Luminescence

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Luminescence

Mamta Garg
Research Scholar
Under the supervision of

Dr. S.K. Tripathi


Topics for this Lecture
 Luminescence in semiconductors
 Excitons
Luminescence
Luminescence is "cold light" that can be emitted at
normal and lower temperatures. In luminescence,
some energy source kicks an electron of an atom
out of its lowest energy "ground" state into a
higher energy "excited" state; then the electron
returns the energy in the form of light so it can fall
back to its "ground" state. With few exceptions, the
excitation energy is always greater than the energy
(wavelength, color) of the emitted light.
Types of Luminescence
• Fluorescence
– Happens quickly after initial photon absorption
(μs to ps lifetime).
• Phosphorescence
– Happens slowly after initial photon absorption
(min to ms lifetime).
• Chemiluminescence
– Excitation arises from a chemical reaction,
instead of photo absorption
Luminescence in semiconductors
Light emission in semiconductors is a
result of
three processes:
• Generation on electron-hole pairs
• Relaxation and/or diffusion of
carriers
• Recombination
Applications:
• Light emitting diodes
• Laser diodes
• Phosphors
Cont….

Excitation source:
• Light (laser) Photoluminescence
• Electron Cathodoluminescence
• Electric field Electroluminescence
• Chemical reaction Chemiluminescence

Relaxation:
• Phonon emission 10-15 seconds
• Carrier migration 10-12 seconds
• Exciton formation 10-12 seconds
• Recombination 10-9 seconds
• Ability to focus to
• very small spots
Pure Semiconductor at 0K
Light Emission in Solids
The excited state is unstable and has a
finite lifetime.
• Electron hole pairs recombine to give
light.
• The energy of the emitted light is
approximately equal to the band gap.
(Why)?
Light Emission in Solids
The emission of light can be classified as spontaneous and stimulated.

Spontaneous emission occurs without the need of any other type of stimulus.
The lifetime of excited states is relatively short, of the order of a few nanoseconds.
It is accompanied by the emission of a photon and/or the dissipation of heat. This
mechanism is also called luminescence or fluorescence.
Some materials have higher lifetimes, of the order of microseconds or
milliseconds, in which case the process is called phosphorescence.
Spontaneous light emission is incoherent (the phase of light waves is random),
nearly isotropic (it has a broad angular emission), and polychromatic (over a range
of wavelengths).

Stimulated emission: Under special conditions, light can be produced by


stimulation with an external means. This results in the emission of a highly
coherent and monochromatic radiation. This phenomenon is used in lasers.
Interband Luminescence
Interband Luminescence
Interband Luminescence

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