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Unit 3: Chemical Kinetics

This document covers chemical kinetics and integrated rate laws, including first order, second order, and zero order reactions. It defines rate laws and integrated rate laws, and gives the equations to calculate concentration over time, half-life, and time to reach a specific concentration for each reaction order. Examples are also provided to demonstrate using the equations to analyze reaction kinetics.

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Caitlene Lee Uy
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27 views11 pages

Unit 3: Chemical Kinetics

This document covers chemical kinetics and integrated rate laws, including first order, second order, and zero order reactions. It defines rate laws and integrated rate laws, and gives the equations to calculate concentration over time, half-life, and time to reach a specific concentration for each reaction order. Examples are also provided to demonstrate using the equations to analyze reaction kinetics.

Uploaded by

Caitlene Lee Uy
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
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CHEM 301 Analytical Chemistry

Unit 3
Chemical Kinetics:
Rate Laws
Integrated Rate Laws
Model for Chemical Kinetics
CHEM 301 Analytical Chemistry

Integrated Rate Laws


First Order Rate Law
CHEM 301 Analytical Chemistry

Integrated Rate Laws


First Order Rate Law
CHEM 301 Analytical Chemistry

Integrated Rate Laws


First Order Rate Law

ln[A] = -akt + ln[A]o


where [A]0 = initial concentration at t=0
[A] = final concentration at any time t

Half-life:
t 1 0.693
2 k
CHEM 301 Analytical Chemistry

Integrated Rate Laws

Second Order Rate Law


CHEM 301 Analytical Chemistry

Integrated Rate Laws

Second Order Rate Law

t1 1
Half-life:
2 k[A]0
CHEM 301 Analytical Chemistry

Integrated Rate Laws

Zero Order Rate Law

[A] = - akt - [A]o

Half-life: [A]0
t1
2 2k
CHEM 301 Analytical Chemistry

Integrated Rate Laws


example:
The decomposition of N2O5 at 67 C is 1st order with k = 0.35/min.

Calculate:

a. the concentration after 4.0 min if the initial concentration is 0.16 M

b. the time required for the concentration to drop from 0.16 M to 0.10 M

c. the half-life for the reaction


CHEM 301 Analytical Chemistry

Integrated Rate Laws


example:
Consider the reaction:

I (g) + I (g) I2 (g)

k = 0.70 M/s at 23 C, 2nd order

Calculate:

a. the concentration after 2.0 sec if the initial concentration is 0.086 M

b. the time required for the concentration to drop from 0.10 M to 0.045 M

c. the half-life for the reaction if the initial concentration is 0.60 M

d. the half-life for the reaction if the initial concentration is 0.42 M


CHEM 301 Analytical Chemistry
CHEM 301 Analytical Chemistry

reaction rate law integrated rate law


half-life
order expression equation

first rate = k[A] ln[A] - ln[A]0 = -kt t = 0.693/k

second rate = k[A]2 1/[A] = kt + 1/[A]0 t = 1/k[A]0

zero rate = k[A]0 [A] = -kt + [A]0 t = [A]0/2k

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