1, For each molecular formula: Draw structural isomers. The number of structural isomers possible is given in (). CHHCIQ) Ev: 0 CHIN (4) EU 0 C2H10(3) coy ° ° nara ] Ath yu, “ ow 2 Ay O Cah (5) CHEB) =) Eusy i 4 mB a hw MY we nw Aa Say C2) Ev-0 Cag (9) bv CsH60 (9) _ a A428 oN No Q A nO eS sb aa Ae Ade b © 4 2, Dofine each term. Use an equation when necessary. Her a Sirverual tomers Seine vlevaly Loe wue! 'b. Resonance strictures =a on Seve emmnertn'ly u diffe~) — tomreedviy ditt) aerprh bem © Formal charge 4. degrees (ements) of wnsatration Ny'ho ¢ fe gor #- mee ~ ‘a bunds Bs Nh (turn) Gr, F,C,t2 4 3, How many possible combinations of structural units exists when a molecular formula has an unsaturation number of 4? Dros t &S, a6 b7 68 (a e10 D4 vgs © Very t 3 2b D wee yet 1 dy, D 2% vy 2 db Dirvyr Ved. + VEL 4, How many structural isomers are possible for CaHs? 123 4G) Se queshe 1 Di bs 5. How many structural isomers are possible for C«HsBr? 1235 Se BVshm Codd. a il cl? 6. How many structural isomers are possible for CHsCH (D23 45 Ores Ayr wy . DOD + 333. The structure of amlodipine, a Ca’ channel blocking agent used to teat hypertension is shown: a, How many carbon atoms does amlodipine have? 17 18 19 @O) 2 22 a 2 | ° © om '. How many hydrogen atoms does amlodipine have? -22,«23—=—«24 GD 2627 ye, amlodipine c. Indicate the degrees of unsaturation. a ® wo 12:13 Lowmse A dy, YY Cervera -26) 27 4, Warfarin (Coumadin), a very popular blood thinning agent, has the following structure, 2. How many carbon atoms does warfarin have sO» un b. How many hydrogen atoms docs warfarin have? 2 3B 4 os GB Indicate the degrees of unsaturation? se 9 op un @ ‘Warfarin Rome Ao ML FID Va (Bg tt bye ta 5. The structure of Flumazenil, a GABA antagonist, used to treat benzodiazepine overdose is shown. ome nto ‘a How many carbon atoms does Flumazenil have? B 4 @ 16 7 "5, How many hydrogen toms des Flomazenl have? B@ 6 6 17 F N . Indicate the degrees of unsaturation. s 9 u 2 ° 3 ys 4 oh Mle bs et 1s) 2 10 or many aon sons oer Moher? 39 u wv ‘lw many byogen tos doe Molecule ve? sof u w fue& a(t wr2- 10) va aay Seb7, Draw Lewis structures for the following molecules. “ iii, NLC Heo y 1 wy 4 w-n-4 Ch : 4 0 - iv. HNO; (70-N—04 v.NO oe vi. NaN; ow ues ww 09 Not N=N2N 8. Which of the following compounds have nitrogen atom(s) with a formal charge equal to zero? i NaNEy (GON; i, NEGCL HNO, (NO LNA 9. Which of the following structures is a cation?” : ° C... tT = fetscoh cn Cendeuen, Agu s As )cHolet ) CHO} Hoo u, © won = 4) 04 cole) 0H SY ells )ycH] CO cA, cB Agrron = fleece oto), beMolecule A O=< 11, How many carbon atoms docs Molecule A have? 12. How many hydrogen atoms does Molecule A have? 13, Add formal charges to each structure. w Ni, a (7 13s ANE) w14, Convert the following line angle structure to a condensed structure. cH me on (ch), ele ), Oo (0%), €elhedo cH © ok, = fnew cnevey yh = (eu), cH cHeH, ) cho,0 (cu) ,e4 cen Jen S 15. Select the structure(s) where the formal charge on carbon is 0. Any lone pairs on each carbon atom are shown. i $CHENt HCH H#—G—H 4 ia 3 A. tony BAgnyy) c. 9 only D. tand2 £. tand3 (F. Zand3) 16. Which of the following describes the relationship between the following two structures? OH on w= 4 Cees seta ‘rere fms ‘4. there is no elationship between thene structures 17. Which of the following molecules contain both covalent and ionic bonds? w 2. NaNH HROH Ill. NHaF IV. HO2 18. Rank the following atoms by electronegativity £e¢ a. Most EN atom iu . 2 most EN atom, bw c. 3" most EN atom a) 4. Least EN atom alan (6.1end Wi) ¢.1 andIV ad MWand It e WandIV fllandIv19. Draw Lewis structures. 3a. KOH e ; Heo-o-H 30 $032 ke oH 3b. H,0) ic. SOx . 4. NaNa vo YM wo 5.HySO, }J- 0-5 —0 -# ( 6.HCLOs Net NoNow j pr ceo od 7.803 oa 8. SOCh f 7 SO:Ch 25 26 ~f-c1 a ° ane Cj-f-er } 10. NaC 11, CH,OH, 12. HNO; Net Not ©, W e yee (6-Nn -04 1 TH y 20. Define the following terms. ofthese b ¢ Aufbau principle Q)) e> Jo Pauli principle Hund’s rule foun ng} Sesh no dw e bwe Lit er brhh Se guste Hs Crest 21. Convert the Lewis structure to a line angle structure. hol ed weer UR “A, Z P 45 < Y dv 4 . 22a? or False The molecular formula Cs11-Cl has more than one structural isomer. “A 23.(fiue) or False The molecular formula C:110 has more than one structural isomer, 24,Tre or ‘The molecular formula CzH:Cl has more than one structural isomer. a as.) or False The molecular formula CHCl, has more than one structural isomer. ¢, ~\7° pA o 26. or False The molecular formula C:H;N has more than one struetural isomer. W ~wi,Draw a Lewis structure for each compound, Include all nonbonding pairs of electrons. (a) CH,COCH3;CHCHCOOH (b), NCCH;COCH;CHO W # ae hore t -~c.c-d ¢-¢ 0H Nee~ ee S © W a (c) CHJCHCHOH CH :CO3H (d) CHCHC(CHy)CHCOOCH; \ ( Draw a fine-angle formula for each compound (a). CH;COCH;CHCHCOOH ¢bh), NCCHyCOCH,CHO \ o a aH wy" ( fe) CHyCHCH(OH ICH3COnH (d) CH;CHCICHyCHCOOCH; 2 oD nr OW ‘Which ofthe following compounds has an stom with an unfilled valence shel of electrons? 0 a.thO (b.BF; ¢.CH, d.CO; ¢.CO wo 8 4 oo a Neen art 1 eze~cBe- c-0- +H / | ’ u p ee “sy 4