F1-000728 MSDS

Isopropyl Alcohol
MATERIAL SAFETY DATA SHEET

Finished Product
Date-Issued : MSDS Ref. No : Date-Revised : Revision No : 12/20/2002 MS1610Bulk 09/29/2005 3
Isopropyl Alcohol 1. PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: Isopropyl Alcohol GENERAL USE: General Purpose Cleaning PRODUCT DESCRIPTION: Alcohol PRODUCT CODE: 1610/CAN/EUR-GS, G4, G, 5G, 54G
MANUFACTURER
Techspray, L.P. 1001 N.W. 1st Street P.O. Box 949 Amarillo, TX 79107 Contact: Chemtrec Product Stewardship: 1-800-858-4043
24 HR. EMERGENCY TELEPHONE NUMBERS

CHEMTREC (US Transportation) : (800) 424 - 9300 CANUTEC (Canadian Transportation) : (613) 996 - 6666 Emergency Phone : (800) 858 - 4043
2. COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name 2-Propanol EEC LABEL SYMBOL AND CLASSIFICATION Content > 90 CAS 67-63-0 EINECS 200-6610
R11 - Highly flammable.
EEC Highly flammable - "F"
R36/38 - Irritating to eyes and skin.
EEC Irritant - "Xi"
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Isopropyl Alcohol
R52 - Harmful to aquatic organisms.
EEC Environment - "N"
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW PHYSICAL APPEARANCE: Clear, Colorless, Volatile Liquid IMMEDIATE CONCERNS: Flammable liquid and vapor. POTENTIAL HEALTH EFFECTS EYES: Moderately irritating to the eyes. SKIN: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). SKIN ABSORPTION: Skin absorption can occur. INGESTION: This product is toxic by ingestion. Ingestion may cause irritation of the digestive tract. Nausea and vomiting will most likely occur. INHALATION: High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness, and possibly death with longer exposure. Keep people away from such vapors without selfcontained breathing apparatus.
4. FIRST AID MEASURES

EYES: Immediately flush eyes with plenty of water. Get medical attention, if irritation persists. SKIN: Immediately wash skin with soap and plenty of water. Remove contaminated clothing. Get medical attention if symptoms occur. Wash clothing before reuse. INGESTION: Do not induce vomiting. Give milk or water. Get immediate medical attention immediately. INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention.
5. FIRE FIGHTING MEASURES

FLASHPOINT AND METHOD: 11.7C (53F)TAG CC FLAMMABLE LIMITS: 2.0 to 12.0 EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes and oxides of carbon.
Isopropyl Alcohol
EXPLOSION HAZARDS: Vapors, when present in the flammable range (listed above), especially in a confined or poorly ventilated space, can be ignited with a flame or high intesity source of heat. FIRE FIGHTING PROCEDURES: Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. FIRE FIGHTING EQUIPMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES

GENERAL PROCEDURES: Dike area to contain spill. Take precautions as necessary to prevent contamination of ground and surface waters. Recover spilled material on adsorbent, such as sawdust or vermiculite, and sweep into closed containers for disposal. After all visible traces, including vapors, have been removed thoroughly wet vacuum the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc. as necessary and place in closed containers for disposal. SPECIAL PROTECTIVE EQUIPMENT: Only personnel equipped with proper respiratory and skin/eye protection should be permitted in area. See Section 8 for details. COMMENTS: Remove all sources of ignition. Use spark-proof tools.
7. HANDLING AND STORAGE

GENERAL PROCEDURES: Use spark proof tools and explosion proof equipment. HANDLING: Ground and bond containers when transferring material.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) EXPOSURE LIMITS Chemical Name OSHA PEL ppm 2-Propanol TWA STEL OSHA TABLE COMMENTS: 1. NL = Not Listed ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits.
ACGIH TLV
3
Supplier OEL
3
mg/m
ppm
mg/m
ppm
mg/m NL NL
400 ppm 500 ppm
980 mg/ 400 m3 ppm 1225 500 mg/m3 ppm
983 mg/ [1] NL m3 1230 NL mg/m3
Isopropyl Alcohol
PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. SKIN: The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection. Viton, Solvex, Butyl, Buna, Neoprene. RESPIRATORY: NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection.
9. PHYSICAL AND CHEMICAL PROPERTIES

PHYSICAL STATE: Liquid ODOR: Alcohol odor APPEARANCE: Clear, Colorless liquid pH: Neutral PERCENT VOLATILE: 100 VAPOR PRESSURE: 33 mmHg at 20C VAPOR DENSITY: 2.07 (Air=1) BOILING POINT: to 82C (180F) FREEZING POINT: to -88C SOLUBILITY IN WATER: Miscible MOLECULAR WEIGHT: 60.09 MOLE. WT. FORMULA: C3H8O (VOC): 787 g/L (non-exempt VOC)
10. STABILITY AND REACTIVITY

STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: Heat, flames, ignition sources, and incompatables. STABILITY: Stable under normal conditions. POLYMERIZATION: Will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of Carbon (CO and CO2) may form when heated to decomposition. INCOMPATIBLE MATERIALS: Strong acids and alkalis, reactive metals and strong oxidizing agents.
11. TOXICOLOGICAL INFORMATION
Isopropyl Alcohol
ACUTE DERMAL LD : 12800 mg/kg (rabbit)

50
ORAL LD : 5045 mg/kg (rat)

50
INHALATION LC : 16000 ppm, 8-hour

50
EYE EFFECTS: Draize test, rabbit, eye: 100 mg Severe; Draize test, rabbit, eye: 10 mg Moderate SKIN EFFECTS: Draize test, rabbit, skin: 500 mg Mild. CARCINOGENICITY: IARC: NOT listed NTP: NOT listed OSHA: NOT listed TERATOGENIC EFFECTS: Test results indicate this compound/mixture is not teratogenic.
12. ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION: Isopropyl alcohol has a high biochemical oxygen demand and a potential to cause oxygen depletion in aqueous systems, a low potential to affect aquatic organisms, a low potential to affect secondary waste treatment microbial metabolism, a low potential to affect the germination of some plants, a high potential to biodegrade (low persistence) with unacclimated microorganisms from activated sludge.
13. DISPOSAL CONSIDERATIONS

DISPOSAL METHOD: Federal, State, and Local laws governing disposal of materials can differ. Ensure compliance with proper authorities before disposal.
14. TRANSPORT INFORMATION

DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: ISOPROPANOL PRIMARY HAZARD CLASS/DIVISION: 3 UN/NA NUMBER: UN1219 PACKING GROUP: II ROAD AND RAIL (ADR/RID): KEMLER NUMBER: UN1219 HAZARD CLASS: 3 AIR (ICAO/IATA) PROPER SHIPPING NAME: ISOPROPANOL UN/NA NUMBER: UN1219
Isopropyl Alcohol
PRIMARY HAZARD CLASS/DIVISION: 3 PACKING GROUP: II NOTE: Domestic shipments only. When shipping International contact TechSpray shipping department. VESSEL (IMO/IMDG) PROPER SHIPPING NAME: ISOPROPANOL UN/NA NUMBER: UN1219 PRIMARY HAZARD CLASS/DIVISION: 3 PACKING GROUP: II NOTE: Page 3244 CANADA TRANSPORT OF DANGEROUS GOODS PROPER SHIPPING NAME: ISOPROPANOL PRIMARY HAZARD CLASS/DIVISION: 3 UN/NA NUMBER: UN1219 TDG NOTE: FLASHPOINT 12 C
15. REGULATORY INFORMATION

UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: FIRE: YES ACUTE: YES CHRONIC: YES 313 REPORTABLE INGREDIENTS: 2-propanol (CAS #67-63-0) CANADA WHMIS CLASS: Class B2 - Flammable Liquids. Class D2B - Toxic Materials. CANADA INGREDIENT DISCLOSURE LIST: CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List. DOMESTIC SUBSTANCE LIST (INVENTORY): All components of this product are listed on the Canadian DSL. EUROPEAN COMMUNITY EEC LABEL SYMBOL AND CLASSIFICATION
R11 - Highly flammable.
EEC Highly flammable - "F"
R36/38 - Irritating to eyes and skin.
EEC Irritant - "Xi"
Isopropyl Alcohol
R52 - Harmful to aquatic organisms.
EEC Environment - "N"
16. OTHER INFORMATION

APPROVED BY: Pierce A. Pillon PREPARED BY: Steve Cook REVISION SUMMARY Revision #: 3 This MSDS replaces the December 01, 2004 MSDS. Any changes in information are as follows: In Section 9 VOC (Unit) VOC (From) HMIS RATING HEALTH: FLAMMABILITY: PHYSICAL HAZARD: PERSONAL PROTECTION: NFPA CODES TITLE: Chemist
2 3 1
3 1 0
DATA SOURCES: Code of Federal Regulations (CFR) The Sigma-Aldrich Library of Regulatory and Safety Data OSHA Hazard Communication Standard (29CFR1910.1200) Various Federal, State and Local Regulations MANUFACTURER DISCLAIMER: To the best of our knowledge, the information contained herein is accurate. However, neither Tech Spray, L.P., or any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist.

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Isopropyl Alcohol

MATERIAL SAFETY DATA SHEET

Isopropyl Alcohol 1. PRODUCT AND COMPANY IDENTIFICATION

24 HR. EMERGENCY TELEPHONE NUMBERS

2. COMPOSITION / INFORMATION ON INGREDIENTS

R11 - Highly flammable.

EEC Highly flammable - "F"

R36/38 - Irritating to eyes and skin.

EEC Irritant - "Xi"

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R52 - Harmful to aquatic organisms.

EEC Environment - "N"

4. FIRST AID MEASURES

5. FIRE FIGHTING MEASURES

6. ACCIDENTAL RELEASE MEASURES

7. HANDLING AND STORAGE

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

400 ppm 500 ppm

980 mg/ 400 m3 ppm 1225 500 mg/m3 ppm

983 mg/ [1] NL m3 1230 NL mg/m3

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION

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ACUTE DERMAL LD : 12800 mg/kg (rabbit)

ORAL LD : 5045 mg/kg (rat)

INHALATION LC : 16000 ppm, 8-hour

12. ECOLOGICAL INFORMATION

13. DISPOSAL CONSIDERATIONS

14. TRANSPORT INFORMATION

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15. REGULATORY INFORMATION

R11 - Highly flammable.

EEC Highly flammable - "F"

R36/38 - Irritating to eyes and skin.

EEC Irritant - "Xi"

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R52 - Harmful to aquatic organisms.

EEC Environment - "N"

16. OTHER INFORMATION

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