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    Phosporescene

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    Yasherly Amrina
    The document discusses phosphorescence, which is the process where a molecule holds a transition from the triplet to the ground level and re-emits radiation over a longer time scale than fluorescence. It describes excited states that can produce phosphorescence related to electron spin and singlet/triplet states. Energy level diagrams of photoluminescent molecules are also explained. The document also mentions instruments that can measure phosphorescence by irradiating and measuring a sample over time.

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    Phosporescene

    Uploaded by

    Yasherly Amrina
    98 views10 pages
    The document discusses phosphorescence, which is the process where a molecule holds a transition from the triplet to the ground level and re-emits radiation over a longer time scale than fluorescence. It describes excited states that can produce phosphorescence related to electron spin and singlet/triplet states. Energy level diagrams of photoluminescent molecules are also explained. The document also mentions instruments that can measure phosphorescence by irradiating and measuring a sample over time.

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    fosforisensi, luminescene,

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    phosporescene

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    The document discusses phosphorescence, which is the process where a molecule holds a transition from the triplet to the ground level and re-emits radiation over a longer time scale than fluorescence. It describes excited states that can produce phosphorescence related to electron spin and singlet/triplet states. Energy level diagrams of photoluminescent molecules are also explained. The document also mentions instruments that can measure phosphorescence by irradiating and measuring a sample over time.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
    Download as pptx, pdf, or txt
    98 views10 pages

    Phosporescene

    Uploaded by

    Yasherly Amrina
    The document discusses phosphorescence, which is the process where a molecule holds a transition from the triplet to the ground level and re-emits radiation over a longer time scale than fluorescence. It describes excited states that can produce phosphorescence related to electron spin and singlet/triplet states. Energy level diagrams of photoluminescent molecules are also explained. The document also mentions instruments that can measure phosphorescence by irradiating and measuring a sample over time.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PPTX, PDF, TXT or read online from Scribd
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    PHOSPORESCENCE

    GROUP 4 : 1. ADRIAN SAPUTRA 2. JERVITA SARI 3. NADIRA 4. NANDA RAUDHATIL J 5. VANELLA INDAH P 6. LOVERA ANGGRAINI

    (0910412041) (1110412018) (1110412021) (1110412024) (1110412028) (1110413017)

    Phosphorescence

    The process of a molecule hold a transition (emission) from the triplet to the ground level. A phosphorescent material does not immediately re-emit the radiation it absorbs. Phosphorescence (molecular fluorescence) bands are found centered at wavelengths that are longer than the resonance line

    The slower time scales of the re-emission are associated with "forbidden" energy state transitions in quantum mechanics. As these transitions occur very slowly in certain materials, absorbed radiation may be reemitted at a lower intensity for up to several hours after the original excitation.

    Excited States Producing Phosphorescence

    Electron spin The Pauli exclusion principle states that no two electrons in an atom can have the same set of four quantum numbers. This restriction requires that no more than two electrons can occupy an orbital and furthermore the two must have opposed spin states

    Singlet/Triplet Excited States Singlet state is a molecular electronic state in which all electron spins are paired. When one of a pair of electrons of a molecule is excited to a higher energy level, either a singlet or triplet state is formed.

    In the excited singlet state, a spin of the promoted electron is still paired with the ground-state electron ; in the triplet state however the spin of the two electrons have become unpaired, and are thus parallel. The excited triplet state is less energetic than the corresponding excited singlet state.

    Energy-Level diagrams for Photoluminescent Molecules

    The lowest heavy horizontal line represents the groundstate energy of the molecule, which is normally a singlet state and is labeled So The two lines on the left represent the first (S1) and second (S2) electronic singlet state. T1 represents the energy of the first electronic triplet state.

    The Instrument for measuring The Phosphorescence

    The first is the device that will alternately irradiate a sample an after a suitable time delay, measure intensity of phosphorescence. The time delay is required to differentiate between long-lived phosphorescence emission an short live fluorescence emission, both of which would originate from the same sample.

    APPLICATION OF PHOSPHORIMETRIC METHOD


    Phosphorimetry has been used for determination of a variety of organic and biochemical species including such substances as : 1. Nucleid acid 2. Amino Acid 3. Pyrine and pyrimidine 4. Enzymes 5. Petroleum hydrocarbon 6. pesticides

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