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ConciseChemistryWorkbook2

The document is a chemistry workbook that covers topics such as the periodic table, chemical reactions, and factors affecting reaction rates. It includes sections with fill-in-the-blank questions, true or false statements, and prompts for writing chemical equations. The workbook is designed for educational purposes and was authored by Okoye Ebelechukwu Ifeoma.

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0% found this document useful (0 votes)
2 views

ConciseChemistryWorkbook2

The document is a chemistry workbook that covers topics such as the periodic table, chemical reactions, and factors affecting reaction rates. It includes sections with fill-in-the-blank questions, true or false statements, and prompts for writing chemical equations. The workbook is designed for educational purposes and was authored by Okoye Ebelechukwu Ifeoma.

Uploaded by

anyakahc
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© © All Rights Reserved
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Concise Chemistry Workbook 2

Book · January 2012

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Okoye Ebelechukwu Ifeoma


Chukwuemeka Odumegwu Ojukwu University
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1
CHAPTER 1
THE PERIODIC TABLE

Section A
1. ____________________ is a table of elements arranged in order of their
increasing atomic number.
2. A Russian Chemist named ________________________________ was
the man who created the modern periodic table.
3. Modern periodic table is divided into vertical columns called
__________________ and horizontal row called __________________
4. ________________ is a vertical column in the periodic table containing
elements with the same number of electrons in the outermost shell.
5. A _________________________ is a horizontal elements with the same
number of shells.
6. Write True or False in the space provided:
a. Elements in the same group have similar chemical properties ________
b. The elements in period one have only 1 main shell and elements in
period three have 3 main shells ________________________________
c. The number of the group indicates the number of electrons in the
outermost shell of the elements in the group ______________________
7. The group 1 elements are called the _____________________________
8. Two group 1 elements I know are:
(a) __________________________ (b) _________________________
9. The group 2 elements are known as the __________________________

10. Two group 2 elements are:


2
(a)___________________________ (b)_________________________
11. Group 2 elements have the valency of ___________________________
12. Group VII elements are called the ______________________________
13. Inert gases, rare gases or noble gases are the names called the group
______________ elements.

Section B
1. Periodic law states that the
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
2. The periodic table contains _____________ vertical columns called the
groups and the horizontal columns called the _____________________
3. ______________________ is the regular patterns or trends in which the
physical and chemical properties of element occurs when the elements
are arranged according to their atomic number in the periodic table.
4. Other trends in properties of the elements down the groups and across
the periods of the periodic table includes: the following: atomic volume,
atomic and ionic radii, ionization energy or ionization potential, electron
affinity and electro-negativity.
a. The ease with which an atom in a molecule attracts the shared electron
to itself is known as _________________________________________
b. ________________________________ is the energy released when an
electron is added to a gaseous atom to form a gaseous ion.

3
c. The energy required to remove an electron from a gaseous atom to
produce a gaseous ion is called ________________________________
d. _______________________ is the distance from the nucleus of an atom
to the outermost shell.
e. __________________ is the volume occupied by 1 mole of the element.
5. Electronegativity is the chemical opposite of _____________________
6. The ratio of the relative atomic mass of an element to its density is
known as its _______________________________________________
7. S block elements are groups __________ and _____________ elements.
Write ‘True’ or ‘False’ in the space provided for you;
8. Rare gases are said to be very stable because:
a. they are very reactive _______________________________________
b. they are polyatomic _________________________________________
c. they have eight electrons in their outermost shell __________________
d. they are very unreactive _____________________________________
e. they are diatomic __________________________________________

CORRECTION: CHAPTER 1; Section A - B

4
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_
5
CHAPTER 2
CHEMICAL REACTIONS/REACTANTS AND PRODUCTS

Section A
1. Types of chemical reactions are:
(a) __________________________(f)________________________
(b) __________________________(g)________________________
(c) __________________________(h)________________________
(d) __________________________(i)________________________
(e) __________________________ (j)________________________
2. When two or more substances combine to form a single substances, the
type of chemical reaction taking place is_________________________
3. ___________________ reaction occurs when a compound splits up into
simpler substances.
4. _____________________ reaction occurs when one element (or group)
takes the place of another element (or group) in a compound.
5. _____________________ reaction is the one which can be made to go
in both forward and backward direction.
6. A reversible reaction brought about by the application of heat is called
__________________________________________________________
7. A chemical reaction in which two compounds taking part in the reaction
are decomposed and two new substances formed by an exchange of
radicals is called____________________________________________
8. ______________________ reaction occurs when the rate of a chemical
reaction is altered by an agent caused by a catalyst.
9. A substance which alters the rate of a chemical reaction but remains
chemically uncharged at the end of the reaction is called a___________

6
10. Write down a catalyst for the given common catalytic reactions.
a. 2KCl03 2KCl + 3O2 Catalyst ____________________________

b. N2 (g) + 3H2(g) 2NH3 (g) Catalyst______________________


Catalyst = _________________________________________________
11. ____________________ catalyst lowers the rate of a chemical reaction.
12. __________________ catalyst increases the rate of a chemical reaction.
13. is the sign of ______________________________________

Section B
1. Oxidation occurs when:
a. oxygen is added to a substance. True or False?____________________
b. oxygen is removed from a substance. True or False?________________
c. hydrogen is removed from a substance. True or False?______________
d. hydrogen is added to a substance. True or False?___________________
e. there is increase in oxidation number of a substance. True or
False?____________________________________________________
f. there is an increase in oxidation number of a substance. True or
False?____________________________________________________
2. Reduction occurs when:
a. oxygen is added to a substance. True or False?____________________
b. oxygen is removed from a substance True or False?________________
c. hydrogen is removed from a substance. True or False?______________
d. hydrogen is added to a substance. True or False?___________________
e. there is an increase in oxidation number of a substance. True or False?
__________________________________________________________
f. there is a decrease in oxidation number of a substance. True or False?
__________________________________________________________

7
3. Oxidation is the process of electron loss but reduction is the process of
electron gain. True or False?___________________________________
4. Oxidation is the opposite of reduction. True or False?_______________
5. The reaction which involves both reduction and oxidation reactions is
known as___________________________________________reaction.

6. A+B AB. This reaction is an example of___________ reaction.


7. An organic catalyst is called an_________________________________
8. Write the type of reaction that has taking place in each of the following
equations:
a. Fe(g) + S(s) FeS(s) ___________________________________
b. 2Pb (NO3)2 (s) heat 2Pb O(s) + O2 (g) _______________________
c. 2KClO2 (s) heat 2KCl (s) 3O2(g) _____________________________
MnO2
d. Zn (s) + CuSO4 (aq) ZnSO4 + Cu _________________________
e. AgNO3 + Nacl Agcl + NaNO3 _______________________
f. N2 (g) + 3H2 (g) iron 2NH3(g) ____________________________
g. 2S02 (g) + O2 (g) V2O5 SO3 (g) ______________________________
h. NH4Cl heat NH3 (g) ___________________________________
i. CaCO3 (s) CaO (s) + CO 2 (g) ___________________________
9. An oxidizing agent is a substance which adds oxygen to another
substance or removes hydrogen from that substance. True or
False?____________________________________________________
10. A reducing agent is a substance which adds hydrogen to another
substance or removes oxygen from that substance. True or
False?____________________________________________________

8
Section C
RATE OF CHEMICAL REACTION AND FACTORS AFFECTING IT

1. The field of study concerned with the rate of chemical reaction is


known as _________________________________________________
2. ______________________________________________ is the amount
in moles of reactants converted to product per unit time.
3. The number of moles of product formed per unit time is known as the
__________________________________________________________
4. The factors which affect the rate of a chemical reaction are:
(a) ____________________________ (e) __________________________
(b) ____________________________ (f) ___________________________
(c) ____________________________ (g) __________________________
(d) __________________________________________________________
5. Write „A‟ in the box provided if you agree with the statement or write
„D‟ if you disagree with it.
a. If a solid substance is in powdered form, the reaction occurs faster than
if the solid is in lumps.
b. Grinding a solid into powder exposes the reacting particles in the solid
and increases the surface area of the solid.
c. A positive catalyst increases the rate of a chemical reaction.
d. A positive catalyst increases the activation energy of the reactants.
e. A positive catalyst reduces the activation energy of the reacting
molecules.

9
f. Light is a source of energy and influences the rate of some chemical
reactions.
g. Catalyst changes the energy of activation.
h. Temperature changes the energy content of the particles and frequency of
collision.

Section D
COLLISION THEORY: ENERGY AND REACTION RATES
1. Write True or False in the space provided: According to the collision
theory;
a. For a chemical reaction to occur, the reacting particles must collide and
the collision must be effective _________________________________
b. The rate of a reaction therefore depends on frequency of effective
collision __________________________________________________
c. Chemical reaction involves breaking of bonds and formation of new
bonds ____________________________________________________
2. The energy barrier which the reacting particles must posses in order to
react is known as the ____________________________ of the reaction.

3. Activated Complex

EA

Hr
ΔH = - Ve
Hp

10
i. The above diagram is called an ________________________________
ii. If the reacting particles acquire enough activation energy, an unstable
compound called ___________________________________ is formed.
iii. In the above diagram;
EA means _________________________________________________
Hr means _________________________________________________
Hp means _________________________________________________
ΔH means _________________________________________________
4. Write „A‟ in the box provided if you agree with the statement or write
„D‟ if you disagree with it.
a. A reaction with low activation energy will take place spontaneously at
low temperature.
b. If the energy of the colliding molecule is less than the activation energy,
no reaction will occur.
c. A reaction with low activation energy will take place at high
temperature.
d. A reaction with high activation energy will take place if energy is
supplied usually in form of heat, electrical or light energy.

11
Section E
EXOTHERMIC AND ENDOTHERMIC REACTION AND ALSO ENERGY
PROFILE
1. A reaction in which heat is liberated to the surrounding is called an
__________________________________________________________

2.
Activated Complex

EA
Energy H

ΔH = - Ve

a. The diagram is an energy profile for an __________________ reaction.


b. In __________________________ reaction, the total heat content of the
product is less than that of the reactants.
c. The ΔH for an exothermic reaction is ___________________________

Activated Complex
3.

EA
Energy H

ΔH = - Ve

12
a. This diagram is an energy profile for an _________________ reaction.
b. The total heat content of the product is more than that of the reactants in
an __________________________ reaction.
c. The ΔH for an endothermic reaction is _________________________
4. In endothermic reaction, the total heat content of the product is more
than that of the _____________________________________________
5. ________________________ is the heat content of a body or a system.
6. Enthalpy is represented by the symbol __________________________
7. The change in energy or enthalpy is represented as ΔH (Delta ΔH)
Δ means _________________________________________________
8. Standard ____________ is the heat change accompanying the formation
of 1 mole of a compound from its elements in their standard states.
9. The state in which an element is at 1 atmosphere and 250C is called its
__________________________________________________________
10. The instruments used for measuring heat change is called ___________
11. The heat change accompanying the complete combustion of 1 mole of a
substance in oxygen is known as enthalpy of _____________________
12. ___________________________ is the heat evolved or absorbed when
1 mole of a substance is dissolved in so much water that further dilution
results in no detectable heat change.
13. The amount of heat evolved when one mole of water is formed from a
neutralization reaction between an acid and an alkali, is known as
__________________________________________________________
14. _____________________________ is the amount of heat evolved when
one mole of hydrogen ions, H+, from an acid reacts with one mole of
hydroxide ions, OH-, from an alkali to form one mole of water.

13
Section F
1.

E1
Chemical Energy H

Reactants E2
Hr
ΔH = -Ve
Hp
Products
Reaction Time

Write True or False in the space provided.


For all reactions:
a. E1 is greater than E2 _________________________________________
b. E1 is smaller than E2 _________________________________________
c. Addition of catalyst has no effect on Hr _________________________
d. Addition of catalyst has no effect on Hp _________________________
e. Addition of catalyst has positive or negative effect on Hr and Hp _____
f. Addition of catalyst lowers the activation energy __________________

g. The key means what? _____________________________

h. The key means what? _____________________________

CALCULATION OF ENTHALPY CHANGE:


2. Calculate the enthalpy change accompanying the following reaction
given that;
ΔH0F of C2H2 = +227Kjmole–1
ΔH0F of C2H4 = + 52.3KJ mole-1
C2H2(g) + H2(g) C2H4(g)

14
_________________________________________________________
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__________________________________________________________

3. 2S02 (g) + O2(g) 2SO3 ΔH = -196KJ mol-1


Given that H0F of SO2 = -297 KJ mole-1 Calculate the heat of
formation of sulphur (vi) oxide.
__________________________________________________________
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__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
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15
4. 2SO2 (g) + O2 (g) 2SO3 (g)
Given that
H0f SO2 = -297 KJ mole-1
H0f SO3 = 395 KJ mole-1
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
5. Calculate the heat of formation of carbon(iv) oxide given that
CO (g) + O2(g) CO2(g) ΔH = -285kg mol-1 and
Hof CO = -108KJ mol-1
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
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__________________________________________________________
__________________________________________________________
__________________________________________________________
6. Calculate the enthalpy change for this reaction
2NO(g) + O2(g) 2NO2(g)
Hfo NO2 = 34 KJ mol-1
Hfo NO = +90.3 KJ mol-1

16
_________________________________________________________
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Section G
SPONTANEITY OF REACTION ENTROPY AND FREE ENERGY:
1. _______________________ is the degree of disorderliness of a system.
2. Measure of the randomness or mixed-upness of the molecules of a
substance is referred to as ____________________________________
3. Entropy is represented with the letter ___________________________
4. The entropy of a substance can be increased by;
a. __________________________________________________________
b. __________________________________________________________
c. __________________________________________________________
d. __________________________________________________________
e. __________________________________________________________
5. ΔS means _________________________________________________
6. If q is the heat absorbed by 1 mole of a substance at Kelvin temperature
T, it follows that:
q = ΔS
T

17
a. Make q the subject of this equation.
__________________________________________________________
__________________________________________________________
__________________________________________________________
b. Make T the subject of the equation
__________________________________________________________
__________________________________________________________
7. The total heat energy of a substance is called its ___________________
8. The heat energy of a substance that can be converted into useful work is
called ____________________________________________________
9. ΔG means _________________________________________________
10. For changes carried out at constant temperature and pressure:
ΔH - ΔG = ΔT S
a. Make ΔG the subject of the equation
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
11. A chemical reaction is probable only if the value of ΔG is __________
12. The reaction is in equilibrium if ΔG is __________________________
13. For any reaction which has ΔH positive and ΔS negative, the ΔG must
be________________________________________________________
14. The reaction is not possible if ΔG is ___________________________

18
Section H
SYSTEMS IN EQUILIBRIUM AND FACTORS AFFECTING THEM,
LE CHATELIER’S PRINCIPLE.

1. Define chemical equilibrium


__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
2. Define „a reversible‟ reaction;
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
3. Write True or False in the space provided the;
The system in equilibrium possesses the following:
a. Equilibrium Constant ___________________________________
b. Equilibrium mechanism _________________________________
c. Rate of backward reaction ________________________________
d. Rate of forward reaction _________________________________
e. Rate of constant proportion ______________________________
f. ΔG = O _____________________________________________

19
4. Write True or False in the space provided for you; At equilibrium,
a. the two opposing reactions go on at unequal rates _________________
b. the two opposing reactions go on at equal rates ____________________
c. there is a slight net change in the amounts of substances involved _____
d. there is no net change in the amounts of substances involved _________
e. there is a remarkable change in the amounts of substances involved ___

5. A B + C is a reversible reaction
a. The rate of backward reaction can be represented mathematically as
__________________________________________________________
b. The rate of forward reaction can be represented as
__________________________________________________________
6. State Le Chatelier‟s principle
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
7. A reaction is said to be in a dynamic equilibrium when; _____________
__________________________________________________________
__________________________________________________________

20
Section I
1. What is equilibrium constant?
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
2. A B + C. At equilibrium K1 [A] = K2 [B] [C]
a. K1 means _________________________________________________
b. Means ___________________________________________________
c. [A] means ________________________________________________
d. Make K1 the subject of the equation; __
__________________________________________________________
__________________________________________________________
__________________________________________________________
e. Make K2 the subject of the equation;
__________________________________________________________
__________________________________________________________
__________________________________________________________
3. Three factors that affect the position of equilibrium are:
a. ______________________________ b. _______________________
c. ________________________________________________________
4. For endothermic reactions; increase in temperature will favour the
_________________________ reaction.

21
5. For exothermic reactions, lowering the temperature will favour the
________________________ reactions.
6. For uptimum yield of NH3, high pressure of about _________________
atmosphere is required.
7. Pressure change will have no effect on equilibrium where there is
________________________ in the number of molecules (left to right).
8. N2(g) + 3H2(g) 2NH3(g).
a. Decrease in pressure will cause the production of more _______________
in the equilibrium mixture.
b. Increase in pressure will cause the production of more _______________
in the equilibrium mixture.
9. i. 3 Fe(s) + 4H2O(g) Fe3O4(s) + 4H2(g)
Steam Hydrogen
4 moles 4 moles
ii. H2(g) + I2(g) 2HI(g)
1 mole 1mole 2 moles
a. Increase in the pressure of equation (i) will have ______________
on the position of equilibrium.
b. Decrease in pressure of equation (i) will have _________________
on the position of equilibrium.
c. Increase in the pressure of equation (ii) will have _____________
on the position of equilibrium.
10. Two ways of favouring the forward reaction are:
a. _______________________________________________________
_______________________________________________________
_______________________________________________________
b. _______________________________________________________
_______________________________________________________
_______________________________________________________

22
CORRECTION: CHAPTER 2; Section A – I
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23
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24
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25
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26
CHAPTER 3
MASS-MOLE, MASS-VOLUME RELATIONSHIP

Section A
1. How many moles are in 15.0g of carbon atom? [C = 12]
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
2. If 0.123 mole of an element X weighs 8.0g, what is the relative atomic
mass of X?
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________

3. Zinc react with copper (ii) tetraoxosulphate (vi) according to the following
equation:
Zn(s) + CuSO4(aq) → ZnSO4(aq) + Cu(s)

(a) State the type of chemical reaction involved:_________________________


(b) Determine the amount of zinc, that would react completely with 48.0g of
copper(ii)tetraoxosulphate (vi). [CuSO4 = 160; Zn = 65]

27
___________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
4. When 10.0g of razor blade completely reacted with an excess solution of
hydrochloric acid, 0.110 mole of FeCl2 was obtained. Calculate the mass of
iron in the razor blade. [Fe = 56]
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________

Section B
1. A solution contains 1.0g of pure NaOH in 250cm3 of solution. Calculate its
concentration in (a) gdm-3, (b) moldm-3 [NaOH = 40g mol-1].
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
28
___________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
2. Calculate the mass of anhydrous Na2CO3 present in 25.0cm3 of 0.100mol
dm-3.
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
3. In the creation:
Zn(s) + HCl(aq) → ZnCl2(aq) + H2(g)
(a) Interpret the reaction in terms of moles.
(b) How many moles of the metal will react with three moles of hydrogen gas?
(c) How many moles of hydrochloric acid will produce three moles of
hydrogen gas?
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
29
___________________________________________________________
____________________________________________________________
____________________________________________________________
4. A contains 2.5g of HCl in 250cm3 of solution; B contains 8.5g of HCl in
1dm3 of solution. Which solution is more concentrated and why?
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________

CORRECTION: CHAPTER 3; Section A – B


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30
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31
CHAPTER 4
ACID/BASE TITRATION
Section A
1. A substance which in aqueous solution ionizes to produce oxonium ion
as the only positive ion is called an_____________________________
2. A substance which can combine with oxonium ion is called a_________
3. Neutralization reaction is correctly represented as follows:
H30+Cl-(aq) + K+0H-(aq) K+Cl-(aq) + 4H20(1)
(H30+)2 S02-4(aq) + 2(Na+0H- Na2+S02-4(aq) + 4 H20(1)
From these chemical equation, write the formula of
a. Potassium chloride __________________________________________
b. Aqueous hydrochloric acid ___________________________________
c. Aqueous tetraoxosulphate (vi) acid _____________________________
d. Aqueous sodium tetraoxosulphate (vi) __________________________
4. ____________________ is the estimation of the volume of an acid that
will neutralize a given volume of a base.
5. The point at which an acid completely neutralized a base is known as
the _______________________________________________________
6. A solution of known concentration is called a_____________________
7. A substance that shows one colour in an acid and another in a base is
called the _________________________________________________
8. Four equipment we use in the chemistry laboratory for acid/base
titration are
(a)___________________________ (c)_________________________
(b)___________________________ (d)_________________________
9. Pipette is used to measure the _________________________________
10. The colour of methyl orange in:
(a) Acid solution is_____________________________________________
(b) Basic solution is____________________________________________
(c) Neutral solution is___________________________________________

32
CORRECTION: CHAPTER 4; Section A
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33
CHAPTER 5
SOLUTION
Section A
1. ___________________________ is a uniform or homogenous mixture
of solute and solvent.
2. ________________________ is the substance that dissolves in solvent.
3. Solvent is a substance that dissolves ____________________________
4. Write True or False in the space provided:
a. The most common solvent in nature is water _____________________
b. Water is usually referred to as a universal solvent __________________
c. Water is ionic in its molecular structure _________________________
d. An aqueous solution is a resultant solution formed when a solid
dissolves in water ___________________________________________
5. Two types of solution are (a) _________________ (b) ______________
6. Water as a solvent is used in laundries and dry cleaners. True or False?
__________________________________________________________
7. In most chemical reactions, water being the common solvent serves as a
very suitable medium. True or False? __________________________
8. True solution is formed when solute is completely dissolved in
___________________ to form a homogeneous mixture.
9. The solutes that form true solutions are called ____________________
10. Write True or False in the space provided.
a. Two examples of crystalloid are NaCl and CuSO4 _________________
b. An example of colloid is starch ________________________________
c. An example of crystalloid is starch _____________________________
d. False solution is also called colloidal solution _____________________

34
11. A heterogeneous mixture of undissolved particles in a given medium is
called a ___________________________________________________
12. Three differences between true and false solutions are:

TRUE SOLUTION FALSE SOLUTION


1. ______________________ ________________________
______________________ ________________________
______________________ ________________________
______________________ ________________________
2. ______________________ ________________________
______________________ ________________________
______________________ ________________________
______________________ ________________________
3. ______________________ ________________________
______________________ ________________________
______________________ ________________________
______________________ ________________________

Section B
SOLUBILITY
1. A _____________________ of a solute in a solvent is a solution which
contains as much solute as it can dissolve at a particular temperature in
the presence of undissolved solute particles.
2. A solution which contains more of the solute than it can normally hold
at a particular temperature is called a ____________________________
3. An _________________________ is a solution which does not contain
as much solute as it can dissolve at that temperature.

35
4. The maximum amount of solute in moles that will saturate 1dm3 of the
solvent at a given temperature is known as the _________________ of a
solute in a solvent.
5. Write True or False in the space provided.
a. Increase in temperature generally increases the solubility of the
substances. ________________________________________________
b. The solubility of gases decrease with increase in temperature ________
6. If 50g of calcium trioxocarbonate (iv) saturate 500cm3 of water at 600C,
calculate the solubility of the salt at that temperature.
(Ca = 40, C = 12, 0 = 16)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
7. How many grams are there in 0.5 mole of tetraoxosulphate (vi) acid
(H = 1, S = 32, 0 = 16)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

36
_________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
8. Graphs of Solubility

70- KNO3

60- NaCl

50-
Solubility/mol dm-3

KCl
40-

30-

20-

10-

0-
100C 200C 300C 400C
Temperature

a. The salt which its solubility increases most rapidly with rise in
temperature is ______________________________________________
b. The salt, which shows little or no change in solubility with rise in
temperature, is _____________________________________________
c. Which of the salts – KNO3 and KCl has greater solubility at 100C?
__________________________________________________________
d. KNO3 and KCl do have the same solubility at the temperature of
__________________________________________________________

37
CORRECTION: CHAPTER 5; Section A – B
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38
CHAPTER 6
AIR AND FLAME
Section A
1. Air is a mixture of _____________________________________________
2. The constituents of air are:
(a)____________________________ (d)___________________________
(b)____________________________ (e)___________________________
(c)__________________________________________________________
3. The percentage composition of:
(a) oxygen in air is _____________________________________________
(b) nitrogen in air is ____________________________________________
4. Write “True” or “False” in the space provided.
(a) Air can be represented by a chemical formula_____________________
(b) Air cannot be represented by a chemical formula___________________
(c) Air has no mass_____________________________________________
(d) Air occupies space__________________________________________
5. The products of burning or combustion are:
(a)___________________________ (c) ____________________________
(b) __________________________ (d) ____________________________
6. The four zones of a luminous Bunsen flame are:
(a)___________________________ (c) ____________________________
(b) __________________________ (d) ____________________________
7. The region of incomplete combustion is known as the _________________
8. The region of complete combustion is called the _____________________

39
9. Tick “ ” or “X” in the boxes provided.
(a) A luminous zone is hotter than the non luminous zone
(b) Non luminous zone is hotter than the luminous zone
(c) Luminous bunsen flame produce more soot than the non luminous
bunsen flame
(d) Luminous zone is cleaner than the non luminous zone
10. While cooking it is advisable to use _______________________________
(a) Luminous flame (b) Non luminous flame

CORRECTION: CHAPTER 6; Section A


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40
CHAPTER 7
HYDROGEN
Section A
1. When metals react with dilute mineral acids,_________ gas is liberated.
2. Metals which occur below hydrogen in the activity series will not
liberated it from acids. True or False?___________________________
3. Zn + HCl ___________________________________ + H2
4. A mixture of hydrogen and air explode with a pop sound when flame is
applied True or False?________________________________________
5. Write down a chemical equation to show:
a. The burning of hydrogen in air to form
water._____________________________________________________
b. The reduction of lead II oxide to lead by
hydrogen,_________________________________________________
6. Write the products of these reaction:
a. H2 + Cl2 _________________________________________
b. Na + H2 _________________________________________
c. N2 + H 2 _________________________________________
7. Copper cannot displace hydrogen from an acid or water because______
__________________________________________________________
8. A binary compound of hydrogen is known as _____________________

CORRECTION: CHAPTER 7; Section A


__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
41
CHAPTER 8
OXYGEN, OXIDE
Section A
1. 2KClO3 MnO2 _________________________________________

a. this reaction can be used in the preparation of the gas______________


b. manganese (iv) oxide is acting as a _____________________________
2. Oxygen rekindles a growing splint of wood. True or False?__________
3. A binary compound of oxygen is known as an_____________________
4. A basic oxide is a metallic oxide which reacts with an acid to produce
________________________ and __________________________only
5. Four important types of oxide are
(a)_________________________(c)____________________________
(b)_________________________(d)____________________________
6. Two examples of basic oxide are:
(a)_________________________ (b)___________________________
7. Write the products of these reactions:
a. SO2 + H2O ___________________________________
b. CO2 + H2O ___________________________________
8. SO2 and CO2 are examples of___________________________ Oxide.
9. Two examples of amphoteric oxides are:
(a)___________________________ (b)_________________________
10. Carbon (ii) oxide and dinitrogen (i) oxide are examples of a
___________________oxide
11. The volume of oxygen in the atmosphere is_______________________

42
CORRECTION: CHAPTER 8; Section A
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43
CHAPTER 9
HALOGEN
Section A
1. Write „A‟ in the box provided if you agree with the statement or write
„D‟ if you disagree with it.
a. Chlorine is a halogen.
b. Halogens are the non-metals that form the group 7 of the
periodic table.
c. Flourine, Chlorine, Bromine, Iodine and Astatine are the
halogens.
d. Halogens have 8 electrons each in their outermost shell.
e. The halogens exist as diatomic molecules.
f. The halogens are univalent and form electrovalent compounds with
metals and covalent compounds with hydrogen.
2. Being electron acceptors, the halogens are strong __________________
3. Hydride is a binary compound of _______________________________
4. The hydrides of the halogens are gases at room temperature and they
dissolve easily in water to form strong __________________________
5 (i) MnO2 + 4HCl MnCl2 + H2O + Cl2
(ii) 2KMnO4 + 16HCl 2MnCl2 + 2KCl + 8H2O + 5Cl2
a. The above two equations represent the laboratory method of preparing
__________________ gas.
b. The oxidizing agents in the above equation are ____________________
and ______________________
c. In the equation, concentrated hydrochloric acid is oxidized to
__________________________________________________________

44
6. Write True or False in the space provide
a. Cl2 is used as a germicide and disinfectant ________________________
b. Cl2 is used in the sterilization of public water supply ________________

Section B
LAB. PREPARATION OF HYDROCHLORIC ACID (HCl)

1. Hydrochloric acid is prepared in the laboratory by the action of conc.


H2SO4 on _________________________________________________
2. Hydrogen chloride gas is dried using conc. _______________________
3. The solution of hydrogen chloride gas in water is called ____________
4. Hydrogen chloride gas react with ammonia to form white dense fumes
which consist of solid particles of ______________________________
5. Hydrogen chloride dissolve in water to form _____________________
6. Write the products of these reactions:
a. Zn(s) + HCl (aq) ___________________________________
b. CaO + HCl (aq) ___________________________________
c. NaOH + HCl (aq) ___________________________________
d. Na2CO3 (s) + HCl (aq) ___________________________________
e. AgNO3 (aq) + HCl (aq) ___________________________________
7. Hydrochloric acid reacts with a base or alkali to produce ____________
and _____________________ only.
8. Hydrochloric acid reacts with trioxocarbonate (iv) to liberate ________

45
CORRECTION: CHAPTER 9; Section A – B
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46
CHAPTER 10
NITROGEN

Section A
1. The percentage of nitrogen in the atmosphere is ___________________
2. Nitrogen is prepared in the laboratory from air and from decomposition
of ammonium dioxonitrate (iii). True or False? ___________________
3. The chemical formula of ammonium dioxonitrate (iii) is ____________
4. The nitrogen prepared from air is denser than the one prepared from
ammonium dioxonitrate (iii) because it contains ___________________
5. The boiling point of liquid nitrogen is ___________________________
6. Nitrogen is prepared in the industry by ________________ of liquid air.
7. Write the products of these reaction:
a. Mg3N2(s) + H2O(l) Mg(OH)2 + __________________________
b. Mg + N2 ___________________________________________
c. N2(g) + H2(g) __________________________________
8. Two uses of nitrogen are:
a. __________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
b. __________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

47
Section B
AMMONIA
1. In the laboratory, ammonia is prepared by heating any ammonium salt
with any __________________________________________________
2. Ammonia is dried with _______________________________________
3. Ammonia is not dried by usual drying agent such as concentrated
H2SO4 and Fused CaCl2 because they_______________with ammonia.
4. Ammonia gas is collected by upward delivery because it is __________
than air.
5. Write the product of these reactions:
a. NH3(g) + H2SO4(aq) __________________________________
b. NH3(g) + CaCl2(s) __________________________________
c. Ca(OH)2 + NH4Cl CaCl2 + H2O + __________________
6. In the industrial preparation of ammonia by Haber process, ammonia
gas is prepared by direct combination of _________________________
and ___________________________
7. Special conditions necessary for the optimum yield of ammonia are:
a. __________________________________________________________
b. __________________________________________________________
c. __________________________________________________________
8. In the Haber process, nitrogen and hydrogen are mixed in the volume
ratio of ___________________________________________________
9. Ammonia is a colourless gas with a chocking smell. True or False?
________________

48
10. NH3 is an alkaline gas and turns wet red litmus paper blue. True or
False? ___________________
11. One test of ammonia is that it:
a. Forms black dense fumes with concentrated hydrochloric acid. True or
False? ___________________
b. Forms white dense fumes with concentrated hydrochloric acid, True or
False? ___________________
12. Ammonia undergoes thermal decomposition at a high temperature to
yield __________________________ and _______________________

Section C
OXIDES OF NITROGEN
1. Five oxides of nitrogen are:
(a) ______________________________ (d) ________________________
(b) ______________________________ (e) ________________________
(c) ______________________________
2. The chemical formula of an oxide of nitrogen with:
a. +3 oxidation number ________________________________________
b. +5 oxidation number ________________________________________
3. Dinitrogen (i) oxide rekindles a bright glowing splinter. True or False?
__________________________________________________________
4. Nitrogen (ii) oxide is a neutral oxide. True or False? _______________
5. Write the products of these reactions. Balance the equations too.
a. NO + O2 _________________________________________
b. Cu + NO CuO + ______________________________

49
6. Nitrogen (iv) oxide is a:
a. Colourless gas. True or False? ________________________________
b. Reddish brown gas. True or False? _____________________________
7. NO2 gas turns wet blue litmus paper red. True or False? ____________
8. NO2 is a mixed acid anhydride. True or False? ___________________
9. Write the products of these reactions. Balance the equations too.
a. Pb (NO3)2 heat Pb + NO2 + _____________________________

b. NO2 + H2O __________________ + ________________


10. HNO2 (acid) is easily oxidized to HNO3 in the presence of __________

Section D
TRIOXONITRATE (V) ACID

1. An acid anhydride of trioxonitrate (v) acid is _____________________


2. Laboratory preparation of trioxonitrate (v) acid can be represented with
this chemical equation. _______________________________________
3. HNO3 is a:
a. Weak acid. True or False? ____________________________________
b. Strong acid. True or False? __________________________________
4. The apparatus used in the preparation of HNO3 must all be
_____________ because the acid vapour rapidly attack rubber and cork.
5. Trioxonitrate v acid is a powerful oxidizing agent. True or False?
_________________________

50
6a. HNO3 + H2O __________________ + _______________
b. NaOH + HNO3(aq) _________________ + ______________
c. CaCO3(g) + HNO3(aq) Ca(NO3)2 + H2O + ______________
7. The brown ring test is a popular test use for the identification of
____________________ ion.
8. One way by which atmospheric nitrogen is:
a. being removed from the atmosphere is by ________________________
b. being re-introduced into the atmosphere is by _____________________
9. Ammonium trioxonitrate (v) decomposes to water and dinitrogen (i)
oxide True or False? _________________________________________
10. Complete the following decomposition reaction:
a. 2KNO3(s) 2KNO2(g) + ______________ (g)
b. 2AgNO3(s) + 2_________ + 2___________ + __________ (l)
11. The sign in question 10 a – b means ___________________________

Section E
NITROGEN CYCLE
1. Nitrogen cycle is a continuous process by which the atmospheric
nitrogen enter into the soil as the soil nitrates, followed by continuous
decomposition of these nitrates to release nitrogen back into the
__________________________________________________________
2. Write True or False in the space provided.
a. All living cell is made of protoplasm which is merely protein _________
b. The major constituent of protein is nitrogen _______________________

51
c. Animal cannot make their protein but depend on plant or by eating other
animals _____________________________________________________
d. Animals can make or manufacture their protein _____________________
e. Plants make their protein from simpler nitrogenous compound _________
f. Plants cannot make use of the free atmospheric nitrogen rather they use
ammonium salt or nitrate which they absorb from the soil _____________
3. Write the product of these reactions which occur during nitrogen cycle.
a. N2 + O 2 2
__________________________________________
b. NO + O2 2
__________________________________________
c. 4NO2 + O2 +H2O ___________________________________
4
d. HNO3 + Na+ ____________________________________
4. _____________________ bacteria converts the nitrogenous compounds
in the soil to free nitrogen.

CORRECTION: CHAPTER 10; Section A – E


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54
CHAPTER 11
SULPHUR ALLOTROPES; PREPARATION, PROPERTIES AND
USES: COMPOUNDS OF SULPHUR

Section A
1. In the periodic table, sulphur is in the group ______________________
and period ________________________________________________
2. Solid sulphur is ____________________________________ in colour.
3. The boiling point of sulphur is ______________________________ 0C
4. Write the product of direct combination of these metals with sulphur, in
the absence of air:
a. Na(s) + S(s) ____________________________________(s)
b. Zn(s) + S(s) ____________________________________(s)
c. 2Cu(s) + S(s) ____________________________________(s)
5. Write the products of these reaction
a. O2(g) + S(s) ___________________________________
b. H2(g) + S(s) ___________________________________
c. C(s) + S(s) ___________________________________
6. Reaction of sulphur with oxidizing acids:
S(s) + 2H2SO4 3SO2 + 2H2O
i. In the reaction sulphur is oxidized to _______________________ while
H2SO4 is reduced to _________________________________________
S(s) + 6HNO3 Br2 H2SO4 + 6NO2 + 2H2O
ii. In this reaction, sulphur is oxidized to ___________________________
7. Sulphur exists in ______________________________ allotropic forms.

55
8. Three other elements that can show allotropy are: (a) _____________
(b) __________________________ (c) _________________________
9. The allotropes of sulphur are:
(a) ____________________________ (c) __________________________
(b) ____________________________ (d) _________________________
10. The only stable allotrope of sulphur at temperature bellow 960C is
__________________________________________________________
11. The only stable allotrope of sulphur at temperature between 960C and
1190C is __________________________________________________
12. Whether sulphur exist as the Rhombic or Monoclinic allotropes is
dependent on ______________________________________________
13. Two main crystalline allotropes of sulphur are (a) _________________
(b) __________________________
14. Two main non-crystalline allotropes of sulphur are:
(a) ___________________________ (b) ________________________
15. Hydrogen sulphide smells like a _______________________________

Section B
HYDROGEN SULPHIDE
1. In the laboratory, H2S is prepared by the action of dil HCl on ________
2. If H2S gas is required dry, it is passed through fused _______________
3. Since H2S gas is denser than air, it is collected by _________________
delivery in fume chamber.
4. H2S gas is tested in the laboratory by dipping into the gas a stripe of
filter paper soaked in;

56
(a) ________________________________________________ solution or
(b) __________________________________________________ solution.
5. Write a balanced chemical equation to show what happens when dilute
hydrochloric acid reacts with iron (ii) sulphide ____________________
6. Pb (NO3)2(aq) + H2S(g) PbS + 2HNO3
(a) (b) (c) (d)
i. The colour of (c) is __________________________________________
ii. IUPAC name of (c) is _______________________________________
iii. IUPAC name of (a) is _______________________________________
7. Pb (CH3COO)2(aq) turns black in the presence of H2S gas due to the
formation of _______________________________________________
8. Write True or False in the space provided
a. H2S is a colourless gas with a repulsive smell similar to that of a rotten
egg. ______________________________________________________
b. H2S is a powerful reducing agent _______________________________
9. 2 FeCl3(aq) + H2S 2FeCl2(aq) + 2Hclaq + S(s)
In this reaction, FeCl3 is reduced to (a) ____________________ while
H2S is oxidized to (b) ________________________________________
10. Cl2 + H2S(g) 2HCl + S
a. In this reaction ___________________________ is an oxidizing agent.
b. _________________________________________ is a reducing agent.
11. ______________________________ is a device designed for obtaining
intermittent supplies of a frequently used gas such as H2, CO2 or H2S.

57
Section C
OXIDES OF SULPHUR; TRIOXOSULPHATE (IV) ACID AND
TRIOXOSULPHATE (VI) SALTS
1. Sulphur (iv) oxide is prepared industrially by the burning of sulphur in
air or _____________________________________________________
2. In the laboratory _____________________ (gas) is readily generated by
heating potassium or sodium trioxosulphate (iv) with concentrated
hydrochloric acid or tetraoxosulphate (vi) acid.
3. Sulphur (iv) oxide dissolves in water to form _________________ acid.
4. Sulphur (iv) oxide is an ________________ of trioxosulphate (iv) acid.
5. Sodium trioxosulphate (iv) reacts with concentrated tetraoxosulphate
(vi) acid to yield ____________________________ (gas) when heated.
6. Complete and balance these equations:
i. Cu(s) + 2H2SO4(aq) CuSO4(aq) + ________(l) + __________(g)
ii. SO32- (aq) + 2H+ (aq) H2O(L) + _______________________(g)
7. SO2 being acidic in nature reacts with alkalis to form a normal salt and
water only. Then complete.
i. 2NaOH(aq) + SO2(g) ______________________(aq) + H2O(l)
8. Alkalis react with excess sulphur (iv) oxide to form an acid salt only.
Then complete.
i. NaOH(aq) + SO2(g) ________________________________(aq)
excess
ii. KOH(aq) + SO2(g) ________________________________(aq)
excess

58
9. Sulphur (iv) oxide is a strong reducing agent in the presence of water:.
In this reaction,
i. 2MnO4(aq) + 5SO2(g) + 2H2O(L) 2Mn2+(aq) + 5SO42-(aq) + 4H+(aq)
manganate (vii) solution is reduced to ____________________ by SO2.
ii. Cr2O72-(aq) + 3SO2(g) + 2H+(aq) 2Cr3+(aq) + 3SO42-(aq) + H2O(l)
SO2 reduced _____________________ to ______________________
iii. 2Fe3+(aq) + SO2(g) + 2H2O(l) 2Fe2+(aq) + SO42-(aq) + 4H+(aq)
SO2 reduced _____________________ to _______________________

Section D
1. PbO2 (s) + SO2(g) PbSO4(s)
A B C
a. The IUPAC nomenclature of compound A is ________________ while
compound C is _____________________________________________
b. 2SO2 + O2 2SO3
A B
The IUPAC nomenclature of Compound B is _____________________
2. 2SO2 + O2 3SO3
In the above reaction, a good yield of sulphur (vi) oxide requires the
presence of a catalyst like (a) _______________________________ or
(b) _______________________________________________________
3. SO2 which is a strong reducing agent in the presence of water can also
act as an oxidizing agent in the presence of a stronger reducing agent.
In this equation:

59
i. 2H2S + SO2 2H2O + 3S
H2S is a ______________ agent while SO2 is an _____________ agent
ii. C + SO2 CO2 + S
C is ________________ agent while SO2 is ________________ agent.

4. Write True or False in the box provided:


a. Trioxosulphate (iv) acid is an unstable acid formed when sulphur (iv)
oxide dissolves in water.
b. Trioxosulphate (iv) acid has never been obtained pure (free from water)
because any attempt to do so will result in its decomposition.
H2SO3(aq) SO2(g) + H2O(l)
c. Trioxosulphate (iv) acid is dibasic.
d. Sulphur (vi) oxide (SO3) is an acidic oxide.
e. SO3 combines exothermically with water to form tetraoxosulphate (vi)
acid.
f. Trioxosulphate (iv) acid ie H2SO3 being dibasic, ionizes as follows:
H2SO3 HSO3- + H+ OR H2SO3 SO32- + 2H+

Section E
TETRAOXOSULPHATE (VI) ACID AND ITS SALTS
1. The product of these reactions are:
a. H2O(l) + SO3(g) ___________________________________
b. SO3(g) + H2SO4(aq) ___________________________________
c. 2H2SO3(aq) + O2(g) 2________________________________(aq)

60
2. H2SO3 is an unstable dibasic acid but H2SO4 is a ________ dibasic
acid.
3. H2SO3 and H2SO4 acids being dibasic in nature can form two series of
salts. Write the product of these reactions and balance the equations:
a. NaOH + H2SO3 _________________ + _______________
limited
b. 2NaOH + H2SO3 __________________ + _______________
excess
c. NaOH + H2SO4 __________________ + _______________
limited
d. 2NaOH + H2SO4 __________________ + _______________
excess
4. H2SO4 as a dehydrating agent can remove molecule or molecules of
water from compounds like sugar and ethanol, thus decomposing them.
Write the product of these reactions:
a. C12H22O11 (s) -11H2O ___________________________(s)
Sugar (Conc. H2SO4) Sugar Charcoal

b. CH2 – H -H2O __________________________(g)


(Conc. H2SO4) ethene

CH2 – OH
c. In another form of dehydration, the water of crystallization is removed
from a compound so that the compound becomes anhydrous, e.g. in the
dehydration of copper (ii) tetraoxosulphate (vi) pentahydrate. Write the
product of this reaction:
CuSO4 .5H2O -5H2O ____________________________
blue (Conc. H2SO4) white
(hydrated form) (anhydrous form)

61
5. Write True or False in the space provided
a. H2SO4 acid is used as an electrolyte in lead accumulators and
batteries.
b. H2SO4 is used as a dehydrating agent.
c. MgSO4 and ZnSO4 are prepared by the action of dilute tetraoxosulphate
(vi) acid on Magnesium and Zinc metals respectively.

6. Test Observation Inference


Unknown soln + dil.HCl A white precipitate of SO42-suspected
or dil HNO3 + Bacl2 soln BaSO4 is formed
or Ba(NO3)2 soln.
White precipitate + White precipitate is SO42- confirmed
Excess dil HCl or dil HNO3 insoluble.

a. The above experiment shows the test for ____________________ ions.


b. In the above test, the unknown solution is first of all acidified with dil.
___________________________ or dil. _________________________
c. The acidification process is necessary to prevent the precipitation of
other insoluble barium compounds like ___________ or ____________
7. H2SO4 is manufactured by the method called ______________ process.
8. The more recent process of manufacturing H2SO4 involves the catalytic
combination of sulphur (iv) oxide and oxygen to form ______________
9. During the manufacture of H2SO4, SO3 is first of all dissolved in
concentrated tetraoxosulphate (vi) acid to produce a very thick liquid
called_________________________________, which is then diluted to
produce pure (or 98%) ____________________________ acid.

62
Section F
1. Write ‘A’ for Agreed or ‘D’ for Disagreed in the space provided:
a. Tetraoxosulphate (vi) acid is not a powerful dehydrating agent
__________________________________________________________
b. Teraoxosulphate acid cannot char sugar, cellulose, cloth and human skin
__________________________________________________________
c. Dilute H2SO4 acid cannot react with the more electropositive metals to
liberate hydrogen ___________________________________________
d. H2SO4 acid reacts with trioxocarbonate (iv) to produce carbon (iv)
oxide _____________________________________________________
e. H2SO4 acid is not capable of forming salt with dilute hydroxides
__________________________________________________________
f. H2SO4 acid is used in the manufacture of fertilizers and detergents
__________________________________________________________
g. Hot concentrated H2SO4 acid removes the element of water from many
compounds ________________________________________________
2. Write balanced chemical equations for the reactions of dilute
tetraoxosulphate (vi) acid with the following;
i. Copper Trioxocarbonate (iv)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

63
ii. Zinc Oxide
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
iii. Magnesium
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
iv. Calcium hydroxide
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

CORRECTION: CHAPTER 11; Section A – F


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66
CHAPTER 12
OXIDATION REDUCTION REACTIONS

Section A
1. Oxidation reduction reaction is also known as ____________________
reaction.
2. Define oxidation and reduction in terms of;
(a) Oxygen:
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
(b) Hydrogen:
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
(c) Electronegativity:
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
(d) Electron transfer:
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________

67
(e) Oxidation Number:
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
3. Identify the reducing and oxidizing agents in the chemical equations by
writing under the substance, R.A. (for reducing agent) and O.A. (for
oxidizing agent).
(i) Zn(s) + CuSO4  ZnSO4(aq) + Cu(s)
(ii) 2KBr(aq) + Cl2(g)  2KCl(aq) + Br2(l)

Section B

1. Identify the type of reaction by writing oxidation or reduction in the space


provided:
(a) 2Cu + O2  2CuO ___________________________________
(b) CuO + H2  Cu + H2O ___________________________________
(c) N2 + 3H2  2NH3 ___________________________________
(d) 2NH3  N2 + 3H2 ___________________________________
(e) 2Na + I2  2NaI ___________________________________
(f) S + 2e-  S2- ___________________________________
(g) Ca + 2e  Ca2+ ___________________________________

68
2. Calculate the oxidation number of manganese in KMnO4. Then write the
IUPAC nomenclature of the compound.
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
3. Determine the oxidation number of Chromium in Cr2O72-. Write the IUPAC
nomenclature of the radical.
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
____________________________________________________________
4. Define:
(i) An oxidizing agent. _________________________________________
_________________________________________________________
(ii) A reducing agent. __________________________________________
_________________________________________________________

5. Write the IUPAC nomenclature of these compounds:


(i) NaBrO3 ___________________________________________________
(ii) K2SO4 ____________________________________________________

69
CORRECTION: CHAPTER 12; Section A – B
_______________________________________________________________
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70
CHAPTER 13
ELECTROLYSIS

Section A
1. In the year _______________ Arrhenius first presented the ionic theory
to explain the phenomenon of electrolysis.
2. The ionic theory proposed that when an electrolyte is melted or
dissolved in water, some or all the electrolyte dissociate into freely
moving charge particles called _________________________________
3. The process by which electrolyte dissociates into ion is known as
__________________________________________________________
4. The metallic ions, ammonium ions and hydrogen ion (H+) are said to be
_________________________ charged.
5. Non-metallic ions and hydroxyl ion are said to be __________ charged.
6. The number of electrical charges carried by an ion is equal to the
____________________________ of the corresponding atom or group.
7. The valency of
a. Oxygen (O2-) is _____________________________________________
b. Aluminium (Al3+) is _________________________________________
c. Sodium (Na+) is ____________________________________________
8. Metallic ions are formed by the corresponding atom by the
________________________ of electron equivalent to its valency.
9. Non-metallic ion is formed from the corresponding atom by
the_____________________ of a number of electron equal to the
valency of the atom.
10. A charged group of atom is called a ____________________________

71
11. A charged atom or group of atoms is known as an ________________
12. _______________________________ is the chemical decomposition of
electrolyte by the passage of electric current through a molten or
solution of the electrolyte.
13. A compound in solution or in molten form which conducts electricity,
and is decomposed by the electric current is known as an ____________
14. Two types of electrode are (a) ______________ and (b) ____________
15. ____________________ are conductors by which electric current enters
or leaves the electrolyte.
16. _______________________ is the positive electrode through which the
electrons leaves the electrolyte.
17. The negative electrode through which the electrons enters the
electrolytes is known as ______________________________________

Section B
1. __________________ is a compound which in solution or molten form
does not conduct electricity or allow electric current to pass through it.
2. Write True or False in the space provided.
a. Salts, alkalis and acids are examples of electrolyte _________________
b. Salt, alkalis and acids are examples of non-electrolyte ______________
c. Non-electrolyte is not decomposed by electric current ______________
d. Non electrolytes are covalent compounds and contain no ions ________
e. Ether, and Benzen are examples of electrolyte ____________________
f. Non-electrolytes do not dissociate or ionize. ______________________
g. Anode and Cathode are two electrodes that conduct electricity _______

72
3. Write out the ions in these compound
Compound Ions
e.g. H2SO4 2H+ SO42-
a. CuSO4 _______________
b. NaCl _______________
c. Ca (OH)2 _______________
d. MgCl2 _______________

4. This is a simple electrolytic cell. Label numbers i – iii

+
i
ii
iii

i is __________________________________________________
ii is __________________________________________________
iii is __________________________________________________
5. An electrolyte, which ionizes completely, is said to be ______________
but the one which does not ionize completely is said to be ___________
6. Write True or False in the space provided
a. Most inorganic acids are strong electrolytes ______________________
b. Most organic acids are weak electrolyte _________________________
7. Two examples of organic acid are
(a) _________________________ and (b) _______________________

73
8. Two examples of inorganic acid are
(a) ___________________________ and (b) _____________________
9. When an electric current is passed through the electrolyte, the free ions
lose their random movement. The positive ions are attracted to the
cathode and are called ________________________ while the negative
ions move towards the anode and are called ______________________
10. At the cathode, _____________________ reaction takes place but at the
anode _____________________________ reaction takes place.
11. Preferential or selective discharge of ions at the electrodes during
electrolysis is dependent on the following three factors:
a. __________________________________________________________
b. __________________________________________________________
c. __________________________________________________________
12. Electrodes which take no part in the electrolytic reaction, are described
as _______________ electrodes, while the ones which take no part in
the electrolytic reaction, are described as________________ electrodes.
13. Two examples of inert electrodes are:
(a) ____________________________ (b)________________________

Section C
ELECTROLYSIS OF MOLTEN/FUSED SALTS AND SOLUTION OF SOME
SALTS

1. Electrolysis of acidified water is also called the electrolysis of dilute


_________________________acid.
2. The apparatus used in the electrolysis of acidified water is known as
__________________________________________________________

74
3. In the electrolysis of acidified water, the electrodes are made up of
metal called _______________________________________________
4. The ions present in dilute tetraoxosulphate (vi) acid are:
From H2SO4 _______________________ and ____________________
From H2O _________________________ and ____________________
5. During the electrolysis of acidified water, ________________________
migrates to the cathode while ________________and ______________
migrate to the anode.
6. During the electrolysis of dilute tetraoxosulphate (vi) acid, OH- is
discharged at the anode (in preference to S042-) because OH- is
__________________________________________________________
7. Write the products of these electrodes‟ reactions:
H+ + e- ___________________________________
H + H ___________________________________
OH- - e- ___________________________________
OH + OH ___________________________________
O + O ___________________________________
8. In the electrolysis of acidified water, 2 volume of _________________
is liberated at the cathode while 1 volume of ____________________ is
formed at the anode.
9. The ions present in sodium chloride solution (brine) are:
Cation Anion
NaCl _________________ + _________________
H2 O _________________ + _________________

75
10. During the electrolysis of NaCl solution;
a. Cl- and OH- ions migrate to the anode but Cl- is preferentially
discharged because __________________________________________
b. The anode must be made of ____________________________ to resist
the attack by chlorine.
c. ____________________ ion is preferentially discharged at the cathode.
11. In the electrolysis of molten or fused NaCl, ___________________ ion
is discharged at the cathode.
12. Write True or False in the space provided:
a. During the electrolysis of copper (ii) tetraoxosulphate (vi) solution
using C or Pt electrodes, H+ is not charged in preference to Cu2+
because it is higher in electrochemical series than Cu2+ _____________
b. In the electrolysis of CuSO4 solution using copper anode, copper from
the anode passes into the solution to form copper ion _______________
c. In the electrolysis of CuSO4 solution using copper anode, the blue
colour of the solution will not change because there is no change in the
composition of the electrolyte _________________________________

76
CORRECTION: CHAPTER 13; Section A – C
_______________________________________________________________
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77
CHAPTER 14
FARADAY’S LAW OF ELECTROLYSIS

Section A
1. The quantity of products liberated at the electrodes during electrolysis is
depended on three factors. They are:
a. __________________________________________________________
__________________________________________________________
b. __________________________________________________________
__________________________________________________________
c. __________________________________________________________
__________________________________________________________
2. Faraday‟s first law of electrolysis states that:
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
3. Faraday‟s first law can be represented mathematically as ____________
4. The unit of quantity of electricity is the __________________________
5. Current is measured in __________________________________ while
time is measured in _________________________________________
6. Q = I x t. From this mathematical equation;
Q stands for _______________________________________________
I stands for ________________________________________________
t stands for ________________________________________________

78
7. M = E I t; In this equation, E is a constant popularly known as the
______________________________ of the substance.
8. The mass in gram of a substance liberated by the passage of I coulomb
(c) of electricity is called the __________________________________
9. Faraday‟s second law of electrolysis state that:
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
10. The minimum quantity of electricity required to liberate one mole of a
single – charged ion is ______________________________ coulombs.
11. 1 Faraday (F) is equivalent to _________________________ coulombs.
12. The number of Faradays required to liberate 1 mole of these ions are:

1 mole of ions Number of Faradays


a. H+ _______________________
b. Na+ _______________________
c. Al3+ _______________________
d. Ca2+ _______________________
e. Cu2+ _______________________

79
Section B
1 Calculate the mass of silver deposited when a current of 2.6A is passed
through a solution of a silver salt for 70 minutes. (Ag = 108; 1 Faraday
= 96,500C)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
2. Calculate the mass of copper deposited when a current of 0.9A is passed
through a solution of a copper salt for 1hr 20 mins (Ca = 63.5; 1
Faraday = 96, 500C)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

80
3. Three electrolytic cells containing solutions of copper (ii)
tetraoxosulphate (vi), silver trioxonitrate (v) and tetraoxosulphate (vi)
acid respectively are connected in series. A steady current is then
passed through these solutions. If 6.55g of copper are deposited at the
cathode of the copper electrolytic cell calculate:
a. The mass of silver deposited at the cathode of the silver electrolyte cell.
b. The volume of hydrogen gas liberated at 250C and 730 mm Hg in the
third electrolytic cell.)
(Cu = 63.5, Ag = 180, 1 Faraday = 96,500C, molar volume of H2 at S.T.P is 22.4dm3)
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
_________________________________________________________

81
Section C
USES OF ELECTROLYSIS; ELECTRO-CHEMICAL CELLS
Write True or False in the space provided.
1. Electrolysis is important in the
a. Preparation of oxygen from the electrolysis of acidified water ________
b. Electroplating of one metal by another __________________________
c. Extraction of elements _______________________________________
2. The potential difference between an element (electrode) and the solution
containing its ions (electrolyte) in which it is immersed is known as the
__________________________________________________________
3. The potential difference set up when an electrode is in contact with one
molar solution of its ions at 250C is called the _____________________
4. The electrode potential varies from element to element and it is
dependent on _______________________ and ___________________
5. Hydrogen electrode has an electrode potential of ________________ at
all temperature.
6. _________________________ has been chosen as an arbitrary standard
upon which the electrode potential of other elements are determined.
7. Write True or False in the space provided
a. The + or – sign of the electrode potential of an element will depend on
whether electron flows from or to the hydrogen electrode ___________
b. The flow of electron or electricity from one electrode to another is due
to the difference in electrode potential of the two electrodes. _________
c. A device that can change chemical energy to electrical energy is known
as an electrochemical cell ____________________________________
d. Battery is an example of an electrochemical cell ___________________

82
8. Three examples of electrochemical cells we have studied are
___________________________, __________________________ and
__________________________________________________________
9. The anode of a fully-charged lead accumulator is __________________
and its cathode is ___________________________________________
10. The electrolyte in the lead accumulator is ________________________
11. When the two electrodes of lead accumulator are connected to an
external circuit, it produces electricity by ________________________
12. When both electrodes of lead accumulator are covered with PbSO4
deposits, the cell ceases to discharge any more current until it is
__________________________________________________________
13. Recharging the battery removes the deposited __________________ on
the cathode and anode.

CORRECTION: CHAPTER 14; Section A – C


_______________________________________________________________
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84
CHAPTER 15
ORGANIC CHEMISTRY: HYBRIDIZATION, HOMOLOGOUS
SERIES, ISOMERISM

Section A
Write true or false in the space provided:
1. Some characteristics of organic compounds are:
a. They are electrovalent compounds _______________________________
b. They are covalent compounds __________________________________
c. Organic compounds are soluble in water __________________________
d. Organic compounds are soluble in organic solvents _________________
e. Most organic compounds burn in excess supply of air to form carbon (iv)
oxide and hydrogen ___________________________________________
f. They have high melting and boiling points ________________________
2. Three types of hybridization are (a) ______________________________
(b) ___________________________ (c) __________________________
3. The new orbitals of equal energy formed after the hybridization of atomic
orbitals are known as _________________________________________
4. The mixing up and redistribution of orbitals of nearly the some energy to
form the same number of orbitals of equal energy is known as _________
5. If one 2S and one 2P orbitals take part in hybridization, ______________
hybridization is said to be formed.

85
Section B
1. ______________________________ is a family of organic compounds
with the same molecular formulae in which each successive member
differs from that of its nieghbour by CH2 or by mass of 14.
2. An individual member of a ______________ is known as a homologue
3. The characteristics of a homologous series are:
a. They show different chemical reaction __________________________
b. They have a general molecular formulae _________________________
4. Organic isomers have different physical and chemical properties _____
5. Two types of isomerism are:
(a) _________________________ (b) __________________________
6. Two types of sterio isomerism are
(a) _________________________ (b) __________________________
7. Draw a named structure of an aromatic compound
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

Section C
1. The occurrence of two or more compounds with the same molecular
formula but different molecular structure is known as ______________
2. Two types of isomerism in organic chemistry are:
(a) ____________________________________________________
(b) ____________________________________________________

86
3. Geometric and optical isomers are studied under _________________
isomerism.
4. Draw a structural isomer of these organic compounds:
a. C4H10
H H H H
H C C C C H
H H H H
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

b. C2H6O H H
H C C OH
H H
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

87
5. Draw two structural isomers of this organic compound
a. C5H12
H H H H H
H C C C C C H
H H H H H
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
6. Draw a Trans isomer of this compound:
CH3 CH3

C = C
H H

__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

88
7. Draw an optical isomer of 2 hydroxyl propanoic acid:
H
CH3 C COOH
OH
L. Form D. Form

Section D
CRACKING; REFORMATION OF GASSOLINE AND OCTANE
RATING

1. Refining of petroleum involves three main processes namely;


(a) ____________________________ (b) _________________________
(c) _________________________________________________________
2. The breaking of the complex petroleum fraction into smaller or simpler
units that are more useful and are in high demand is called
_____________ of petroleum.

89
3. _________________ involves joining small molecules of hydrocarbon
gases in the C1 - C4 range to produce molecules in C5 – C10 range.
4. Fill in „Polymerization‟ or „Cracking‟ C15H30  C8H18 + C2H4 + C3H6
The above reaction is an example of ____________________________
5. Two types of cracking are:
(a) ____________________________ (b) _______________________
6. The process by which hydrocarbon fractions of long carbon chains are
broken down into the shorter chains of petrol by heating under very
high temperature and pressure is called __________________________
7. Two examples of catalyst used in catalytic cracking are:
(a) ____________________________ (b) _______________________
8. __________________ involves joining small molecules of hydrocarbon
to produce molecules of hydrocarbon of long carbon chains.
9. Write True or False in the space provided.
a. Reformation is used to improve the quality of petrol by converting
straight chain alkanes to branched chain and cyclic hydrocarbon which
yield better or high performance fuel ____________________________
b. The hydrocarbons may occur as straight chain or branched chain
molecules _________________________________________________

c. Tetraethyl lead is added to petrol as antiknock ____________________


d. High sulphur content in some petrol reduces the response of petrol to
the added Pb(C2H5)4. ________________________________________
e. The octane number of a fuel is raised by the presence of branched chain
hydrocarbons and aromatic compounds __________________________

90
Section E
SATURATED HYDROCARBON – THE ALKANES
1. Hydrocarbons are binary compounds of (a) _______________________
and (b) __________________________________________________
2. The cyclic or ring structured hydrocarbon is called an ______________
hydrocarbon.
3. A chained structured hydrocarbon is called an ____________________
hydrocarbon
4. Two examples of cyclic hydrocarbon are:
(a) ____________________________ (b) _______________________
5. Two examples of chain structured hydrocarbon are:
(a) ____________________________ (b) _______________________
6. Write True or False in the space provided.
a. The saturated hydrocarbons are the alkanes ______________________
b. Alkanes are hydrocarbons with general molecular formular CnH2n ____
c. Alkanes have little affinity for other elements or compounds _________
d. Alkanes have the general molecular formular CnH2n + 2 ___________

7. The first member of the alkane family is ____________________ while


the second member is ________________________________________
8. ________________________ is the sequence in which atoms are joined
together in a molecule and the orientation of these atoms in space.
9. Each member of a homologous series differs in molecular formular
from the next by ____________________________________________
10. The name of these alkyl groups are:
a. CH3 = _______________________________________________
b. C2H5 = ________________________________________________

91
c. C3H7 = _______________________________________________
d. C4H9 = ________________________________________________
11. Name these alkanes
H

a. H C H
H H
H C C C H
H H
H C H
H ____________________________________________

b. H C H
H C H
H H H H H
H C C C C C C H
H H H H H
H C H
H ______________________________________________

12. Write the products of these reactions


light
a. CH4 + Cl2 _________________ + _________________
b. CH3Cl + Cl2 light _________________ + _________________
13. CH3COONa(s) + NaOH Na2CO3 + CH4
a. The above equation shows a laboratory method of preparing
_____________ gas.
b. The IUPAC nomenclature of CH3COONa is _____________________
_________________________________________________________
92
Section F
UNSATURATED HYDROCARBON – THE ALKENES
1. The unsaturated hydrocarbons that contain one or more carbon-carbon
double bond per molecule are called the _________________________
2. Alkenes have ___________________________ hydrogen atoms less
than their corresponding alkanes.
3. Alkenes are members of a homologous series with general molecular
formular __________________________________________________
4. Alkenes are sometimes called the ______________________________
5. The molecular formular of the first member of the alkenes is
_____________ while that of the second member is ________________
6. The structural formular of the second member of the alkene series is
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
7. Write the IUPAC nomenclature of these alkenes:
H H H H H
(a) C = C C - H (b) H C C C C H
H H H H H H
______________________ _________________________
______________________ _________________________
(c) H H
H C C C
H H
H C H
H

93
8. Alkenes are more reactive than alkanes due to the presence of
__________________________________________________________
9. Write True or False in the space provided.
a. Addition reactions are typical reactions undergone by all unsaturated
hydrocarbons ______________________________________________
b. In addition reaction, two substances combine to give a single substance
__________________________________________________________
c. In addition reaction, two substances combine to give one or more
substance _________________________________________________
10. Fill in either „substitution reaction‟ OR „Addition reaction‟ in the space
provided: The type of reaction undergone by these reacting substances
are:
a. C2H4 + Cl2 CH2ClCH2Cl
__________________________________________________________
light
b. CH4 + Cl2 CH3Cl + HCl
__________________________________________________________
c. C2H4 + Br2 CH2BrCH2Br
__________________________________________________________
d. C2H6 + Br2 C2H5Br + HBr
__________________________________________________________
e. CH3Cl + Cl2 CH2Cl2 + HCl
__________________________________________________________
11. Ethane undergoes substitution reaction while ethene undergoes
_______________________ reaction.

94
12. Write the IUPAC nomenclature of these products:
H H
a. C2H4 + HOBr H C C OH
Br H ________________________

H H

b. C2H4 + HOCl H C C OH _________________________


Cl H

Section G

1. Write the IUPAC nomenclature of the products of these reactions:


H H
a. C2H4 + HI H C C I
H H ____________________________

b. C2H4 + H2SO4 H H
H C C HSO4 ______________________
H H

2. __________________________ is a process whereby two or more


simple molecules link together to form a much longer and complex
molecule called the polymer.
3. Ethane can be polymerized to _________________________________
4. During polymerization simple molecules called _______________ link
together to form polymer.

95
5. Write „A‟ in the space provided if you agree with the statement or
write „D‟ if you disagree with it.
a. Polyethene is a polymer ___________
b. Polyethene is resistant to common chemical actions ___________
c. Polyethene can be moulded when hot into a great variety of articles like
funnels, bags etc. ___________
d. Ethene is produced in the laboratory by the dehydration of ethanol by
hot concentrated H2SO4. ____________
6. Natural rubber is a polymer of _________________________________
7. The heating of raw rubber with about 3% by mass of sulphur is known
as _______________________________________________________
8. Synthetic rubber is produced by the polymerization of ______________
9. The structural formulae of an isopreme is________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

Section H
UNSATURATED HYDROCARBON – THE ALKYNES
1. ____________________ are the unsaturated hydrocarbons that contain
a triple bonds per molecule.
2. Alkynes have _____________________ hydrogen atoms less than their
corresponding alkanes.

96
3. Alkynes are members of a homologous series with general molecular
formular __________________________________________________
4. The molecular formular of the first member of the alkynes is _________
While its structural formular is ________________________________
5. Ethyne is produced when water is dropped on ____________________
6. Write the products of these reactions:
a. C2H2 + 2Br2 ______________________________
0
b. C2H2 + 2H2 200 C ______________________________
c. C2H2 + 2HI(g) 250C ______________________________
7. Write two reactions (Metallic derivatives of ethyne) that distinguish
ethyne from ethane.
a. __________________________________________________________
__________________________________________________________
__________________________________________________________
b. __________________________________________________________
__________________________________________________________
__________________________________________________________
8. If ethyne is passed through a hot tube, it polymerizes to _____________

Section I
AROMATIC HYDROCARBON – BENZENE
1. The molecular formular of benzene is ___________________________
2. When benzene is compared with corresponding alkane i.e. hexane
(C6H14), benzene has _______________________ hydrogen atoms less.

97
3. Write True or False in the space provide if you agree or disagree with
the statement.
a. Benzene undergoes addition reaction with hydrogen, halogens and
ozone ____________________________________________________
b. Benzene does not decolourize pink colour of acidified KMnO4 solution
__________________________________________________________
c. Benzene undergoes substitution reactions with halogens ____________
d. Benzene is a solvent for many substances ________________________
e. Benzene is not an important chemical in the manufacture of phenol,
methyl benzene and nitro-benzene ______________________________
4. Write the products of these reactions

a. + Br2 AlBrs ______________________________

AlCl3
b. + Cl2 ______________________________

c. + 3Cl2 sunlight ______________________________

d. + 3H2 1000C ______________________________


Pt or Ni

98
CORRECTION: CHAPTER 15; Section A – I
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102
CHAPTER 16
ALKANOLS

Section A
1. Alkanols form a homologous series with general molecular formular
__________________________________________________________
2. The molecular formular of methanol is __________________________

3. Write the IUPAC nomenclature of these alkanols:


(a) H H H
H C C C OH ___________________________________
H H H

(b) H OH H H
H C C C C H ________________________________
H H H H
4. _____________ is an atom or group of atoms common to a homologous
series which determines the chemical properties of the series.
5. The functional group of the alkanols is __________________________
6. Alkanols can be classified according to the number of hydroxyl group
present per molecule. These are; (a) __________________________
(b) _________________________ (c) _________________________
7. Write down the IUPAC nomenclature of these alkanols.
(a) H H (b) H
H C C H H C OH
H OH H C OH
H C OH
______________________ H _______________________

103
(c) H H
H C C H
OH OH _______________________
8. Monohydric alcohols are classified into three as: (a) _______________
(b) _________________________ (c) _________________________
9. A tertiary Alcohol is one that the OH group is attached to a __________
10. A secondary carbon atom is one that is joined to ______________ other
carbon atom.
11. A tertiary carbon atom is one that is attached to _______________ other
carbon atoms.
12. What type of monohydric alcohols are these;
H H H H H H
(a) H C C C OH (b) H C C C H
H H H H OH H

_______________________ ________________________

(c) H
H C H
H H
H C C C H ___________________________________
H OH H

104
Section B
1 Some of the general methods of preparing alkanols (alcohol) are by:
a. the hydrolysis of alkyl halides e.g. R - X + NaOH R – OH + NaX
True or False? _____________________________________________
b. the hydrolysis of esters e.g. R – COO – R+KOH R–OH + RCOOK
True or False? _____________________________________________
c. the fermentation of glucose. True or False? ______________________
2. _________________________ is the catalytic decomposition of
complex organic compound (C6H12O6) into simpler substances like
alcohol, carbon (iv) oxide and energy.
3. ____________________ is an organic catalyst secreted in a living cells.
4. In the fermentation process, ______________________ is converted to
alcohol by an enzyme called __________________ present in the yeast.
5. Sodium metal reacts with ethanol at room temperature to liberate
__________________________________________________________
6. All organic alcohols (alkanols) react with organic acids to form
__________________________________________________________
7. Ethanol boils at _________________________________________ OC.

Section C
ALKANOIC ACID
1. Organic acids contain the _____________________________________
group as their functional group.
2. Alkanoic (organic) acids form a homologous series with the general
molecular formular __________________________________________
3. The first member of the homologous series (alkanoic acid series) is
__________________________________________________________

105
4. The IUPAC nomenclature of these organic acids are
Organic acid Old name IUPAC name
a. C15H31COOH Palmitic acid ________________
b. C17H35COOH Stearic acid ________________
5. Two examples of monocarboxylic acid are:
(a) ___________________________ (b) ________________________
6. Two example of dicarboxylic acid are:
(a) ___________________________ (b) ________________________
7. _____________________________________ acid is present in vinegar.
8. Complete oxidation of ethanol results in the formation of
____________________________ acid.
9. Write a balanced chemical equation to show the following reactions:
a. Ethanoic acid liberates carbon (iv) oxide from trioxocarbonates (iv) and
hydrogen trioxocarbonate (iv).
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
b. Ethanoic acid reacts with strongly electropositive metals to liberate
hydrogen gas
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________

106
c. Ethanoic acid neutralizes alkalis to form salt and water only.
__________________________________________________________
__________________________________________________________
__________________________________________________________
_________________________________________________________
d. Ethanoic acid reacts with an alcohol to form ester.
__________________________________________________________
__________________________________________________________
__________________________________________________________
__________________________________________________________
10. Is ethanoic acid a monobasic or a dibasic acid? ____________________
11. The reaction between an organic acid and an alcohol to form an ester is
known as _________________________________________________

Section D
ESTERS, SAPONIFICATION AND HYDROGENATION OF OIL
1. _______________________ is the formation of an ester by the reaction
between an alkanol and organic acid.
2. R = alkyl group. RCOOR is the formular of ____________________
3. Alkanoate is another name for the ______________________________
4. Write the IUPAC nomenclature of these esters:
Ester IUPAC name
a. HCOOCH3 ___________________
b. CH3COOCH3 ____________________
c. C3H7COOC2H5 ____________________
5. Esters of saturated fatty acids are called _________________________
6. Esters of unsaturated fatty acids are called _______________________
107
7. Is fat solid or liquid at room temperature?
________________________
8. Is oil solid or liquid at room temperature? _______________________
9. An oil can be converted to fat by ______________________________
10. __________________________ is the alkaline hydrolysis of an ester,
fat or oil to form soap and propane – 1, 2, 3 – triol.
11. ___________________ is the sodium or potassium salt of organic acid.
12. Fat or oil + NaOH Soap + Propan-1, 2, 3 triol.
This reaction is popularly known as _____________________ reaction.
13. Soap is the product of ________________________________ reaction.
14. R = alkyl group, 3RCOONa is the formular of __________________
H H H
15. H C C C H The IUPAC nomenclature of this alcohol is
OH OH OH ____________________________________
16. An example of synthetic detergent is ____________________________
17. __________________________ is a sodium salt of sulphonated alkene.
18. R = alkyl group. RSO4Na is the formular of ___________________

CORRECTION: CHAPTER 16; Section A – D


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110
CONCISE CHEMISTRY

FOR SENIOR SECONDARY SCHOOLS


WORKBOOK 2

OKOYE E. I.
Ph.D, MSc., MSc.Ed, BSc.Ed, NCE

NAME ________________________________________
SCHOOL ______________________________________
CLASS ________________________________________
DATE _________________________________________

111
EBINCO Press
Rev. J.C. Okoye‟s Compound
Umuabu Village,
Adazi-Enu,
Anambra State,
08068575646
08038816693

© E.I. Okoye

1st Published 2003


2nd Edition 2006
3rd Edition 2012

All Right Reserved,


No part of this publication may be reproduced,
stored in a retrieval system, or transmitted in any
form, or by any means electronic, mechanical,
photocopying, recording or otherwise without
the prior permission of the publisher.

ISBN: 978-076-158-61

112
Preface

This workbook reflected all the contents of senior secondary school chemistry
curriculum. It is meant to offer a very good helpful assistance to chemistry
teachers in their continuous assessment tests. The exercises were carefully
selected to test the students understanding of the various content topics treated.
The content topics were carefully selected to cover the scheme of work for SS2
chemistry curriculum. This makes the workbook a very good working
companion to any recommended text. It is hoped that at the end of the
exercises in this workbook, SS2 students would have a clearer understanding
of what chemistry is all about. This in no doubt will help to equip them more
effectively to face the contents of SS3 chemistry curriculum.

Okoye E.l. (Ph.D)

i
113
CONTENTS
Page
Chapter 1: The Periodic Table - - - - - - 1
Section A
Section B
Chapter 2: Chemical Reactions/Reactants and Products - - 5
Section A
Section B
Section C: Rate of Chemical Reaction and Factors Affecting it
Section D: Collision Theory: Energy and Reaction Rates
Section E: Exothermic and Endothermic Reaction and also Energy Profile
Section F:
Section G: Spontaneity of Reaction, Entropy and Free Energy
Section H: Systems in Equilibrium and Factors Affecting them,
Le Chatelier‟s Principle
Section I
Chapter 3: Mass-Mole and Mass-Volume Relationship - - - 26
Section A
Section B
Chapter 4: Acid/Base Titration - - - - - - 31
Section A
Chapter 5: Solution - - - - - - - - 33
Section A
Section B: Solubility
Chapter 6: Air and Flame - - - - - - - 38
Section A:
Chapter 7: Hydrogen - - - - - - - 40
Section A
Chapter 8: Oxygen, Oxide - - - - - - - 41
Section A
Chapter 9: Halogen - - - - - - - - 43
Section A
Section B: Lab. Preparation of Hydrochloric Acid (HCl)
Chapter 10: Nitrogen - - - - - - - 46
Section A
Section B: Ammonia

ii
114
Section C: Oxides of Nitrogen
Section D: Trioxonitrate (v) Acid
Section E: Nitrogen Circle
Chapter 11: Sulphur Allotropes; Preparation, Properties and Uses:
Compounds of Sulphur - - - - - 54
Section A
Section B: Hydrogen Sulphide
Section C: Oxides of Sulphur; Trioxosulphate (iv) Acid and
Trioxosulphate (vi) Salts
Section D
Section E: Tetraoxosulphate (vi) Acid and Its Salts
Section F
Chapter 12: Oxidation-Reduction Reactions - - - - 66
Section A
Section B
Chapter 13: Electrolysis - - - - - - - 70
Section A
Section B
Section C: Electrolysis of Molten/Fused Salts and Solution of Some Salts
Chapter 14: Faraday‟s Law of Electrolysis - - - - 77
Section A
Section B
Section C: Uses of Electrolysis, Electro-Chemical Cells
Chapter 15: Organic Chemistry: Hybridization, Homologous Series,
Isomerism - - - - - - - 84
Section A
Section B
Section C
Section D: Cracking: Reformation of Gassoline and Octane Rating
Section E: Saturated Hydrocarbons – The Alkanes
Section F: Unsaturated Hydrocarbons; The Alkenes
Section G
Section H: Unsaturated Hydrocarbon; The Alkynes
Section I: Aromatic Hydrocarbon; Benzene
Cheaper 16: Alkanols - - - - - - - 102
Section A
Section B
Section C: Alkanoic Acid
Section D: Esters, Saponification and Hydrogenation of Oil
115
iii
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