Chapter 1 Introduction - Matter & Measurements A
Chapter 1 Introduction - Matter & Measurements A
Sections covered:
1.2 - Classification of matter
1.3 - Properties of matter
1.4 - Units of measurement
1.5 - Uncertainty in measurement
1.6 - Dimensional analysis
What is
CHEMISTRY
?
CHEMISTRY is the branch of
of MATTER
Every aspect of the world
today – even politics and
international relations – is
Linus Pauling affected by chemistry.
(1901- 1994)
What is
MATTER
?
It is anything that
occupies
SPACE and
has MASS
Section 2.3
The Modern View of Atomic Structure
Matter is
made of
atoms
The atom is the
smallest unit of
substance.
We can view
the atom using
the simple
Rutherford
model.
NUCLEUS
contains
NEUTRONS
and
PROTONS.
ELECTRON CLOUD
Sub-atomic particle Charge
Only the
Proton +1 protons and
electrons
Neutron None have a
Electron -1 charge.
10-4 Å
1 to 5 Å
1 Å = 100 pm = 10 -10
m
If the atom was the size of the a
ball with a width of 1m then
the NUCLEUS would be
approximately the size of one
fine grain of sand with a
width of 0.1mM.
1m
The unit for the mass of an
element or sub-atomic
particle is amu
amu is based on the
mass of an atom of the
12
C isotope
1 atom of C isotope = 12
12
amu
1 amu =
1
/12 of the weight of C atom
12
Sub-atomic particle Mass (amu) Protons and
neutrons have
essentially the
Proton 1.0073 same mass.
Neutron 1.0087
The mass of an
Electron 0.0005486 electron is so
small we ignore
it.
Elements can
be symbolised
Atomic number or Proton number (Z)
= Number of Protons
2
He
4.003
Elemental symbol.
Typically symbolised by 1 or 2 letters
H 1.01
C 12.01
Ar 39.95
Atoms with different
different proton numbers
are called…
ELEMENTS
There are
many elements
CARBON NITROGEN OXYGEN
http://www.rsc.org/periodic-table
• The Periodic Table was developed over a 200 year period
• The red line on the right separates the METALS from the NON-
METALS
• The main groups are numbered from 1 to 18 going from left
to right
Na Form +1 Naughty
Rb Rob
Cs Cosmetic
Fr Fragrances
elements are
known as the
ALKALINE
EARTH
Be Beautiful
Mg Magnificent
Ca Form +2 Cats
Sr oxidation states
Strike
Ba
Ra Bad
Rats
Group 13
elements
B Boys
Al Form +3 And
Ga oxidation states Gals
In In
Tl
Thailand
Group 14
elements
C Chemistry
Si Form +4 Sir
Ge oxidation states Gives
Sn Snappy
Pb Problems
Group 15
elements
N New
P Form -3 Popes
Sb Subordinate
Bi Bishops
elements are
known as the
CHALCOGEN
S
O O’
S Form -2 Sullivan
Se oxidation states Sells
Te Tea
Po Pots
Group 17
elements are
known as the
HALOGENS
F Floor
Cl Form -1 Cleaners
Br oxidation states Bring
I In
At Ants
elements are
known as the
NOBLE
He
He
Ne Neatly
Ar These are very stable Arranged
elements. Karen’s
Kr eXtraordinary
Xe Ring
Rn
Group 12-13 are
known as the
TRANSITION
METALS
Sc Ti V Cr Ma Fe Co Ni Cu Zn
MOLECU
O
H H
A chemical substance has a
constant chemical
composition.
What is a pure
chemical
substance?
It is a substance that is made of ONE
TYPE of molecule that has distinct
properties and chemical composition
(e.g. H2O, N2, CO2, NaCl).
O
H
H
O
H
O
H H
H
If the chemical substance is
Oxygen
Hydrogen
An elemental substance
CANNOT BE decomposed to
simpler substances.
Cannot be
turned into a
simpler
Nitrogen substance
If the chemical substance is
made up of more than one
element, it is called a…
COMPOUN
Examples
include…
Water (H2O)
Methane (CH4)
O
O H H
+
O
H H
If we physically MIX an ‘elemental
becomes a…
MIXTURE
The substances are combine
of mixtures
Homogeneous
mixture
This has a uniform
composition and
appearance.
Example: salt in water
https://www.youtube.com/watch?v=2WS5eFc8x1U
Heterogeneous
mixture
This does not have a
uniform composition and
has a varied appearance.
Example: sand in water, oil in water
Matter can be defined in their
PHYSICAL STATES
heat heat
cool cool
SOLIDS: LIQUIDS: GASES:
• Fixed shape • Changeable shape • No fixed shape
• Fixed volume • Fixed volume • No fixed volume
• Incompressible • Incompressible • Compressible
Separation of mixtures
Iron and gold can be separated by magnetism.
In filtration, solid substances are separated
from liquids with use of filter papers.
Distillation uses boiling points to separate a
homogeneous mixture into its components.
Chromatography technique separates
substances on the basis of differences in
solubility in a solvent.
Other separation methods include:
• Crystallization
• Sublimation
• Evaporation
• Centrifugation
• Precipitation
HOMEWO
RK
1. Which of the following can be classified as
a pure substance?
A. Ocean water
B. C6H12O6
C. Some Fe powder mixed with S powder
D. Air
2. Which of the following can be classified as a
compound?
A. Diamond (C)
B. Some Fe powder mixed with S powder
C. FeS
D. Silver (Ag)
3. Which of the following is a homogeneous
mixture?
A. NaCl
B. Mixture of sand and water
C. Pure Gold (Au)
D. NaCl completely dissolved in water
4. Which of the following is a heterogeneous
mixture?
1. B
2. C
3. D
4. B
Section 1.3
Properties of matter
What is a chemical
change?
These are changes that result
in new chemical substances
ie chemical reaction.
It involves the breaking and
making of new atomic
bonds.
Chemical properties are used to measure
or describe a substance’s reactivity
https://www.youtube.com/watch?v=J3kBkkk-SqM
What is a physical
change?
These are changes that result in an
alteration of the physical state or
appearance of a substance but not its
composition.
It is the same substance before
and after the change.
PHYSICAL PROPERTIES are used to measure or describe
a substance without changing its composition eg color,
odour, boiling point, melting point, mass, hardness,
appearance, density, solubility, polarity.
Example of physical change
heat
H2O (s) H2O (l)
Ice liquid water
Example of physical change
compression + refrigeration
CO2 (g) CO2 (s)
carbon dioxide gas solid carbon dioxide (dry ice)
EXTensive Properties
Before After
Addition of water
A. Combustion of hydrogen
B. Melting of ice to water
C. Rusting of iron
D. N2 (g) + 3H2 (g) 2NH3 (g)
7. Which of the following is a
chemical change?
6. B
7. A
The International System of
Units
=m×m×m
=m 3
Length (m)
Length (m)
Length (m)
10 cm x 10 cm x 10 cm
= 1000 cm = 1L
3
weighs 1 g
What is the SI
unit for
DENSITY?
Densi
m kg
ty = = 3
m
V
= kg/m 3
Density is also commonly
expressed in g/cm which
3
unit.
Rather than writing 1000m, we
1 kilometer (=1km)
Mnemonic to remember the top scale
prefixes
Yelling = Yotta = base unit x 10-24
Zebras = Zetta = base unit x 10-21
Encourage = Exa = base unit x 10-18
Penguins = Peta = base unit x 10-15
To = Terra = base unit x 10-12
Grow = Giga = base unit x 10-9
Mighty = Mega = base unit x 10-6
Kingly = Kilo = base unit x 10-3
Beards = Base unit = base unit x 1
Mnemonic to remember the bottom scale prefixes
x
3 0.001 KB
10 0 BASE UNIT 1 BYTE
Using lower prefixes
eg grams
x 10 BASE UNIT 1 gram
0
x 10 3 1000 mg
x 106 1000000 mg
x
1000000000 ng
10
x
9
1000000000000 pg
1012
How to convert
between
prefixes
• Work out how many prefix jumps
are needed.
• This will give you the exponent (x)
• Multiply your original value by 10x
to get the final answer.
10 microwatts
6
= ? megawatts
There are
4 jumps up ((-3) + (-3) + (-3) + (-3))
therefore the exponent is
-12.
So you will multiply by 10 -12
10-
12 terra
10- giga
10-9 10-
-6 mega 10 -3
12
10 10 -3
3 kilo
100 10 -3
BASE UNIT base
103 milli 10 -3
106 micro
10 9 nano
101 pico
2
10 1
femto
5
10 microwatts
6
= 10 x 10 megawatts
6 -12
= 10 megawatts
-6
Convert 0.001 metres
to micrometers
There are
2 jumps down ((+3) + (+3) )
therefore the exponent is
6.
So you will multiply by 10 6
10- terra
12
10- giga
10-9
-6
mega
10 kilo
3 106
100 BASE UNIT base 103
103 milli 103
106 micro
10 9 nano
101 pico
2
10 1
femto
5
0.001 metres = 10 metres
-3
= 10 x 10 micrometres
-3 6
= 10 mm (micrometres)
3
Temperatu
re scales
Celsius
scale
The scale is based on the properties of water.
0 oC is the freezing point of water
100 oC is the boiling point of water.
Fahrenheit
scale
The scale is based on the properties
of salt/water.
0o F is the melting point of
brine(water/salt)
32 oF melting point of ice
Kelvin
scale
This scale is based on the properties of ideal
gases:
0oC is the (theoretical) point at which
thermal motion ceases.
There are no negative Kelvin temperatures.
FC183
2
F= (C x 1.8) +32
Convert 25 C to F
o o
F = (C x 1.8) +32
= (25 x 1.8) + 32
= 77 F o
KC27
3
K= C + 273
Convert 20 C to K
o
K = C + 273
= 20 + 273
= 293K
HOMEWO
RK
8. Which of the following is not an SI unit?
A. metres
B. inches
C. seconds
D. moles
9. How many Kelvins are there in
25oC?
A. 298
B. 77
C. 157
D. 312
10. How many oC are there in 25oF?
A. 77
B. 13.9
C. -18.1
D. -3.9
11. A volume of 5ml is the same as …
A. 5 litres
B. 5 cm3
C. 5 moles
D. 5 dm3
Answers
8. B
9. A
10. D
11. B
Section 1.5
Uncertainty in measurements
Accuracy versus
Precision
Accuracy tells us how close
the measured value is to the true
value of a quantity.
Precision tells us how close
the measured values are to each
other and not the true value.
POOR ACCURACY
Apple is weighed
MEASURED WEIGHTS
1st read = 1.964 g
TRUE WEIGHT OF APPLE 2nd read = 1.954 g
= 1.500 g
3rd read = 1.983 g
4th read = 1.984 g
5th read = 1.973 g
POOR PRECISION
Apple is weighed
MEASURED WEIGHTS
1st read = 1.314 g
TRUE WEIGHT OF APPLE 2nd read = 1.504 g
= 1.500 g
3rd read = 2.002 g
4th read = 1.532 g
5th read = 1.512 g
Types of empirical
numbers in
science
EXACT
NUMBERS
These numbers are counted or given
by definition. For example, there are
exactly 35 students in GC1 class or
1 inch = 2.54 cm
INEXACT
NUMBERS
These numbers are measured. The
number will not be exact. It will
have a certain level of accuracy.
MEASURING
DEVICES
Different measuring devices for making
measurements of all kinds.
Pressure Weighing
Voltmeter gauge scale
Measuring devices have
different degrees of
accuracy.
Kitchen scale Analytical balance
Weight = 6.1 g (2sf) Weight = 6.1434 g (5sf)
All the digits of a measured
quantity including the
estimated ones are called…
Significant
figures
This is sometimes
abbreviated to
sig figs, SF, or sf.
The basic rule for
significant figures is that…
All digits are significant
except…
Zeros on the left of
the first non-zero
digit
Zeros on the right of a
non-zero digit WITHOUT
a decimal point
0.000005 1sf
0.0000050100 5sf
506700 4sf
0025 2sf
7520
Sometimes the zeros at the end of a
whole number may be significant.
How do I show that
it is significant?
I can use
scientific notation and
write…
7.520 x 10 3
More examples:
3200 becomes 3.20 x10 to 3sf
3
off numbers
Look at the last digit to be removed:
105.933 g
The least accurate values are 122.8 and 2.3g which have 1 dp.
The final answer will therefore have 1 dp.
The value also needs to be rounded off.
3 sf =12.9 (1 dp)
2 sf
3 sf
This value has the least sf so the final answer
will need to be given to 2sf
Final answer = 73
Example 2
=8.6 (2 sf) 3 dp 2 dp
1 dp
This value has the least dp so the final answer will need to be given to 1dp
This value has the least sf so the final answer will need to be given to 2sf
Final answer = 19
HOMEWO
RK
12. In three trials, a student records the following sample
masses: 1.200 g, 1.250g, 1.200 g, and 1.250 g. The true value is
0.340 g. The student’s data have?
a 0.06750 e 2000
b 10.25001 f 5.06700
c 6.582 x 103 g 20.6780590
d 0.007225 h 123, 456.700
15. How many significant figures in each of the following
numbers?
a 23.560 e 2000
b 0.0890 f 5.06700
c 24.5 x 104 g 20.6780590
d 123.098 h 123, 456.700
16. The following measurements are added: 4.1 g and
7.08g. How should the final value be expressed?
A. 11.180
B. 11.18
C. 11.2
D. 11
17. The following measurements are added: 4.100 g and
7.08g. How should the final value be expressed?
A. 11.180
B. 11.18
C. 11.2
D. 11
18. The following operation is performed: 6.9 g -
5.07 g. What is the final value?
A. 1.830
B. 1.83
C. 1.8
D. 1
19. The following operation is performed: 6.912 g
- 5.07 g. What is the final value?
A. 1.842
B. 1.84
C. 1.8
D. 1
20. What is the final value after performing the following
calculation:
5.2 cm × 7.01 cm = ____ cm2
A. 36
B. 36.4
C. 36.45
D. 36.452
21. What is the final value after performing the following
calculation:
5.2 cm × 7.012 cm = ____ cm2
A. 36
B. 36.4
C. 36.46
D. 36.462
22. What is the final value after performing the following
calculation:
6.03 g ÷ 7.1 mL = _____ g/mL
A. 0.8
B. 0.85
C. 0.849
D. 0.849257
23. What is the final measured value after
performing the following calculation: 6.03 g ÷ 6.50
mL = _____ g/mL
A. 0.93
B. 0.927
C. 0.928
D. 0.927692
Answers
Question 14
Question 15
Part Number Correct Answer Part Number Correct Answer
a 23.560 5 e 2000 1
b 0.0890 3 f 5.06700 6
c 24.5 x 104 3 g 20.6780590 9
d 123.098 6 h 123, 456.700 9
Answers
The given unit = unit that is given to you and the desired unit= unit you want to convert to.
100 Fils = 1 Dhiram
3 Dhirams = ??? Fils
3 x 100 = 300 fils
3 Dhirams = 300 Fils
A conversion factor
is used
Dhirams Fils
1 100
= 0.3198 miles
So the speed is
0.3198 miles/s
Scale up the
distance/time
= 0.3198 miles/s
x 60 x 60
= 19.189 miles/min
x 60 x 60
= 1151 miles/h
HOMEWO
RK
Example 5: Calculate the mass in
grams of 2.00 in gold which has a
3
density of 19.3g/cm .
3
conversion conversion
inch3 cm3 factor 2 g
factor 1
1 2.54 1 2.54 3
1 inch 3
1 inch 3
Volume = 2 inch x 16.4 cm
3 3
= 32.8 cm 3
1 inch 3
Density = mass
volume
Mass = volume x density
= 32.8 cm x 19.3g/cm
3 3
= 633g