CO2
b. 2C4H10 + 12O2 → 8CO2 + 10H2O
c. 2AI + 6H2O → 2Al(OH)3 + 3H2
d. 4NH3 + 5O2 → 4NO + 6H2O
v. Which of the following statements is/ are correct?
a. A chemical equation tells us about the substances involved in a reaction.
b. A chemical equation informs us about the symbols and formulae of the
substances involved in a reaction.
c. A chemical equation tells us about the atoms or molecules of the reactants and
products involved in a reaction.
d. All the above.
✔ Answer Key-
⮚ Multiple Choice Answers:
1. (b)
2. (a) basic magnesium carbonate
CHEMIST CHEMICAL REACTIONS AND
EQUATIONS
RY 3. (c) (i), (ii) and (iv)
4. (a) (i) and (ii)
5. (a) addition of oxygen
6. (b) addition of hydrogen
7. (c) (i) and (iv)
8. (a) 1 : 2
9. (a) (i) only
10. (d) MnO2
⮚ Very Short Answers:
1. Answer: Food becomes rancid when fat and oils present in the food are
oxidized.
2. Answer: X = Mg, Y = MgO, Mg + O2 → 2MgO
3. Answer: An equation that has equal number of atoms of each element on both
the sides of the equation is called a balanced chemical equation, i.e., mass of
the reactants is equal to mass of the products.
4. Answer: BaCl2(aq) + Na2SO4 (aq) → BaSO4(s) + 2NaCl(aq)
5. Answer: It is a brown mass known as hydrated ferric oxide. Its formula is Fe 2O3.
xH2O.
6. Answer: The zinc rod will change into zinc sulphate.
7. Answer: Both silver chloride and silver bromide are used in black and white
photography.
8. Answer: The process is known as the reduction of metal oxide.
9. Answer: Corrosion is responsible for the formation of this coating. Black coating
is due to formation of Ag2S and green coating is due to formation of
CuCO3.Cu(OH)2.
10. Answer: Lime water (calcium hydroxide) combines with carbon dioxide to form
a suspension of calcium carbonate which makes lime water milky.
Ca(OH)2 + CO2 → CaCO3 + H2O
⮚ Short Answer:
1. Answer:
(i) Marble chips react with dilute hydrochloric acid to form calcium chloride and
carbon dioxide. It is a double displacement reaction.
CaCO3 + 2HCl → CaCl2 + H2O + CO2
(ii) Zinc granules react with dilute hydrochloric acid to give hydrogen gas. It is a
displacement reaction.
CHEMIST CHEMICAL REACTIONS AND
RY Zn (s) +EQUATIONS
2HCl → ZnCl2 (aq) + H2 (g)
2. Answer:
The reaction in which two compounds in their aqueous state react to form an
insoluble compound. When two reactants react and product formed remains
insoluble and settles as a solid it is substance (precipitate) is called a
precipitation reaction.
For example,
(i) When aqueous solution of sodium sulphate is mixed with an aqueous
solution or barium chloride, barium sulphate is obtained as a white precipitate.
Na2SO4 (aq) + BaCl2 (aq) → BaSO4 (s) + 2NaCl (ag)
(ii) When aqueous solution of sodium chloride is mixed with an aqueous
solution of silver nitrate, silver chloride is obtained as a white precipitate.
3. Answer:
On mixing the solutions of sodium sulphate and barium chloride, a white
precipitate of barium sulphate is obtained.
7. Answer:
(a) The most reactive element is ‘B’. It has displaced both ‘A’ and ‘C’ from their
compounds.
(b) The least reactive element is ‘C’ as it has been displaced by both ‘A’ and ‘B’.
8. Answer:
⮚ Long Answer:
1. Answer:
(a) Bacl2 + H2SO4 → BaSO4 + 2HCl
(b) CH4 + 2O2 → CO2 + 2H2O
2. Answer: