Nucle9986665
Nucle9986665
CHAPTER – 13
NUCLEI
In every atom, the positive charge and mass are densely No. of Protons, Electrons, nucleons and Neutrons in an
concentrated at the center of the atom forming its nucleus. Atom:
More than 99.9% mass of the atom is concentrated in the (a) Number of protons in an atom = Z
nucleus. (b) Number of electrons in an atom = Z
Composition Of Nuclei (c) Number of nucleons in an atom = A
the nucleus has two main components: protons and neutrons. (d) Number of neutrons in an atom = N = A – Z
The positively-charged entities are protons that are solely Isotopes –
present inside the nucleus and neutrons are neutral in charge The nuclides having the same atomic number (Z) but
and do not carry any charge. different mass number (A) are called isotopes.
Atomic number Isobars-
The total number of protons present inside a nucleus of an The nuclides having the same mass number (A), but different
atom is called atomic number. The atomic number is denoted atomic number (Z) are called isobars.
by the letter ‘Z’. Isotones-
Atomic mass The nuclides having the same number of neutrons (A–Z) are
The total combined number of neutrons and protons present called isotones.
inside a nucleus is called atomic mass. While calculating the Mass – Energy
mass of an atom, the mass of electrons should not be Einstein showed that mass is another form of energy and one
calculated; rather only the mass of neutrons and protons are can convert mass-energy into other forms of energy, say
taken into consideration. This is because the electrons are the kinetic energy and vice-versa. Einstein gave the famous mass-
lightest particles in a nucleus, and hence their mass is never energy equivalence relation E = mc2
considered while calculating atomic mass. The atomic mass Here the energy equivalent of mass m is related by the above
number is also known as mass number. The atomic mass equation and c is the velocity of light in vacuum and is
number is denoted by the letter ‘A’. approximately equal to 3×108 m s
It is the nearest integer value of mass represented in a.m.u.
(atomic mass unit). Nuclear Binding Energy
1 It is the minimum energy required to break the nucleus into
1 a.m.u. = [mass of one atom of 6C12 atom at rest and in its constituent particles.
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ground state] Or
= 1.6603 × 10–27 kg 931.478 MeV/c2 Amount of energy released during the formation of nucleus
mass of proton (mp) = mass of neutron (mn) = 1 a.m.u. by its constituent particles and bringing them from infinite
separation.
Binding Energy (B.E.) = mc2 Radioactivity
BE = m (in amu) × 931 MeV/amu It was discovered by Henry Becquerel. Spontaneous emission
= m × 931 MeV of radiations ( ) from unstable nucleus is called
Note radioactivity. Substances which show radioactivity are
known as radioactive substance. Radioactivity was studied
If binding energy per nucleon is more for a nucleus, in detail by Rutherford.
then it is more stable.
Law Of Radioactive Decay
When a radioactive material decays, the number of nuclei
Example decaying per unit time is proportional to the total number of
nuclei in the sample material. So,
If (
𝐵.𝐸1
)>(
𝐵.𝐸2
) If N is the total number of nuclei in the sample and ΔN is the
𝐴1 𝐴2 number of nuclei that decay in time Δt, then
then nucleus 1 would be more stable. 𝛥𝑁
∝ 𝑁
𝛥𝑡
𝛥𝑁
Or, = 𝜆𝑁
Variation of binding energy per nucleon with mass 𝛥𝑡
Q. For the 𝛽 + (positron) emission from a nucleus, there is another competing process known as electron capture
(electron from inner orbit, say, the K-shell is captured by the nucleus and a neutrino is emitted.
𝑒 − + AZ 𝑋 ⟶ AZ−1 𝑌 + 𝜈
Show that if 𝛽 + emission is energetically allowed, electron capture is necessarily allowed but not vice-versa.
Sol. Consider the two competing processes
Positron emission: ZZX X ⟶ AZ−1 Y + 𝑒 + + 𝜈 + 𝑄1 and
Electron capture, 𝑒 − + AZ X ⟶ AZ−1 Y + 𝜈 + 𝑄2
𝑄l = [𝑚𝑁 ( AZ X) − 𝑚𝑁 (z−1
A
Y) − 𝑚𝑒 ]𝑐 2
Converting nuclear masses into atomic masses
𝑄1 = [𝑚( AZ X) − 𝑍𝑚𝑒 − {𝑚(z−1 A
Y) + (Z − 1)𝑚𝑒 } − 𝑚𝑒 ]𝑐 2
= [𝑚( AZ X) − 𝑚( AZ−1 Y) − 2𝑚𝑒 ]𝑐 2
𝑄2 = [𝑚𝑁 ( AZ X) + 𝑚𝑒 − 𝑚𝑁 (z−1
A
Y)]𝑐 2
= [𝑚( AZ X) − 𝑚𝑒 + 𝑚𝑒 − {𝑚(z−1
A
Y) + (Z − 1)𝑚𝑒 }]𝑐 2
= [𝑚( AZ X) − 𝑚(z−1
A
Y)]𝑐 2
This means that 𝑄1 > 0 implies 𝑄2 > 0; but 𝑄2 > 0 does not necessarily imply 𝑄1 > 0. Thus if 𝛽 + emission is
energetically allowed, electron capture is necessarily allowed, but not vice-versa.
Q. The fission properties of 239 94 Pu are very similar to those of 235 92 U. The average energy released per fission is
180MeV. How much energy, in MeV, is released if all the atoms in 1 kg of pure 239 94 Pu undergo fission?
Sol. Average energy released per fission of 239
94 Pu, E av = 180MeV
Amount of pure 239 94 Pu, m = 1 kg = 1000 grams
Avogadro's number = NA = 6.023 × 1023
Mass number of 239 94 Pu = 239
Now, 1 mole of 239 94 Pu contains NA atoms. Therefore, ' m ' grams of 239 94 Pu will contain {(NA /Mass number)
× m} number of atoms, = [(6.023 × 1023 )/239] × 1000 = 2.52 × 1024 atoms.
Hence, total energy released during the fission of 1 kg of 239 94 Pu is:
𝐸 = 𝐸𝑎𝑣 × 2.52 × 1024
= 180 × 2.52 × 1024 = 4.536 × 1026 MeV
Mass Defect Nuclear fusion – energy generation in stars
It has been observed that there is a difference between It has been calculated that the sun radiates energy at the rate
expected mass and actual mass of a nucleus. of about 1026 J per second. The sun is radiating at this rate
Mexpected = Z mp + (A – Z)mn for several millions of years. The sources of energy of the sun
cannot be the chemical reactions because the energy released
Mobserved = Matom – Zme
in chemical reactions cannot last so long. It has also been
It is found that found that hydrogen and helium constitute about 90% of the
Mobserved < Mexpected mass of the sun and 10% are other elements. Since heavy
Hence, mass defect is defined as elements present in the sun are very small in quantity, so the
Mass defect = Mexpected – Mobserved source of energy of the sun cannot be nuclear fission. Fusion
∆m = [Zmp + (A – Z)mn] – [Matom – Zme] reactions are the source of energy in the sun and the stars,
inside which the temperature is of the order of 107 -108K. The
Nuclear Reactor basic energy-producing process in the sun is the fusion of
When 23592U undergoes a fission after being bombarded by a hydrogen nuclei and the same is true for many other stars.
neutron, it splits into two nuclei and releases a neutron. This The sequence of nuclear reactions is as follows:
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extra neutron now initiates the fission of another 23592U 6C + 1 H1 → 7 N13 + Q1 (MeV)
13
nucleus. For that matter, 2.5 neutrons are released per fission 7N → 6 C13 + 1 e0 + v
13
of a uranium nucleus. Also, fission produces more neutrons 6C 1
H → 7 N14 + Q 2 (MeV)
1
14
than what can be consumed. 7N + 1 H1 → 8 O15 + Q 3 (MeV)
15
This increases the chances of a chain reaction with each 8O → 7 N15 + 1 e0 + v
15
neutron that is produced, triggering another fission. If this 7N + 1 H1 → 6 C12 + 2 He4
chain reaction is uncontrolled, then it can lead to destruction Total energy released in this cycle = 𝟐𝟒. 𝟔𝟖MeV
(like a nuclear bomb). On the other hand, in a controlled The above combinations give:
1 4 0
manner, it can be harnessed to generate electric power. 4 H →2 He + 21 e + 2v + 2Y + 24.68MeV
12
The initial 6 C acts as a kind of catalyst for the process since
However, there was a small problem. The neutrons generated
it reappears at its end. The above stated thermo-nuclear
in fission were highly energetic. They would escape rather
reactions take place in the sun and other stars and hence they
than trigger another fission reaction. Also, it was observed are the source of energy in the solar system. Thus, energy
that slow neutrons have a higher possibility of inducing fission released by fusion is greater than the energy released by
in 23592U than their faster counterparts. fission.
Now, the energy of a neutron produced in fission of 23592U is
around 2 MeV. Unless these neutrons are slowed down, they DID YOU KNOW?
tend to escape without inducing fission. This simply means Because of very high temperature (∼107) needed for
that we need a lot of fissionable material to sustain the chain nuclear fusion cannot be attained by any known
reaction. method in the laboratory.
• Atomic Number: 4
He +94 Be →10 n +12
2 1 C
The number of protons in the nucleus is called the atomic
(c) A free neutron decays spontaneously, with a half- life
number. It is denoted by Z.
of about 900 s, into a proton, electron and an
• Mass number:
antineutrino.
The total number of protons and neutrons present in a
nucleus is called the mass number of the element. It is
1
0 n →11 H +0−1 e + v
denoted by A. • Size of the Nucleus:
• No. of Protons, Electrons, nucleons and Neutrons in (a) It is found that a nucleus of mass number A has a
an Atom: radius
(a) Number of protons in an atom = Z a. R = R0A1/3
(b) Number of electrons in an atom = Z Where, R0 = 1.2 x 10-15 m
(c) Number of nucleons in an atom = A (b) This implies that the volume of the nucleus, which is
(d) Number of neutrons in an atom = N = A – Z. proportional to R3 is proportional A.
• Nuclear Mass: • Density of the Nucleus:
The total mass of the protons and neutrons present in a Density of nucleus is constant; independent of A, for all
nucleus is called the nuclear mass. nuclei and density of nuclear matter is approximately 2.3
• Nuclide: x 1017 kg m−3 which is very large as compared to ordinary
A nuclide is a specific nucleus of an atom characterized matter, say water which is 103 kg m-3.
by its atomic number Z and mass number A. It is • Mass-Energy equivalence:
represented as, ZAA Einstein proved that it is necessary to treat mass as
another form of energy. He gave the mass-energy
Where X = chemical symbol of the element, Z = atomic
equivalence relation as,
number and A = mass number
E = mc2
• Isotopes: Where m is the mass and c is the velocity of light in
(a) The atoms of an element which have the same atomic vacuum.
number but different mass number are called • Mass Defect:
isotopes. The difference between the rest mass of a nucleus and the
(b) Isotopes have similar chemical properties but sum of the rest masses of its constituent nucleons is
different physical properties. called its mass defect. It is given by,
• Isobars: ∆m = [Zmp + (A− Z)mn] − m
The atoms having the same mass number but different • Binding Energy:
atomic number are called isobars. (a) It may be defined as the energy required to break a
• Isotones: nucleus into its constituent protons and neutrons
The nuclides having the same number of neutrons are and to separate them to such a large distance that
called isotones. they may not interact with each other.
• Isomers: (b) It may also be defined as the surplus energy which the
These are nuclei with same atomic number and same nucleus gives up by virtue of their attractions which they
mass number but in different energy states. become bound together to form a nucleus.
• Electron Volt: (c) The binding energy of a nucleus ZXA is,
It is defined as the energy acquired by an electron when B.E. = [Zmp + (A− Z)mn – m]c2
it is accelerated through a potential difference of 1 volt • Binding Energy per Nucleon:
and is denoted by eV. It is average energy required to extract one nucleon from
• Atomic Mass Unit: the nucleus.
(a) It is
1
th of the actual mass of a carbon atom of It is obtained by dividing the binding energy of a nucleus
12 by its mass number.
isotope 6C12. It is denoted by amu or just by u. 𝐵.𝐸 [𝑍𝑚𝑝 +(𝐴−𝑍)𝑚𝑛 −]𝑐 2
(b) 1 amu = 1.660565 X 10-27 kg 𝐵̄ = =
𝐴 𝐴
(c) The energy equivalence of 1 amu is 1 amu = 931 MeV • Nuclear Forces:
• Discovery of Neutrons: (a) These are the strong in attractive forces which hold
(a) Neutrons were discovered by Chadwick in 1932. protons and neutrons together in a tiny nucleus.
(b) When beryllium nuclei are bombarded by alpha- (b) These are short range forces which operate over very
particles, highly penetrating radiations are emitted, short distance of about 2 – 3 fm of separation
which consists of neutral particles, each having mass between any two nucleons.
nearly that of a proton. These particles were called (c) The nuclear force does not depend on the charge of
neutrons. the nucleon.
• Nuclear Density: • Half-life:
The density of a nucleus is independent of the size of the The half-life of a radioactive substance is the time in
nucleus and is given by, which one-half of its nuclei will disintegrate. It is
Nuclear mass inversely proportional to the decay constant of the
𝜌𝑣 =
Nuclear volume
𝑚𝑣 radioactive substance.
=4 = 2.9𝑥10 kg𝑚−3
17
𝜋𝑅 2 0.693
•
3
Radioactivity:
T1/2 =
(a) It is the phenomenon of spontaneous disintegration • Mean Life:
of the nucleus of an atom with the emission of one or The mean-life of a radioactive sample is defined as the
more radiations like α -particles, β -particles or γ - ratio of the combined age of all the atoms and the total
rays. number of atoms in the given sample. It is given by,
(b) The substances which spontaneously emit
T1/2
penetrating radiation are called radioactive = = 1.44T1/2
substances. 0.693
• Radioactivity Displacement Law: • Rate of Decay or Activity of a Radioactive Sample:
It states that, It is defined as the number of radioactive disintegrations
(a) When a radioactive nucleus emits an α -particle, taking place per second in a given sample. It is expressed
atomic number decreases by 2 and mass number as,
decreases by 4. dN
(b) When a radioactive nucleus emits β -particle, its R(t ) = = N (t ) = N (0)e− t
atomic number increases by 1 but mass number dt
remains same. • Curie:
(c) The emission of a γ -particle does not change the (a) It is the SI unit of decay.
mass number or the atomic number of the (b) One curie is the decay rate of 3.7 X 1010
radioactive nucleus. The γ -particle emission by a disintegrations per second.
radioactive nucleus lowers its energy state. • Rutherford:
• Alpha Decay: One Rutherford is the decay rate of 106 disintegrations
It is the process of emission of an α -particle from a per second.
radioactive nucleus. It may be represented as, • Natural Radioactivity:
A
X→ A− 4
Y + He + Q
4 It is the phenomenon of the spontaneous emission of-α, β
Z Z −2 2
and γ radiations from the nuclei of naturally occurring
• Beta Decay:
isotopes.
It is the process of emission of an electron from a
• Artificial or Induced Radioactivity:
radioactive nucleus. It may be represented as,
𝐴 𝐴 0 It is the phenomenon of inducing radioactivity in certain
𝑍 𝑋 →𝑍+ 1 𝑌+− 1 𝑒 + 𝑣̄ stable nuclei by bombarding them by suitable high
• Gamma Decay: energy sub atomic particles.
It is the process of emission of a γ -ray photon during the • Nuclear Reaction:
radioactive disintegration of a nucleus. It can be It is a reaction which involves the change of stable nuclei
represented as, of one element into the nucleus of another element.
A
Z X → A
Z X + • Nuclear Fission:
(Excited State) (Ground State) It is the process in which a heavy nucleus when excited
• Radioactive Decay Law: gets split into two smaller nuclei of nearly comparable
It states that the number of nuclei disintegrated of masses. For example,
undecayed radioactive nuclei present at that instant. It 235
92 U +10 n →141
56 Ba +36 Kr + 30 n + Q
92 1
means light nuclei are less stable than that of For 64 Cu, 𝑅 = 𝑅0 𝐴1/3 = 1.2 (64)1/3 = 4.8 fm
intermediate nuclei. As 35Cl has a large binding S3. We have, 𝑃 = 200 MW = 200 × 106 W = 2 ×
energy therefore it cannot be used as fuel for 108 W, 𝑡 = 1ℎ = 3600 s
fusion energy. As, energy, 𝐸 = 𝑃 × 𝑡 = 2 × 108 × 36000
S3. (d) We know that energy is released when heavy Also, 𝐸 = 𝑚𝑐 2
𝐸 2 × 108 × 3600
nuclei undergo fission or light nuclei undergo ⇒ 𝑚= =
𝑐2 (3 × 108 )2
fusion. Therefore statement (1) is correct. The = 8 × 10−6 kg
second statement is false because for heavy nuclei
the binding energy per nucleon decreases with S4. Velocity ratio (𝑣1 : 𝑣2 ) = 2 : 1
increasing Z and for light nuclei, B.E/nucleon Mass (𝑚) ∝ Volume ∝ 𝑟 3 .
increases with increasing Z. According to law of conservation of momentum,
𝑚1 𝑣1 = 𝑚2 𝑣2
𝑣1 𝑚2 𝑟23
SHORT ANSWER QUESTIONS Therefore
𝑣2
=
𝑚1
=
𝑟13
𝑟1 𝑣 1/3 1 1/3 1
S1. (i) Basic nuclear reaction for 𝛽 + decay is the Or = ( 2) =( ) =
𝑟2 𝑣1 2 21/3
conversion of proton to neutron. Or 𝑟1 : 𝑟2 = 1 : 21/3
𝑝 → 𝑛 + 𝑒+ + v
(ii) (a) 𝑥 = 𝛽 + / 10 𝑒, 𝑦 = 5, 𝑧 = 11 S5. Given, 𝑡1/2 = 2.2 × 109 s
(b) 𝑎 = 10, 𝑏 = 2, 𝑐 = 4 and rate of radioactive disintegration,
𝑑𝑁
= 1010 s −1
S2. Properties of nuclear forces 𝑑𝑡
0.693 0.693
(1) Nuclear forces are the strongest attractive ∴ 𝜆= = = 3.15 × 10−10 s −1
𝑡1/2 2.2×109
forces. Now, we know that, 𝑁 = 𝑁0 𝑒 −𝜆𝑡
(2) Nuclear forces are short ranged upto 10–15 m. 𝑑𝑁
⇒ = −𝜆𝑁0 𝑒 −𝜆𝑡 = −𝜆𝑁
(3) Nuclear forces are charge independent 𝑑𝑡
⇒ 1010 = 3.15 × 10−10 × 𝑁 ⇒ 𝑁 = 3.17 × 1019
S3. Initial binding energy
𝐵𝐸1 = (2.23 + 2.23) = 4.46MeV S6. In two half-lives, the activity becomes one fourth.
Final binding energy Activity on 1 - 8 - 91 was 2 micro curies.
𝐵𝐸2 = 7.73MeV ∴ Activity before two months,
∴ Energy released = (7.73 − 4.46)MeV = 4 × 2 micro-Curie = 8 micro curies
3.27MeV S7. There is requirement of three half-lives so age of
S4. Protons are positively charged and repel one the rock
another electrically. This repulsion becomes so 𝑡 = 𝑛𝑇1/2 = 3 × 20 years = 60 years
great in nuclei with more than 10 protons or so, 𝑁 1 𝑛
that an excess of neutrons which produce only S8. = ( ) ; 𝑛 → no. of decays
𝑁0 2
attractive forces, is required for stability. 1 1 8 1 𝑛
=( ) =( ) ∴𝑛=8
256 2 2
S5. The daughter nucleus would have a higher Time for 8 half-life = 100 hours
binding energy per nucleon.
𝑁 1 𝑛
S9. =( )
𝑁0 2
NUMERICAL TYPE QUESTIONS where 𝑛 is number of half lives
1 1 𝑛 1 4 1 𝑛
∴ = ( ) or ( ) = ( ) or 𝑛 = 4
S1. The average atomic mass of a chlorine atom is 16 2 2 2
obtained by the weighted average of the masses Let the age of rock be 𝑡 years.
𝑡
of the two isotopes, which is ∵ 𝑛=
𝑇1/2
Average atomic mass or 𝑡 = 𝑛𝑇1/2 = 4 × 50 years = 200 years
75.4×34.98+24.6×36.98
= 𝑡 6400
100 S10. Number of half-lives, 𝑛 = = =8
= 35.47 𝑢 𝑇 800
𝑁 1 8 1
=( ) =
𝑁0 2 256