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Xi Chem MS

The document is a marking scheme for a chemistry class XI exam, detailing answers for multiple-choice questions and descriptive questions across various sections. It includes explanations for concepts such as empirical and molecular formulas, limiting reagents, dipole moments, and enthalpy changes. Each question is assigned a specific mark allocation, providing a structured assessment framework for evaluating student responses.

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YASH GAMER YT
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14 views6 pages

Xi Chem MS

The document is a marking scheme for a chemistry class XI exam, detailing answers for multiple-choice questions and descriptive questions across various sections. It includes explanations for concepts such as empirical and molecular formulas, limiting reagents, dipole moments, and enthalpy changes. Each question is assigned a specific mark allocation, providing a structured assessment framework for evaluating student responses.

Uploaded by

YASH GAMER YT
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Marking scheme chemistry class –XI set-3

SECTION-A-

Q1-a Q2-d Q3-b Q4-c Q5-b Q6-a Q7-c Q8-b Q9-c


Q10-c Q11-d Q12- d Q13-c Q14-a Q15-c Q16-a Q17-a Q18-d
SECTION -B

Q19- An empirical formula represents the simplest whole number ratio of various atoms 1+1=2M
present in a compound, whereas, the molecular formula shows the exact number
of different types of atoms present in a molecule of a compound.

Q-20 2M.

Q-21 Roots for 1,2 and 0 are un, bi and nil, respectively. Hence, the symbol and the name 1+1=2M
respectively are Ubn and unbinilium.it will be s-block element.
OR
Sp2 to sp3.
Q-22 Entropy is decreasing ΔS(−ve) in the reaction. Further the addition reaction is 1+1=2M
exothermic since a bond is being formed, therefore ΔH is also -ve.
Q-23 (i)Buffer solution- the solutions which resist change in pH on dilution or with the 1+1=2M
addition of small amounts of acid or alkali are called buffer Solutions

(ii) Solubility product- is defined as the product of the concentration of the


ions which is in equilibrium with the solid compound in a saturated solution.
OR
(a) Hydroxyl ion is a Lewis base as it can donate an electron lone pair (:OH – ).
(b) Flouride ion acts as a Lewis base as it can donate any one of its four
electron lone pairs.
(c) A proton is a Lewis acid as it can accept a lone pair of electrons from OR
bases like hydroxyl ion and fluoride ion.
(d) BCl3 acts as a Lewis acid as it can accept a lone pair of electrons from
species like ammonia or amine molecules
1/2x4=2M
Q-24 1/2x4=2M
Except
step one

Q-25 2M

Explanation through hepercongugatiob or inductive effect.


Section-c

Q26 (i) According to the given reaction, 1 atom of A reacts with 1 molecule of 1x3=3M
B. Thus, 200 molecules of B will react with 200 atoms of A, thereby leaving
100 atoms of A unused. Hence, B is the limiting reagent.

(ii) According to the reaction, 1 mol of A reacts with 1 mol of B. Thus, 2 mol
of A will react with only 2 mol of B. As a result, 1 mol of B will not be
consumed. Hence, A is the limiting reagent.

(iii) According to the given reaction, 1 atom of A combines with 1 molecule


of B. Thus, all 100 atoms of A will combine with all 100 molecules of B.
Hence, the mixture is stoichiometric where no limiting reagent is present.
Q27 1x3=3M
(i)ns2np4 for n=3 (p-block), 16 group,3 period
(ii) (n-1)d2ns2 for n=4, and (d-block),4group,4 period
(iii) (n-2) f 7 (n-1)d1ns2 for n=6, in the periodic table.(f-block) 3 group 6period,
Q28 (i) dipole moment of NH3 (4.90 ×10–30 Cm) is greater than that of NF3 (0.8 1x3=3M
×10–30 Cm).This is because, in case of NH3 the orbital dipole due to lone pair is in
the same direction as the resultant dipole moment of the N–H bonds, wherea
in NF3 the orbital dipole is in the direction opposite to the resultant dipole
moment of the three N–F bonds. The orbital dipole because of lone pair
decreases the effect of the resultant N–F bond moments, which results in the
low dipole moment of NF3

(ii)due to presence of unpaired electron in antibonding molecular orbitals


OR
(i) Resonting structure of carbonate ion
(ii) Bond order =3
Q29 3M

M= 0.5M, V=50mL,V1= 60mL And m=0.5g on solving N%=56


0r

Q30 (i)- Although the addition of sulphuric acid will precipitate lead 1+1+1=3M
sulphate, the addition of acetic acid will ensure a complete precipitation of
sulphur in the form of lead sulphate due to common ion effect.
(ii) CCl4 will not give the white precipitate of AgCl on heating it with silver
nitrate. This is because the chlorine atoms are covalently bonded to carbon
in CCl4. To obtain the precipitate it should be present in ionic form and for
this it is necessary to prepare the Lassaigne's extract of CCl4.

(iii) Nitric acid is added to sodium fusion extract and the solution is boiled
before adding silver nitrate for testing halogens because. the extract is
alkaline and thus must be neutralized. nitric acid decomposes sodium
cyanide or sodium sulphide (if present) to hydrogen cyanide and hydrogen
sulphide gases, respectively
SECTION-D

Q31 (i) H2SO4 & SO42- 1+1+2=4


(ii) Its conjugate base have less tendency to accept proton .
(iii)

OR

Q32 (i) 120 1+1+2=4


(ii) (4n+2) π electron
(iii) (a) Generation of the eletrophile
(b) Formation of carbocation intermediate
(c) Removal of proton from the carbocation intermediate
OR
Benzene is a planar molecule which has delocalized electrons above and below
the plane of the ring. Being electron-rich, it is highly attractive to electron-
deficient species i.e., electrophiles.
Q33 (I)Energy associated with the fifth orbit of hydrogen atom is calculated as: 3+1+1=5M

E5 = –8.72 × 10–20 J
(II) Cr
(iii)2S & 2P

Or
(i) From de Broglie’s equation,
λ=hmv
Given, Kinetic energy (K.E) of the electron = 3.0 × 10–25 J
Since K.E=1/2mv2∴Velocity(v)=√ 2K.Em
=√ 2(3.0×10−25J)9.10939×10−31kg =√ 6.5866×104
v=811.579ms−1
Substituting the value in the expression of λ:
λ=6.626×10−34Js(9.10939×10−31kg)(811.579ms−1)λ=8.9625×10−7m
Hence, the wavelength of the electron is 8.9625 × 10–7 m.
(ii) 15
(ii) 16
Q34 (i) Enthalpy change for a reaction (Δ H) is given by the expression, 3+2=5M
Δ H=Δ U+Δ ngRT
Where,
Δ U = change in internal energy
Δ ng = change in number of moles
For the given reaction,
Δ ng=∑ng (products) - ∑ng (reactants)
= (2 - 2.5) moles
Δ ng=–0.5 moles
And,
Δ U=–742.7 kJ mol−1T=298KR=8.314×10–3 kJ mol−1K−1
Substituting the values in the expression of \Delta~H:
Δ H=(–742.7kJ mol−1)+(–0.5 mol)(298 K)(8.314×10−3 kJ
mol−1K−1)=−742.7–1.2Δ H=–743.9 kJ mol−1
(ii) Hess;s law-correct statement & application
OR
(i)- The reaction that takes place during the formation of CH3OH(l) can be
written as:

C(s) + 2H2O(g) + O2(g) CH3OH(l) (1)


The reaction (1) can be obtained from the given reactions by following the
algebraic calculations as:
Equation (ii) + 2 × equation (iii) – equation (i)
ΔfHθ [CH3OH(l)] = ΔcHθ + 2ΔfHθ [H2O(l)] – ΔrHθ
= (–393 kJ mol–1) + 2(–286 kJ mol–1) – (–726 kJ mol–1)
= (–393 – 572 + 726) kJ mol–1
ΔfHθ [CH3OH(l)] = –239 kJ mol–1

(ii)- Mass and volume are examples of extensive properties. An


intensive property is a property of matter that depends only on the
type of matter in a sample and not on the amount. Color,
temperature, and solubility are examples of intensive properties.
Q35 (a)-(i)Methane (ii)1-bromobutane (iii)Ethane
(b) This ozonide is formed as an addition of ozone to 'A'. The
desired structure of 'A' can be obtained by the removal of
ozone from the ozonide. Hence, the structural formula of 'A' is:
The IUPAC name of 'A' is 3-Ethylpent-2-ene.
OR
(a) (i) Benzene formation
(ii)Formation of formaldehye & acetaldehyde
(iii)Wurtz reaction

(b)

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