SAFETY DATA SHEET according to Regulation (EC) No.

1907/2006

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Version 3 / IRL Revision Date: 19.12.2023
102000037803 Print Date: 26.02.2024

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Trade name ROUNDUP XL
UFI KPF1-E0Y7-K009-RH2Q
Product code (UVP) 86789574

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Herbicide

1.3 Details of the supplier of the safety data sheet

Supplier Bayer CropScience Ltd
Bayer Ltd
1st Floor, The Grange Offices
The Grange, Brewery Road
Stillorgan
A94 H2K7 Co. Dublin
Ireland
Telephone +353 1 216 3300

Responsible Department Email: gb-bcs-crop-regulatory-affairs@bayer.com

1.4 Emergency telephone no.

Emergency telephone no. 00800 1020 3333 (24 hr) (not available on non-contract mobile phones)

For Medical Professionals: You can also contact Dublin NPIS.

For Members of the Public: You can also contact 01 809 2166 (for Republic of Ireland).

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
Eye irritation: Category 2
H319 Causes serious eye irritation.
Chronic aquatic toxicity: Category 2
H411 Toxic to aquatic life with long lasting effects.
2.2 Label elements
Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and
packaging of substances and mixtures, as amended.
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Hazard label for supply/use required.

Signal word: Warning

Hazard statements
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
EUH401 To avoid risks to human health and the environment, comply with the instructions for
use.
Precautionary statements
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P234 Keep only in original container.
P305 + P351 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
+ P338 present and easy to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/ attention.
P501 Dispose of contents/container to a licensed hazardous waste disposal contractor or
collection site, except for triple rinsed empty containers which can be disposed of as
non-hazardous waste.
2.3 Other hazards
No additional hazards known beside those mentioned.
Potassium salt of glyphosate: This substance is not considered to be persistent, bioaccumulative and
toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

Ecological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f)
or Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f)
or Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures
Chemical nature
Soluble concentrate (SL)
Potassium salt of Glyphosate 441 g/l
Hazardous components
Hazard statements according to Regulation (EC) No. 1272/2008
Name CAS-No. / Classification Conc. [%]
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EC-No. / REGULATION (EC) No

REACH Reg. No. 1272/2008
Potassium salt of 70901-12-1 Aquatic Chronic 2, H411 35.5
glyphosate
Fatty alkyl ether alkyl 68478-96-6 Acute Tox. 4, H302 > 1 – < 10
amine ethoxylate Eye Dam. 1, H318
Aquatic Chronic 2, H411
Further information

For the full text of the H-Statements mentioned in this Section, see Section 16.

Particle characteristics
This substance/ mixture does not contain nanoforms

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice Move out of dangerous area. Place and transport victim in stable
position (lying sideways). Remove contaminated clothing immediately
and dispose of safely.
Inhalation Move to fresh air. Keep patient warm and at rest. Call a physician or
poison control center immediately.
Skin contact Wash off immediately with plenty of water for at least 15 minutes. Take
off contaminated clothing and shoes immediately. Get medical
attention if irritation develops and persists.
Eye contact Rinse immediately with plenty of water, also under the eyelids, for at
least 15 minutes. Remove contact lenses, if present, after the first 5
minutes, then continue rinsing eye. Get medical attention if irritation
develops and persists.
Ingestion Do NOT induce vomiting. Rinse mouth. Call a physician or poison
control center immediately.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms Skin, eye and mucous membrane irritation
4.3 Indication of any immediate medical attention and special treatment needed
Risks This product is not a cholinesterase inhibitor.
Treatment Appropriate supportive and symptomatic treatment as indicated by the
patient's condition is recommended. Treatment with atropine and
oximes is not indicated. There is no specific antidote.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable Use water spray, alcohol-resistant foam, dry chemical or carbon
dioxide.
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Unsuitable High volume water jet

5.2 Special hazards arising In the event of fire the following may be released:, Carbon monoxide
from the substance or (CO), Carbon dioxide (CO2), Nitrogen oxides (NOx), Oxides of
mixture phosphorus
5.3 Advice for firefighters
Special protective In the event of fire and/or explosion do not breathe fumes. In the event
equipment for firefighters of fire, wear self-contained breathing apparatus.
Further information Contain the spread of the fire-fighting media. Do not allow water to
come into direct contact with the product.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Precautions Avoid contact with spilled product or contaminated surfaces. Use
personal protective equipment.

6.2 Environmental Do not allow to get into surface water, drains and ground water.
precautions
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid
binder, universal binder, sawdust). Collect and transfer the product
into a properly labelled and tightly closed container. Clean
contaminated floors and objects thoroughly, observing environmental
regulations.

6.4 Reference to other Information regarding safe handling, see section 7.

sections Information regarding personal protective equipment, see section 8.
Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling Ensure adequate ventilation. Avoid contact with skin, eyes and clothing.
Hygiene measures Avoid contact with skin, eyes and clothing. Keep working clothes
separately. Wash hands before breaks and immediately after handling
the product. Wash hands immediately after work, if necessary take a
shower. Remove soiled clothing immediately and clean thoroughly
before using again. Garments that cannot be cleaned must be
destroyed (burnt).
7.2 Conditions for safe storage, including any incompatibilities
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Requirements for storage Store in original container. Store in a cool, dry place and in such a
areas and containers manner as to prevent cross contamination with other crop protection
products, fertilizers, food, and feed. Store in a place accessible by
authorized persons only. Reacts with galvanised steel or unlined mild
steel to produce hydrogen, a highly flammable gas that could explode.
Protect from frost. Partial crystallization may occur on prolonged storage
below the minimum storage temperature. Freezing will affect the
physical condition but will not damage the material. Thaw and mix
before using.
Advice on common storage Keep away from food, drink and animal feedingstuffs.
Suitable materials HDPE (high density polyethylene)
HDPE - steel case
7.3 Specific end use(s) Refer to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

No known occupational limit values.

8.2 Exposure controls

Personal protective equipment
In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the
following recommendations would apply.
Respiratory protection Respiratory protection is not required under anticipated
circumstances of exposure.
Respiratory protection should only be used to control residual risk of
short duration activities, when all reasonably practicable steps have
been taken to reduce exposure at source e.g. containment and/or
local extract ventilation. Always follow respirator manufacturer's
instructions regarding wearing and maintenance.

Hand protection Please observe the instructions regarding permeability and

breakthrough time which are provided by the supplier of the gloves.
Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion, and the
contact time.
Wash gloves when contaminated. Dispose of when contaminated
inside, when perforated or when contamination outside cannot be
removed.
Material Nitrile rubber
Rate of permeability > 480 min
Glove thickness > 0.4 mm
Protective index Class 6
Directive Protective gloves complying with EN
374.
Eye protection Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).
Skin and body protection Wear standard coveralls and Category 3 Type 6 suit.
If there is a risk of significant exposure, consider a higher protective
type suit.
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Wear two layers of clothing wherever possible. Polyester/cotton or

cotton overalls should be worn under chemical protection suit and
should be professionally laundered frequently.
If chemical protection suit is splashed, sprayed or significantly
contaminated, decontaminate as far as possible, then carefully
remove and dispose of as advised by manufacturer.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Form Liquid, clear to slightly turbid

Colour yellow to amber
Odour slight amine odour
Odour Threshold No data available
Melting point/range Not applicable
Boiling Point No data available
Flammability No data available
Upper explosion limit No data available
Lower explosion limit No data available
Flash point does not flash
Auto-ignition temperature No data available

Self-accelarating No data available

decomposition temperature
(SADT)
pH 4.5 - 5.5 (10 g/l) (23 °C) (deionized water)
Viscosity, dynamic 8.0 mPa.s (20 °C)
Viscosity, kinematic No data available
Water solubility miscible

Partition coefficient: n- Potassium salt of glyphosate: log Pow: < -3.2 (25 °C)
octanol/water

Vapour pressure No data available

Density 1.25 g/cm³ (20 °C)
Relative density No data available
Relative vapour density No data available
Assessment nano particles This substance/ mixture does not contain nanoforms

Particle size No data available

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9.2 Other information

Explosivity Not explosive

Oxidizing properties No data available
Evaporation rate No data available
Other physico-chemical Further safety related physical-chemical data are not known.
properties

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity Stable under normal conditions.

Self heating not self-heating
10.2 Chemical stability Stable under recommended storage conditions.

10.3 Possibility of Reacts with galvanised steel or unlined mild steel to produce hydrogen,
hazardous reactions a highly flammable gas that could explode.

10.4 Conditions to avoid Extremes of temperature and direct sunlight.

10.5 Incompatible materials Unlined mild steel, Carbon steel, Galvanised steel
Store only in the original container.

10.6 Hazardous No decomposition products expected under normal conditions of use.

decomposition products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on hazard classes as defined in regulation (EC) No 1272/2008

Acute oral toxicity LD50 (Rat) > 5,000 mg/kg

Test conducted with a similar formulation.
Acute inhalation toxicity LC50 (Rat) > 5.05 mg/l
Exposure time: 4 h
Test conducted with a similar formulation.
Acute dermal toxicity LD50 (Rat) > 5,000 mg/kg
Test conducted with a similar formulation.
Skin corrosion/irritation Slight irritant effect - does not require labelling. (Rabbit)
Test conducted with a similar formulation.
Serious eye damage/eye Severe eye irritation. (Rabbit)
irritation Test conducted with a similar formulation.
Respiratory or skin Skin: Non-sensitizing. (Guinea pig)
sensitisation OECD Test Guideline 406, Buehler test
Test conducted with a similar formulation.
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Assessment STOT Specific target organ toxicity – single exposure

Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment STOT Specific target organ toxicity – repeated exposure
Potassium salt of glyphosate did not cause specific target organ toxicity in experimental animal studies.
Assessment mutagenicity
Potassium salt of glyphosate is not considered mutagenic.
Assessment carcinogenicity
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment toxicity to reproduction
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Assessment developmental toxicity
Potassium salt of glyphosate: Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
11.2 Information on other hazards

Endocrine disrupting properties

Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish LC50 (Cyprinus carpio (Carp)) 12 mg/l
Exposure time: 96 h
Test conducted with a similar formulation.
Chronic toxicity to fish Brachydanio rerio (zebrafish)
NOEC: 1.0 mg/l
Exposure time: 7 d
The value mentioned relates to the active ingredient glyphosate.
Toxicity to aquatic EC50 (Daphnia magna (Water flea)) 56 mg/l
invertebrates Exposure time: 48 h
Test conducted with a similar formulation.

Toxicity to aquatic plants EC50 (Selenastrum capricornutum (green algae)) 14 mg/l

Exposure time: 72 h
Test conducted with a similar formulation.
NOEC (Selenastrum capricornutum (green algae)) 2.0 mg/l
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Exposure time: 72 h
Test conducted with a similar formulation.
NOAEC (Lemna gibba (gibbous duckweed)) < 0.42 mg/l
Exposure time: 7 d
Test conducted with a similar formulation.
12.2 Persistence and degradability
Biodegradability Potassium salt of glyphosate:
Not readily biodegradable.
Koc Potassium salt of glyphosate: Koc: 884
12.3 Bioaccumulative potential
Bioaccumulation Potassium salt of glyphosate: Bioconcentration factor (BCF) < 1
12.4 Mobility in soil
Mobility in soil Potassium salt of glyphosate: Variable, depends on temperature, soil
type, soil moisture, soil pH and organic matter content.
12.5 Results of PBT and vPvB assessment
PBT and vPvB assessment Potassium salt of glyphosate: This substance is not considered to be
persistent, bioaccumulative and toxic (PBT). This substance is not
considered to be very persistent and very bioaccumulative (vPvB).
12.6 Endocrine disrupting properties
Assessment The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or
Commission Delegated regulation (EU) 2017/2100 or Commission
Regulation (EU) 2018/605 at levels of 0.1% or higher.
12.7 Other adverse effects
Additional ecological No other effects to be mentioned.
information

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product In accordance with current regulations and, if necessary, after
consultation with the site operator and/or with the responsible authority,
the product may be taken to a waste disposal site or incineration plant.
Contaminated packaging Triple rinse containers.
Do not re-use empty containers.
Not completely emptied packagings should be disposed of as
hazardous waste.
Waste key for the unused 02 01 08* agrochemical waste containing hazardous substances
product

SECTION 14: TRANSPORT INFORMATION

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ADR/RID/ADN
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES
Hazard no. 90
Tunnel Code -

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please
refer to the manufacturer for further information.

IMDG
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION)
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Marine pollutant YES

IATA
14.1 UN number 3082
14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(GLYPHOSATE POTASSIUM SALT SOLUTION )
14.3 Transport hazard class(es) 9
14.4 Packaging Group III
14.5 Environm. Hazardous Mark YES

14.6 Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to IMO instruments

No transport in bulk according to the IBC Code.

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Republic of Ireland Regulations
This material may be subject to some or all of the following regulations (and any subsequent
ammendments). Users must ensure that any uses and restrictions as indicated on the label and/or
leaflet are followed.
Supply and Use
European Communities (Prohibition of Certain Active Substances in Plant Protection Products)
Regulations 1981 (SI No 320/1981)
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European Communities (Authorization, Placing on the Market, Use and Control of Plant Protection
Products) Regulations 2003 (SI No 83/2003)
European Communities (Classification, Packaging and Labelling of Plant Protection Products and
Biocide Products) Regulations 2001 (SI No 624/2001
2010 Code of Practice for the Safety, Health and Welfare at Work (Chemical Agents) Regulations, 2001
(SI No 619/2001)
Waste Treatment
Landfill Directive
Regulation on Substances That Deplete the Ozone Layer 1994 (EEC/3093/94)
Further information
WHO-classification: U (Unlikely to present acute hazard in normal use)

15.2 Chemical safety assessment

A chemical safety assessment is not required.

SECTION 16: OTHER INFORMATION

Text of the hazard statements mentioned in Section 3

H302 Harmful if swallowed.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.
Abbreviations and acronyms
ADN European Agreement concerning the International Carriage of Dangerous Goods by
Inland Waterways
ADR European Agreement concerning the International Carriage of Dangerous Goods by
Road
ATE Acute toxicity estimate
CAS-Nr. Chemical Abstracts Service number
Conc. Concentration
EC-No. European community number
ECx Effective concentration to x %
EINECS European inventory of existing commercial substances
ELINCS European list of notified chemical substances
ELV Exposure Limit Value
EN European Standard
EU European Union
IATA International Air Transport Association
IBC International Code for the Construction and Equipment of Ships Carrying Dangerous
Chemicals in Bulk (IBC Code)
ICx Inhibition concentration to x %
IMDG International Maritime Dangerous Goods
LCx Lethal concentration to x %
LDx Lethal dose to x %
LOEC/LOEL Lowest observed effect concentration/level
MARPOL MARPOL: International Convention for the prevention of marine pollution from ships
N.O.S. Not otherwise specified
NOEC/NOEL No observed effect concentration/level
OECD Organization for Economic Co-operation and Development
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RID Regulations concerning the International Carriage of Dangerous Goods by Rail

SI Statutory Instrument
TWA Time weighted average
UN United Nations
WHO World health organisation

The above information is intended to give general health and safety guidance on the storage and
transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any
appropriate technical usage literature available should be consulted and any relevant licenses,
consents or approvals complied with.
The requirements or recommendations of any relevant site or working procedure, system or policy in
force or arising from any risk assessment involving the substance or product should take precedence
over any of the guidance contained in this safety data sheet where there is a difference in the
information given.
The information provided in this safety data sheet is accurate at the date of publication and will be
updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account of
information or advice contained in this safety data sheet.

Reason for Revision: The following sections have been revised: Section 2: Hazards
Identification. Section 12. Ecological information. Section 14: Transport
Information.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.