Luminescence
Luminescence
Luminescence
Mamta Garg
Research Scholar
Under the supervision of
Excitation source:
• Light (laser) Photoluminescence
• Electron Cathodoluminescence
• Electric field Electroluminescence
• Chemical reaction Chemiluminescence
Relaxation:
• Phonon emission 10-15 seconds
• Carrier migration 10-12 seconds
• Exciton formation 10-12 seconds
• Recombination 10-9 seconds
• Ability to focus to
• very small spots
Pure Semiconductor at 0K
Light Emission in Solids
The excited state is unstable and has a
finite lifetime.
• Electron hole pairs recombine to give
light.
• The energy of the emitted light is
approximately equal to the band gap.
(Why)?
Light Emission in Solids
The emission of light can be classified as spontaneous and stimulated.
Spontaneous emission occurs without the need of any other type of stimulus.
The lifetime of excited states is relatively short, of the order of a few nanoseconds.
It is accompanied by the emission of a photon and/or the dissipation of heat. This
mechanism is also called luminescence or fluorescence.
Some materials have higher lifetimes, of the order of microseconds or
milliseconds, in which case the process is called phosphorescence.
Spontaneous light emission is incoherent (the phase of light waves is random),
nearly isotropic (it has a broad angular emission), and polychromatic (over a range
of wavelengths).