CHEMISTRY COORDINATION COMPOUNDS

R-DPP
Day

46
REVISION DAILY
PRACTICE PROBLEMS Date: 27/12/24
FOCUS JEE 2025 Revision Sub.: CHEMISTRY
Course: JP Revision Topic: COORDINATION COMPOUNDS

1. The pair Co  NH3 5 NO3  SO4 and Co  NH3 5 SO4  NO3 will be
A) Hydrate isomers B) Linkage isomers C) Ionization isomers D) Coordinate isomers
2. One mole of the complex compound Co(NH3)5Cl3 gives 3 moles of ions on dissolution in water.
One mole of the same complex reacts with two moles of AgNO3 solution to yield two moles of
AgCl(s). The structure of the complex is
A) Co  NH3 4 Cl  Cl2.NH3 B) Co  NH3 5 Cl  Cl2
C) Co  NH3 3 Cl3  .2NH3 D) Co  NH3 4 Cl2  Cl.NH3
3. Which of the following aqua metal ions has the highest paramagnetism?
3 2 2 2
A) Cr  H2O6  B) Fe  H2O6  C) Cu  H2O6  D) Zn  H2O2 
4. Which of the following species is expected to be colourless?
3 2 4
A)  Ti  H2O6  B)  Ti  NO3 4  C) Cu  NH3 4  D) Fe  CN6 
5. The compounds [Cr(H2O)6]Cl3, [Cr(H2O)5Cl]Cl2.H2O and [Cr(H2O)4Cl2]Cl.2H2O exhibit
A) Linkage isomerism B) Geometrical isomerism
C) Ionization isomerism D) Hydrate isomerism
6. What is the name of the complex Ni  H2O4  NH2CH2CH2NH2  SO4.5H2O as per IUPAC rules?
A) Aquaethylenediaminenickel(II) sulfate 1-water
B) Tetraaquaethylenediaminenickel(II) sulfate 5-water
C) Tetraaquabis(ethylenediamine)nickel(II) sulfate 5-water
D) Tetraaquabis(ethylenediamine)nickel(III) sulfate 5-water
7. The correct order of magnetic moments (spin values in BM) among is:
A) [Fe(CN)6]4– > [CoCl4]2– > [MnCl4]2– B) [MnCl4]2– > [Fe(CN)6]4– > [CoCl4]2–
C) [Fe(CN)6]4– > [MnCl4]2– > [CoCl4]2– D) [MnCl4]2– > [CoCl4]2– > [Fe(CN)6]4–
8. How many unpaired electrons are present in the high spin form of the [CoF 6]3- complex and
which metal orbitals are used in bonding?
A) 0 unpaired electrons and 4s, 4p and 4d orbitals to give sp3d2 hybridization
B) 4 unpaired electrons and 4s, 4p and 4d orbitals to give sp3d2 hybridization
C) 0 unpaired electrons and 3d, 4s and 4p orbitals to gives d2sp3 hybridization
D) 4 unpaired electrons and 3d, 4s and 4p orbitals to give d2sp3 hybridization
9. Which ion would you expect to have the largest splitting of d-orbitals?
4 3 2 3
A) Fe  CN6  B) Fe  CN6  C) Fe  H2O6  D) Fe  H2O6 
10. If 0  P, what is electronic arrangement of metal atom/ion in octahedral complex with d4
configuration:
4 0 4 0 3 1 2 2
A) t2g ,eg B) eg ,t2g C) t2g ,eg D) eg ,t2g
11. Set of d-orbitals which are used by central metal during formation of MnO4 ?
A) dx2 y2 ,dz2 ,dxy B) dxy ,d yz ,dxz C) dx2 y2 ,dxy ,dxz D) dx2 y2 ,dz2 ,dxz
12. The total possible coordination isomers for the following compounds respectively are:
[Co(en)3][Cr(C2O4)3] [Cu(NH3)4][CuCl4] [Ni(en)3][Co(NO2)6]
A) 4, 4, 4 B) 2, 2, 2 C) 2, 2, 4 D) 4, 2, 4

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CHEMISTRY COORDINATION COMPOUNDS

13. The following complexes are given:

1) trans-[Co(NH3)4Cl2]+ 2) cis-[Co(NH3)2(en)2]3+ 3) trans-[Co(NH3)2(en)2]3+
4) NiCl24 5) TiF62 6) CoF63
Choose the correct code:
A) 1), 2) are optically active, 3) is optically inactive
B) 2) is optically active; 1), 3) are optically inactive
C) 4), 5) are coloured and 6) is colourless
D) 4) is coloured and (5), (6) are colourless
14. Select the correct code regarding total number of space isomers for the following compounds:
n
II. M  AB3 
n n
I. Ma 3b2c III. Ma 2b2c2 
I II III
A) 4 4 6
B) 4 3 5
C) 3 3 5
D) 3 4 6
2
15. A M  H2O6  complex typically absorbs at around 600 nm. It is allowed to react with
2
ammonia to form a new complex M  NH3 6  that should have absorption at:
A) 800 nm B) 580 nm C) 620 nm D) 320 nm
complex is 18000 cm–1. The  for CoCl4 
2
16. The CFSE for CoCl6 
4
will be:
A) 18000 cm–1 B) 16000 cm–1 C) 8000 cm–1 D) 2000 cm–1
17. The optical activity is shown by which of the following.

A) B) C) D)

18. Which of the following complex has highest C  O bond energy?

3 
A) Ni  CO4  B) Co  CO6  C) Mn  CO6  D) None
19. The pair in which both species have same magnetic moment [spin only]
2 2 2
A) Cr  H2O6  , CoCl4  B) Cr  H2O6  , Fe  H2O6 
2

2 2 2
C) Mn  H2O6  , Cr  H2O6  D) CoCl4  , Fe  H2O6 
2

20. Which has maximum EAN of the underlined atoms? (Cr = 24, Co = 27, Fe = 26, Ni = 28)
A) [Cr(EDTA)] B) [Co(en)3 ]3 C) [Fe(C2O4 )3 ]3 D) Ni(CN)4 2
21. Primary and secondary valency of Pt in [Pt(en)2 Cl2 ]Cl2 are:
A) 2, 4 B)4, 6 C)6, 6 D)4, 4
22. Arrange the following in order of increasing number of unpaired electrons:
(I) [Fe(H2O)6 ]2 (II) [Fe(CN)6 ]3 (III) [Fe(CN)6 ]4 (IV) [Fe(H2O)6 ]3
A) IV, I, II, III B)I, II, III, IV C)III, II, I, IV (V) II, III, I, IV
23. Which of the following complexes exhibits geometrical isomerism? [gly = glycinato, en =
ethylene diamine, Py = pyridine, ox = oxalate]
2 2 2
A) Pt  gly 2  B) Pt  en2  C) Pt  Py 4  D) Pt  ox 2 
24. Which has maximum conductance?
A) PtCl4  6NH3 B)PtCl4  5NH3 C)PtCl4  4NH3 D)equal

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CHEMISTRY COORDINATION COMPOUNDS

25. Statement 1: [Co(NH3)5NO2]Cl2 and [Co(NH3)5ONO]Cl2 exhibit ionization isomerism

Statement 2: Both compounds form chloride ions in solution
A) If both the statements are true and statement 2 is the correct explanation of statement 1
B) If both the statements are true but statement 2 is not the correct explanation of statement
1
C) If statement 1 is true and statement 2 is false
D) If statement 1 is false and state 2 is true
26. Amongst the following the most stable complex is:
A) [Fe(H2O)6]3+ B) [Fe(C2O4)3]3– C) [Fe(H2O)5NO]2+ D)[FeF6]3–

27. Which complex is likely to show optical activity?

 3
A) Trans  Co  NH3 4 Cl2  B) Cr  H2O6 
3 3
C) Cis  Co  NH3 2 en2  D) Trans  Co  NH3 2  en2 

28. Which of the following is a bidentate ligand

A) H2O B) CN C) ethylene diammine D) OH
29. The IUPAC name of the complex Na Co  CO4  is
A) sodium tetra carbonylcobaltate (1) B) Sodium tetracarbonylcobaltate(I)
C) Sodium tetracarboxycobaltate (I) D) Sodiumtetracarbonyl cobalt (I)
30. Which of the following is a π- acceptor ligand.
A) NH3 B) CN C) H2O D) NO2

1 6 11 16 21 26
2 7 12 17 22 27
OMR

3 8 13 18 23 28
4 9 14 19 24 29
5 10 15 20 25 30
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CHEMISTRY COORDINATION COMPOUNDS

1) B 2) B 3) B 4) B 5) D 6) B 7) D 8) B 9) B 10) C

11) B 12) D 13) B 14) D 15) B 16) C 17) B 18) C 19) B 20) B

21) B 22) C 23) A 24) A 25) B 26) B 27) C 28) C 29) B 30) B

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