Exactly your chemistry.

Division Functional Chemicals

Surfactants for Industrial Applications

Nonionic and Anionic Emulsifiers, Copolymerizable Surfactants, Dispersing Agents and Defoamers

Contents

Surfactants from Clariant What we offer for industrial customers Product Range Nonionic Surfactants Alkyl ethoxylates Nonylphenol ethoxylates Tributylphenol ethoxylates Tristyrylphenol ethoxylates Alkyl alkoxylates Ethylene oxide-propylene oxide block polymers Fatty acid polyethyleneglycol esters Fatty acid polyglycerol esters Fatty acid polyglycerol ester ethoxylates Castor oil ethoxylates Sorbitan ester ethoxylates Wax emulsifiers Anionic Surfactants Secondary alkyl sulphonates Olefin sulphonates Alkyl sulphates Alkyl ether sulphates Alkyl aryl ether sulphates Polyglycol ether sulphates Sulphosuccinic acid esters Fatty alkyl amine sulphosuccinamates Alkyl phosphoric acid esters 12 12 12 12 12 12 12 12 12 11 11 11 11 11 11 6 9 9 9 10 10 4

Alkyl polyethyleneglycol ether phosphoric acid esters Alkyl phosphonic acids Alkyl polyethylene glycol ether carboxylic acid Fatty acid condensates (fatty acid isethionates, methyl taurides, sarkosin and sarkoside) Alkyl benzene sulphonates, Ca-salts Copolymerizable Surfactants Vinyl ether alkoxylates (PO-EO-block polymers) Allyl ether alkoxylates (PO-EO-block polymers) Allyl polyoxyalkylene sulphates Dispersing Agents Defoamers Fluorine containing defoamers Silicone containing defoamers Silicone and fluorine-free defoamers Surfactants from Clariant Emulsifiers for emulsion polymerization

13 13 13 13

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14 14 14 15

16 16 16

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Registered trademark of Clariant

Surfactants from Clariant

What we offer for industrial customers
Clariants Division Functional Chemicals is one of the world's leading manufacturers of surfactants and polyglycols. The product range encompasses anionic, nonionic, cationic and amphoteric surfactants. These include raw materials for detergents and cleaners, cosmetics and special products for chemical and industrial applications. This brochure presents a selection of our products for chemical and industrial applications. Production and sales Our surfactants are manufactured at our production sites in Gendorf/Burgkirchen and Wiesbaden (Germany), Tarragona (Spain), Charlotte (USA), Clear Lake (USA), Mexico City (Mexico), Coatzacoalcos (Mexico), Maracay (Venezuela), Sao Paulo (Brazil), Zarate (Argentina) and elsewhere, and are available worldwide through our sales organization. Research and development In addition to the product range we offer our customers comprehensive advice and technical service. Our application laboratories assist you in developing modern system solutions and help you to select the products that are suitable for your applications. Our product range is constantly being expanded by intensive research and development work and is thus geared to the requirements of our customers as well as to optimization of the production methods. Quality and environment Clariants Functional Chemicals Division in Germany has established a quality management system in accordance with ISO 9001 in the production, research & development and marketing sectors. All products are subject to strict quality control in our analytical department to ensure our high quality standard. To safeguard environmentally friendly operations the environment management system in accordance with the eco audit regulations (EEC 1836/93) was introduced at Gendorf/Burgkirchen
The largest production site of Division Functional Chemicals: Clariant Gendorf/ Burgkirchen.

(Germany), our largest production site.

Production site of Division Functional Chemicals in Tarragona (Spain).

Industrial Applications of Surfactants Surfactants are used as wetting agents, emulsifiers and dispersing agents for different chemical and industrial applications. Clariant offers products for the following fields:

Our service: new emulsifiers from the laboratory to production In selecting suitable emulsifier systems preliminary trials are necessary to determine the stability of the monomer emulsion and polymer dispersion and the properties of the polymer films. We will gladly supply product samples from our commercial range for these preliminary trials.

Besides the existing range Clariant offers smaller sample amounts of non-commercial products for laboratory investigations. These include nonionic emulsifiers based on alcohol ethoxylates, which are synthesized in our development laboratory. If required, almost any alcohol can be reacted with the desired amount of ethylene oxide and a sample provided. Our production know-how permits rapid scale-up of new products from the laboratory to the production stage. Development products are thus rapidly available commercially. We will gladly advise you of what we can do for you.

s Emulsifiers for emulsion polymerization s Dispersing agents for pigment preparations, coatings, inks and paints

s Wetting agents for hard surfaces,

ceramics, wood, plastics and metals

s Emulsifiers for micro- and macro

emulsions of fats, hydrocarbons and silicon oils

s Emulsifiers for polyolefin wax

emulsions

s Wetting agents for electroplating

processes

s Surfactants for the building industry s Emulsifiers for bitumen emulsions s Auxiliaries for the sugar industry s Defoamers

Nonionic Surfactants
Product range
The following product range provides a selection of our products and contains nonionic and anionic surfactants used as emulsifiers and wetting agents, and further more dispersing agents and defoamers. New development products, which will extend our product range, are not yet included in this list.

Trade name Alkyl ethoxylates Emulsogen EPN 118 Emulsogen EPN 217 Emulsogen EPN 287 Emulsogen EPN 407 Emulsogen LCN 050 Emulsogen LCN 070 Emulsogen LCN 088 Emulsogen LCN 118 Emulsogen LCN 158 Emulsogen LCN 217 Emulsogen LCN 287 Emulsogen LCN 407 Emulsogen 3896 Genapol C 050 Genapol C 100 Genapol C 200 Genapol C 250 Genapol LA 030 Genapol LA 040 Genapol LA 050 Genapol LA 070 Genapol LA 079 Genapol V 4463
(1) 1

Chemical name Alkyl polyglycol ether with 11 EO Alkyl polyglycol ether with 21 EO Alkyl polyglycol ether with 28 EO Alkyl polyglycol ether with 40 EO Alkyl polyglycol ether with 5 EO Alkyl polyglycol ether with 7 EO Alkyl polyglycol ether with 8 EO Alkyl polyglycol ether with 11 EO Alkyl polyglycol ether with 15 EO Alkyl polyglycol ether with 21 EO Alkyl polyglycol ether with 28 EO Alkyl polyglycol ether with 40 EO Fatty alcohol ethoxylate Coconut fatty alcohol ethoxylate with 5 EO

Active content Appearance (20C) Cloud point (C) HLB value ca. 80 % ca. 70 % ca. 70 % ca. 70 % ca. 100% ca. 100% ca. 80% ca. 80 % ca. 80 % ca. 70 % ca. 70 % ca. 70 % ca. 100 % ca. 100 % liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid waxy liquid paste waxy waxy liquid liquid liquid liquid liquid waxy 62 65 (3)* 67 70 (2) 54 56 (1) 62 62 69 73 75 (3) 71 74 (2) 89 92 (1) 76 77 53 64 70 53 53 78 (3) 79 (3) 55 (2) 66 (2) 73 (2) 59 (1) 59 (1)* 65 (1)* 65 (3)* 71 (3)* ca. 15 ca. 17 ca. 18 ca. 18 ca. 11 ca. 13 ca. 13 ca. 15 ca. 16 ca. 17 ca. 18 ca. 18 ca. 15 ca. 10 ca. 14 ca. 16 ca. 17 ca. 8 ca. 10 ca. 11 ca. 12 ca. 12 ca. 14

Coconut fatty alcohol ethoxylate with 10 EO ca. 100 % Coconut fatty alcohol ethoxylate with 20 EO ca. 100 % Coconut fatty alcohol ethoxylate with 25 EO ca. 100 % C12 / C14 fatty alcohol ethoxylate with 3 EO C12 / C14 fatty alcohol ethoxylate with 4 EO C12 / C14 fatty alcohol ethoxylate with 5 EO C12 / C14 fatty alcohol ethoxylate with 7 EO C12 / C14 fatty alcohol ethoxylate with 7 EO ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 90 %

C12 / C14 fatty alcohol ethoxylate with 10 EO ca. 100 %

(2) 5

g in 100 cm 3 distilled water

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance

Trade name Alkyl ethoxylates Genapol O 020 Genapol O 050 Genapol O 080 Genapol O 100 Genapol O 150 Genapol O 200 Genapol O 300 Genapol OA 040 Genapol OA 070 Genapol OA 080 Genapol OA 089 Genapol OX 050 Genapol OX 060 Genapol OX 070 Genapol OX 080 Genapol OX 100 Genapol OX 109
(1) 1

Chemical name Oleyl alcohol ethoxylate with 2 EO Oleyl alcohol ethoxylate with 5 EO Oleyl alcohol ethoxylate with 8 EO Oleyl alcohol ethoxylate with 10 EO Oleyl alcohol ethoxylate with 15 EO Oleyl alcohol ethoxylate with 20 EO Oleyl alcohol ethoxylate with 30 EO C14 / C15 oxo alcohol ethoxylate with 4 EO C14 / C15 oxo alcohol ethoxylate with 7 EO C14 / C15 oxo alcohol ethoxylate with 8 EO C14 / C15 oxo alcohol ethoxylate with 8 EO C12 / C15 oxo alcohol ethoxylate with 5 EO C12 / C15 oxo alcohol ethoxylate with 6 EO C12 / C15 oxo alcohol ethoxylate with 7 EO C12 / C15 oxo alcohol ethoxylate with 8 EO C12 / C15 oxo alcohol ethoxylate with 10 EO C12 / C15 oxo alcohol ethoxylate with 10 EO
(2) 5

Active content Appearance (20C) Cloud point (C) ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 90 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 90 % liquid liquid liquid paste paste waxy waxy waxy liquid paste paste liquid liquid liquid paste liquid paste paste paste liquid 35 38 (2) 67 > 69 (2) 40 (1)

HLB value ca. 5 ca. 9 ca. 11 ca. 12 ca. 13 ca. 15 ca. 17 ca. 9 ca. 12 ca. 12 ca. 12 ca. 10 ca. 11 ca. 12 ca. 13 ca. 14 ca. 14

79 81 (2) > 75 (1) 49 74 51 +/72 76 76 1,5 (2) 74 (2) 80 (2) 80 (2)* 51 (3) 76 (3) 71 73 (3)

63 64,5 (2) 64 67 (2) ca. 75 62 62 73 (2) 78 (2) 65 (1) 65 (1)*

g in 100 cm 3 distilled water

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance Alkyl ethoxylates to be continued on page 8

Nonionic Surfactants
Product range
Trade name Genapol T 080 Genapol T 110 Genapol T 150 Genapol T 200 Genapol T 250 Genapol T 250 p Genapol T 500 Genapol T 500 p Genapol T 800 Genapol T 800 p Genapol UD 030 Genapol UD 050 Genapol UD 079 Genapol UD 080 Genapol UD 088 Genapol UD 110 Genapol X 020 Genapol X 050 Genapol X 060 Genapol X 080 Genapol X 089 Genapol X 090 Genapol X 158 Genapol X 250 Genapol X 307 Genapol X 407 Genapol X 1000 Genapol X 1003 Genapol X 1005 Genapol 1879 Genapol 3214
(1) 1

Chemical name Tallow fatty alcohol ethoxylate with 8 EO

Active content Appearance (20C) Cloud point (C) HLB value ca. 100 % waxy waxy waxy waxy waxy powder waxy powder waxy powder liquid liquid liquid liquid liquid liquid paste liquid liquid liquid liquid liquid liquid liquid waxy liquid liquid solid liquid liquid liquid liquid 83 85 (2) 84 60 90 (1) 63 (3) ca. 14 ca. 15 ca. 16 ca. 16 ca. 18 ca. 18 ca. 19 ca. 19 41 (2) 69 (2) ca. 9 ca. 11 ca. 13 ca. 13 ca. 13 ca. 15 ca. 6 ca. 10 ca. 11 ca. 13 ca. 13 ca. 13 ca. 15 ca. 18 ca. 17 ca. 18 ca. 19 ca. 19 ca. 19 ca. 15 ca. 18 ca. 11 ca. 13

Alkyl ethoxylates continued from page 7 Tallow fatty alcohol ethoxylate with 11 EO ca. 100 % Tallow fatty alcohol ethoxylate with 15 EO ca. 100 % Tallow fatty alcohol ethoxylate with 20 EO ca. 100 % Tallow fatty alcohol ethoxylate with 25 EO ca. 100 % Tallow fatty alcohol ethoxylate with 25 EO ca. 100 % Tallow fatty alcohol ethoxylate with 50 EO ca. 100 % Tallow fatty alcohol ethoxylate with 50 EO ca. 100 % Tallow fatty alcohol ethoxylate with 80 EO ca. 100 % Tallow fatty alcohol ethoxylate with 80 EO ca. 100 % C11 oxo alcohol ethoxylate with 3 EO C11 oxo alcohol ethoxylate with 5 EO C11 oxo alcohol ethoxylate with 7 EO C11 oxo alcohol ethoxylate with 8 EO C11 oxo alcohol ethoxylate with 8 EO C11 oxo alcohol ethoxylate with 11 EO C13 oxo alcohol ethoxylate with 2 EO C13 oxo alcohol ethoxylate with 5 EO C13 oxo alcohol ethoxylate with 6 EO C13 oxo alcohol ethoxylate with 8 EO C13 oxo alcohol ethoxylate with 8 EO C13 oxo alcohol ethoxylate with 9 EO C13 oxo alcohol ethoxylate with 15 EO C13 oxo alcohol ethoxylate with 25 EO C13 oxo alcohol ethoxylate with 30 EO C13 oxo alcohol ethoxylate with 40 EO C13 oxo alcohol ethoxylate with 100 EO C13 oxo alcohol ethoxylate with 100 EO C13 oxo alcohol ethoxylate with 100 EO C13 oxo alcohol ethoxylate C13 oxo alcohol ethoxylate
(2) 5

71 73 (3) 75 77 (3) 77 77 37 66 79 (3) 79 (3)

ca. 100 % ca. 100 % ca. 90 % ca. 100 % ca. 80 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 90 % ca. 100 % ca. 80 % ca. 100 % ca. 70 % ca. 70 % ca. 100 % ca. 35 % ca. 50 % ca. 40 % ca. 25 %

52 55 (1)* 62 65 (1) 62 62 25 59 64 > 74 65 (1)* 65 (3) 30 (2) 62 (2) 66 (2) 45 (1) 76 (2)

> 45 (1)* 74 76 (2)* 62 65 (1)

g in 100 cm 3 distilled water

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance

Trade name
Arkopal

Chemical name Nonylphenol ethoxylate with 4 EO Nonylphenol ethoxylate with 6 EO Nonylphenol ethoxylate with 8 EO Nonylphenol ethoxylate with 9 EO Nonylphenol ethoxylate with 10 EO Nonylphenol ethoxylate with 11 EO Nonylphenol ethoxylate with 13 EO Nonylphenol ethoxylate with 15 EO Nonylphenol ethoxylate with 20 EO Nonylphenol ethoxylate with 20 EO Nonylphenol ethoxylate with 23 EO Nonylphenol ethoxylate with 23 EO Nonylphenol ethoxylate with 30 EO Nonylphenol ethoxylate with 30 EO Nonylphenol ethoxylate with 30 EO Nonylphenol ethoxylate with 100 EO Tributylphenol ethoxylate with 6 EO Tributylphenol ethoxylate with 8 EO Tributylphenol ethoxylate with 11 EO Tributylphenol ethoxylate with 13 EO Tributylphenol ethoxylate with 13 EO Tributylphenol ethoxylate with 18 EO Tributylphenol ethoxylate with 30 EO Tributylphenol ethoxylate with 50 EO Tristyrylphenol ethoxylate with 5 EO

Active content ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 80 % ca. 100 % ca. 80 % ca. 100 % ca. 70 % ca. 80 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 90 % ca. 100 % ca. 100 % ca. 100 % ca. 100 %

Appearance (20C) liquid liquid liquid liquid liquid liquid liquid paste paste paste liquid waxy liquid waxy liquid liquid waxy liquid liquid liquid liquid liquid waxy waxy waxy liquid liquid liquid waxy waxy waxy waxy

Cloud point (C) 36 38 (2) 61 32 63 (2) 34 (1)

HLB value ca. 9 ca. 11 ca. 12 ca. 13 ca. 13 ca. 14 ca. 14 ca. 15 ca. 16 ca. 16 ca. 16 ca. 16 ca. 17 ca. 17 ca. 17 ca. 19 ca. 10 ca. 11 ca. 13 ca. 14 ca. 14 ca. 15 ca. 17 ca. 18 ca. 7 ca. 10 ca. 13 ca. 14 ca. 15 ca. 17 ca. 17

Nonylphenol ethoxylates N 040 Arkopal N 060 Arkopal N 080 Arkopal N 090 Arkopal N 100 Arkopal N 110 Arkopal N 130 Arkopal N 150 Arkopal N 200 Arkopal N 208 Arkopal N 230 Arkopal N 238 Arkopal N 300 Arkopal N 307 Arkopal N 308 Arkopal N 1000
Sapogenat

76 78 (2) 52 54 (1) 62 71 83 92 61 70 73 65 (1) 74 (1) 86 (1) 95 (1) 63 (3) 73 (3)* 75 (3)

70 73 (3)

73 75 (3)* 76 78 (3) 76 76 53 56 (2) 60 42 68 (2) 44 (1) 78 (3)* 78 (3)*

Tributylphenol ethoxylates T 060 Sapogenat T 080 Sapogenat T 110 Sapogenat T 130 Sapogenat T 139 Sapogenat T 180 Sapogenat T 300 Sapogenat T 500
Emulsogen

62 64 (1) 62 64 (1)* 61 23 27 (2) 65 69 (2) 58 55 62 (1) 60 (3) 64 (3)

Tristyrylphenol ethoxylates TS 050 Emulsogen TS 100 Emulsogen TS 160 Emulsogen TS 200 Emulsogen TS 290 Emulsogen TS 540 Emulsogen TS 600
(1) 1

Tristyrylphenol ethoxylate with 10 EO ca. 100 % Tristyrylphenol ethoxylate with 16 EO ca. 100 % Tristyrylphenol ethoxylate with 20 EO ca. 100 % Tristyrylphenol ethoxylate with 29 EO ca. 100 % Tristyrylphenol ethoxylate with 54 EO ca. 100 % Tristyrylphenol ethoxylate with 60 EO ca. 100 %
(2) 5

67 69 (3) 72 74 (3)

g in 100 cm 3 distilled water

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution *relative to the active substance

Nonionic Surfactants
Product range
Trade name Alkyl alkoxylates Genapol EP 0244
(former name Genapol 2822)

Chemical name Alcohol EO-PO adduct Alcohol EO-PO adduct Alcohol EO-PO adduct Oxoalcohol EO-PO adduct Oxoalcohol EO-PO adduct Oxoalcohol EO-PO adduct Oxoalcohol EO-PO adduct Alcohol EO-PO adduct

Active content ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 %

Appearance (20C) Cloud point (C) HLB value liquid liquid liquid liquid liquid liquid liquid liquid ca. 20 (1) 33,5 36,5 (2) 25 27 (2) 42 44 (2) 31 33 (2) 39 41 (2) 27,5 31 (1) 39 42 (1) > 25 (1) 31 34 (2)

Genapol EP 2424
(former name Genapol 3970)

Genapol EP 2464
(former name Genapol 3938)

Genapol EP 2544
(former name Genapol 2544)

Genapol EP 2552
(former name Genapol 2552)

Genapol EP 2564
(former name Genapol 2908)

Genapol EP 2584
(former name Genapol 2909)

Genapol PL 120

Ethylene oxide-propylene oxide block polymers Emulsogen 4084 Genapol PF 10 Genapol PF 20 Genapol PF 40 Genapol PF 80 p Genapol ED 3030
(former name Genapol B)

EO-PO block polymer with 60 % EO EO-PO block polymer with 10 % EO EO-PO block polymer with 20 % EO EO-PO block polymer with 40 % EO EO-PO block polymer with 80 % EO Ethylenediamine EO-PO block polymer Ethylenediamine EO-PO block polymer

ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 %

waxy liquid liquid liquid powder liquid liquid

68 70 (3) 34 55 66 69 37 (2) 58 (2) 69 (2) 72 (3)

ca. 12 ca. 2 ca. 4 ca. 8 ca. 16 ca. 9 ca. 6

52 55 (2) 27 30 (2)

Genapol ED 3060
(former name Genapol PN 30)

End capped Alkylethoxylates

10

Genapol BE 2410 Genapol BE 2805 Genapol BE 2810

Lauryl ethoxylate with 10 EO, butyl-end capped Coconut fatty alkyl ethoxylate with 5 EO, butyl-end capped Coconut fatty alkyl ethoxylate with 10 EO, butyl-end capped ca. 100 % liquid 39 42 (2) ca. 100 % liquid ca. 100 % liquid 36 39 (2)

(1) 1

g in 100 cm 3 distilled water

(2) 5

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance

Trade name
Genagen

Chemical name C12 / C14 fatty acid polyglycol ester with 10 EO C16 / C18 fatty acid polyglycol ester with 6 EO C16 / C18 fatty acid polyglycol ester with 10 EO C16 / C18 fatty acid polyglycol ester with 15 EO Stearic acid polyglycol ester with 25 EO Diglycerol oleate Diglycerol diisostearate Diglycerol monostearate Polyglycerol diisostearate Diglycerol distearate ethoxylated with 4 EO Diglycerol laurate ethoxylated with 10 EO Castor oil ethoxylate with 20 EO Castor oil ethoxylate with 36 EO Castor oil ethoxylate with 40 EO Castor oil ethoxylate with 54 EO Hydrogenated castor oil ethoxylate with 40 EO Hydrogenated castor oil ethoxylate with 60 EO Hydrogenated castor oil ethoxylate with 40 EO Lauroyl sorbitane ethoxylate with 20 EO Alkylethoxylate Mixture of different alkyl ethoxylates

Active content ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 100 % ca. 090 % ca. 100 % ca. 100 % ca. 100 %

Appearance (20C) liquid liquid liquid liquid waxy liquid liquid pellets liquid waxy liquid liquid liquid liquid liquid paste paste liquid liquid paste paste

Fatty acid polyethyleneglycol esters C 100 Genagen O 060 Genagen O 100 Genagen O 150 Genagen S 250 Emulsogen OG Hostacerin DGI Hostacerin DGMS Hostacerin TGI Hostacerin DGSB Hostacerin DGL Castor oil ethoxylates Emulsogen EL 200 Emulsogen EL 360 Emulsogen EL 400 Emulsogen EL 540 Emulsogen HCO 040 Emulsogen HCO 060 Emulsogen HCP 049 Sorbitane ester ethoxylate Emulsogen 4156 Wax emulsifiers Emulsogen P Emulsogen PN extra

Fatty acid polyglycerol esters

Fatty acid polyglycerol ester ethoxylates

(1) 1

g in 100 cm 3 distilled water

(2) 5

g in 25 cm 3 25 % aqueous BDG

(3) 1

g in 100 cm 3 10 % aqueous NaCl solution * relative to the active substance

11

Anionic Surfactants
Product range
Trade name
Hostapur

Chemical name Secondary alkyl sulphonate, Na salt Secondary alkyl sulphonate, Na salt Secondary alkyl sulphonate, Na salt C14 / C16 alpha-olefin sulphonate, Na salt C14 / C16 alpha-olefin sulphonate, Na salt C12 / C14 alkyl sulphate, Na salt C12 alkyl sulphate, Na salt Alkyl ether sulphate with 7 EO, Na salt Alkyl ether sulphate with 7 EO, Na salt Alkyl ether sulphate with 8 EO, Ammonium salt C12 / C 14 alkyl ether sulphate with 2 EO, Na salt C12 / C 14 alkyl ether sulphate with 2 EO, Na salt C12 / C 14 alkyl ether sulphate with 3 EO, Na salt Lauryl ether sulphate with 3 EO, ammonium salt + organ. solvent Tributyl phenol ether sulphate with 7 EO, Na salt Tributyl phenol ether sulphate with 7 EO, Na salt Polyalkylene glycol ether sulphate, ammonium salt Diisodecyl sulphosuccinate, Na salt +IPA Diisooctyl sulphosuccinate, Na salt Octyl amine sulphosuccinamate, Na salt Tallow alkyl amine sulphosuccinamate, Na salt Cetyl phosphoric acid ester, acid form Phosphoric acid ester of lauryl ethoxylate (2 EO) and polyethylene glycol

Active content ca. 30 % ca. 60 % ca. 93 % ca. 42 % ca. 90 % ca. 30 % ca. 15 % ca. 28 % ca. 28 % ca. 30 % ca. 27 % ca. 68 % ca. 27 % ca. 50 % ca. 50 % ca. 17 % ca. 50 % ca. 65 % ca. 50 % ca. 36 % ca. 36 % ca. 100 % ca. 95 %

Appearance (20C) liquid paste waxy pellets liquid powder liquid liquid liquid liquid liquid liquid paste liquid liquid paste liquid liquid liquid liquid liquid liquid powder liquid

Secondary alkyl sulphonates (Secondary alkane sulphonates) SAS 30 Hostapur SAS 60 Hostapur SAS 93 Olefin sulphonates Hostapur OS liquid Hostapur OSB Alkyl sulphates Emulsogen EPA 1954 Emulsogen LS Alkyl ether sulphates Emulsogen EPA 073 Emulsogen LCA 073 Emulsogen LA 083
Genapol

LRO liquid

Genapol LRO paste Emulsogen ZRO liquid Zeliquid LP 2 Alkyl aryl ether sulphates
Hostapal

BV conc.

Hostapal BV liquid Polyglycol ether sulphates Emulsogen PF 20 S Sulphosuccinic acid esters Emulsogen SB 10 Emulsogen SF 8 Emulsogen OLS Emulsogen TAS Hostaphat CC 100

Fatty alkyl amine sulphosuccinamates

Phosphoric acid mono esters

12

Phosphoric acid di esters Hostaphat L 327

Phosphoric acid mono/di esters Hostaphat MDAH Hostaphat CG 120 Hostaphat CS 120 Hostaphat 1306 Mono-/di-2-ethylhexyl phosphoric acid ester, acid form Mono-/diisostearyl phosphoric acid ester, acid form Mono-/distearyl phosphoric acid ester, acid form Isotridecyl polyoxethyl (6 EO) phosphoric acid mono/diester, acid form ca. 98 % ca. 90 % ca. 92 % ca. 96 % liquid liquid wax liquid

Trade name Emulsogen DMR Hostaphat B 310 Hostaphat KL 340 D Hostaphat KL 340 N Hostaphat KW 340 D Hostaphat KW 340 N Hostaphat OPS 100 Hostaphat OPS 75 Emulsogen CLA 020 Emulsogen CLA 030 Emulsogen CLA 050 Emulsogen CLA 070 Emulsogen CLA 110 Emulsogen COA 070 Emulsogen COL 020 Emulsogen COL 050 Emulsogen COL 080 Emulsogen COL 100 Fatty acid isethionates Hostapon SCI-65 Arkopon T Teig 8015 Hostapon CT Teig Hostapon TPHC Arkomon SO Medialan LD Calsogen 3546 Calsogen 4814 Phenylsulfonate CA Phenylsulfonate CA 100 Phenylsulfonate CAL

Chemical name Stearoyl polyoxyethylene phosphate Tributoxyethyl phosphate, acid form Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt Lauryl polyethoxy (4 EO) phosphoric acid ester, Na-salt Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt Stearyl polyethoxy (4 EO) phosphoric acid ester, Na-salt n-Octane phosphonic acid n-Octane phosphonic acid + organ. solvent/water Fatty alcohol polyoxyethylene carboxylic acid with 2 EO Fatty alcohol polyoxyethylene carboxylic acid with 3 EO Fatty alcohol polyoxyethylene carboxylic acid with 5 EO Fatty alcohol polyoxyethylene carboxylic acid with 7 EO Fatty alcohol polyoxyethylene carboxylic acid with 11 EO Fatty alcohol polyoxyethylene carboxylic acid with 7 EO Fatty alcohol polyoxyethylene carboxylic acid with 2 EO Fatty alcohol polyoxyethylene carboxylic acid with 5 EO Fatty alcohol polyoxyethylene carboxylic acid with 8 EO Fatty alcohol polyoxyethylene carboxylic acid with 10 EO Coconut fatty acid isethionate, Na salt Oleic acid methyl tauride, Na salt Coconut fatty acid methyl tauride, Na salt Oleic acid methyl tauride, Na salt Oleyl sarkosin Lauroyl sarcoside, Na salt Tetrapropylene benzenesulphonate, Ca-salt in 2-ethyl hexanol n-Dodecyl benzenesulphonate, Ca-salt in 2-ethyl hexanol Tetrapropylene benzenesulphonate, Ca-salt in isobutanol Tetrapropylene benzenesulphonate, Ca-salt in solvent naphtha and a nonionic surfactant, flash point > 100C n-Dodecyl benzenesulphonate, Ca-salt in isobutanol and a nonionic surfactant

Active content ca. 100 % ca. 87 % ca. 90 % ca. 90 % ca. 90 % ca. 90 % ca. 100 % ca. 75 % ca. 90 % ca. 90 % ca. 90 % ca. 90 % ca. 90 % ca. 90 % ca. 90 % ca. 94 % ca. 90 % ca. 90 % ca. 65 % ca. 40 % ca. 30 % ca. 60 % ca. 95 % ca. 30 % ca. 60 % ca. 60 % ca. 70 % ca. 40 % ca. 70 % ca. 62 %

Appearance (20C) flakers liquid liquid liquid liquid liquid waxy liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid flakes paste paste powder liquid liquid liquid liquid pasty viscous liquid pasty liquid

Phosphoric acid mono/di/tri esters

Alkyl phosphonic acids

Alkyl polyethylene glycol ether carboxylic acids

Fatty acid methyl taurides

Fatty acid sarkosin and sarkoside

Alkyl benzenesulphonates, Ca-salts

13

Phenylsulfonate CAN Tetrapropylene benzenesulphonate, Ca-salt in isobutanol

Copolymerizable Emulsifiers & Speciality Monomers

Product range
Trade name Emulsogen R 109 Emulsogen R 208 Emulsogen R 307 Emulsogen RAL 109 Emulsogen RAL 208 Emulsogen RAL 307 Emulsogen APS 100 Emulsogen APS 104 Chemical name Vinyl ether alkoxylate with 10 EO Vinyl ether alkoxylate with 20 EO Vinyl ether alkoxylate with 30 EO Allyl ether alkoxylate with 10 EO Allyl ether alkoxylate with 20 EO Allyl ether alkoxylate with 30 EO Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt Allyl polyoxyalkylene sulphate with 10 EO, ammonium salt Active content ca. 90 % ca. 80 % ca. 70 % ca. 90 % ca. 80 % ca. 70 % ca. 100 % ca. 40 % ca. 100 % ca. 90 % ca. 100 % ca. 100 % ca. 100 % Appearance (20C) liquid liquid liquid liquid liquid liquid liquid liquid liquid liquid pasty waxy liquid Vinyl ether alkoxylates (PO-EO-block polymers)

Allyl ether alkoxylates (PO-EO-block polymers)

Allyl polyoxyalkylene sulphates

Emulsogen APS 100 S Allyl polyoxyalkylene sulphate with 10 EO, Na salt Allyl polyoxyarylene sulphates Emulsogen APG 2019 Allyl phenylpolyol ether sulphate with 20 EO, ammonium salt Methacrylic acid esters Genagen M 750 MA Genagen M 1100 MA Genagen LA 070 MA Methacrylic acid ester of polyethyleneglycol ether Methacrylic acid ester of polyethyleneglycol ether Methacrylic acid ester of C12/C14 fatty alcohol ethoxylate with 7 EO

14

Dispersing Agents
Product range
Trade name Dispersogen NN Dispersogen R 5 Dispersogen 5338 Chemical name Condensation product of formaldehyde and naphthalene sulphonate, sodium salt, max. 20 % Na2SO4 Condensation product of formaldehyde and naphthalene sulphonate, sodium salt, max. 5 % Na2SO4 Condensation product of formaldehyde and naphthalene sulphonate, sodium salt, max. 10 % Na2SO4 Alkylphenol - formaldehyde - bisulphite condensates Dispersogen 1494 Dispersogen 1494 liquid Dispersogen P liquid Novolac derivatives Dispersogen 1728 Dispersogen 2774 Dispersogen 2774-1 Dispersogen 2774-2 Dispersogen LFH Dispersogen LFS Castor oil derivatives, anionic Dispersogen 4387 Quaternary dispersing agents Dispersogen SPS Stabilizer and dispersing agent for sodium silicate in silicate paints n.n. liquid Castor oil polyoxyethylene sulphosuccinic acid ester, Na salt ca. 80 % liquid Nonylphenol novolac polyoxyethylene sulphosuccinate, Na salt Nonylphenol novolac ethoxylate Nonylphenol novolac ethoxylate in ethylene glycol Nonylphenol novolac ethoxylate in propylene glycol Tristyrylphenol polyoxyethylene phosphoric acid ester Tristyrylphenol polyoxyethylene phosphoric acid ester, triethanolamine salt ca. 100 % ca. 50 % ca. 50 % ca. 96 % ca. 92 % liquid liquid liquid liquid liquid ca. 35 % liquid Condensation product of formaldehyde, cresol, nonylphenol and sodium bisulphite; contains NaCl Condensation product of formaldehyde, cresol, nonylphenol and sodium bisulphite; contains NaCl Condensation product of formaldehyde, cresol and sodium bisulphite; contains NaCl ca. 26 % liquid ca. 35 % liquid ca. 80 % powder ca. 92 % powder ca. 95 % powder Active content ca. 80 % Appearance (20C) powder Naphthalene sulphonic acid - formaldehyde condensates

Tristyrylphenol derivatives, anionic

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Defoamers
Product range
Trade name Antimussol 4752 Ionicity nonionic Flash Point > 100C Appearance (20C) liquid Application example FDA-approved defoamer for paper treatment and other industrial applications Antimussol V 4847 Antimussol V 5282 nonionic nonionic > 100C > 100C liquid liquid EPA-approved defoamer for crop protection defoamer for water miscible formulations Polyalkylene glycol based defoamers Antimussol TW Antimussol V 5084 Genapol PH 10 Genapol PF 10 nonionic nonionic nonionic nonionic > 100C > 100C > 100C > 100C liquid liquid liquid liquid emulsion polymers, water treatment defoaming of surfactant formulations EO/PO block polymer for metal working fluids and other industrial applications EO/PO block polymer for industrial applications e.g. sugar refinement Phosphate ester based defoamers Antimussol TIP anionic ca. 27C liquid Phosphorus containing defoamer for emulsion polymerization and other industrial applications, water treatment Mineral oil based defoamers Antimussol 4846 N anionic > 100C liquid Phosphorus containing defoamer for emulsion polymers and other industrial applications Antimussol V 5348 nonionic > 150C liquid emulsion paints, coatings, pigment preparations Silicone containing defoamers

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Surfactants from Clariant

Emulsifiers for emulsion polymerization
Diagram: emulsion polymerization Emulsifiers are substances that become active at interfaces. They perform a number of tasks in the complex system of emulsion polymerization. For example they enable the water-insoluble monomers to be distributed extremely finely in the aqueous phase and stabilize the polymer dispersion produced from it. Clariant emulsifiers are used to manufacture a variety of polymer systems:

s In the polymerization of vinyl acetate

Polymer Particle to homopolymers or co- and terpolymers together with other vinyl esters, acrylates, vinyl chloride and ethylene

s In the polymerization of pure acrylate

and styrene-acrylate dispersions

s In the manufacture of butadienestyrene latices

s In the manufacture of polyvinyl

chloride using the emulsion polymerization process

s In the manufacture of butadieneExplanation:

styrene rubber

s In the manufacture of ABS plastic

Protective Colloid Molecules

The diagram beside shows a model of the complex interactions involved in the stabilization of the polymer particles.

OH Groups

Emulsifier Molecules

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Surfactants from Clariant

Emulsifiers for emulsion polymerization
Apart from stabilizing the monomer emulsion, emulsifiers have a great influence on the properties of the polymer dispersions. These include important parameters such as particle size and particle size distribution of the polymer particles, viscosity, electrolyte stability, frost resistance of the dispersion, filmforming properties and many other application properties of the polymer dispersion. The slightest changes to the polymerization system can lead to considerable variations in the dispersion properties. To ensure consistent quality of the polymer dispersion, our emulsifiers are subject to strict quality control. The influence of the nonionic emulsifier on the dispersion properties was investigated by means of a model formulation for a polyvinyl acetate dispersion. Nonionic emulsifier Emulsogen EPN 118 Emulsogen EPN 207 Emulsogen EPN 287 Emulsogen EPN 407
1)

Vinyl acetate dispersion, model formulation Composition Water

Tylose

Concentration 32.02 % 1.06 % 0.26 % 0.91 % 1.51 % 0.11 % 0.15 % 4.50 % 5.30 % 6.48 % 47.70 %

H 200 YG4 EPA 073 EPN grade

Borax
Emulsogen Emulsogen

Acetic acid 98 %
Nipacide

CI 15 (preservative)

Initiator solution (to liquor) Monomer mixture (to liquor) Initiator solution (stock batch) Monomer mixture (stock batch) Monomer mixture
VeoVa

10, Shell1)

25 % 1.17 %

Vinyl acetate Water

75 % 98.83 %

Initiator solution Potassium peroxodisulphate

The Emulsogen EPN grades investigated are nonionic emulsifiers based on an oxoalcohol with different degrees of ethoxylation. Degree of ethoxylation 11 mol ethylene oxide 20 mol ethylene oxide 28 mol ethylene oxide 40 mol ethylene oxide

VeoVa 10 is a registered trademark of Shell for 2,2-dimethyloctanoic acid vinyl ester

The two graphs that follow on page 8 show the influence of the degree of ethoxylation of the fatty alcohol ethoxylates on the viscosity of the dispersion and on the particle size. The emulsifier concentrations were kept constant.

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Influence of the emulsifier on the viscosity of a vinyl acetate/ VeoVa 10 dispersion

Viscosities of Emulsogen-containing polymer dispersions (vinyl acetate/ VeoVa 10) Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %)

Influence of the emulsifier on the particle size2) of a vinyl acetate/ VeoVa 10 dispersion

Particle size of polymer dispersions (vinyl acetate/ VeoVa 10) with: Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %); Emulsogen EPN grades (1.51 %)
2)

Determined by turbidity measurements, these values are not absolute but indicate a tendency

Not only the constitution of the emulsifier but also its concentration has an influence on the properties of the dispersion. The next four graphs

illustrate this effect on the viscosity of the dispersion by means of the model formulation vinyl acetate/ VeoVa 10.

19

Surfactants from Clariant

Emulsifiers for emulsion polymerization
Influence of the concentration of Emulsogen EPN 118 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 118-containing polymer dispersions (vinyl acetate/ VeoVa 10); Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %)

Influence of the concentration of Emulsogen EPN 207 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 207containing polymer dispersions (vinyl acetate/ VeoVa 10); Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %)

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Influence of the concentration of Emulsogen EPN 287 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 287-containing polymer dispersions (vinyl acetate/ VeoVa 10); Tylose H 200 YG4 (1.06%); Emulsogen EPA 073 (0.91%)

Influence of the concentration of Emulsogen EPN 407 on the viscosity of the dispersion

Viscosities of Emulsogen EPN 407-containing polymer dispersions (vinyl acetate/ VeoVa 10); Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %)

21

Surfactants from Clariant

Emulsifiers for emulsion polymerization
The following graphs on this page show amount of coagulate and the water abthe effect of the emulsifier system on the sorption of the polymer film. Influence of the emulsifier on the amount of coagulate in a vinyl acetate/ VeoVa 10 dispersion

Amount of coagulate in Emulsogen-containing polymer dispersions (vinyl acetate/ VeoVa 10) with: Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %); Emulsogen EPN grades (1.51%)

Method: Filtration of the dispersion through a 100- m screen, then filtration of the filtrate through the finer 40- m screen.

Influence of the emulsifier on the water absorption of a dispersion film based on vinyl acetate/ VeoVa 10

Water absorption of Emulsogen-containing polymer dispersions (vinyl acetate/ VeoVa 10) with: Tylose H 200 YG4 (1.06 %); Emulsogen EPA 073 (0.91 %); Emulsogen EPN grades (1.51%)

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This information is based on our present knowledge and is intended to provide general notes on our products and their uses. It should not therefore be construed as guaranteeing specific Our products are constantly upgraded on the basis of the latest research results. Products may occasionally be deleted in the course of updating the sales range. Development products that have reached the production stage are not included in this list. properties of the products described or their suitability for a particular application. Any existing industrial property rights must be observed. The quality of our products is guaranteed under our General Conditions of Sale. February 2004

23

Exactly your chemistry.

Clariant GmbH Division Functional Chemicals Industrial Performance Chemicals Research & Development Worldwide 65926 Frankfurt, Tel.: +49-69-305-6308, Fax: +49-69-305-16504 Marketing Europe 65840 Sulzbach, Tel.: +49-6196-757-7437, Fax: +49-6196-757-8945 USA & Canada Mount Holly NC 28120, Tel.: +1-704-822-2514, Fax: +1-704-822-2193 Mexico 53500 Naucalpan, Tel.: +52-55-5329-1877, Fax: +52-55-5387-3248 Latin America 04795-900 So Paulo SP, Tel.: +55-11-5683-7413, Fax: +55-11-5683-7694 China Tsuen Wan, Hong Kong, Tel.: +852-2406-4189, Fax: +852-2506-1636 Japan Tokyo 113-8662, Tel.: +81-3-5977-7934, Fax: +81-3-5977-7893 South-East Asia Tangerang, Jakarta, Tel.: +62-21-5579-3656, Fax: +62-21-5579-7139 Australia/New Zealand Chadstone Vic 3148, Tel.: +61-3-9254-1092, Fax: +61-3-9254-1011 Internet: www.ipc.clariant.com
EBR 5216 E 02/04 DSB&K