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C12 Practice Exam 2

The document contains a series of chemistry questions and answers related to acid-base chemistry, solubility, and pH calculations. It includes classifications of acids and bases, calculations of pH for various solutions, and assessments of solubility products (Ksp) for different salts. The answers provided indicate a focus on understanding chemical equilibria and the behavior of solutions in various contexts.

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0% found this document useful (0 votes)
16 views

C12 Practice Exam 2

The document contains a series of chemistry questions and answers related to acid-base chemistry, solubility, and pH calculations. It includes classifications of acids and bases, calculations of pH for various solutions, and assessments of solubility products (Ksp) for different salts. The answers provided indicate a focus on understanding chemical equilibria and the behavior of solutions in various contexts.

Uploaded by

65dw7wphh8
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
You are on page 1/ 9

Your best submission for each entire question

1 in = 2.54 cm, 1 lbs = 453.6 g, 1 calorie = 4.184 J and 1 Cal (dietary) = is used for your score.
1000 cal

For linear scales, the default grading tolerance is plus or minus 2%. For
log base units, the tolerance is plus or minus 0.02 units.

1. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Classify HClO 2Wedika strong acids


strong HC04
acid

weak acid

strong
12504
base HCI
weak
base

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Page 2 of 10
2. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

The common name of CaO (56.08 g/mol ) is lime. When lime is dissolved in water to make "limewater" the following reaction
occurs:

CaO(s) + H 2O(l) Ca 2+(aq) + 2OH -(aq). log 7.84e 2.1 14 2.1 119
What is the pH of "limewater" prepared by dissolving 0.440 gram of solid CaO in enough water to make 2.00 L of solution?
11.9

3. [1/1 Points] DETAILS MY NOTES


481 foragain PREVIOUS ANSWERS

Give the conjugate base of H 2S.


Her Htt HS
-
HS

HS^-

Formatting counts; use superscripts and subscripts if needed.

4. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS


pott log OH
What is the pOH of a 0.0748 M solution of RbOH?
1.13

1091.11.9
5. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS
b c Given Ka
Ka 10 -10. What is the pH of 0.050 M HCN?
We Justneed to
The K a of HCN is 5.0
take the log
after finding At
Tso
Between 3.5 and 4.5

Between 5.0 and 5.5


5.0 10
10
oso
Between 4.5 and 5.0

Between 8.5 and 9.5


Me w̅
Between 9.5 and 10.5
5.00 6
10g 5 0e 6
pH 513

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6. [1/1 Points] DETAILS MY NOTES bc given Kb we needto PREVIOUS ANSWERS
take log afterfinding OH
also subtracting
Calculate the pH of a 0.30 M solution of aniline (C 6H 5NH 2), with a K b = 3.8 -10
10 .
it from 74
to get the pH
9.03

4.97
73 3.8 10 10
13 3
9.42 F The 10
2.55
X 1.078 5
11.45

109
14 4 97 9.03
7. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

At a certain temperature, the percent dissociation (ionization) of chlorous acid, HClO 2, in a 1.63 M solution water is 10.0%.

Calculate the value of K a for chlorous acid at this temperature.

H 1 163
1.8 10 -2 Tea 1.63
80b
6.5 10 -3 1.63 insta
1.0 10 -1

1.6

2.7
10 -1

10 -2
f6
T.ly
1i8e1
8. [1/1 Points] DETAILS MY NOTES weak acids bases PREVIOUS ANSWERS
have higher pH
I
Rank the following 0.10 M solutions in order of increasing pH.
(Use superscripts and subscripts as appropriate. Use the less than symbol (<) to separate substances in the list.

HF, HBr, LiBr, LiF

HBr< HF< LiBr< LiF

HBr< HF< LiBr< LiF

bese
why tweaks
it

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Page 4 of 10
9. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Choose the weaker acid in each of the following pairs.

T
Formatting counts; remember to use subscripts as needed.

EFFY(a) HBr or H 2Se


The weaker acid is:

H 2Se

H_2Se

iii
(b) H 2SO 3 or H 2SO 4
The weaker acid is:

H 2SO 3

H_2SO_3

10. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Determine whether aqueous solutions of the following salts are acidic, basic, or neutral.

(a) (C 2H 5) 3NHNO 3

War
acidic

basic

neutral

(b) Mg(CN) 2
ToeYase
acidic

basic

neutral

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Page 5 of 10
m L reactants

11. [1/1 Points] DETAILS MY NOTES titration PREVIOUS ANSWERS

Over the course of a titration, 17.8 mL 0.0341 M sodium hydroxide (NaOH), a strong base, is added to 111.0 mL 0.0584 M
potassium hydrogen phthalate (KHP), a monoprotic weak acid. What is the concentration of potassium sodium phthalate (KNaP)

C0341 6,06 10 1 4ge 3


in the resulting solution?
4.71e-3 M KNaP
0178 time
3
10584 111 6 45 10

12. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

What is the pH of a buffered system made by dissolving 18.9 g of KH 2PO 4 (MM 136.1 g/mol) and 18.7 g of K 2HPO 4 (MM 174.2
g/mol) in water to give a volume of 200.0 mL?

For dihydrogen phosphate the equilibrium reaction:

H 2PO 4 -(aq) H +(aq) + HPO 4 2-(aq),


I ba Fas
has a value of K a2 = 6.2 ✕✕ 10 −8 Y 107 2 535tlimititant

7.1
ijiiiiiiiiii.se
13. [1/1 Points] DETAILS MY NOTES
pH 719 PREVIOUS ANSWERS

Calculate the pH of a solution prepared by adding 20.0 mL of 0.100 M HCl to 80.0 mL of a buffer that is comprised of 0.25 M
CH 3NH 2 and 0.25 M CH 3NH 3Cl.

K b of CH 3NH 2 = 6.8 ✕✕ 10 −5

9.75

4.25

9.92

4.08

9.83

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Page 6 of 10
14. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Calculate the pH of a solution formed by mixing 100.0 mL of 0.100 M NaF and 100.0 mL of 0.040 M HCl.
K a of HF = 7.24 ✕✕✕ 10 −4

1 01MNaf
3.32

3.14
f 100M
2.96
040m 1 004 MHCl
2.74 01 004 1.2L
3.54

15. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Aniline (C 6H 5NH 2 ) has a K b = 3.8 ✕✕ 10 −10. If 100.0 mL of a 0.3000 M aqueous aniline solution is mixed with 50.0 mL of 0.3000
M aqueous hydrochloric acid, the resulting solution will have a pH _____.

4.58

9.42

7.00

1.00

0.52

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Page 7 of 10
16. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

O
Calculate the pH of a 0.10 M solution of sodium acetate (NaCH 3COO)

Given: K a of acetic acid (CH 3COOH )is 1.8 ✕✕ 10 −5.

8.87

5.13
Feel
9.26

11.13 sisy.EE
2.87
7,450 6
use I

17. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

Calculate the pH of a solution prepared by dissolving 0.358 mol of formic acid (HCO 2H) and 0.314 mol of sodium formate
(NaCO 2H) in water sufficient to yield 1.00 L of solution.
35 358
The K a of formic acid is 1.77 ✕✕ 10 −4
1311 314

3.69
pH log 1.77 10 4 109 30 3.61
18. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

At 25 °C the solubility of magnesium hydroxide is 1.40 ✕✕ 10 −4 mol/L. Calculate the value of K sp at this temperature.

F
1.1e-11

Mg mg 20H
3
x 2x 4
4 P

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Page 8 of 10
19. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

The K sp of AgCl at 25°C is 1.6 ✕✕ 10 −10. Consider a solution that is 1.0 ✕✕ 10 −2 M in CaCl 2 and 1.0 ✕✕ 10 −8 M in AgNO 3.

Q > K sp and a precipitate will form.

Q > K sp and a precipitate will not form.

Q < K sp and a precipitate will not form.

Q < K sp and a precipitate will form.

The solution is saturated.

20. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

In an experiment, one liter of a saturated solution of CaF 2 was measured to contain 0.0049 g of dissolved CaF 2 (78.1 g/mol).

T.fi iiF ane s


Based on this experiment, what is the K sp for CaF 2?

9.79e-13

21. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

What is the molar solubility of CaF 2, assume K sp = 4.0 ✕✕ 10 −12 in 0.035 M NaF?

3.3 ✕✕✕ 10 −9
Cafe Cat F
2.0 ✕✕✕ 10 −6
S 5
4.0 ✕✕✕ 10 −12

3.5 ✕✕✕ 10 −2 4 0 10 J 0355


8.2 ✕✕✕ 10 −10

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Page 9 of 10
22. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

For which salt in each of the following groups will the solubility depend on pH? forahead
i) AgF, AgBr
u
ii) Sr(ClO 4) 2, Sr(ClO 2) 2
u
iii) Pb(OH) 2, PbI 2
u
iv) Ni(NO 3) 2, Ni(CN) 2
u
i) AgF; ii) Sr(ClO 2) 2; iii) Pb(OH) 2; iv) Ni(CN) 2

i) AgBr; ii) Sr(ClO 2) 2; iii) PbI 2; iv) Ni(CN) 2

i) AgBr; ii) Sr(ClO 4) 2; iii) PbI 2; iv) Ni(NO 3) 2

i) AgF; ii) Sr(ClO 4) 2; iii) Pb(OH) 2; iv) Ni(NO 3) 2

i) AgF; ii) Sr(ClO 2) 2; iii) PbI 2; iv) Ni(CN) 2

23. [1/1 Points] DETAILS MY NOTES PREVIOUS ANSWERS

The K sp of AgCl is 1.61 ✕✕ 10 −10. What is the solubility of AgCl in a solution of 2.30 x 10 -4 M SrCl 2?

3.49e-7 M
Urc 2 Jc
o 21 5
1.61 10 S 2Submit
2.30 e 4
Assignment

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