Phase Transition

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A phase is a state of matter whose properties vary

smoothly (i.e.it is an analytic function of P; V; T etc.).

If a function is not continuous or differentiable (for non analytic


function derivatives of P, V, T vanish) then it is not analytic. In
physics, it happens only at critical point.
A phase transition is an abrupt, discontinuous change in the
properties of a system. We’ve already seen one example of a
phase transition -Bose-Einstein condensation.
In that case, we had to look fairly closely to see the discontinuity:
it was lurking in the derivative of the heat capacity. In other phase
transitions — many of them already familiar — the discontinuity
is more manifest. Examples include steam condensing to water
and water freezing to ice.
Spontaneous symmetry breaking is a
spontaneous process of symmetry breaking, by
which a physical system in a symmetric state
spontaneously ends up in an asymmetric state

By definition, spontaneous symmetry breaking requires the


existence of physical laws (e.g. quantum mechanics) which are
invariant under a symmetry transformation (such as translation or
rotation), so that any pair of outcomes differing only by that
transformation have the same probability distribution. For
example if measurements of an observable at any two different
positions have the same probability distribution, the observable
has translational symmetry.

Spontaneous symmetry breaking occurs when this relation breaks


down, while the underlying physical laws remain symmetrical.
Critical phenomena
Some examples of phase
transition
Liquid-Gas Transition

The Clausius-Clapeyron Equation


Bose–Einstein condensate

Velocity-distribution data (3 views) for a gas of rubidium


atoms, confirming the discovery of a new phase of
matter, the Bose–Einstein condensate
Superconductivity
Phase diagram of QCD matter : Quark-Gluon Plasma
Understanding phase transition
If we can calculate the free energy F we can then calculate all
desired thermodynamic quantities by appropriate derivatives.∗
Landau Theory of Phase Transitions. This was developed
by Landau in the 1940’s, originally to describe
superconductivity. The procedure is general, and is one of
the most useful tools in condensed matter physics. Not
only can we use Landau Theory to describe and
understand the nature of phase transitions among
ordered (and disordered) states, but we can use it as a
starting point for understanding the behavior of ordered
states.
We will see how to use the nature of the order parameter
to understand deformations in a broken symmetry state:
Landau theory is a mean field theory, in the sense that the
system is assumed to be adequately described by a single
macroscopic state
It is the energy required to create a system
at constant pressure and temperature.
Helmholtz free energy finds less application
as the volume of the system should be
constant. Gibbs free energy finds more
application as the pressure of the system is
constant.
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