FIITJEE

ALL INDIA TEST SERIES

OPEN TEST

JEE (Main)-2025
TEST DATE: 12-01-2025
Time Allotted: 3 Hours Maximum Marks: 300

General Instructions:

 The test consists of total 75 questions.

 Each subject (PCM) has 25 questions.

 This question paper contains Three Parts.

 Part-A is Physics, Part-B is Chemistry and Part-C is Mathematics.

 Each part has only two sections: Section-A and Section-B.

Section-A (01 – 20, 26 – 45, 51 – 70) contains 60 multiple choice questions which have only one
correct answer. Each question carries +4 marks for correct answer and –1 mark for wrong
answer.

Section-B (21 – 25, 46 – 50, 71 – 75) contains 15 Numerical based questions. The answer to each
question is rounded off to the nearest integer value. Each question carries +4 marks for correct
answer and –1 mark for wrong answer.

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Physics PART – A

SECTION – A
(One Options Correct Type)

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

1. On heating water, bubbles being formed at the bottom of the vessel

detach and rise. Take the bubbles to be spherical of radius R and
making a circular contact of radius r with the bottom of the vessel. If r
<< R, and the surface tension of water is T, value of r just before
R
bubbles detach is (density of water is W )
2w g  g
(A) R2 (B) R2 w 2r
3T 6T
w g 3w g
(C) R2 (D) R2
T 2T

2. A parallel plate capacitor of capacitance C is connected to a battery + 

and is charge to a potential difference V. Another capacitor of
capacitance 2C is similarly charged to a potential difference 2V. The C
charging battery is then disconnected and the capacitors are
connected in parallel to each other in such a way that the positive
terminal of one is connected to the negative terminal of the other.
Then the energy lost in the final circuit of only capacitor C and 2C is
3
(A) CV 2 (B) 3CV 2 2C
2
9  +
(C) CV 2 (D) zero
2

3. A photoelectric surface is illuminated successively by monochromatic light of wavelength  and


. If the maximum kinetic energy of the emitted photoelectron in the second case is 3 times that
2
in the first case, then the threshold wavelength for the surface is
(A) 2 (B) 3
(C) 4 (D) 6

4. The resultant intensity after interference of two coherent waves represented by the equations.
y1  A1 sin(t)
 
and y 2  A 2 sin  t  
 2
will be proportional to
(A) A12  A 22 (B) (A1  A 2 )2
(C) A1A 2 (D) (A1  A 2 )2

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5. In the circuit shown in the figure, the reading of the ammeter 100
A
is the same with both switches open as with both closed.
Then find the resistance R. The ammeter is ideal. S1
(A) 600  R S2 50
(B) 400 
(C) 200 
(D) 100 
300  = 1.5 V

6. Two identical charges, 4 C each are in vacuum. What is the charge to be transferred from one
charge to another keeping the separation same as before, so that their columbic force of
interaction decreases to half ?
(A) 2 C (B) 2 6 C
(C) 2 2 C (D) 2 C

7. If unpolarized light is incident on a block of crystal at 60 so that the reflected light is completely
polarized. Then refractive index of the block is
(A) 1 (B) 3
(C) 2 (D) 1.5

8. A thin wire is bent into the shape of a parabola (y2 = 4ax) in the y
B
vertical plane as shown in the figure. A small bead B can freely slide
along the wire. The coefficient of static friction between the bead and
the wire is S . The minimum y-coordinate of the wire y0(y0 > 0), y2 = 4ax x
where the bead does not slip on the wire is
2a
(A) 2aS (B)
S
a
(C) aS (D)
S

 y
9. In the diagram shown, a non-uniform magnetic field B  B0 x( k) ˆ
has been applied in the direction shown, where B0 is a positive
constant and x is coordinate. A particle of mass m and positive 
B
charge q is projected with an initial velocity (u ˆi) form origin. The
displacement of the charge particle along x-direction when its
velocity becomes parallel to y-direction is (neglect gravity) q, m u x

mu 2mu
(A) (B)
qB0 qB0
mu 4mu
(C) (D)
2qB0 qB0

10. The value of displacement current at t = 1 time constant after closing of 100
100 F
the switch is
120 120
(A) mA (B) 2 mA
e e
60
(C) 120 mA (D) mA
e
12V

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11. The amplitude of a damped oscillation decreases to 0.9 times its original magnitude in 5 sec. In
another 10 s it will decreases to  times its original magnitude. Then  is
(A) 0.346 (B) 0.693
(C) 0.363 (D) 0.729

12. At time t = 0 a battery of 10V is connected 2M 2F

across points A and B in the given circuit. If
the capacitor have no charge initially, the time
t (in seconds) when the voltage across the
A B
capacitor becomes 4V is

2M 2F
5 5
(A) 3n   (B) 4n  
2 3
4
(C) 5n   (D) 10n(4)
3

13. In an optics experiment, with the position of the object fixed, v

a student varies the position of convex lens and for each
position, the screen is adjusted to get a clear image of the P
object. A graph between the object distance u and the
image distance v, from the lens, is plotted using the same
scale for the two axes. A straight line passing through the
origin and making an angle of 45 with the x-axis meets the
experimental curve at P. The coordinates of P will be u
(A) (f, f) (B) (4f, 4f)
f f
(C) (2f, 2f) (D)  , 
2 2

14. A particle of mass m is attached to a light spring and vibrates with its natural angular frequency
0. An external force F = F0cos(t) is applied to the oscillator. The maximum displacement of the
oscillator is proportional to
m 1
(A) 2 2
(B)
(0   ) m(0  2 )
2

1 m
(C) (D)
m(20 2
 ) (02  2 )

15. A uniform thin rod AB of length  and mass m is undergoing m, 

fixed axis rotation about end A such that end A remains A P B

stationary as shown in the figure. The kinetic energy of 
section AP of rod is equal to kinetic energy of section BP of
rod at an instant. Then the ratio of length AP and length AB,
AP
that is is equal to
AB
1 1
(A) (B) 1/3
2 2
1 1
(C) (D)
2 2 2

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16. 400 gm of ice at 253 K is mixed with 0.05 kg of steam at 100C. Latent heat of vaporization of
steam is 540 cal/gm. Latent heat of fusion of ice is 80 cal/gm. Specific heat capacity of ice is 0.5
cal/gC. The resultant temperature of the mixture is
(A) 273 K (B) 300 K
(C) 330 K (D) 373 K

17. Two rods of different materials having coefficient of thermal expansion 1, 2 and Young’s
modulus Y1, Y2 respectively are fixed separately between two rigid massive walls. The rods are
heated such that they undergo the same increase in temperatures. There is no bending of the
rods. If 1 :  2  2 : 3 , then thermal stress developed in the two rods are equal provided Y1 : Y2 is
equal to
(A) 2 : 3 (B) 1 : 1
(C) 3 : 2 (D) 4 : 9

18. A nucleus of mass no. 220, initially at rest emits an -particle. If the Q value of the reaction is 5.5
MeV, the energy of the emitted -particle will be
(A) 4.8 MeV (B) 5.4 MeV
(C) 6.0 MeV (D) 6.8 MeV

19. A thin convex lens of focal length 1 m is cut into

three parts A, B and C along the parallel to A A
principal axis of the lens as shown in the figure
(a). The thickness of the middle layer C is 1 cm. C 1 cm C
The middle layer is now removed and the two B B
parts A and B are put together to from a
composite lens. Then the part C is also placed in Figure (a) Figure (b)
front of the composite lens symmetrically as
shown in the figure (b). Paraxial beam of light is
incident along the axis of the part C. Then the
distance between the two final images formed is
(A) 0.2 cm (B) 0.4 cm
(C) 0.5 cm (D) 0.6 cm

20. The magnetic susceptibility of paramagnetic substance at 73C is 0.0060. The its value at
 173C will be
(A) 0.0030 (B) 0.0120
(C) 0.0180 (D) 0.0045

SECTION – B
(Numerical Answer Type)
This section contains 05 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

21. A simple second pendulum is constructed out of a very thin string of thermal coefficient of linear
expansions   20  104 /C and a heavy particle attached to one end. The free end of the string
is suspended from the ceiling of an elevator at rest. The pendulum keeps correct time at 0C.
When the temperature rises to 50C the elevator operator of mass 70 kg being a student of
physics accelerates the elevator vertically to have the pendulum correct time. The apparent
weight of the operator when the pendulum keeps correct time at 50 is ………Newton. (Take
2
g = 10 m/s )

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22. A record player of radius r = 10 cm turns at 10 rad/s is mounted on

a 30 inclined plane as shown in the figure. A particle of mass m
can be placed anywhere on the rotating record. If the minimum
value of coefficient of static friction is  S that must exist for no
2
slipping to occur, then find the value of 2S . (Take g = 10 m/s )
30

23. A uniform rigid ribbon of mass 3m and length 3d is bent at B as shown A

and placed on a horizontal table in vertical plane. An insect of mass m
is sitting at point A. If the angle  = 0 at which the ribbon is just about 2d
to topple. Then find 8cos 0 .


B C
d

24. Water flowing along an open channel drives an undershot

waterwheel of radius 0.5 m as shown in the figure. The water
approaches the wheel with a speed of v 1 = 5 m/s and leaves
with a speed of v2 = 2.5 m/s, the amount of water passing by is
100 kg/sec. At what rate does the water deliver angular v1 v2
momentum to the wheel (in J)

25. A circuit shown in the figure contains a box having either a C

capacitor or an inductor. The power factor of the circuit is 0.8. Box
Current lags behind the source voltage. Then find the VC = 1000 V
inductance/capacitance of the box in S.I. unit. The circuit draws 1
ampere current.

~
800 
400
V, Hz


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Chemistry PART – B

SECTION – A
(One Options Correct Type)

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

26. K 2 Cr2 O7 on reaction with conc. H2 SO4 under cold and warm condition produces x and y are
product respectively. x and y are:
(A) Cr2  SO 4 3 and CrO3
(B) Cr2  SO 4 3 , Cr2  SO4 3
(C) CrO3 and Cr2  SO 4 3
(D) Cr2 O3 , CrO3

27. Which of the following is not a byproduct when excess F2 reacts with H2O:
(A) O2 (B) HF
(C) HOF (D) O3

28. The reaction of NiBr2 with 2 equivalent of PPh3 is CS2 at 78o C gives a red coloured diamagnetic
complex NiBr2 PPh3 2  . This transforms to a green coloured paramagnetic complex with same
molecular formula at 25oC. The geometry and number of unpaired electrons in the coloured
complex respectively are:
(A) Square planar and 2 (B) Tetrahedral and 2
(C) Square planar and 4 (D) Tetrahedral and 1

29. H

(I) (II)
Choose the correct statement regarding (I) and (II)
(A) Peripheral  bonds are out of configuration in both (I) and (II)
(B) Non-peripheral  bonds are out of configuration in both (I) and (II)
(C) Peripheral  bonds are out of configuration in (I) and not in (II)
(D) Peripheral  bonds are out of configuration in (II) and not in (I)

30. Which of the following has the largest enol content out of the following:
(A) O O

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(B) O O

EtO OEt
(C) O

H H
(D) O

31. An adiabatic cylinder fitted with an adiabatic piston at the right end of cylinder, is divided into two
equal halves with a monoatomic gas on left side and diatomic gas on right side, using an
impermeable movable adiabatic wall. If the piston is pushed slowly to compress the diatomic gas
3
to th of its original volume. The ratio of new volume of monoatomic gas to its initial volume
4
would be
25 3
 4  21  7 4
(A)   (B)  
3 5
21
 3  25 3
(C)   (D)
4 4

32. I2  I  I3 . The reaction is set up in aqueous medium we start with

1 mole of I2 and 0.5 mol of I in 1 L flask. After equilibrium is reached, excess of AgNO3 gave
0.25 mol of yellow precipitate. Using this information, calculate the equilibrium constant for
1 1 1
I2  I  I3
2 2 2
(A) 1.33 (B) 1.15
(C) 1.77 (D) 1.45

33. Choose the correct graph which represents the energy transformation involved in the formation of
product for
O
 HO  Product  Major 
R OMe

(A)


E

Extent of reaction 

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(B)


E

Extent of reaction 
(C)


E

Extent of reaction 
(D)


E

Extent of reaction 

34. The binding energy of an electron in the ground state of hydrogen-like ions in whose spectrum,
the third line of the Balmer series is equal to 108.5 nm, is
(A) 13.6 eV (B) 54.4 eV
(C) 122.4 eV (D) 14.4 eV

K1
35. For the first order gaseous reaction A  g  2B  g , the initial pressure in a container of
fixed volume, V litre, is 1 atm. Pressure of the system is 1.4 atm at t = 10 minute and the
pressure is 1.5 atm after a very long time. The only correct information about the reactions is
[ln2 = 0.7, ln10 = 2.3]
(A) 2K1  K 2  0.08 min1
(B) K1  K 2  0.08 min1
(C) K1  2K 2  0.08 min1
(D) K1  K 2  0.16 min1

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36. The last step in the synthesis of Valium is treatment of the following aromatic compound with
NH3. Choose the correct structure of Valium
Cl
H3C
O N
O
NH3
  Valium
 C6H13 ClN2 O 

Cl
(A) NH2
H3C
O N

Cl
(B) O

CH3
HN N

Cl

(C) O

CH3
N N

Cl

(D) O

N
N CH3

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37. Which of the following amino acid contains an amide group?

(A) Glutamine (B) Alanine
(C) Proline (D) Serine

38. Identify rate of solvolysis or hydrolysis

Cl Cl

Cl
(i) (ii) (iii)
(A) i > ii > iii (B) ii > iii > i
(C) ii > i > iii (D) iii > i > ii

39. Which of the following is a primary standard?

(A) NaOH (B) HCl
(C) H2 C2O 4 (D) KMnO 4

40. When glycerin is added to a litre of water, then which of the following is observed?
(A) Water evaporates more easily.
(B) The temperature of water increases.
(C) The freezing point of water is lowered.
(D) The viscosity of water is lowered.

41. Identify the final product of the reaction

CHO
 i Br2 , H2 O
H OH  2 2 ii H O /Fe3

 iii KCN, NH Cl  4
H OH  iv  H3 O

HO

(A) COOH
HO H
H OH
CH2OH
(B) COOH
H2N H
HO H
COOH

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(C) CHO
HO H
HO H
COOH
(D) CHO
H2N H
HO H
CHO

42. The EMF of cell: H2(g) | Buffer || Normal calomel electrode, is 0.70 V at 25oC, when barometric
pressure is 760 mm. What is the pH of the buffer solution? EoCalomel  0.28 V.2.303RT / F  0.06
(A) 3.5 (B) 7.0
(C) tending to zero (D) tending to 14.0

43. Identify final product in following sequence

H3C
NH2
Ph Br
CH2 H3C
NaNH2 MCPBA
  X   Y   Z  Product
Ph
(A)

NH NH

(B)

CH3
HO NH
CH3
(C) CH3
O

CH3

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(D)
CH3

NH CH3
HN CH3

CH3

44. Choose the correct option regarding correct statements out of the following:
I. IE1  IE2  IE3  for indium is more than that of Al.
II. IE1 of Sc is higher than cobalt.
III. IE1 of Ga is lower than that of Se.
IV. IE of N is greater than that of O.
(A) I, II and IV (B) III and IV
(C) I and IV (D) II and III

45. The decreasing order of ionic nature of the following compound is:
(A) LiI > NaBr > KCl > CsF
(B) LiI > KCl > NaBr > CsF
(C) CsF > NaBr > KCl > LiI
(D) CsF > KCl > NaBr > LiI
SECTION – B
(Numerical Answer Type)
This section contains 05 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

46. The oxidation state of molybdenum in its oxocomplex

2
Mo2 O4  C2H4 2 H2O 2  is

47. A mixture of Xe and F2 was heated. A sample of white solid thus formed reacted with hydrogen to
give 56 ml of Xe at 0oC and 1 atm and HF formed required 60 ml of 0.25 M NaOH for complete
neutralization. If the molecular formula of the solid formed is XeF x, then the value of x is:
2 xy
48. The hybridization of central atom in H6 SnO 6  is sx p y dz . Then the value of is?
z
49. The total sum of correct statement number(s) out of the following is/are:
(1) AgCl, PbCl2 and Hg2Cl2 are insoluble in cold H2O while other chlorides are soluble.
3+ 3+
(3) In presence of NH4OH and NH4Cl Fe precipitate as red-brown compound whereas Cr as
green coloured compound.
(7) Basic sulphides are soluble in yellow ammonium sulphides and are grouped in IIA.
(5) CuSO4 on reaction with K4[Fe(CN)6] gives a chocolate brown precipitate.
 A 3 
50. 20 mL of 0.2 M H3A (Tribasic acid) is titrated with 0.2 M NaOH. The ratio of  at second
H3 A 
x
equivalence point is 10 . The value of x is?
Given: K a1  10 3
K a2  108
K a3  10 12

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Mathematics PART – C

SECTION – A
(One Options Correct Type)

This section contains 20 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

51. If both roots of the quadratic ax 2 + bx + c = 0 lie in (0, 2) then 25ac + 20bc + 16c2 is always
(A) positive (B) negative
(C) equal to zero (D) cannot say with given information

52. Let L1, L2 be two distinct lines such that L1 and L2 are not perpendicular. Let P be a plane such
that L1 and L2 are not perpendicular to P. Let L3 and L4 be projections of L1 and L2 on plane P
respectively. If  be angle between L3 and L4 then  CANNOT be equal to

(A) 0 (B)
3

(C) (D) none of these
2

53. Let 'A' be a non-singular idempotent matrix of order 2025  2025, then consider these statements
(i) Trace of matrix A has to be 2025
(ii) A has to be a scalar matrix
(iii) Trace of adjoint matrix of A2 has to be equal to 2025
Which of the given statements are true ?
(A) (i) and (ii) (B) (ii) and (iii)
(C) (i), (ii) and (iii) (D) none of these

54. Let A, B, C be 3 points on the parabola y2 = 4x. Let D, E, F be midpoints of AB, BC and AC
respectively. If G is the centroid of triangle DEF and normals to the parabola at points A, B and C
are concurrent at Point H(5, 1) then slope of the line GH is
1 1
(A) (B)
2 3
3
(C) 1 (D)
4

2
55. Minimum value of the expression (a  b)2 +  4 1  a2  2 2b  b2  is
(A) 16 (B) 4
(C) 8 2 (D) none of these

56. The curve satisfying the differential equation 2xy(y2cos(x2y)  1) + x2y(y2cos(x2y) + 1) = 0 and
passing through (0, 1) is
2 2 2 2
(A) sin (x y) = x (B) sin(x y) = xy
2
x
(C) sin(x2y) = x2y (D) sin(x2y) =
y

57. Let x1, x2, …. , x100 be an A.P with x1 = 1 and x100 = 199. If yi = i(xi + 1); i = 1, 2, …. , 100 then
mean of y1, y2, …… , y100 is
(A) 6867 (B) 6767
(C) 6967 (D) none of these

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58. Let P(A) be defined as power set of set A = {1, 2, 3, ….. , 2025}. Let R be a relation defined on
P(A) as (B, C)  R if B is superset of C, then R is
(A) reflexive and transitive relation (B) reflexive and symmetric relation
(C) symmetric and transitive relation (D) equivalence relation

3  2x 
59. Let set A denotes the solutions of the equation cos1(4x  3x) = tan1   then
 1 x2 
(A) n(A) = 0
1
(B) n(A) = 1 and only one element in A is less than 
2
1
(C) n(A) = 1 and only one element in A is greater than
2
1
(D) n(A) = 2 and absolute value of two elements in A is greater than
2
sin x  1 sin 2x sin3x
60. If sin2x sin3x  a sin 4x = 2025 (f(x) + 45) where f(x) is some function of 'x' and 'a' is a
2
sin3x sin 4x sin5x  a
complex number then sum of all possible values of 'a' is
(A) 0 (B) 45
(C) 135 (D) 2025
  2
sin   2x  1   x 4p ex 1  x 4p
61. Let f : R  R be defined as f(x) = lim  2 . f(x) is continuous for all x in
p  1  x 4p 2  x 4p
(A) R (B) R  {1}
(C) R  {1} (D) R  {1, 1}
62. A ladder of 3m length leans against a wall. Initially the ladder forms a vertical angle of 30° with
the wall. If the top of the ladder begins to slide down the wall at constant rate of 20 cm/s, the
bottom of the ladder slides away from the wall at rate of 20 cm/s at time 't' seconds. The average
velocity of a person halfway up the ladder for the first 't' seconds is
3  2  1 ˆ  3  ˆ 3  2  1 ˆ  3  ˆ
(A)   1  i  1  j (B) 1   i  1  j
5  2  2  10  2  2  
3 2 3 2
(C)  2  1 ˆi   2  3  ˆj  (D)  2  1 ˆi   2  3  ˆj 
5 10
63. The probability that in a random arrangement of the word MATHEMATICS, the two M's are not
together given that the two A's are not together is
73 36
(A) (B)
90 45
5 37
(C) (D)
6 45
1
sin x
64. Value of  dx lies in the interval
0
x
 1695 1699   1699 1703 
(A)  ,  (B)  , 
 1800 1800   1800 1800 
 1703 1707   1707 1711 
(C)  ,  (D)  , 
 1800 1800   1800 1800 

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65. Let ABCDEF be a hexagon which has unequal side lengths.

      
Let G and H be centroids of ACE
and BDF respectively. If AB  BC  CD  DE  EF  FA  HG , then  equals
(A) 4 (B) 4
(C) 6 (D) 6

66. Let f(x) = x2 + x be written as f(x) = g(x) + h(x) where g(x) is an odd function and h(x) is an even
x
function. Then g(xy) + h   equals
y
x2 x2
(A) xy  (B) xy 
y2 y2
x2
(C)  xy (D) none of these
y2

2 2
67. Given that  z  z    0 is equation of a line where  is purely imaginary number. If    = 2,
where Re() and Im() are whole numbers, then slope of the line is
3
(A) 0 (B)
5
3
(C)  (D) none of these
5


9n2
68. The sum   3n ! is equal to
n 1

1  3 2 1  3
(A) e  cos   (B) e cos  
e  2  3 e  2 
2 1  3  2 1  3 
(C) e 
 cos   (D) e  cos  
3 e  2   3
e  2  

69. Let (, ) be circumcentre of the triangle formed by vertices (1,5), (3, 4) and (10, 31) then value
of 8  2 equals
(A) 55 (B) 2
(C) 108 (D) none of these

70. Sum of length of all the common tangents of the circles

x2 + y2  2x  8y + 15 = 0
x2 + y2  6x  12y + 43 = 0
is
(A) 2 (B) 2 2
(C) 4 2 (D) 5 2

SECTION – B
(Numerical Answer Type)
This section contains 05 Numerical based questions. The answer to each question is rounded off to the
nearest integer value.

71. Let A = {1, 2, 3, ….. , 10}, B = {4, 8, 12, 16, 20} and C = {D : D  A, D  B  } then number of
elements in set C which have atleast 3 but atmost 6 cardinal number is

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16 4
72. The number of integral values of  for which the equation    does not have any
tan x 4  tan x
solution is

 
x 1 1   xe x   2  xe x    
73. Let I(x) =  x  x2 e2x dx  ln    c , then  +  +  equals
 1 4  x 4 e4x 

74. Area bounded by the set of points S = {(x, y) : ||x|  1| + ||y|  1|  1} is

75. If 30C0 30C20  30C1 30C19 + 30C2 30C18  ……. + 30

C20 30C0 equals nCr then maximum possible value
of n + r equals

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