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    9701 Chemistry: MARK SCHEME For The October/November 2011 Question Paper For The Guidance of Teachers

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    Mark SCHEME is published as an aid to teachers and candidates, to indicate the requirements of the examination. It does not indicate the details of the discussions that took place at an Examiners' meeting before marking began.

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    9701 Chemistry: MARK SCHEME For The October/November 2011 Question Paper For The Guidance of Teachers

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    fairy56
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    Mark SCHEME is published as an aid to teachers and candidates, to indicate the requirements of the examination. It does not indicate the details of the discussions that took place at an Examiners' meeting before marking began.

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    9701_w11_ms_22

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    Mark SCHEME is published as an aid to teachers and candidates, to indicate the requirements of the examination. It does not indicate the details of the discussions that took place at an Examiners' meeting before marking began.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    120 views7 pages

    9701 Chemistry: MARK SCHEME For The October/November 2011 Question Paper For The Guidance of Teachers

    Uploaded by

    fairy56
    Mark SCHEME is published as an aid to teachers and candidates, to indicate the requirements of the examination. It does not indicate the details of the discussions that took place at an Examiners' meeting before marking began.

    Copyright:

    Attribution Non-Commercial (BY-NC)
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    You are on page 1of 7

    w w w e tr .

    X m ap eP

    UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS


    GCE Advanced Subsidiary Level and GCE Advanced Level

    s er om .c

    MARK SCHEME for the October/November 2011 question paper for the guidance of teachers

    9701 CHEMISTRY
    9701/22 Paper 2 (AS Structured Questions), maximum raw mark 60

    This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of the examination. It shows the basis on which Examiners were instructed to award marks. It does not indicate the details of the discussions that took place at an Examiners meeting before marking began, which would have considered the acceptability of alternative answers. Mark schemes must be read in conjunction with the question papers and the report on the examination.

    Cambridge will not enter into discussions or correspondence in connection with these mark schemes.

    Cambridge is publishing the mark schemes for the October/November 2011 question papers for most IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.

    Page 2 1

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22 (1) (1) (1) (1) (1) (1) [6]

    (a) (i) mass of C = 12 0.352 = 0.096g 44 n(C) = 0.096 = 0.008 12 (ii) mass of H = 2 0.144 = 0.016g 18 n(H) = 0.016 = 0.016 1 (iii) mass of oxygen = 0.240 (0.096 + 0.016) = 0.128g n(O) = 0.128 = 0.008 16 allow ecf at any stage (b) C : H : O = 0.008: 0.016 : 0.008 = 1:2:1 allow C : H : O = 0.096 : 0.016 : 0.128 = 1:2:1 12 1 16 gives C H2O (c) (i) Mr = mRT pV = 59.89 allow 59.9 or 60 (ii) C2H4O2 (d) CH3CO2H HCO2CH3 (e) the only products of the reaction are the two oxides H2O and CO2 and copper = 0.148 x 8.31 x 333 1.01 x 105 x 67.7 x 106

    (1) (1)

    [1]

    (1) (1) (1) (1) (1) [2] [1] [3]

    [Total: 13]

    University of Cambridge International Examinations 2011

    Page 3

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22 (1) (1)

    (a) S(g) S+(g) + e correct equation correct state symbols (b) from Na to Ar, electrons are added to the same shell/have same shielding electrons are subject to increasing nuclear charge/proton number electrons are closer to the nucleus or atom gets smaller (c) (i) Mg and Al in Mg outermost electron is in 3s and in Al outermost electron is in 3p 3p electron is at higher energy or is further away from the nucleus or is more shielded from the nucleus (ii) S and P for S one 3p orbital has paired electrons and for P 3p sub-shell is singly filled paired electrons repel (d) (i) and (ii) element conductivity melting point Na high low (1) Mg high high (1) Al Si moderate high (1) P low low (1) S low low (1)

    [2]

    (1) (1) (1)

    [3]

    (1)

    (1)

    (1) (1) [4]

    one mark for each correct column (e) germanium/Ge (1)

    [5] [1]

    [Total: 15]

    University of Cambridge International Examinations 2011

    Page 4 3

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22 (1)

    (a) the overall enthalpy change/energy change/H for a reaction is independent of the route taken or is independent of the number of steps involved provided the initial and final conditions are the same (b) (i) K2CO3 + 2HCl 2KCl + H2O + CO2 (ii) heat produced = m c T = 30.0 4.18 5.2 = 652.08 J per 0.0200 mol of K2CO3 (iii) 0.020 mol K2CO3 652.08 J 1 mol K2CO3 652.08 1 = 32604 J 0.0200 enthalpy change = 32.60 kJmol1 (iv) to prevent the formation of KHCO3 or to ensure complete neutralisation (c) (i) KHCO3 + HCl KCl + H2O + CO2 (ii) heat absorbed = m c T = 30.0 4.18 3.7 = 463.98 J per 0.0200 mol of KHCO3 (iii) 0.020 mol KHCO3 463.98 J 1 mol KHCO3 463.98 1 = 23199 J 0.0200 enthalpy change = +23.20 kJmol1 (d) H = 2 (+23.20) (32.60) = +79.00 kJ mol1

    (1)

    [2]

    (1)

    (1)

    (1) (1) [4]

    (1)

    (1)

    (1)

    [3]

    (2)

    [2]

    [Total: 11]

    University of Cambridge International Examinations 2011

    Page 5 4 (a)

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22

    CH3CH2CH=CH2 H2O(g) H3PO4 MnO4/H+ hot, concentrated

    catalyst

    CH3CH2CH2CH2OH or CH3CH2CH(OH)CH3

    MnO4/H+ cold, dilute

    CH3CH2CO2H

    U T CH3CH2CH(OH)CH2OH

    Cr2O72/H+ heat under reflux

    CH3CH2COCO2H W

    correct T correct U correct V correct > CO group in W correct CO2H group in W

    (1) (1) (1) (1) (1)

    [5]

    University of Cambridge International Examinations 2011

    Page 6 (b) T + U

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22

    or

    correct structures correctly displayed ester group

    (1) (1)

    [2]

    [Total: 7] 5 (a) (i) 1 2 (ii) test 1 reagent observation test 2 reagent observation Tollens reagent Ag mirror/silver/ black ppt Fehlings reagent brick-red ppt red ppt 2,4-dinitrophenylhydrazine orange/red/yellow ppt/solid (4) [7] Na gas/H2/effervescence/ fizzing PCl3/PCl5/PBr3 HCl/HBr steamy fumes RCO2H/H+ fruity smell primary alcohol not hydroxyl aldehyde not carbonyl (1) (1) (1)

    only award the observation mark if reagent is correct

    University of Cambridge International Examinations 2011

    Page 7 (b) (i)

    Mark Scheme: Teachers version GCE AS/A LEVEL October/November 2011

    Syllabus 9701

    Paper 22

    (1) (ii)

    (1) 5 route (c) starting compound first reagent PCl3 PCl5 SOCl2 etc. intermediate X second reagent K2Cr2O7/H+ KMnO4/H+ KMnO4/OH Tollens' or Fehling's reagents K2Cr2O7/H+ KMnO4/H+ KMnO4/OH Tollens' or Fehling's reagents intermediate Y third reagent

    [2]

    final compound

    A/1

    HOCH2CHO

    ClCH2CHO

    ClCH2CO2H

    NH3

    H2NCH2CO2H

    A/2

    HOCH2CHO

    HBr P/Br2 etc.

    BrCH2CHO

    BrCH2CO2H

    NH3

    H2NCH2CO2H

    B/1

    HOCH2CHO

    PCl3 PCl5 SOCl2 etc.

    ClCH2CHO

    NH3

    B/2

    HOCH2CHO

    HBr P/Br2 etc.

    BrCH2CHO

    NH3

    K2Cr2O7/H+ KMnO4/H+ KMnO4/OH H2NCH2CHO H2NCH2CO2H Tollens' or Fehling's reagents K2Cr2O7/H+ KMnO4/H+ KMnO4/OH H2NCH2CHO H2NCH2CO2H Tollens' or Fehling's reagents

    Tollens' or HOCH2CO2H HOCH2CHO Fehling's reagents (1) (1)

    KBr/conc. H2SO4

    BrCH2CO2H

    NH3

    H2NCH2CO2H

    mark

    (1)

    (1)

    (1) [5] [Total: 14]

    University of Cambridge International Examinations 2011

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