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    Stanley Sibanda
    mdawini

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    Stanley Sibanda
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    mdawini

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    mdawini

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    Download as pdf or txt
    111 views6 pages

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    Uploaded by

    Stanley Sibanda
    mdawini

    Copyright:

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    You are on page 1of 6

    Objec&ves

    for previous lecture


    Describe a cascade of equilibrium stages Explain the advantages of a countercurrent cascade Dene boiling point, satura&on vapor pressure, bubble point, dew point, azeotrope, vola&lity, isotherm, subcooled liquid, superheated vapor Read two kinds of VLE diagrams: - temperature-composi&on (lens) diagram - McCabe-Thiele diagram

    Figure 2-3 Temperature-composi&on diagram for ethanol-water

    superheated vapor 2-phase region saturated vapor line saturated liquid line M V

    M V

    L/V = (MV)/(LM) inverse lever arm rule L/V = (yE/zE)/(zE-xE)

    subcooled liquid

    Figure 2-2 McCabe-Thiele diagram for ethanol-water

    Vola&lity = yE/xE = KE(T) Azeotrope: K = 1.0

    From Separa&on Process Engineering, Third Edi&on by Phillip C. Wankat (ISBN: 0131382276) Copyright 2012 Pearson Educa&on, Inc. All rights reserved.

    Todays objec&ves
    Extract informa&on (boiling point, saturated vapor pressure, vola&lity) from a DePriester chart Calculate the dew point and bubble point for a mul&component mixture using a DePriester chart and trial-and-error Dene rela&ve vola&lity

    (D. B. Dadyburjor, Chem. Eng. Prog.,85, April 1978; copyright 1978, AIChE; reproduced by permission of the American Ins&tute of Chemical Engineers)

    Figure 2-11 Modied DePriester chart (in S.I. units) at low temperatures

    showing K as a func&on of T, P for pure compounds at a given T, P: K > 1 compound prefers vapor phase K < 1 compound prefers liquid phase K = 1.0 at boiling point

    From Separa&on Process Engineering, Third Edi&on by Phillip C. Wankat (ISBN: 0131382276) Copyright 2012 Pearson Educa&on, Inc. All rights reserved.

    Homework problem
    due Friday

    (a) Find the bubble point and dew point for a mixture that is 20 mol% n-butane, 60 mol% n- pentane, and 20 mol% n-hexane, at 300 kPa. (b) For this mixture, nd the composi&ons of the rst bubble formed and the last drop of liquid vaporized. Use a DePriester chart and the trial-and-error method.

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