(0999DJM262103230003) Test Pattern

DISTANCE LEARNING PROGRAMME JEE (Main)

UNIT TEST # 03
(Academic Session : 2023 - 2024)
06-08-2023

JEE(Main) : LEADER TEST SERIES / JOINT PACKAGE COURSE

ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. D A C A B A A B A B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C C C C B C B B D C
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 400 8 12 2 3 4 2 1 6 0

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. D D B B A C C C A C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. B D A C A D D A A B
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 3 3 3 4 6 -940 -20 250 18 60

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A C A C B A D A C A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A C D C A D A D B B
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 7 15 2 17 91 1 1 2 22 1

HINT – SHEET
PART-1 : PHYSICS 2. Ans ( A )
SECTION-I For a force of 100N on 10 kg block, relative
1. Ans ( D ) motion will take place.
f = µN
∴ The frictional force between 10 kg block and
N=F 40 kg block,

f = μ mg = 0.4 × 100 × 9.8N

The acceleration of the slab of 40 kg is

0.4 × 10 × 9.8
f = 0.2 × 10 a= = 0.98 m/s2
40

mg = f = 2N ∴ (A) is the correct answer

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3. Ans ( C ) 8. Ans ( B )
Blocks A and C both move due to friction. But
less friction is available to A as compared to C
because normal reaction between A and B is less.
Maximum friction between A and B can be:
1
fmax = μ mAg = ( ) mg
2
∴ Maximum acceleration of A can be:
N – 25g = 25 × 1
fmax g N = 275
amax = ( ) =
2 2
mD g ∴ W = 275 + 50 = 325 N
further amax =
3m + mD
g mD g 12. Ans ( C )
or =
2 3m + mD Apparent weight = actual weight – upthrust force
∴ (3) is the right answer.
Vdg' = Vdg – Vrg
4. Ans ( A )
d−ρ
⇒ g' = ( ) g
d
14. Ans ( C )
From COME

1 1 1
m (Vf 2 − Vi 2 ) = −GMe m ( − )
Applied force 2 10 Re Re

fa = P + Qsin θ 1 GMm 1
m ( Vf 2 − Vi 2 ) = (1 − )

Normal reaction 2 Re 10

N = mg + Qcot θ 2GM 1
Vf 2 = Vi 2 + ( 1− )
Re 10
f ℓ = µN = µ(mg + Qcos θ )
Now, condition for no slipping 15. Ans ( B )
GMm GMm
fa ≤ f ℓ F1 = 2
=
(2R) 4R2
P + Qsinq ≤ µ(mg + Qcos θ ) Force applied by remains sphere = force applied
P + Q sin θ
µ ≥
mgℓ Q cos θ by complete sphere – force applied by remain
5. Ans ( B )
140 − 100
sphere.
a= = 4 m/s2
10 M
G× m
Now from II law GMm 8
F2 = − 2
T – 5g = 5a (2R)2 3R
( )
2
T – 50 = 5 × 4 7GMm F2 7
= = =
T = 70 N 36R2 F1 9

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16. Ans ( C ) 20. Ans ( C )
νA gA R We know that,
ν e = √2gR ⇒ = √ × A = √ x×r
νB gB RB 1
νA g∝
∴= √ rx R2
νB As the passenger moves away from Earth at
17. Ans ( B ) some point gravitational force due to earth will
Let velocities of these masses at r distance from
be minimized and then start increasing as the
each other be v1 and v2 respectively. passenger moves towards the mars, due to
By conservation of momentum gravitational force offered by mars, and
m1v1 – m2v2 = 0 gravitational force can't be negative.

⇒ m1v1 = m2v2 PART-1 : PHYSICS

.....(i) SECTION-II

By conservation of energy 2. Ans ( 8 )

1
1 2
−0
change in P.E. = change in K.E. −0= (x − 0)
v 4−0
Gm1 m2 1 1
= m1 v21 + m2 v22 1 x 8 dx 8
r 2 2 = ⇒v= ⇒ =
m21 v21 m22 v22 2Gm1 m2 v 8 x dt x
⇒ + = .....(ii)
m1 m2 r 12 t

On solving equation (i) and (ii) ∫ xdx =8 ∫ dt

4 0
2Gm22 2Gm21
v1 = √ and v2 = √ x2
12
r(m1 + m2 ) r(m1 + m2 ) [ ] = 8t ⇒ t = 8 sec
2G 2 4
∴ vapp = |v1| + |v2| = √ (m1 + m2 )
r
4. Ans ( 2 )
18. Ans ( B )
F = O, r < R1
F increase when
R1 ≤ r ≤ R2
GMm 1
F= ,F∝ , r > R2
r2 r2
19. Ans ( D )
As →v = 5ti^ + 2tj^
Angular momentum,

L = mnr = mωr2 = m × 2π
× r2 ∴ →a = ax ^i + ay ^j = 5i^ + 2j^
T
2 × 3.14 × 6 × 1024 × (1.5 × 1011 )
2 → = ma ^i + m (g + a ) ^j
F x y
=
3.14 × 107
∴ |F→ | = m√a2x + (g + ay ) = 26 N
2
= 2.7 × 1040 kg-m2/s

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5. Ans ( 3 ) PART-2 : CHEMISTRY
F1 = mgsin θ + μ mgcos θ × 1 sin θ 3
= mg sin θ SECTION-I
2 cos θ 2
1. Ans ( D )
1 sin θ 1
F2 = mgsin θ – mmgcos θ × 2 cos θ
= mg sin θ
2 1
CaO Ca+ O2­
2
F1
=3
F2 2. Ans ( D )
6. Ans ( 4 ) Out of cations having comparable size and
GMp 4 GMe charge the one having Noble gas configuration
gp = ⇒ gp = ..(1)
Rp 2 9 Re 2
has less polarizing power.
GMe
[ g= ] ..(2) LiCl is a covalent compound hence, it is soluble
Re 2
in organic solvents.
by (1) & (2)
Order of solubility of heavy metal halides
4 4 depends on hydration energy.
gp = g, wp = mgp = mg, [mg = 9N]
9 9
(AgF > AgCl > Ag Br > AgI)
wp = = 4N
The hydration of ions involves evolution of heat.
7. Ans ( 2 ) M+(g) + H2O —→ M+(aq); Δ H = – ve
2GM √ 2Gρ4/3GπR3 3. Ans ( B )
v=√ =
R R
Odd e – species always paramagnetic
v∝R 4. Ans ( B )
vA NH3 + H+ NH4+
=2
vB
sp3 sp3
8. Ans ( 1 )
GMe
Orbital velocity V = √

r H3BO3 + OH – B(OH)4 –
1
TA = mA VA2 sp2 sp3
2
1
TB = mB VB2
2
m× Gm NH3 NH2 – + H+
TA R
⇒ =
TB 2m × Gm
2R
sp3 sp3
TA
⇒ =1
TB
H2O + H+ H3O+
9. Ans ( 6 )
Gravitational force between the masses are same. sp3 sp3

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5. Ans ( A ) 14. Ans ( C )
sp3 hybrid orbital of 'O' overlap with 2p orbital of For isothermal process
'F'?
ΔH = 0
6. Ans ( C )
SiC is a covalent network solid. 15. Ans ( A )
7. Ans ( C ) 2 × R × 320
V1 =
4
Due to s-p mixing, σ2px has greater energy than π2py .
2 × R × 640
V2 =
8. Ans ( C ) 8
The correct order of dipole moment is :
CH4 < CHCl3 < CH2Cl2 < CH3Cl ΔV = 0

9. Ans ( A ) so w = 0
Structure of HNO2 is
10. Ans ( C ) 16. Ans ( D )
V2
'N' can form NCl3, N2O5 and Ca3N2 but not Δ S = 2.303 nRlog
V1
NCl5 . 20
= 2.303 × 2 × 2 × log = 9.2 cal
12. Ans ( D ) 2
17. Ans ( D )
Δ H° = – 3 Δ H1° + Δ H2° + 2 Δ H3° + 3 Δ H4° =
Number of moles of gaseous product is less than
– 747.4 kJ

Δ H° = Δ U° + Δ ng RT ; where Δ ng = – 8
number of moles of gaseous reactant.
8 × 8.314 × 300
– 747.4 = Δ U° – ∴ Volume decreases do entropy decreases.
1000
Δ U° = – 727.44 kJ 18. Ans ( A )
13. Ans ( A ) Δ G° = – RT ln Kp ; Kp = (2x)2X = 4X3
w = – nR Δ T = – 2 × 8.314 × 100
Δ G° = – RT ln(4X3)
= – 1662.8 J
Δ G° = – RT ln 4 – 3RT ln X
Δ U = n ∫ Cv, m dT
20. Ans ( B )
=2× ∫ (20 + 10−2 T ) dT
P1
= 2 × 20 × (T2 – T1) + 2 × 10 – 2 × Δ S = 2.303 nR log (
P2
) = 2.303 × 2 × 8.314
(T22 − T12 ) 1
2 log ( )
0.25
= 4700 J
~ 23 J mol – 1 K – 1
4700 = θ – 1662.8
∴ θ = 6362.8 J

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PART-2 : CHEMISTRY 7. Ans ( -20 )
SECTION-II
1. Ans ( 3 )
KMnO4, Ca(NO3)2 and NaNO3 will evolve O2 Δ H = 110 + 150 – 80 – 2 × 100
gas upon heating.
= – 20 kcal/mol
2. Ans ( 3 )
8. Ans ( 250 )
Species Hybridization
nCv(T2 – T1) = – 75 cal
XeF2, SOF4 sp3 dz 2
3R
0.1 × (T2 – T1) = – 75
CO2 sp 2
−75
XeF4 sp3 dz 2 dx2 − y 2
T2 – T1 =
0.3
H2CO3 sp2 T2 – 500 = – 250
SO42 – sp3 T2 = 250 K.
NO3 – sp2 9. Ans ( 18 )
3. Ans ( 3 ) Δ ng = 5 – 3 = 2
Species Number of unpaired e – Δ H = Δ U + Δ ng RT
K+O2 – 1 19 = Δ U + 2 × (2 × 10 – 3) × 300
O2+[BF4] – 1 Δ U = 19 – 1200 × 10 – 3
2K+ O2 – 2 0 = 19 – 1.2 = 17.8 KCal
O2 2 PART-3 : MATHEMATICS
N2 0 SECTION-I
NO2 1 1. Ans ( A )
B2H6 0 ϕ '(x) = f '(x) + f '(2a – x)
4. Ans ( 4 )
given, f"(x) > 0, ⇒ f '(x) is increasing function, if
Valid Formulas as are :
HI, SF4, BH4 – , B(OH)4 – x < 2a – x ⇒ x < a
5. Ans ( 6 ) f '(x) < f '(2a – x)
XeF5⊕ sp3 d 2
⇒ ϕ (x) < 0
6. Ans ( -940 )
Δ rHo = Σ Δ fHo (products) – Σ Δ fHo (reactants) ∴ ϕ (x) decreases in (0, a)
Δf HNo o
+ 3 × Δf HCO − [Δf HNo o
+ 3 × Δf HCO(g)
[
2 O(g) 2 (g)
]
2 O4 (g)
]
and if x > 2a – x ⇒ x > a
⇒ ( – 81 + 3 × – 393) – (10 + 3 × ( – 110))
f '(x) > f '(2a – x) ⇒ f'(x) > 0
= – 1260 + 320
∴ ϕ (x) increases in (a, 2a)
= – 940

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2. Ans ( C ) 5. Ans ( B )
We have, f(x) = (x – 1)(x – 2)(x – 3) Let g(x) = 4x3 – 12x2 + 11x – 3
= x3 – 6x2 + 11x – 6
∴ g'(x) = 12x2 – 24x + 11
∴ f(a) = 0 – 0 + 0 – 6 = – 6
∴ f(b) = 43 – 6·42 + 11·4 – 6 = 12(x – 1)2 – 1
= 64 – 96 + 44 – 6 = 6 > 0 for x Î [2, 3]
f(b) − f(a) 6 − (−6)
∴ = = =3 Thus, g(x) is increasing in [2, 3].
b−a 4−0
Also, f '(x) = 3x2 – 12x + 11 f(x)max = f(3)
f '(c) = 3c2 – 12c + 11
= log10(4.27 – 12.9 + 11.3 – 3)
f(b) − f(a)
From LMVT , = f '(c)
b−a = 1og10(30) = 1 + log103
2
⇒ 3 = 3c – 12c + 11
6. Ans ( A )
∴ 3c2 – 12c + 8 = 0
1 2
Vol = πr h
12 ± √(144 − 96)
=2±2 2
√
∴ c= 3
6 3
As both of the values of c lie in the open 1 a2 a
V= π ( − x2 ) ( + x )
interval (0, 4) 3 4 2

2 √2 1 a a2
∴ λ= V'(x) = π [[−2x] ( + x) + ( − x2 )]
3 3 2 4
a 2
2 √2 π 2
Then, 450 √ 2λ = 450× √ 2× = 600 V'(x) = [−ax − 2x + − x2 ]
3 3 4
3. Ans ( A ) π 2 a2
=– [3x + ax − ] =0
3 4
f '(x) =
−a ± √a2 + 3a2
x=
minimum at x = 1 6
∴ f(1) = sin – 1 α + 12 ⇒ 2 = sin – 1 α + 1 −a ± 2a a a
x= =− ,
sin – 1 α = 1 ⇒ α = sin 1 6 2 6
a a a 4a 2a
4. Ans ( C ) ∴ Height = +x= + = =
2 2 6 6 3
Let f(x) = x2 – x sinx – cosx
∴ f '(x) = 2x – x cos x
7. Ans ( D )
f '(x) = 0 ⇒ x(2 – cosx) = 0 or x = 0 (1, 2) lies on y1
( ∵ 2 – cosx > 0 for all real x) 7
2=a+b+ ⇒ a+b=−3 ....(1)
Also, x = 0 is point of minima. 2 2
dy1 1
f(0) = – 1 < 0 and x→∞
lim f(x) → ∞, lim f(x) → ∞. ( ) =−
x→−∞ dx (1,2) (
dy2
)
dx (−2,2)
1
2a + b = −
2
5
From (1) & (2) a = 1 & b = −
Hence, it meets x-axis at two points and, hence, 2
two solutions. a – 2b = 6

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8. Ans ( A ) 12. Ans ( C )
dy y
=− We have
dx nx
L.S.N. y = tan–1 (
log e − log x2
) + tan−1 (
3 + 2 log x
1 − 6 log x
)
log e + log x2
∣ dy ∣ ∣ y y2 y 2+n
= ∣ y⋅ ∣ = y (− )
∣
= =
= tan−1
1 − 2 log x
+ tan−1 (
3 + 2 log x
∣ dx ∣ ∣ nx ∣
nx n ⋅ an+1 ( ) )
1 + 2 log x 1 − 6 log x
Which is constant
= tan–1 1 – tan–1 (2logx) + tan–1 3 + tan–1 (2 logx)
When 2 + n = 0 ⇒ n = – 2
= tan–1 1 + tan–1 3
9. Ans ( C )
dy d2y
or =0 or =0
∵ ƒ(x) = 0 ∀ x ∈ (1,2) dx dx2
13. Ans ( D )
⇒ ƒ'(x) = 0 ∀ x ∈ (1,2)
Let given functions be y and z respectively, then
⇒ infinitely many critical points.

10. Ans ( A ) y = cot – 1 (

2 √1 + x 2 − 5 √1 − x 2
)

5 √1 + x 2 + 2 √1 − x 2
f(x) = |x||sin x|
= tan – 1 (
5 √1 + x 2 + 2 √1 − x 2
)

2 √1 + x 2 − 5 √1 − x 2
ℓ n f(x) = |sin x| ℓ n |x|

1
× f ′ (x) = tan – 1 (
5 cos θ/2 + 2 sin θ/2
2 cos θ/2 − 5 sin θ/2
) , where x2 = cos θ
f(x)
| sin x| |x| | sin x| 5/2 + tan θ/2
=
|x|
×
x
+
sin x
× cos x ℓn |x| = tan – 1 ( )
1 − 5/2 tan θ/2
−π π 1/ 2 1/√2
√
1 π
f′ ( ) = ( − ℓn )
= tan – 1[tan( α + θ /2)], where tan α = 5/2
) (
4 4 −π/4 √2 4

1/ 2 2 4 2 √2
= α + θ /2 .....(1)
=(π)
√ √
( ℓn − )
4 2 π π

11. Ans ( A ) Also z = cos – 1 √

1 − x4

f(x) = 3 α x + 3 β x
= cos – 1 √
1 − cos2 θ

f '(x) = α 3 α x ln3 + 3 β x b ln3

= cos – 1(sin θ ) = π
− θ......(2)
2
f ''(x) = α 23 α x (ln3)2 + 3 β x β 2 (ln3)2

Put it in given condition and solve ∴

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14. Ans ( C ) 17. Ans ( A )
A+B A−B A+B
y = √(x − sin x) + y a = 2 cos cos − 2cos2 ( ) +1
2 2 2
A+B A−B A+B
y2 = (x – sinx) + y a = 1 + 2 cos(
2
)[ cos(
2
) − cos(
2
)]

A+B A B
d.w.r.to x a = 1 + 4 cos( ) sin sin
2 2 2
dy dy ∴ a–b=1
2y = 1 − cos x +
dx dx 18. Ans ( D )
dy 1 − cos x
( ) = ..(1)
dx 2y − 1 We have,
π
when x = , y = yp (Let) π
2 tan(θ + ) = 3 tan 3θ
π 4
x2p = − 1 + yp 3 tan θ − tan3 θ
2 1 + tan θ
π ⇒ = 3.
yp2 − y1 + (1 − ) = 0 1 − tan θ 1 − 3tan2 θ
2 1+t 3t − t3
⇒
1−t
= 3( ) [putting t = tan θ ]
1 + √1 − 4 (1 − π
)
1 − 3t2
2
yp = ⇒ 3t4 – 6t2 + 8t – 1 = 0
2
0
2yp − 1 = √ 2π − 3 So, t1 + t2 + t3 + t4 = =0
3
from (1) ∴ tan α + tan β + tan γ + tan δ = 0
dx 2yp − 1
( ) = Hence, (D) is the correct answer.
dy x= π2 1−0
dx
2 19. Ans ( B )
( ) = 2π − 3
dy x= π2 π π 7π
λ= { tan2 ( 2
) + cot ( − )}
16 2 16
15. Ans ( A )
+ {tan2 ( 2π ) + cot2 ( π − 6π )}
tan A + tan B + tan C = tan A tanB tan C 16 2 16
6 + {tan2 ( 3π ) + cot2 ( π − 5π )} + 1
∴ tan A tan B tan C = 6 ⇒ tanC = =3 16 2 16
2 2

Also tan A + tan B = 6 – 3 = 3 = {tan( π ) + cot( π )}

16 16
2
tan A, tan B = 2,1 or 1,2 and tan C = 3 2π 2π
+ {tan( ) + cot( )} +
16 16
16. Ans ( D ) 3π 3π
2
{tan( ) + cot( )}
16 16
–2 – 2 – 2 + 1
π 3π 5π 4 4 4
= sin sin sin ×1 = π
+
π
+ − 5 = 35
14 14 14 sin 2 2
sin 2 3π
8 4 sin ( )
8

× sin ( π−
5π
) sin(π −
3π
) sin(π −
π
)
∴ xy + yx = 35
14 14 14

⇒ x = 3y, y = 1 or x = 1, y = 3x
2
π 3π 5π 1
= [ sin sin sin ] = ∴ (x + y)2 = 352 = 1225
14 14 14 64

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20. Ans ( B ) 3. Ans ( 2 )
o o o o
1 sin(1 − 0 ) sin(2 − 1 ) ƒ(x) = x2 + ax + 1
o [ o o +
sin 1 cos 0 cos 1 cos 1o cos 2o
sin(3o − 2o ) sin(45o − 44o ) ƒ'(x) = 2x + a
+ + . . . + ]
cos 2o cos 3o cos 44o cos 45o when ƒ(x) is increasing on [1, 2]
1
= [tan 1∘ + (tan 2∘ − tan 1∘ ) +
sin 1∘ 2x + a ≥ 0 ∀ x ∈ [1, 2]

(tan 3° – tan2°) + (tan4° – tan3°) a ≥ – 2x ∀ x ∈ [1, 2]

R = –4
+ ...+ (tan 45° – tan 44°)]
when ƒ(x) is decreasing on [1, 2]
1 1
= =
sin 1o x 2x + a ≤ 0 ∀ x ∈ [1, 2]
PART-3 : MATHEMATICS
a ≤ – 2 ∀ x ∈ [1, 2]
SECTION-II
S = –2
1. Ans ( 7 )
f' (x) = 3x2 – 6(a – 2)x + 3a |R – S| = | – 4 + 2| = 2
f' (x) ≥ 0 ∀ x ∈ (0, 1]
4. Ans ( 17 )
f' (x) ≤ 0 ∀ x ∈ [1, 5) 1
1
⇒ f' (x) = 0 at x = 1 ⇒ a = 5 y4 + 1
= 2x
y4
f(x) – 14 = (x – 1)2 (x – 7) 1 2 (
1
)
⇒ (y 4 ) − 2xy 4
+1=0
f(x) − 14
=x–7 1

(x − 1)2 ⇒ y = x + √x2 − 1 or x − √x2 − 1

4

2. Ans ( 15 ) 1 1 dy x
So, =1+
4 34 dx x2 − 1
Graph of x2 + 2x y √

1
1 1 dy y 4
⇒ =
4 y 3/4 dx √x 2 − 1

dy 4y
⇒ = ...(1)
dx √x 2 − 1

2 ′ yx
( √x − 1 ) y −
2
d y x2 −1 √

Hence, 2 = 4 2
dx x −1
Graph of |5x – 7| 2
(x − 1) y − xy
′
2
⇒ (x – 1)y” = 4
√x 2 − 1

2 xy
⇒ (x – 1)y" = 4 (√x2 − 1y ′ − )
√x 2 − 1

′
xy
7 ⇒ (x2 – 1)y" = 4 (4y − ) (from I)
f (x) |min = 4 + 0 = 4, at x = 4
5
⇒ (x2 – 1)y" + xy' – 16y = 0
f (x) |max = 8 + 3 =11 , at x = 2
So, | α – β | = 17
∴ Required sum = 15

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5. Ans ( 91 ) 7. Ans ( 1 )
3 4 π π π
Put cos α = , sin α = 0 < α < θ = ⇒ 4n θ = π ⇒ 2n θ =
5 5 2 4n 2

3 4 tan θ tan2 θ ________ tan(2n – 2) θ tan(2n – 1) θ

Now cos kx − sin kx
5 5

(tan θ tan(2n – 1) θ ) (tan2 θ tan(2n – 2) θ +.....tan n θ )

= cos α . cos kx – sin α . sin kx
π π
( tan θ tan( − θ))(tan 2θ tan( − 2θ))
2 2
= cos( α + kx)
_____tan π
4
As we have to find derivate at x = 0
1 × 1 × 1 ....... × 1 = 1

We have cos – 1 (cos( α + kx)) 8. Ans ( 2 )

1 + tan θ 1 − tan θ
+
= ( α + kx) 1 − tan θ 1 + tan θ

6
2 (1 + tan2 θ)
⇒ y = ∑ (α + kx) = = 2 sec 2θ
k=1 1 − tan2 θ
6
dy ∣ 6 × 7 × 13
⇒ ∣ = ∑k = = 91 10. Ans ( 1 )
dx at x=0 k=x
∣ 6

6. Ans ( 1 ) y = 3x – 1 ln x & y = xx – 1

Point of intersection (1, 0)

cos2 1∘ − cos2 2∘ sin2 2∘ − sin2 1∘
=
2 sin 3∘ sin 1∘ 2 sin 3∘ sin 1∘ 3x−1
y' = 3x – 1 ln 3 ln x + = 1 = m1
x

sin(2∘ + 1∘ ) sin(2∘ − 1∘ ) 1
y' = xx(1 + lnx) = 1 = m2
= =
2 sin 3∘ sin 1∘ 2
∴ Angle = 0 ∴ cos 0 = 1

0999DJM262103230003 HS-11/11

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