NEET 2021-22

Time : 60 Min Chem : Co ordination Compound Marks : 180

01) On hydrolysis (Me)2 SiCl2 will produce B) H

A) Me2SiCl(OH) C) H
B) [O  (Me)2 Si  O]n  D) None of these
C) (Me)2 Si  O 08) The compound that is not olefinic
D) (Me)2 Si(OH)2 organometallic is
A) C4H4Fe(CO)3
02) The total number of possible isomers for the B) (C2H4PtCl3 )2
complex compound CuII (NH3 )4  PtIICl4  are C) Be(CH2 )2
  
A) 6 D) K C2H4PtCl3  .3H2O
B) 5
C) 4 09) CH3MgI is an organometallic compound due
D) 3
to
03) Which kind of isomerism is exhibited by A) C-H bond.
octahedral Co(NH3 )4 Br2Cl ? B) C-Mg bond.
C) C-I bond.
A) Geometrical only D) Mg-I Bond.
B) Geometrical and Optical
C) Geometrical and Ionization 10) Which one of the following complexes is an
D) Optical and Ionization outer orbital complex?
Atomic nos. : Mn  25, Fe  26, Co  27, Ni  28
04) How many ions are produced from
[Co  NH3 6 ]Cl3 in solution? A) [Ni(NH3 )6 ]2
A) 2 B) [Fe(CN)6 ]4
B) 3 C) [Mn(CN)6 ]4
C) 4
D) 6 D) [Co(NH3 )6 ]3

05) In the process of extraction of gold, 11) Which one will give Fe3 ions in solution
 O2 
Roasted gold ore CN  H2O 
[X]  OH A) Fe2  SO4 3
[X]  Zn  [Y]  Au 3
Identify the complexes [X] and [Y] B) Fe  CN6 
A) X  [Au(CN)4 ] , Y  [Zn(CN)4 ]2 C) Fe  CN6 
4

B) X  [Au(CN)2 ] , Y  Zn(CN)6 ]4

D) NH4 (SO4 )2.FeSO4.6H2O
C) X  [Au(CN)2 ] , Y  [Zn(CN)4 ]2
12) The pair of the compounds in which both the
D) X  [Au(CN)4 ]3 , Y  [Zn(CN)4 ]2
metals are in the highest possible oxidation state is
06) The number of moles of AgCl precipitate when A) [Co(CN)6 ]3 , MnO3
excess of AgNO3 is added to one mole of B) TiO3 , MnO2
[Cr  NH3 4 Cl2 ]Cl is C) CrO2Cl2 , MnO4
A) 3.0 D) [Fe(CN)6 ]3 , [Co(CN)6 ]3
B) 2.0
C) 1.0 13) Amongst Ni  CO4 , Ni(CN)4 2 and [NiCl4 ]2 ,
D) Zero
Ni  CO4 is diamagnetic and NiCl4 
2
A) and
07) In the compound lithium tetrahydroaluminate,
2
the ligand is Ni  CN  are paramagnetic.
 4
A) H
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2
B) Ni  CO4 and Ni  CN4  are diamagnetic D) dsp2

and NiCl4 
2
is paramagnetic. 21) Which of the following factors tends to increase
2 the stability of metal ion complexes?
C) NiCl4 
2
and Ni  CN4  are diamagnetic A) Higher charge/size ratio of the metal ion.
B) Higher ionic radius of the metal ion.
and Ni  CO4 is paramagnetic.
C) Lower ionisation potential of the metal ion.
D) Ni  CO4 and NiCl4  D) Lower basicity of the ligand.
2
are diamagnetic and
[Ni(CN)4 ]2 is paramagnetic. 22) In which of the following pairs both the
complexes show optical isomerism
14) AgCl precipitate dissolves in ammonia due to A) cis- [Cr(C2O4 )2 Cl2 ]3 , cis- [Co(NH3 )4 Cl2 ]
the formation of B) [Co(en)3 ]Cl3 , cis- [Co(en)2 Cl2 ]Cl
A) [Ag(NH3 )2 ]Cl C) [Co(NO3 )3 (NH3 )3 ] , cis- [Pt(en)2 Cl2 ]
B) [Ag(NH3 )2 ]OH
D) [PtCl(dien)]Cl , [NiCl2Br2 ]2
C) [Ag(NH4 )2 ]Cl
D) [Ag(NH4 )2 ]OH 23) The chemical formula of diammine silver (I)
chloride is
15) The correct IUPAC name of potassium A) [Ag(NH3 )2 ]Cl
cuprochloride is B) [Ag(NH4 )2 ]Cl
A) tetrachloro copper (I) potassiate.
C) [Ag(NH3 )]Cl
B) tetrachloro potassium cuprate (I).
C) potassium tetrachloro cuprate (I). D) Non of these
D) potassium copper (I) tetrachloride.
24) In which of the following complexes oxidation
16) Which of the following statement is correct? state of metal is zero?
2 A) Cr  en2 Cl2 
A)  Zn(H2O)6  ion is blue coloured.
2 B) Cr  NH3 3 Cl3 
B) Cu  NH3 6  is a colourless ion.
2 C) Cr  CO6 
C) Ni  CN4  ion has a tetrahedral shape.
D) Pt  NH3 2 Cl2 
D) Nickel dimethyl glyoximes is red in colour.

17) The most stable complex among the following is 25) The strongest ligand in the following is
A) [Pt(en)2 ]Cl2 A) F 
B) K3 [Al(C2O4 )3 ] B) HO
C) K2[Ni(EDTA)] C) Br 
D) Ag(NH3 )2 Cl D) CN

18) The type of magnetism exhibited by 26) The diamagnetic specie is

Mn  H2O 
2 A) [CoCl4 ]2
 6
ion is
B) [CoF6 ]2
A) diamagnetism.
B) paramagnetism. C) [Ni(CN)4 ]2
C) both (1) and (2).
D) [NiCl4 ]2
D) none of these.
2
19) In the extraction of which of the following, 27) Cuprammonium ion Cu  NH3 4  is
complex ion forms?
A) Na A) octahedral.
B) Fe B) triangular bipyramid.
C) square planar.
C) Ag
D) tetrahedral.
D) Cu
28) The number of ions per mole of a complex
20) The type of hybridization involved in the metal [CoCl2.5 NH3 ]Cl2 in aqueous solution will be
ion of [Ni(H2O)6 ]2 complex is A) two.
A) d3sp2 B) three.
C) four.
B) sp3d2 D) nine.
C) sp3
29) In the coordination compound, K4 [Ni(CN)4 ]

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oxidation state of nickel is

A) 1 38) Considering H2O as a weak field ligand, the
B) 0 number of unpaired electrons in [Mn(H2O)6 ]2 will
C) 1 be (At. No. of Mn = 25)
D) 2 A) five
B) three
30) Which of the following organometallic
C) four
compound is  and  bonded?
D) two
A) Fe(CH3 )3
B) [Co(CO)5 NH3 ]2 39) The formula of sodium nitroprusside is
A) NaFe Fe  CN6 
C) [Fe(5  C5H5 )2 ]
D) K[PtCl3 (n2  C2H4 )] B) Na 2 Fe  CN6 NO2 

C) Na 2 Fe  CN5 NO

31) The valency of cuprammonium ion is
A) - 4 D) Na 4 Fe  CN5 NOS
B) - 2
C) + 2
D) + 4 40) Which of the following complex will show
geometrical as well as optical isomerism
32) The number of neutral molecules or negative (en = ethylene diamine)?
groups attached to the central metal atom in a A) Pt  en2  Cl2
complex ion is called
4
A) primary valency. B) Pt  en 3 
B) coordination number.
C) atomic number. C) Pt  NH3  Cl4 
D) effective atomic number. D) Pt  NH3 2 Cl2
33) The formula of potassium dicyano bis (oxalato)
nickelate (II) is 41) Which has yellow colour?
A) K2 Ni(CN)2 (Ox)2  A) Fischer's salt
B) Potassium cobaltinitrite
B) K3 Ni2[Ni2 (CN)2 (Ox)2  C) Potassium hexanitrocobaltate (III)
C) K Ni(CN)(Ox)2  D) All the above

D) K4 Ni  CN2 (Ox)2  42) How many unpaired electrons are present in
the central metal ion of [CoCl4 ]2 ?
34) Which one is not an organometallic compound? A) 2
A) KC4H9 B) 3
C) 4
B)  CH3 4 Sn D) 5
C) C2H5ONa
D) RMgX 43) The EAN of iron in potassium ferricyanide is
A) 18
35) The colour of CoCl3 .5NH3 .H2O is B) 54
C) 35
A) violet.
D) 23
B) pink.
C) orange. 44) Which compound is zero valent metal complex?
D) orange yellow. A) K3 [Fe(CN)6 ]
36) The colour of tetrammine copper (II) sulphate is B) [Ni(CO)4 ]
A) green. C) [Pt(NH3 )2 Cl2 ]
B) violet. D) [Cu(NH3 )4 ]SO4
C) red.
D) blue. 45) Which one of the following has largest number
of isomers?
37) Which one of the following octahedral
(R = alkyl group; en = ethylenediamine)
complexes will not show geometric isomerism?
(A and B are monodentate ligands) A) [Co(en)2 Cl2 ]
A) [MA2B4 ] B) [Ru(NH3 )4 Cl2 ]
B) [MA3B3 ]
C) [Co(NH3 )5 Cl]2
C) [MA4B2 ]
D) [Ir(PP3 )2 H(CO)]2
D) [MA5B]

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