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    Tutorial 7 Chapter 7: Carbonyl Compounds: Chm207 (Organic Chemistry)

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    Eqieyn Jerr
    The document discusses carbonyl compounds and their reactions. It provides examples of naming ketones and aldehydes, drawing structures of specific carbonyl compounds, arranging compounds by boiling point, predicting products of reactions between carbonyl compounds and various reagents, identifying compounds using chemical tests, drawing reaction sequences, and converting functional groups using suitable reagents.

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    Tutorial 7 Chapter 7: Carbonyl Compounds: Chm207 (Organic Chemistry)

    Uploaded by

    Eqieyn Jerr
    33 views3 pages
    The document discusses carbonyl compounds and their reactions. It provides examples of naming ketones and aldehydes, drawing structures of specific carbonyl compounds, arranging compounds by boiling point, predicting products of reactions between carbonyl compounds and various reagents, identifying compounds using chemical tests, drawing reaction sequences, and converting functional groups using suitable reagents.

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    Tutorial 7

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    The document discusses carbonyl compounds and their reactions. It provides examples of naming ketones and aldehydes, drawing structures of specific carbonyl compounds, arranging compounds by boiling point, predicting products of reactions between carbonyl compounds and various reagents, identifying compounds using chemical tests, drawing reaction sequences, and converting functional groups using suitable reagents.

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    33 views3 pages

    Tutorial 7 Chapter 7: Carbonyl Compounds: Chm207 (Organic Chemistry)

    Uploaded by

    Eqieyn Jerr
    The document discusses carbonyl compounds and their reactions. It provides examples of naming ketones and aldehydes, drawing structures of specific carbonyl compounds, arranging compounds by boiling point, predicting products of reactions between carbonyl compounds and various reagents, identifying compounds using chemical tests, drawing reaction sequences, and converting functional groups using suitable reagents.

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    CHM207 (ORGANIC CHEMISTRY )

    TUTORIAL 7
    CHAPTER 7: CARBONYL COMPOUNDS
    1)

    Name the following ketones and aldehydes.


    a) CH3CO(CH2)4CH3
    b) CH3(CH2)2CO(CH2)2CH3
    c) CH3(CH2)5CHO
    d)

    O
    C

    e) CH3CH2CH2CHO
    f) CH3CH2CHBrCH2CH(CH3)CHO
    g)

    O
    CH3

    h)

    C CH2 CH3

    i)

    CH3 C CH2 CH2 CH2 C H

    j)

    2)

    CH3-CH2-CH2-CH=CH-CHO

    Draw the structures for the following compounds:


    a) 4-methyl-3-pentanone
    b) isobutyl methyl ketone
    c) hepta-4-one
    d) 4-methyl-4-pentenal
    e) 2-hydroxypentanal
    f) 4-methylcyclohexanone
    1

    CHM207 (ORGANIC CHEMISTRY )

    3)

    Arrange the following compounds in order of increasing boiling point.


    a) ethanal, propane, ethanol, 1-propanol
    b) 2-propanone, 2-butanone, 1-butanol, butane-1,2-diol

    4)

    Give the products formed when ethanal reacts with following reagents:
    i) NaBH4
    ii) K2Cr2O7/H2SO4
    iii)LiAlH4
    iv) HCN
    v) 2,4-dinitrophenylhydrazine
    vi) KMnO4 / H+ / heat
    vii)Ag(NH3)2 / OHviii) NaOH / I2

    5)

    Predict the products formed when cyclohexanone reacts with reagents in


    question (4) above.

    6)

    Give the reagents for the reactions below:


    a)

    OH

    O
    from

    b)

    O
    CH3

    c)

    from

    O
    CH3CH2CH2 C OH

    d)

    CH3CH(OH)CH2CH3

    O
    from CH3CH2CH2 C H
    O
    from CH3CCH2CH3

    CHM207 (ORGANIC CHEMISTRY )

    7)

    How you distinguish each of the following compounds by using chemical


    test?
    a) acetaldehyde and acetone (propanone)
    b) phenyl methyl ketone and ethyl phenyl ketone
    c) propanal and 1-propanol
    d) 2-butene and 2-butanone

    8)

    Compound A with molecular formula C5H10O give the reactions as below:


    a) A + 2,4-DNP : POSITIVE
    b) A + Tollens Reagent: NEGATIVE
    c) A + NaBH4 give compound B
    d) B + CH3COOH
    e) B

    H+

    H+

    C + H2O

    alkenes (2 products) (C5H10)

    Compound A give positive results in iodoform test. Give the structures for
    compound A, B, C and alkenes.
    9)

    A reaction sequence is shown below.

    SOCl2
    CH3CH2OH
    pyridine

    HCN/KCN

    H3O+

    LiAlH4
    R

    Draw the structures of the products P, Q, R and S.

    10)

    Show how to convert each of the following products using a suitable


    reagents and condition.
    a)
    butanone to 2-butene
    b)
    chloroethane to ethanoic acid
    c)
    ethanol to 2-hydroxypropanoic acid.

    11)

    The ozonolysis of an alkene P gives CH3CH2CHO and HCHO. Draw the


    structure of P and give name of the compound.

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