Sewage Treatment: Chapter Four: (Part One) Secondary/Biological and Tertiary Wastewater Treatment by Roman A
Sewage Treatment: Chapter Four: (Part One) Secondary/Biological and Tertiary Wastewater Treatment by Roman A
𝑥 𝑡 =𝑥 𝑜 𝑒 (𝜇 − 𝐷 )𝑡
During chemostat cultivation, equilibrium is established (steady
state) at which the growth rate of the cells equals the dilution
3. Other Kinetic
Three important parameters in microbial growth kinetics:
Parameters
a) yield (Y),
b) specific growth rate (μ), and
c) specific substrate uptake rate (q).
A more simplified equation showing the relationship between
the three parameters is the following:
μ = Yq
Where μ - specific growth rate (time-1),
Y - growth yield (mg cells formed per mg of substrate removed),
and
q – specific substrate uptake rate (mg/L/day).
CONT.
1. Growth Yield
It reflects the efficiency of conversion of substrate to cell material.
The yield coefficient Y is obtained as;
𝑿−𝑿𝑶
Y=
𝑺𝑶−𝑺
Where So and S -initial and final substrate concentrations,
respectively (mg/L or mol/L),
Xo and X - initial and final microbial concentrations,
respectively Factors influence the growth yield:
type of microorganisms, growth medium, substrate
concentration, terminal electron acceptor, pH, and incubation
temperature.
Yield coefficients for several bacterial species are within the range
0.4 – 0.6.
For a pure microbial culture growing on a single substrate,
CONT.
The growth yield Y must be corrected for the amount of cell
decay occurring during the declining phase of growth. This
correction will give the true growth yield coefficient, which is
lower than the measured yield.
μ = Yq − kd
Where kd is the endogenous decay coefficient (day-1)
ii. Specific Substrate Uptake Rate (q)
Where q (time-1) is given by the Monod’s equation
[𝑠
q=𝑞 ]
𝑚 𝑎 𝑥 𝑘 [𝑠]
𝑠−
CONT.
iii. Specific Growth Rate μ
Where μ (day-1) is given by Monod’s equation:
[𝒔]
μ=𝝁
𝒎𝒂𝒙 𝒌
𝒔−[𝒔]
The in situ specific growth rate of bacteria in wastewater was
measured using the labeled thymidine growth assay.
In an aerobic tank, the specific growth rate μ was 0.5 d-1
(doubling time td = 1.4d) whereas in an anaerobic tank μ was
equal to 0.2 d-1 (td = 3.9d) .
In waste treatment, the reciprocal of μ is the biological solid
retention time θc, that is
μ= 𝟏 Thus, 𝟏 =𝒀
θc θc 𝒒−𝑲𝒅
4. Physical and Chemical Factors Affecting Microbial
Growth
i. Substrate Concentration
The relationship between the specific growth rate μ and
substrate concentration S is given by the Monod’s equation.
[𝑠]
μ=𝜇
𝑚 𝑎 𝑥 𝑘 [𝑠]
𝑠−
μ = 𝐴𝑒 −𝐸/𝑅𝑇
Where A - constant,
E - activation energy (kcal/mole),
R - gas constant, and T - absolute temperature (K)
CONT
i.ii. pH
Biological treatment of wastewater occurs generally at neutral pH.
Fungi prefer acidic environments with a pH of 5 or lower.
Cyanobacteria grow optimally at pH higher than 7.
pH affects the activity of microbial enzymes. It affects the ionization
of chemicals and thus plays a role in the transport of nutrients and
toxic chemicals into the cell.
iv. Oxygen Level
Microorganisms can grow in the presence or in the absence of
oxygen.
There are divided into strict aerobes, facultative anaerobes, and
strict
anaerobes.
Aerobic microorganisms use oxygen as the terminal electron acceptor
in respiration. Anaerobic counterparts use other electron acceptors
such as sulfate, nitrate, or CO2. micro-aerophilic and require low
Biological Wastewater Treatment
Purpose:
In other words, the purpose of biological treatment is BOD reduction.
Principle:
The wastewater exiting the system is then much clearer than
it entered.
A key factor is the operation of any biological system is an adequate
supply of oxygen. Indeed, cells need not only organic material as food
but also oxygen to breath, just like humans.
Without an adequate supply of oxygen, the biological degradation of
the waste is slowed down, there by requiring a longer residency time
of the wastewater in the system.
For a given flow rate of wastewater to be treated, this translates into a
system with a larger volume and thus taking more space.
Types of Biological Process for Wastewater Treatment
The common methods of biological wastewater treatment are:
a)Aerobic processes such as trickling filters, Rotating Biological
Contactors, Activated Sludge Process, Oxidation Ponds and
Lagoons, Oxidation Ditches,
b) Anaerobic Processes Such As Anaerobic Digestion, and
C) Anoxic Processes Such As Denitrification.
Trickling Filters
Also known as percolating filters or sprinkling filters.
It is the most common attached growth process.
Consist of tanks of coarser filtering media, over which the sewage is
allowed to sprinkle or trickle down, by means of spray nozzles or
rotary distributors.
The trickling filter is like a circular well having depth up to2- 3meter
filled with granular media like stone, plastic sheets and redwood,
slag, slate.
The percolating sewage is collected at the bottom of the tank
through a well designed under-drainage system.
The effluent obtained from the filter must be taken to the secondary
sedimentation tank for settling out the organic matter oxidized
while passing down the filter.
CONT
.
100
(%) =
𝑌
1 + 0.0044
𝑉∗𝐹
CONT.
Where, = 82.85%
Y = Total BOD in kg = 787.5kg
1+R
F= I 2
R
1 + 0.1 ∗ I
Here,RI = 1.5 (given)
1+R 1 + 1.5
= 𝟏. 𝟖𝟗
F= I 2=
R 1 + 0.1 ∗ 1.5 2
1 + 0.1 ∗ I
100
82.85 =
787.5
1 + 0.0044 𝑉 ∗ 1.89
𝐕 = 𝟐𝟎𝟎𝟎𝐦³
CONT.
Assuming the depth of the filter as 1.5m,
The surface area required
2000
= = 1333.3m2
1.5
Diameter of the circular filter
required
4
= 1333.3 = 41.2 m
π
∗
Hence, use a high rate trickling filter with 41.2m diameter, 1.5m deep
filter media, and with recirculation (single stage) ratio of 1.5.
CONT.
2. A single stage filter is to treat a flow of 3.79*106 l/d of raw sewage with
BOD of240mg/l. It is to be designed for a loading of 11086kg of BOD in raw
sewage per hectare meter, and the recirculation ratio is to be 1. What will be
the strength of the effluent, according to the recommendations of the National
Research Council of USA.
Solution
Total BOD present in raw sewage
= 3.79 ∗ 106l ∗ 240mg/l = 909.6kg
Filter volume required
Total BOD in raw sewage in kg 909.6
= = 0.082 ha − m
Given BOD loading rate of 11,086 kg/ha − m 11,086
Assuming that 35% of BOD is removed in primary clarifier,
The amount of BOD applied to the filter
= 0.65 ∗ 909.6kg = 591.24kg
CONT.
Using equation ,
100
=
𝑌
1 + 0.0044
𝑉∗𝐹
where Y = Total BOD applied to the filter in kg = 591.24kg
V = Vol. of the filter in ha-m = 0.082ha-m
1+R
F= I 2
R
1 + 0.1 ∗ I
Where, RI = 1
1+R 1+1
= 1.65
F= I 2 =
R 1 + 0.1 ∗ 1 2
1 + 0.1 ∗ I
CONT.
100
= = 77.45%
591.24
1 +
0.082 ∗ 1.65
0.0044
The amount of BOD left in the effluent
= 591.24 ∗ (1 − 0.7745]kg
= 133.32kg
BOD concentration in the effluent
Total BOD 133.32 ∗
106 mg/l = 35.18mg/l
=
=
Sewage flow
3.79 ∗ 106
CONT.
3. ( a).Design suitable dimensions of circular trickling filter units
for treating 5 million liters of sewage per day. The BOD of sewage
is 150mg/l.
(b). Also design suitable dimensions for its rotary distribution
system, as well as the underdrainage system.
CONT.
▶ Check for Hydraulic loading
The surface area of the filter bed required can also be worked out by assuming the value of
hydraulic loading, say as, 25 million liters per hectare per day (between 22 to
44ML/ha/day)
Exercise
1. Determine the size of high rate trickling filter for the following data:
I. Sewage flow = 4.5Mld
II. Recirculation ratio =1.4 ;
III. BOD of raw sewage =250mg/l
IV. BOD remove in primary, tank =25%
V. Final effluent BOD desired =50mg/l
2.The sewage is flowing @ 4.5Million liters per day from a primary
clarifier to a standard rate trickling filter. The 5-day BOD of the influent
is 160mg/l. The value of the adopted organic loading is to be 160
gm/m3/day, and surface loading 2000 l/m2/day. Determine the volume of
the filter and its depth. Also calculate the efficiency of this filter unit.
3. Read Other Miscellaneous Type of Filters.
Secondary Sedimentation
Does remove only a very small percentage of the finely
divided suspended organic matter present in sewage.
The effluent of the filter is, therefore, passed through a
sedimentation tank, called Secondary clarifier or Secondary
settling tank or Humus tank.
A secondary clarifier used for settling the effluents from the filters
is similar to a primary settling tank, with a detention period of 1.5
to 2 hours, and over-flow rate ranging between 40,000 to 70,000
liters per sq. m. of plan area per day.
They are circular tanks with deep conical hoppers, with diameter
as well as height ranging between 7.5 to 9m.
Example
1. Design percolating filters with conical humus tanks for treating 7 million
liters of sewage per day.
Solution
We will design
conventional
trickling filters, with
a hydraulic
7
loading,
= 28 ha = 2500m
▶ 28Ml/ha/day [i.e. 222
to 44 ▶
▶ Surface Area of the
Using two equal sized circular tanks, we have the diameter of each tank
filter bed required
2500 4
▶ = 2
∗ π = 39.9m ≈ 40m
▶ Hence, use two trickling filters, each of 40m diameter. A third extra unit as
stand-by unit may also be provided. The depth of the filter provided may be
kept 2m or so.
CONT.
Design of Conical Humus Tank
Assuming the detention period as 1.5 hours, the capacity of the tank required
7
= ∗ 1.5 ∗ 106 l = 0.437106 l = 437cu.
m 24
The volume of each conical tank, such as shown in Fig. .
9.26, is given by
1 𝜋𝑑 2
𝑉= ∗ ∗ 𝐷𝑒𝑝𝑡ℎ
3 4
Using 4 Nos. with 7.5m depth of each tank, we have the total surface area required for all 4
tanks 437
= = 58.27m2
7.5
Diameter of' each tank (d) is given by
1 𝜋𝑑 2 58.27
∗ 4 4
3
d = 7.46m ≈ 7.5 m
▶ Hence, use 4 tanks with diameter 7.5m and height also as 7.5m. One additional tank as
stand- by unit may also be provided; thus, using 5 tanks in all.
Activated Sludge Process
An excellent method of treating either raw sewage or the
settled sewage.
It is the most common Suspended Growth process.
BOD removal is up to 80 - 95 percent and bacteria removal is
up to 90
- 95 percent.
150 25
250 30
400 35
300 40
500 48
600 53
𝑽 𝒊𝒏 𝒎𝟑 𝐕
𝑡= 𝐭= ∗ 𝟐𝟒 𝐡𝐨𝐮𝐫
𝒎𝟑 𝐐
𝑸 𝒊𝒏
CONT.
CONT
.Where, t = aeration period in hours
V = Volume of aeration tank
Q = Quantity of wastewater flow into the aeration tank, excluding the
quantity of recycled sludge.
ii. Volumetric BOD Loading/ organic loading
Which is defined as the BOD51oad applied per unit volume
of
aeration tank..
Volumetric BOD loading or Organic loading
=
Mass of BOD applied perVolume
day toof the
the aeration
aeration tank
tank in m3 influent sewage in gm
through
Q ∗ Yo (gm)
=
V (m3)
CONT
.Where, Q = Sewage flow into the aeration tank in m3
Yo = BOD5 in mg/l (or gm/m3) of the influent sewage
V = Aeration tank volume in m3
This loading is quite similar to the BOD loading rate per cum of filter volume,
as used and adopted in biological filtration.
iii. Food (F) to Micro-organisms (M) Ratio
F/M ratio is an important rational organic loading rate, adopted for an
activated sludge process. It is a manner of expressing BOD loading with
regard to the microbial mass in the system. The BOD load applied to the
system in kg or gm is represented as food (F), and the total microbial
suspended solid in the mixed liquor of the aeration tank is represented by M.
Yo − YE
U=Q∗( )
V ∗ Xt
Under steady state operation, the mass of wasted activated sludge is
further given by :
Q w ∗ X R = α y ∗ Q Yo − YE − K e ∗ X t ∗ V
Where,αy = maximum yield coefficient
microbial mass synthesized
=
mass of substrate utilized
Ke = Endogenous respiration rate constant (per day)
CONT
.The values of αy and Ke are found to be constant for municipal waste
waters, their typical values being:
αy = 1.0 w.r.t TSS (i.e. MLSS);and
= 0.6 w.r.t VSS (i.e. MLVSS)
Ke = 0.06 (per day)
From the above equations, we can also work out as:
= 1 = αy U − K e
θc
Since both αyand Keare constants for a given
wastewater, it becomes
necessary to define either c or U.
2. Sludge Volume Index (SVI)
used to indicate the physical state of the sludge produced in
a biological aeration system.
It represents the degree of concentration of the sludge in the
system,
SVI is defined as the volume of sludge occupied in ml by one gm. of
solids in the mixed liquor after settling for 30 minutes, and is
determined experimentally.
The standard test which is performed in the laboratory to compute
SVI of an aeration system
1. Collection of one liter sample of mixed liquor from the aeration
tank from near its discharge end in a graduated cylinder.
2. This 1 liter sample of mixed liquor is allowed to settle for30
minutes and the settled sludge volume (Vob) in ml is recorded as to
represent sludge volume. This volume Vob in ml per liter of mixed
liquor will represent the quantity of sludge in the liquor in ml/l.
CONT
. The above sample of mixed liquor after remixing the settled solids is
further tested in the laboratory for MLSS by the standard procedure
adopted for measuring the suspended solids in sewage. Let this
concentration of suspended solids in the mixed liquor in mg/l be Xob.
Then SVI is given by the equation
Vob Vob
= ml/mg
ml/l X ob
SVI = Vob
Xob
SVI = ∗ 1000ml/g
mg/lX ob
The usual adopted range of SVI is between 50 - 150 ml/gm and
such a
value indicates good settling sludge.
CONT
. Note: When the given SVI value in ml/gm is divided by 103 * 103 (i.e.
106), we will get SVI value in l/mg. SVI value in l/mg will therefore
SV I 6
be
10
. SVI value in mg/l will, thus, be given by
.
106
SVI
Sludge Recycle and Rate of Return
The MLSS concentration in the aeration tank is controlled by the
Sludge
sludge recirculation rate and the sludge settleability and thickening
in the secondary sedimentation tank.
The relationship between sludge recirculation ratio QR/Q with Xt
(MLSS in tank) and XR (MLSS in returned or wasted sludge) is given
as:
αy ∗ Q(Yo − YE)θc
V ∗ Xt =
1 + K c ∗ θc
It can be seen that economy in reactor volume can be achieved by
assuming a higher value of Xt. However, it is seldom taken to be
more than 5000 g/m3 (i.e. mg/L). A common range is between
1000 to 4000 g/m3 .
CONT.
Considerations which govern the upper limit are:
(i)initial and running cost of sludge recirculation system to maintain a
high value of MLSS;
(ii)limitations of oxygen transfer equipment to supply oxygen at
required rate in a small reactor volume;
(iii)increased solids loading on secondary clarifier which may
necessitate a larger surface area to meet limiting solid flux;
(iv)design criteria for the tank and minimum HRT (t) for the aeration
tank for stable operation under hydraulic surges.
The width and depth of aeration channel for conventional
plants depend upon the type of aeration equipment used.
The depth controls the aeration efficiency and usually ranges from
3 to 4.5m. The higher value of depth of 4.5m is found to be more
economical for plants of more than 50MLD capacity. Beyond 70
MLD, duplicate units are preferred
CONT
. The width controls the mixing and is usually kept between 5 to 10 m.
Width-depth ratio should be adjusted between 1.2 and 2.2. The
length should not be less than 30m and not ordinarily longer than
100m in a single section length before doubling back. The horizontal
velocity should be around 1.5 m/min. Excessive width may lead to
settlement of solids in the tank.
The free-board in the tank is generally kept between 0.3- 0.5m.
The inlet and outlet channels should be designed to maintain a
minimum velocity of 0.2m/s to avoid deposition of solids.
CONT
. xygen Requirement of the Aeration Tanks
O
Oxygen is required in the activated sludge process in the aeration tank
for oxidation of part of the influent organic matter, and also for
endogenous respiration of the micro-organisms in the system.
The total oxygen requirement may be computed by using the equation
Ns ∗ Ds − DL 1.024 T− 20°c ∗
N =
α 9.17
Where, N = Oxygen transferred under field conditions in kg O2/kWh
Ns = Oxygen transfer capacity under standard conditions in kg O2/kWh
Ds = Dissolved oxygen-saturation value for sewage at operating
temperature
DL = Operation DO level in aeration tank, usually 1 to 2 mg/L
T = Temperature in degree c.
α = Correction factor for oxygen transfer for
sewage, usually 0.8 to
0.85
The oxygen transfer capacities of surface aerators, and fine and coarse
CONT
. Tank Dimensions: Adopt aeration tank of depth 3m and width 4.5m.
Rate of Air Supply Required: Assuming the air requirement of the
aeration tank to be 100m3 of air per kg of BOD removed, Air required
Design of Secondary sedimentation Tank: Adopting a surface
loading rate of 20m3/day/m2 at average flow of 6300m3/day,
Design of Sludge Drying Beds: In order to design sludge drying
beds, the quantity of excess wasted sludge will be calculated by using
the equation)as:
V ∗ Xt
θc =
Q w ∗ XR
Note: This secondary sludge volume of 280m3/d shall be taken to sludge
drying beds, along with the primary sludge.
Reading assignment
Advantages and Disadvantages of an Activated Sludge Plant
Activated Sludge Process Vs Trickling Filter Process and the
Choice of One
Rotating biological contractors (Aerobic Attached Culture)
= 8750 kg/day
M = Mass 10900 ∗ 2500
= V ∗of
Xt MLSS
= 10900m3 ∗ 2500 gm/m3 = 1000 kg
= 27,
250kg
8750
F/M ratio = = 0.32 kg BOD per day/kg of MLSS
27,250
CONT
.
(a) Percentage efficiency of BOD removal
Incoming BOD – Outgoing BOD 250 − 20
= = ∗ 100% = 92%
Incoming BOD 250
(a) Sludge age in days (c) is given by Eq. (9.48) as:
V ∗ Xt
θc =
Q w ∗ XR + Q − Q w ∗ XE
27250 kg
=
m3
mg m3 m3 ∗ 30mg/l
220 d ∗ 9700 l + 35000 d − 220 d
= 𝟖. 𝟓𝟖
𝐝𝐚𝐲𝐬
Exercise
2. Design a conventional activated sludge plant to treat
domestic sewage, given the following data :
Population=40,000
Average sewage flow=180 lpcd
BOD of sewage = 240mg/lit
BOD removed in primary clarifier = 25%
Overall BOD reduction = 80%
Based on the information above,
determine
a) Volume of aeration tank.
b) Aeration period or H.R.T.
c) Sludge Retention Time
d) Tank dimensions
CONT
.Solution
Daily sewage flow (Q)= population * average sewage flow
=40000*180
=7200m3/day
BOD of sewage coming to aeration
Yo=75% of BOD of sewage
=0.75*240
=180mg/l
BOD left in effluent (YE)=(100-80)* BOD of sewage
= 20/100*240mg/l
=48mg/l
BOD removal in ASP
=(180-48)=132mg/l
132
Efficiency of ASP (η)=180 *100=74%
CONT
.From the table for efficiency 85-92% we use F/M ratio =0.4-
0.3&MLSS1500-3000for conventional plant .since efficiency required is
lowered side we can used moderate value for F/M and MLSS.
Therefore ,so let us adopt F/M=0.33,MLSS(Xt)=2000 mg/l
𝐹 𝑄 ∗𝑦 𝑜 7200∗180
= =0.33=
𝑀 𝑉∗𝑋𝑡 𝑉∗2000
V=1963.63m3
HRT(t)
t=𝑉*24h=1963.63*24=6.54hr
𝑄 7200
Sludge retention time (θc)
V ∗ Xt = α y ∗Q(Y o −Y E )θ c 1∗7200 180−48 ∗θ c
1+K c ∗θ c =1963.63*2000= 1+0.006∗θ c
1∗7200∗132
1+0.06θ c=( 1963.63∗2000
)θ c
1+0.06θc=0.242θc
θc=5.5 day (5-8day)
CONT
. Tank dimension ,adopting tank depth 3.5& width 4.5m.the total length
of the aeration channel required .
V=L*W*D
1963.63=L*4.5*3.5
L=126M
Provide a conventional channel with 3 aeration chamber of each of
42 m length .Total width of unit ,including 2 baffle each 0.25
thickness .
Number of unit * width+ Number of baffle *thickness of baffles
= 3*4.5+2*0.25
=14m
Provide 0.5m free board
Total depth =3.5+0.5=4m
Providing 3 tank with overall dimension of aeration tank will be ,