1.

SOME BASIC CONCEPTS OF CHEMISTRY

1) i, ii, iii 2) iii, ii, i 3) i, iii, ii 4) ii, iii, i
LEVEL-II (C.W) 8. When 0.44 g of a colourless oxide of nitrogen
SIGNIFICANT FIGURES occupies 224 mL at 1520 mm Hg and 2730C,
then the oxide is
1. The number of significant figures in  are
1) N2O5 2) N2O3 3) NO2 4) N2O
1) Three 2) Infinite number
3) Zero 4) One 9. How many moles of magnesium phosphate
2. Given the numbers: 161cm, 0.161cm, [Mg3(PO4)2] will contain 0.25 mole of oxygen
0.0161cm. The number of significant figure atoms? [AIEEE 2006]
for the three numbers are 1) 3.12510 2 2) 1.25102
1) 3,4 and 5 2) 3, 3 and 3 3) 2.510 2 4) 0.02
3) 3, 3 and 4 4) 3, 4 and 4 10. The number of molecules present in 1.12×10-7
LAWS OF CHEMICAL cc of a gas at STP is
COMBINATIONS 1) 6.02 × 1023 2) 3.01 × 1012
3) 6.02 × 1012 4) 3.01 × 1023
3. Different samples of water were found to
11. Number of electrons in 1.8 grams of H2O are
contain Hydrogen and oxygen in the mass ratio
1) 6.02 × 1023 2) 3.01 × 1023
of 1 : 8. This shows the law of
1) Multiple Proportions 3) 0.602 × 1023 4) 60.22 × 1023
2) Constant Proportions 12. From 320 mg. of O2, 6.023  1020 molecules
3) Reciprocal Proportions are removed, the no. of moles remained are
4) Conservation of mass 1) 9  10-3 moles 2) 9  10-2 moles
4. The % of Hydrogen in water and Hydrogen 3) Zero 4) 3  10-3 moles
peroxide is 11.2% and 5.94% respectively. 13. An oxide of nitrogen has a molecular weight
This illustrates the law of 92. Find the total number of electrons in one
1) Constant Proportions 2) Conservation of mass gram mole of that oxide.
3) Multiple Proportions 1) 4.6N 2) 46N 3) 23N 4) 2.3N
4) Law of Gaseous volume. 14. Total number of species present in 1 mole
of potash alum in terms of avagadro number,
5. The composition of compound A is 40% X and
'N' are
60% Y. The composition of compound B is 25%
1) 3N 2) 5N 3) 8N 4) 32N
X and 75% Y. Accroding to the law of multiple
Proportions the ratio of the weight of element 15. Number of moles of KI required to prepare 0.4
Y in compounds A and B is: moles of K2 Hgl4, when HgCl2 reacts with Kl
1) 1:2 2) 2 : 1 3) 2 : 3 4) 3 :4 1) 0.4 moles of KI 2) 0.8 moles of KI
3) 1.6 moles of KI 4) 3.2 moles of KI
MOLE CONCEPT ATOMIC 16. How many water molecules are there in one
MASS, MOLECULAR MASS, drop of water ( volume 0.0018ml) at room
AVOGADRO NUMBER temperature?
6. The density of water is 1 gm/ml. The volume 1) 6.0231019 2) 1.084 1018
of water drop is 1.8 ml. The no. of molecules 3) 6.0231023 4) 4.841017
present in one water drop are
1) 6.023  1023 2) 6.023  1021 17. 1.5 g of CdCl2 was found to contain 0.9 g of
20 22
3) 3.011  10 4) 6.023  10 Cd. Calculate the atomic weight of Cd.
7. Increasing order of number of moles of the (EAMCET-2009)
species 1) 118 2) 112 3) 106.5 4) 53.25
i) 3 grams of NO ii) 8.5 grams of PH 3 and
iii) 8 grams of methane is
 EQUIVALENT WEIGHT 25. A compound of phosphorous and sulphur contains
18. 2.0g of a metallic carbonate on decomposition 1.24 gm of phosphorous in 2.2 gm of the
gave 1.5g.of metallic oxide. The equivalent compound. The formula of the compound is
mass of metal is 1) P4S3 2) P3S4 3) P3S2 4) P2S3
1) 58 2) 29 3) 5.8 4) 2.9 26. The relative number of atoms of different
19. The vapour density of a tribasic acid is x. The elements in a compound are as follows: A=1.33,
equivalent mass of that acid is B=1 and C=1.5. The emperical formula of the
x 2x compound is
1) b) x  3 3) 4) 2 x  3 1) A2 B2C3 2) ABC 3) A8 B6C9 4) A3 B3C4
3 3
20. The equivalent weight of divalent metal is 27. A compound has 40% of carbon by weight. If
31.82. The weight of a single atom is molecular weight of the compound is 90, the
1) 32.55  6.02  1023 g 2) 32.77  6.02  1023 g number of carbon atoms present in 1 molecule
of the compound are
3) 63.64g 4) 63.64 / 6.02  10 23 g 1) 3 2) 2 3) 1 4) 5
21. When NA is Avogadro’s number then the 28. A compound has 20% of nitrogen by weight. If
number of oxygen atoms in one gm. equivalent one molecule of the compound contains two
of oxygen is nitrogen atoms, the molecular weight of the
NA N compound is
1) N A 2) 3) A 4) 2  N A 1) 35 2) 70 3) 140 4) 280
2 4
PERCENTAGE WEIGHT OF 29. 3.0 gms of an organic compound on combustion
give 8.8 gm of CO2 and 5.4 gm of water. The
ELEMENTS IN COMPOUNDS empirical formula of the compound is
MOLECULAR FORMULA &
1) CH 3 2) C2 H 4 3) C2 H 2 4) C2 H 6
EMPERICAL FORMULA
22. At STP one litre of a gas weighs 1.25 grams. 30. The oxide of a metal contains 40% of oxygen.
The gas contains 85.71% of carbon and The valency of metal is 2. What is the atomic
14.29% of hydrogen. The formula of the weight of the metal ? (EAMCET-2014)
compound is 1) 12 2) 40 3) 36 4) 24
1) CH4 2) C2H6 3) C3H8 4) C2H4 NUMERICAL CALCULATIONS
23. A certain compound contains magnesium,
carbon and Nitrogen in the mass ratio 12 : 12 BASED ON CHEMICAL
: 14. The formula of the compound is EQUATIONS
1) MgCN 2) Mg2CN 31. When a sample of Baking soda is strongly
3) MgCN2 4) Mg(CN)2 ignited in a crucible it suffered a loss in weight
24. An organic compound having molecular mass of 3.1g. The mass of baking soda is
60 is found to contain C = 20%, H = 6.67% 1) 16.8 g 2) 8.4 g 3) 11.6 g 4) 4.2 g
and N = 46.67% while rest is oxygen. On 32. 20 ml of a hydro carbon requires 100 ml of
heating it gives NH3 along with a solid residue. oxygen for complete combustion. In this
The solid residue give violet colour with reaction 60 ml of carbondioxide is produced.
alkaline copper sulphate solution. the The formula of hydro carbon is
compound is [AIEEE 2005] 1) C2H4 2) C3H6 3) C3H8 4) C6H6
1) CH3NCO 2) CH3CONH2
3) (NH2)2CO 4) CH3CH2CONH2
 BASIC CONCEPTS OF CHEMISTRY
33. 18.4 gms of a mixture of calcium carbonate and METHODS OF EXPRESSING CON-
magnesium carbonate on heating gives 4.0 gms
CENTRATIONS
of magnesium oxide. The volume of CO2
40. An aqueous solution of 6.3 g oxalic acid
produced at STP in this process is
dihydrate is made up to 250 ml. The volume of
1) 1.12 lit. 2) 4.48 lit 3) 2.24 lit 4) 3.36 lit.
0.1 N NaOH required to completely neutralize
34. A solution containing 0.2 mole of ferric chloride
10 ml of this solution is
is allowed to react with 0.24 mole of sodium
1) 40 ml 2) 20 ml 3) 10 ml 4) 4 ml
hydroxide. The correct statement for this
41. The normality of orthophosporic acid having
reaction is
purity of 70% by weight (specific gravity is
1) Limiting reagent for this reaction is NaOH
1.54) would be
2) 0.08 moles of Fe(OH.3 is formed 1) 11 N 2) 22 N 3) 33 N 4) 44 N
3) 0.12 mole of FeCl3 is left unreacted 42. Mole fraction of C3H5(OH)3 in a solution of
4) All the above 36 g of water and 46 g of glycerine is
35. CH 4 g  + 2O2 g   CO2 g  + H 2Ol  , as per this 1) 0.46 2) 0.36 3) 0.20 4) 0.40
reaction, if 20ml of CH4 and 20 ml of O2 were 43. The volume of water to be added to 400 ml of
exploded together and if the reaction mixture N/8 HCI to make it exactly N/12 is
is cooled to room temp, the resulting gas 1) 400ml 2) 300ml 3) 200ml 4) 100ml
mixture will have a volume of 44. When 100ml of 10 M solution of H2SO4 and
1) 40 ml 2) 20 ml 3) 60 ml 4) 30 ml 100 ml of 1 M solution of NaOH are mixed
the resulting solution will be
36. The mass of Hydrogen at S.T.P. that is present
1) Acidic 2) Basic
in a vessel which can hold 4 grams of oxygen
3) Neutral 4) Can not predicted
under similar conditions is
45. In order to prepare one litre normal solution
1) 1gm 2) 0.5gm 3) 0.25gm 4) 0.125gm
of KMnO 4, how many grams of KMnO 4
37. KMnO4 reacts with KI in basic medium to from
required if the solution is to be used in acid
I2 and MnO2 . When 250 mL of 0.1 M KI
medium for oxidation
solution is mixed with 250 mL of 0.02M KMnO4
1) 158 2) 79 3) 31.6 4) 790
in basic medium,what is the number of moles
46. 12.5 ml of a solution containg 6 grams of
I2 formed? (EAMCET -2014)
dibasic acid in one litre was found to be
1) 0.0075 2) 0.005 3) 0.01 4) 0.015
neutralised by10 ml of a decinormal solution
38. 19 g og a mixture containing NaHCO3 and
of NaOH. the molecular mass of the acid is
Na2CO3 on complete heating liberated 1,12L
1) 75 2) 110 3) 120 4) 150
of CO2 at STP. The weight of the remaining 47. 50gr of sample of sodium hydroxide required
solid was 15.9 g. What is the weight (in g) of for complete neutralisation, 1 litre 1 NHCl.
Na2CO3 in the mixture before heating? What is the percentage purity of NaOH is
(EAMCET -2011) 1) 50 2) 60 3) 70 4) 80
1)8.4 2) 15.9 3) 4.0 4) 10.6 48. How many grams of 40% pure sodium
39. The number of molecules of CO2 liberated by hydroxide is dissolved in 0.5 M, 250 ml NaOH
the complete combustion of 0.1 g atom of solution?
graphite in air is (EAMCET -2010) 1) 5 gm 2) 2g 3) 12.5 g 4) 4 gm
1) 3.011022 2) 6.02  10 23 49. 100 ml of 0.2N HCl solution is added to 100
3) 6.02  10 22 4) 3.011023 ml of 0.2N AgNO3 solution. The molarity of
nitrate ions in the resulting mixture will be
1) 0.5 M 2) 0.05M 3) 0.1M 4) 0.2M
50. The density of 3 M solution of NaCl is 1.25 g
mL-1. The molality of the solution is
1) 2.79 m 2) 1.79 m 3) 3.5 m 4) 5.58 m