23-04-2025

7101CJA101021250001 JM

PHYSICS

SECTION-I

1) If an object more of substance A rubs an object made of substance B, then A becomes positively
charged and B becomes negatively charged. If, however, an object made of substance A is rubbed
against an object made of substance C, then A becomes negatively charged. What will happen if an
object made of substance B is rubbed against an object more of substance C?

(A) B becomes positively charged and C becomes positively charged

(B) B becomes positively charged and C becomes negatively charged
(C) B becomes negatively charged and C becomes positively charged
(D) B becomes negatively charged and C becomes negatively charged

2) Five positive equal charges are placed at vertices of a regular hexagon and net electric field at the
centre is E1. A negative charge having equal magnitude is placed sixth vertex and then net electric

field is E2. Find .

(A) 2
(B) 1
(C) 3
(D) None of these

3) What is the percentage change in distance if the force of attraction between two point charges
increases to 4 times keeping magnitude of charges constant?

(A) Decreased to 20% of initial value.

(B) Decreased to 25% of initial value.
(C) Decreased to 50% of initial value.
(D) Decreased to 100% of initial value.

4) Three charge +4q, Q and q are placed in a straight line of length l at points distance 0, l/2 and l
respectively. What should be the value of Q in order to make the net force on q to be zero?

(A) –q
(B) –2q
(C) –q/2
(D) 4q

5) The maximum electric field intensity on the axis of a uniformly charged ring of charge q and
radius R will be:
(A)

(B)

(C)

(D)

6) An infinite, uniformly charged sheet with surface charge density σ cuts through a spherical
Gaussian surface of radius R at a distance x from its center, as shown in the figure. The electric flux

ϕ through the Gaussian surface is :-

(A)

(B)

(C)

(D)

7) In the given figure ABCD is square. Net force acting on charge –2q is zero. Then Q is

(A)
(B)
(C) 2q

(D)

8) A linear charge having linear charge density λ, penetrates a cube diagonally and then it penetrate
a sphere diametrically as shown. What will be the ratio of flux coming out of cube and sphere
(A)

(B)

(C)

(D)

9) The charge per unit length of the four quadrant of the ring is 2λ, – 2λ, λ and –λ respectively. The

magnitude of electric field at the centre is :

(A)

(B)

(C)

(D) None

10) A charge –q of mass m is rotating in circle of radius r, around an infinite large uniformly charged

wire as shown. Speed of charge is V then choose the correct option:-

(A)

(B)

(C)

(D)

11) Electric field at the center of the square of side a is :-

(A)

(B)

(C)

(D) None of these

12) Which of the following charge on a body is not possible?

(A) 1 Coulomb
(B) 16 × 10–30 Coulomb
(C) 7 × 10–6 Coulomb
(D) 32 Coulomb

13) The figure shows some of the electric field lines corresponding to an electric field. The figure
suggests

(A) EA > EB > EC

(B) EA = EB = EC
(C) EA = EC > EB
(D) EA = EC < EB

14)

Electric flux through a surface of area 100 m2 lying in the yz plane is (in V-m) if

(A) 100
(B) 141.4
(C) 173.2
(D) 200

15) Two point charges q1 and q2 are placed at a separation r. The force on q2 due to q1 is F. Now the
complete set-up is placed in a dielectric medium having di-electric constant k = 4. The force due to
q1 on q2 is :

(A) F/4

(B)

(C)

(D) F

16) Two semi-infinite wires are joined with a quarter circular arc of radius R as shown in diagram.
The charge density is same on both the wires and the arc. The electric field intensity at point C, the

centre of arc is :

(A)

(B)

(C)
(D)

17) A charged particle of mass m = 2 kg and charge 1µC is projected from a horizontal ground at an
angle θ = 45° with speed 10 ms-1. In space, a horizontal electric field E = 2 × 107 NC–1 exists. The
range of the projectile is

(A) 20m
(B) 60m
(C) 200m
(D) 180m

18) A point charge Q is located on the axis of a disc of radius R at a distance 'a' from the plane of the
disc. If one fourth (1/4th) of the flux from the charge passes through the disc, then value of a is :-

(A)

(B)

(C)

(D)

19) Total flux coming out of the cylindrical Gaussian surface –

(A) ϕ = 100 C
(B) ϕ = 1 C

(C)

(D)

20) A charge Q is to be divided on two small spheres seperated by a distance R. The maximum
possible electrostatic force between the spheres can be
(A)

(B)

(C)

(D)

SECTION-II

1) Find the magnitude of electric field (in N/C) due to a line charge of λ = nC/m at a point P

as shown.

2) A point charge –Q is placed at the centre of a uniformly charged ring of charge Q. Electric field at

a point on the axis of ring at a distance x (x >> R) varies as find n.

3) In a particular system, if number of electric field lines associated by 1C charge is 109. Then net
number of electric field lines passing through the given closed surface is n × 103 find n.

4) A point charge q = 2C and mass m = 1 kg is released from rest in a uniform electric field E = 6
N/C. Find the momentum of the particle after 0.5 s in kg m/s.

5)

The length of each side of a cubical closed surface is l. If charge q is situated on one of the vertices

of the cube as shown then the flux passing through shaded face of the cube is , then b is ?
 CHEMISTRY

SECTION-I

1) Which of the following is isotonic with 15 % glucose solution (sp. gr = 1.2) :

(A) 1 M CaCl2
(B) 1 N CaCl2
(C) 0.5 M NaCl
(D) 0.5 M urea

2)

18 g glucose (C6H12O6) is added to 178.2g water. The vapour pressure of water (in torr) for this
solution at boiling point temperature is

(A) 700 torr

(B) 720 torr
(C) 752.4 torr
(D) 800 torr

3) Ratio of solubilities of gases N2 & O2 in water (as mole of gas in large volume of water) from air at
25º & 1 atm will be, if air is 20 % by mole of O2 & 80% by mole of N2
Given : KH (N2) = 2 × 104 atm
KH (O2) = 104 atm

(A) 8 : 1
(B) 1 : 8
(C) 2 : 1
(D) 1 : 2

4) Liquids A and B form an ideal solution. A certain solution of A and B contains 25 mole percent of
A, whereas the vapours in the equilibrium with the solution at 298 K contains 50 mole percent of A.
The ratio of vapour pressures of pure A to that of pure B at 298 K, is

(A) 1 : 1
(B) 3 : 1
(C) 1 : 3
(D) 2 : 1

5) The variation of total vapour pressure of an ideal solution of two liquids A and B is depicted aside.
The total vapour pressure denoted by the point ‘X’ will be:

(A) 46 mm
(B) 40 mm
(C) 34 mm
(D) 32 mm

6) Among the following, that does not form an ideal solution is :

(A) Benzene & toluene

(B) HNO3 + H2O
(C) n-hexane & n-heptane
(D) C2H5Br and C2H5I

7)

What is the correct sequence of osmotic pressure of 0.01 M aq. solution of :

(i) Al2(SO4)3 (π1)
(ii) Na3PO4 (π2)
(iii) BaCl2 (π3)
(iv) Glucose (π4)

(A) π4 > π2 > π3 > π1

(B) π3 > π4 > π2 > π1
(C) π3 > π4 > π1 > π2
(D) π1 > π2 > π3 > π4

0 0
8) Two liquids A and B have, PA : PB = 1 : 3 at a certain temperature. Assume A and B form an ideal
solution, and the ratio of moles of A to B in the liquid phase are 1 : 3, then mole fraction of A in
vapour phase in equilibrium with the solution will be -

(A) 0.1
(B) 0.2
(C) 0.5
(D) 1.0

9) If vapour pressures of pure liquids ‘A’ & ‘B’ are 300 and 800 torr respectively at 25°C. When
these two liquids are mixed at this temperature to form a solution in which mole percentage of ‘B’ is
92, then the total vapour pressure is observed to be 0.95 atm. Which of the following is true for this
solution.

(A) ΔVmix > 0

(B) ΔHmix < 0
(C) ΔVmix = 0
(D) ΔHmix = 0

10) For an ideal binary liquid solution with which relation between XA (mole fraction of A in
liquid phase) and YA (mole fraction of A in vapour phase) is correct ?

(A) XA < YA
(B) XA > YA
(C) XA = YA
(D) XA & YA can't be co-related

11) When 50 g of non-volatile non-electrolyte solute was dissolved in 810 g water, then there
occured a decrease in vapour pressure by 1% of vapour pressure of solvent. Find molar mass of
solute (in gm/mole).

(A) 62
(B) 110
(C) 78
(D) 94

12) If a ground water contains H2S at concentration of 2 mg/l, determine the pressure of H2S in head
space of a closed tank containing the ground water at 20°C. Given that for H2S, Henry's constant is
equal to 6.8 × 103 bar at 20°C.

(A) 720 Pa
(B) 77 × 102 Pa
(C) 553 Pa
(D) 55 × 102 Pa

13) A solution containing 62 g ethylene glycol in 250 g water is cooled to –10°C. If Kf for water
is 1.86 K kg mol–1, the amount of water (in g) separated as ice is :

(A) 32
(B) 48
(C) 16
(D) 64

14) The relationship between Osmotic pressure at 273K when 10gm of glucose (P1), 10gm urea (P2)
and 10gm sucrose (P3) are dissolved in 250 ml of water is

(A) P1 > P2 > P3

(B) P3 > P1 > P2
(C) P2 > P1 > P3
(D) P2 > P3 > P1
15) The freezing point of benzene decreases by 0.45°C when 0.2 g of acetic acid is added to 20 g of
benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid
in benzene will be
(Kf for benzene = 5.12 K kg mol–1)

(A) 64.6%
(B) 80.4%
(C) 74.6%
(D) 94.5%

16) K2[HgI4] is 40% ionised in aqueous solution. The value of its van't Hoff factor (i) is :-

(A) 1.8
(B) 2.2
(C) 2.0
(D) 1.6

17) Consider the following arrangement Volume of liquid in container I

and II at equilibrium are

(A) I = 100 ml, II = 100 ml

(B) I = 200 ml, II = 0 ml
(C) I = 0 ml, II = 200 ml
(D) I = 110 ml, II = 90 ml

18) A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following
statements is correct regarding the behaviour of the solution ?

(A) The solution is non-ideal, showing –ve deviation from Raoult's law
(B) n-heptane shows +ve deviation while ethanol shows –ve deviation from Raoult's law
(C) The solution formed is an ideal solution.
(D) The solution is non-ideal, showing +ve deviation from Raoult's law

19) Consider separate solution of 0.500 M C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M KBr(aq) and
0.125 M Na3PO4(aq) at 25°C. Which statement is true about these solutions, assuming all salts to be
strong electrolytes ?

(A) 0.125 M Na3PO4 (aq) has the highest osmotic pressure.

(B) 0.500 M C2H5OH (aq) has the highest osmotic pressure.
(C) They all have the same osmotic pressure.
(D) 0.100 M Mg3(PO4)2 (aq) has the highest osmotic pressure.
20) The substance A when dissolved in solvent B shows the molecular mass corresponding to A3. The
vant Hoff's factor will be -

(A) 1
(B) 2
(C) 3
(D) 1/3

SECTION-II

1) Elevation in boiling point of 0.25M aq. solution of weak acid HX is 0.14. What is molarity of H+ ion
in solution.
HXaq.
Given : Kb(H2O) = 0.5
Molality = Molarity
[Give answers as [H+] × 100]

2) Equal mass of A & B are present in liquid solution then total pressure exerted by vapours is X
torr, Give X/6. [A = 80 gm/mol, B = 120 gm/mol]

3)

Relative lowering in vapour pressure of a solution containing 1 mole K2SO4 in 54g H2O is x. The value
of 2x is

4) For an aqueous solution of 0.1M Ba(NO3)2, osmotic pressure at 300K is found to be 6.0 atm.

Degree of dissociation of Ba(NO3)2 in solution is . Then find the value of 'p'. (R = 0.08 atm-L/mole-
K).

5) 60 g urea is dissolved in 2.5 L solution at 27oC. Calculate osmotic pressure in atm.

MATHS

SECTION-I
1) Let A and B are two square matrices of order 2 x 2 and A – 2B = and 2A – 3B =
Then the matrix B is equal to ______.

(A)

(B)

(C)

(D)

2) If then f(100) is equal to

(A) 0
(B) 1
(C) 100
(D) -100

3) If number of elements in a matrix is 100 then how many different order of matrix are
possible______.

(A) 9
(B) 12
(C) 6
(D) 24

4) If the product of ‘n’ matrics

Then the value of n = ______.

(A) 26
(B) 27
(C) 377
(D) 378

5) If
Then matrix A is equal to

(A)

(B)

(C)

(D)

6)

The system of linear equations

x + λy – z = 0; λx – y – z = 0; x + y – λz = 0
has a non-trivial solution for

(A) Infinitely many values of λ

(B) exactly one value of λ
(C) exactly two values of λ
(D) exactly three values of λ

7) Let A and B be two invertible matrics of order 3x3. If det (ABAT) = 8 and det (AB-1) = 8. Then det
(BA-1BT) is equal to ______.

(A) 16

(B)

(C)

(D) 1

8) If A is a symmetric matrix and B is a skew symmetric matrix such that A + B = , then AB

is equal to _______.

(A)

(B)

(C)
(D)

9) Let A =
Given that AAT = I3, then value of P2 = _______.

(A)

(B)

(C)

(D)

10) Let A be a 3x3 matrix such that | adj (adj (adj (A))) | = 124. Then the value of | A-1 adj A | is _____.

(A)
(B)
(C) 12
(D) 1

11) If A = and | A3 | = 125

Then the product of the possible values of α is _____.

(A) - 25
(B) - 4
(C) - 9
(D) - 1

12) If A = and I =

and A-1 = (A2 + αA + βI) for some

α, β ϵR.
Then value of (α, β) order pair is

(A) (-6, -11)

(B) (6, 11)
(C) (-6, 11)
(D) (6, -11)
13) If = P and A = and Q = PAPT
and X = PTQ2025P. then the matrix X is given as _____.

(A)

(B)

(C)

(D)

14) then ‘a’ is equal to:

(A) 12
(B) 24
(C) -24
(D) -12

15) Let X and Y be two arbitary 3x3, non zero. Skew symmetric matrices and Z be an arbitary 3x3,
non zero, symmetric matrix. Then which of the following is skew symmetric matrix

(A) Y3Z4 - Z4Y3

(B) X44 + y44
(C) X4Z3 - Z3X4
(D) Z2025 + X2024

n n 2 2 2
16) If α, β 0, and f(n) = α + β and = K (1 – α) (1 – β) (α – β) , then K
is equal to

(A) 1
(B) - 1
(C) αβ

(D)

17) If A = and it satisfy

T
A. adj (A) = A.A , then 5a + b is equal to ________.
(A) 4
(B) 13
(C) -1
(D) 5

18) Let A is a 3x3 matrix and it is given that P = adj (A) and P =
If det (A) = 4 then the value of α is equal to ______.

(A) 4
(B) 11
(C) 5
(D) 0

19) Let A is a square matrix and det (A) 0 and the matrix A satisfy the equation
A2 - A + I = 0, where 0 = Null matrix, I = Identity matrix.
Then A-1 is ______

(A) A + I
(B) A
(C) A - I
(D) I - A

20) If then the value of

(A) depends only on n

(B) is independent of both a and n
(C) depends only on a
(D) depends both on a and n

SECTION-II

1) Let M be a 3x3 matrix satisfying

, and

Then the sum of main diagonal entries of M is _____.

2) The total number of distincts xϵR for which

3) How many 3 x 3 matrices M with entries {0, 1, 2} are there, For which the sum of the Main
diagonal entries of MTM is 5 _____.

4) Let M =

and adj M =
where a, b ϵ R
Find the value of a + b = _______.

5) Let A is a square matrix

Such that A2 = A and (I + A)5 = I + λA

Then the value of = ____

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A C A C D A C A C A B C A D C A B D B

SECTION-II

Q. 21 22 23 24 25
A. 3 4.00 4 6 1

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C C B C B D A B A B A D C D A B D C D

SECTION-II

Q. 46 47 48 49 50
A. 3 6 1 3 10.00

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A A B A D B C A C C C A B C A D B D B

SECTION-II

Q. 71 72 73 74 75
A. 9 2 198 3 9
 SOLUTIONS

PHYSICS

1) Electrons are move strongly bound with B than A

Also electrons are move strongly bound with A than C
Thus electrons will be more strongly bound with B than C

2)

6) Using Gauss’s law,

8) Flux coming out of the cube …(i)

and from sphere …(ii)

10)

Electric field =

= (independent of r.)

11)
12) By quantization of charge.

13) Density of field lines is proportional to field intensity.

17)

18)
An element is taken in the form of a ring of radius "r" and thickness "dr"
electric field at ring = E

E=
area of element (dA) = 2πrdr
flux through ring (dϕ) = EdA cosθ
dϕ =

tanθ = ⇒ r = a tan θ
dr = a sec2 θ .dθ

dϕ = =

dϕ =

ϕ= =

θ=

0
cos θ =

ϕ= =

2a = , 4a2 = a2 + R2, 3a2 = R2, a =

19)

QT =

21)

E|| =

E=
 22)

23)

qin = 10 µC + (–6 µC) = 4µC

⇒ lines associated = (4 × 10–6) (109) = 4 × 103

24)

p = mv = m at = Ft
p = q Et
= 2 × 6 × 0.5
= 6 kg m/s

CHEMISTRY

26) [Glucose] = = 1M

27)

28)

in air, atm
P = KH X (Henry's law)
0.8 = 2 × 104 .......(1)
4
0.2 = 10 .......(2)
Ratio of solubility of N2 & O2 is 2 : 1
29)

XA = 0.25
YA = 0.5

30)

PoA = 50mm , PoB = 30mm XA = 0.2

PT = PoAXA+PoBXB= 34mm

31)

HNO3 and H2O shows negative deviation from Raoult's law

32)

Al2(SO4)3 i = 5 BaCl2 i = 3
Na3PO4 i = 4 Glucose i = 1

33)

yA = ?

∴ XA =

YA = =

or, YA = = = 0.1

34)

PT = PAo + (PBo - PAo) XB

= 300 + 500 x 0.92
= 760mm = 1 atm
So, it shows negative deviation
from Raoult's law

35) Given
or
or PAXB > > PBXA
or PA(1-XA) > PBXA
or PA > PBXA + PAXA
or PA > (PA + PB)XA
or PA > PTXA

or

or

36)

GMM = 110

37) Henry's law,

Pi = KH.Xi; where;
Pi = partial pressure of gas above the liquid
Xi = mole fraction of gas in the liquid
KH = Henry's constant
substituting values in the expression; we get

⇒
= 7.2 × 10–3 bar = 720 Pa

38) If x gm of water got separated as ice; then molality of solution that freezes at –10°C is:

According to depression in freezing point,

ΔTf = Tf – Tf'
Tf = freezing point of pure solvent
Tf' = freezing point of solution
kf = cryoscopic constant or molal depression constant
m = molality of solution
i = Van't Hoff factor

⇒ ΔTf = 10k =
⇒ x = 64 gm

39)
Higher the concentration, greater will be the osmotic pressure.

40) According to depression in freezing point,

ΔTf = Tf – Tf'
Tf = freezing point of pure solvent
Tf' = freezing point of solution
Kf = cryoscopic constant or molal depression constant
m = molality of solution
i = Van't Hoff factor

Given: 2CH3COOH (CH3COOH)2 ; y =

⇒i=1+ α=1–

⇒ ΔTf = 0.45K =
⇒ α = 0.945

41) Van't Hoff factor (i) = 1 + (m - 1)α; where

m = total moles of product per mole of reactant
α = degree of dissociation
⇒ given: α = 0.4

⇒ i = 1 + (3 – 1) (0.4) = 1.8

42)

Solvent will more from low concentration to high concentration.

44)

Osmotic pressure and boiling point ∝ Net concentration of solute particles.

45) According to given data in question; it can be inferred that entire solute has undergone
trimerisation

⇒ 3A → A3 ⇒ ;α=1

46) ΔTb = i kb m
0.14 = (1 + α) × 0.5 × 0.25
α = 0.12
[H+] = 0.03 M

47)
 PT =

= 40 × + 30 × = 24 + 12 = 36 torr.

48)

49) π = iCRT
6 = [1 + α(3 – 1)] × 0.1 × 0.08 × 300

α = 0.75
p=3

50) Ans. (10)

π = iCRT

MATHS

51)

52)

53)
100 = 22.52
Number of divisors of 100 = 9,
So, answer is 9

54) On multiplications

55) Multiply by inverse

56)

57) | A |2 | B | = 8 -- (I)

-- (II)
Multiply
|A|3 = 64
|A| = 4
58)

59) AAT = I3

4q2 + r2 = 1
6q2 = 1

q2 =

2q2 - r2 = 0
r2 = 2q2

r2 =

P2 + q2 + r2 = 1

P2 =

60)

Both are correct but given in option is

61) | A | = 5
⇒ α2 - 4 = 5
⇒ α2= 9
⇒ α = 3, - 3
So, product of valves of α = - 9

62) Use characteristic Equation

|A - I | = 0

So,
Hence,

63) Here, PPT = I = PTP

Hence, X = PT (PAPT) ..... (PAPT)P
← 2025 ⇾
= A2025

64)

65) Let, A = X4Z3 - Z3X4

AT = Z3X4 - X4Z3
= - (A)
So skew symmetric.
But option A is symmetric.

66)

67) |A| = 10a + 3b

Again A.AT =
Compare b = 3
5a = 2
So, 5a + b = 5

68) |P| = 16
⇒ 2α - 6 = 16
⇒ α = 11

69) A2 - A + I = 0
Multiply by A -1
A - I + A -1 = 0
⇒ A-1 = I - A

70)
So value of determinant = 0

71) Let

Similarly get a and i

Now, a + e + i = 9

72)
Exactly two solution

73) MMT = Sum of diagonal entries

= a2+b2+c2 ....+i2 = 5
So, Possible combination

(I) {1, 1, 1, 1, 1, 0, 0, 0, 0, 0} =
(II) {1, 2, 0, 0, 0, 0, 0, 0, 0} =

74) -1 = 2 - 3b
⇒ 3b = 3
b=1

-6 = -3a
⇒a=2

75) (I + A)5 = I + 31A

λ = 31

So, =9